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Ionic liquid-assisted preparation of hydroxyapatite and its catalytic performance for decarboxylation of itaconic acid

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Chinese Journal of Chemical Engineering 2024年第3期67卷 9-15页

作者： Shutong Pang Hualiang An Xinqiang zhao Yanji Wang Hebei Provincial Key Laboratory of Green Chemical Technology and Efficient Energy Saving Tianjin Key Laboratory of Chemical Process SafetySchool of Chemical Engineering and TechnologyHebei University of TechnologyTianjin 300130China

The synthesis of methacrylic acid from biomass-derived itaconic acid is a green route,for it can get rid of the dependence on fossil *** order to solve the problems on this route such as use of a preciousmetal catalyst and a corrosive homogeneous alkali,we prepared a series of hydroxyapatite catalysts by an ionic liquid-assisted hydrothermal method and evaluated their catalytic *** results showed that the ionic liquid[Bmim]BF_(4) can affect the crystal growth of hydroxyapatite,provide fluoride ion for fluorination of hydroxyapatite,and adjust the surface acidity and basicity,morphology,textural properties,crystallinity,and composition of ***[Bmim]BF4 dosage and hydrothermal temperature can affect the fluoride ion concentration in the hydrothermal system,thus changing the degree of fluoridation of *** fluoride-ion concentration can lead to the formation of CaF_(2) and thus significantly decrease the catalytic performance of *** hydrothermal time mainly affects the growth of hydroxyapatite crystals on the c axis,leading to different catalytic *** suitable conditions for the preparation of this fluoridized hydroxyapatite are as follows:a mass ratio of[Bmim]BF4 to calcium salt=0.2:1,a hydrothermal time of 12 h,and a hydrothermal temperature of 130℃.A maximal methacrylic acid yield of 54.7%was obtained using the fluoridized hydroxyapatite under relatively mild reaction conditions(250℃ and 2 MPa of N_(2))in the absence of a precious-metal catalyst and a corrosive homogeneous alkali.

关键词： Ionic liquid Hydroxyapatite Itaconic acid Methacrylic Decarboxylation reaction

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Integrated separation-electrochemical detection device based on wood column for online identification of enantiomer

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Nano Research 2024年第3期17卷 1893-1901页

作者： Junli Guo Yuanfei Xue Chenxi zhao Junjian zhao Zhida Gao Ye Mei Yan-Yan Song College of Sciences Northeastern UniversityShenyang 110004China State Key Laboratory of Precision Spectroscopy School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200062China NYU-ECNU Center for Computational Chemistry at NYU Shanghai Shanghai 200062China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China

Chiral chemicals have attracted significant interest in the pharmaceutical industry,yet the separation methods to get pure enantiomers from racemic mixture are still *** date,the separation of enantiomers still mainly depends on chromatography using high-cost chiral stationary ***,wood channels were used as the handheld integrated device,and enantiomer separation was simultaneously detected using an electrochemical *** this method,a chiral UIO-66(L-UIO-66)modified enantiomer separation zone and carbonized wood based online detection zone are integrated along a single wood *** on the in situ separation results from the chronoamperometry data,the wood device shows excellent separation ability for a wide range of electrochemically active enantiomers,including 3,4-dihydroxyphenylalanine,amino acids,ascorbic acid,carnitine,and penicillamine with high chirality *** unbiased molecular dynamic simulations indicate that the excellent chiral recognition and separation are attributed to the different barriers from the bound states to the dissociated state of the enantiomers in the homochiral microenvironment of the *** integrated enantiomer separation-electrochemical detection device provides a novel,easy,and low-cost platform for the separation of pure enantiomer from racemic mixture.

关键词： wood column integrated separation-detection device enantioselectivity online sensing free energy barrier

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Enhanced photocatalytic nitrogen fixation performance via in situ constructing BiO_(2-x)/NaNbO_(3) heterojunction

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Chinese Journal of Chemical Engineering 2024年第5期69卷 92-100页

作者： Jiayu Zhang Zhihao Zeng Lin Yue Chunran zhao Xin Hu Leihong zhao Xiuwen Wang Yiming He Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials ScienceZhejiang Normal UniversityJinhua 321004China Heilongjiang Provincial Key Laboratory of Surface Active Agent and Auxiliary School of Chemistry and Chemistry EngineeringQiqihar UniversityQiqihar 161006China Department of Materials Science and Engineering Zhejiang Normal UniversityJinhua 321004China

The fabrication of heterojunction catalysts is an effective strategy to enhance charge separation efficiency,thereby boosting the performance of *** this study,BiO_(2-x)nanosheets were synthesized through a hydrothermal process and loaded onto NaNbO_(3) microcube to construct a series of BiO_(2-x)/NaNbO_(3) heterojunctions for photocatalytic N_(2) *** indicated that 2.5%BiO_(2-x)/NaNbO_(3) had the highest photocatalytic *** NH_(3) production rate under simulated solar light reached 406.4μmol·L^(-1)·g^(-1)·h^(-1),which reaches 2.6 and 3.8 times that of NaNbO_(3) and BiO_(2-x),***_(2-x)nanosheets primarily act as electron trappers to enhance the separation efficiency of charge *** strong interaction between BiO_(2-x)and NaNbO_(3) facilitates the electron migration between ***,the abundant oxygen vacancies in BiO_(2-x)nanosheets may facilitate the adsorption and activation of N_(2),which may be another possible reason of the high photocatalytic activity of the BiO_(2-x)/NaNbO_(3).This study may offer new insights for the development of semiconductor materials in photocatalytic nitrogen fixation.

关键词： Catalyst Solar energy Hydrothermal BiO_(2-x)/NaNbO_(3) Photocatalytic N_(2)-fixation

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Call for knowledge systematization:An example from lithium ion batteries recycling

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Journal of Energy Chemistry 2024年第7期94卷 169-170页

作者： Yun zhao Baohua Li Institute of Materials Research Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055GuangdongChina

Scientific research is one of the primary ways to drive human civilization *** research institutions and researchers worldwide are dedicated to exploring the unknown,resulting in a flood of research findings[1].For instance,Web of Science alone collects over 10,000 academic papers on a daily *** each research field typically has around 10%of review articles,these mainly focus on a limited portion of the subject,failing to provide a comprehensive and real-time updated *** a result,researchers or students in a particular field may spend several months,or even longer,comprehending the state of research that has developed over just a few *** lack of systematic background often leads to redundant or similar studies,which is highly detrimental to the progress of science and technology.

关键词： lithium typically spend

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Next‑Generation Green Hydrogen: Progress and Perspective from Electricity, Catalyst to Electrolyte in Electrocatalytic Water Splitting

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Nano-Micro Letters 2024年第11期16卷 274-322页

作者： Xueqing Gao Yutong Chen Yujun Wang Luyao zhao Xingyuan zhao Juan Du Haixia Wu Aibing Chen College of Chemical and Pharmaceutical Engineering Hebei University of Science and TechnologyShijiazhuang 050018People’s Republic of China

Green hydrogen from electrolysis of water has attracted widespread attention as a renewable power *** several hydrogen production methods,it has become the most promising ***,there is no large-scale renewable hydrogen production system currently that can compete with conventional fossil fuel hydrogen *** energy electrocatalytic water splitting is an ideal production technology with environmental cleanliness protection and good hydrogen purity,which meet the requirements of future *** review summarizes and introduces the current status of hydrogen production by water splitting from three aspects:electricity,catalyst and *** particular,the present situation and the latest progress of the key sources of power,catalytic materials and electrolyzers for electrocatalytic water splitting are ***,the problems of hydrogen generation from electrolytic water splitting and directions of next-generation green hydrogen in the future are discussed and *** is expected that this review will have an important impact on the field of hydrogen production from water.

关键词： Hydrogen Electrolysis Hydrogen production Renewable energy Catalyst

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Illuminating functions of evolutionarily conserved long non-coding RNAs

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Science China(Life Sciences) 2024年第9期67卷 2043-2044页

作者： Ruiqiao He Fangqing zhao Institute of Zoology Chinese Academy of SciencesBeijing 100101China Key Laboratory of Systems Health Science of Zhejiang Province Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China

Long non-coding RNAs(lnc RNAs)serve as crucial regulators of gene expression,influencing various physiological processes and disease states(Cabili et al.,2011;Ulitsky and Bartel,2013;Yao et al.,2019).Dysregulation of certain notable lnc RNAs,such as HOTAIR and MALAT1,has been implicated in a wide range of pathological processes,including tumorigenesis in various human cancers(Gupta et al.,2010;Kim et al.,2018).However,the functions of the majority of lnc RNAs remain elusive.

关键词： MALAT1 HOTAIR

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Rotational Doppler effect of composite vortex beams with tailored OAM spectra

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Photonics Research 2024年第8期12卷 1665-1672页

作者： YUTIAN LIANG RUIJIAN LI JIE zhao XINGYUAN LU TONG LIU ZHENGLIANG LIU YUAN REN CHENGLIANG zhao Department of Aerospace Science and Technology Space Engineering UniversityBeijing 101416China School of Physical Science and Technology Soochow UniversitySuzhou 215006China Department of Basic Course Space Engineering UniversityBeijing 101416China

There recently has been increasing interest in the research and application of the rotational Doppler effect(RDE),which paves a promising way to detect rotating objects *** order to obtain more information about the rotating object from the rotational Doppler signal,composite vortex beams by coaxial superposition of orbital angular momentum(OAM)modes are often used as the probe ***,to the best of our knowledge,the RDE of composite vortex beams with arbitrary OAM spectra has not yet been comprehensively *** this paper,the correspondence between the OAM spectrum of a probe beam and the frequency spectrum of a rotational Doppler signal is theoretically *** is explicitly revealed that the RDE frequency spectrum of scattered light is related to the product of two autocorrelation functions:one from the OAM spectrum of probe beam and the other from the spiral spectrum of rotating *** the basis of this relation,one can regulate the RDE frequency spectrum on demand via tailoring the OAM spectrum of the probe *** a proof of concept we design a special composite vortex beam to eliminate the broadening of the RDE spectrum induced by *** findings are of practical value in applications such as remote sensing and optical metrology.

关键词： OAM composite rotating

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Well-dispersed Sb particles embedded on N-doped carbon nanofibers toward high-performance Li-ion battery

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Rare Metals 2024年第7期43卷 2994-3006页

作者： Ying Li Yi-Han zhao Lu-Lu zhao Peng-Fei Wang Ying Xie Ting-Feng Yi School of Materials Science and Engineering Northeastern UniversityShenyang 110819China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province School of Resources and MaterialsNortheastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Functional Inorganic Material Chemistry Ministry of EducationSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China

The alloy-type material Sb is widely used in the anode materials of lithium-ion batteries(LIBs)due to its high theoretical specific ***,its serious volume expansion problem during alloying/dealloying of Li~+limits its practical *** this work,C-Sb composite was constructed as anode material of LIBs by electrospinning route for the first time,Sb was introduced into the polyacrylonitrile-based hard carbon and coal tar pitch-based soft carbon composite amorphous carbon fiber with a diameter of 300-600 nm,which realized high cycling *** C-Sb-2(the mass ratio of polyacrylonitrile to Sb source is 1:2)electrode displayed charge capacities of 1098.5,930.3,841.7,753.5,643.9 and 545.8 mAh·g^(-1)at 0.1,0.2,0.3,0.5,1 and 2 A·g^(-1),*** when the current density returned to 0.1 A·g^(-1),the charge capacity was 939.3 mAh·g^(-1),revealing good stability and *** introduction of Sb into the amorphous carbon improved its conductivity and addressed the volume expansion issue of high specific capacity Sb during charge/***-situ XRD analysis confirmed the high reversibility of the C-Sb-2 during charging and *** functional theory(DFT)calculations revealed the gradual enhancement of the interface interaction between Sb_(x)Li_(y) and amorphous carbon(AMC)with increasing lithium content,contributing to the anchoring of alloy nanoparticles on the AMC surface and buffering the volume change of the ***,the gradual lithiation of Sb facilitated the electron transfer from Sb_(x)Li_(y) to *** findings hold promise for designing lithium storage materials with exceptional performance,highlighting the potential of C-Sb composites as anode materials for efficient next-generation lithium storage.

关键词： Li-ion battery Metallic Sb Carbon Electrospinning Cycling stability

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Advances in regional nodal management of early-stage breast cancer

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Chinese Journal of Cancer Research 2024年第2期36卷 215-225页

作者： zhao Bi Yongsheng Wang Breast Cancer Center Shandong Cancer Hospital and InstituteShandong First Medical University and Shandong Academy of Medical SciencesJinan 250017China

With the continuous improvement of systemic treatment, reasonable local regional control of early-stage breast cancer can be translated into survival benefits. The optimization of regional nodal management in patients with limited sentinel lymph node(SLN) metastasis needs to be weighed by surgical complications, regional recurrence risk, and lymph node status, as well as other escalating treatment(systemic/radiotherapy) that may result from deescalating surgery. With the effective support and supplementation of systemic therapy and radiotherapy, the management of axillary surgery is developing in a de-escalating trend. The widespread application of neoadjuvant therapy has contributed to optimizing the management of patients with clinically node-negative/imaging nodepositive disease. In clinical practice, it is necessary to consider the residual tumor burden of regional lymph nodes when formulating the optimal irradiation fields in patients with limited positive SLN without axillary lymph node dissection. The combined application of genomic tests and American College of Surgeons Oncology Group Z0011/AMAROS criteria could provide patients with a better strategy of dual de-escalation treatment, which includes the de-escalation of both axillary surgery and systemic treatment. In the era of sentinel lymph node biopsy(SLNB), the regional nodal management of breast cancer should adhere to the concept of “updating ideas, making bold assumptions, and carefully seeking proof”, make full use of the benefits of systemic therapy and radiotherapy to reduce the scope of surgery and complications, and expand the “net benefit” of efficacy and quality of life. This review discusses the optimization of regional nodal management in the era of SLNB, in order to provide reference information for clinicians.

关键词： Breast cancer sentinel lymph node biopsy internal mammary lymph node radiotherapy surgery

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Deep kernel extreme learning machine classifier based on the improved sparrow search algorithm

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The Journal of China Universities of Posts and Telecommunications 2024年第3期31卷 15-29页

作者： zhao Guangyuan Lei Yu School of Automation Xi'an University of Posts and TelecommunicationsXi'an 710000China

In the classification problem,deep kernel extreme learning machine(DKELM)has the characteristics of efficient processing and superior performance,but its parameters optimization is *** improve the classification accuracy of DKELM,a DKELM algorithm optimized by the improved sparrow search algorithm(ISSA),named as ISSA-DKELM,is proposed in this *** at the parameter selection problem of DKELM,the DKELM classifier is constructed by using the optimal parameters obtained by ISSA *** order to make up for the shortcomings of the basic sparrow search algorithm(SSA),the chaotic transformation is first applied to initialize the sparrow ***,the position of the discoverer sparrow population is dynamically adjusted.A learning operator in the teaching-learning-based algorithm is fused to improve the position update operation of the ***,the Gaussian mutation strategy is added in the later iteration of the algorithm to make the sparrow jump out of local *** experimental results show that the proposed DKELM classifier is feasible and effective,and compared with other classification algorithms,the proposed DKELM algorithm aciheves better test accuracy.

关键词： deep kernel extreme learning machine(DKELM) improved sparrow search algorithm(ISSA) classifier parameters optimization

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