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Trace-element geochemistry and S–O isotopes in the fluorite-barite mineralization of Merguechoum,Moroccan eastern Meseta:insights into ore genesis to the Pangea rifting

引用

Acta Geochimica 2023年第3期42卷 435-452页

作者： mohammed cherai Larbi Rddad Fouad Talbi Benjamin F.Walter Faculte´des Sciences Laboratoire de GeosciencesGeo-Environnement et Prospection Miniere et HydriqueBP 71760000 OujdaMaroc Earth and Planetary Science Division Physical Science DepartmentKingsborough Community College of the City University of New York(CUNY)2001 Oriental BoulevardBrooklynNY 11235–2398USA Chair of Economic Geology and Geochemistry Karlsruhe Institute of Technology(KIT)Adenauerring 20B76131 KarlsruheGermany Laboratory for Environmental and Raw Material Analyses(LERA) Adenauerring 20B76131 KarlsruheGermany

The Merguechoum fluorite-barite mineralization,located in the Eastern Meseta of Morocco,is hosted in the Late Hercynian *** ore consists of fine crystals of fluorite 1,massive barite 1,euhedral crystals of fluorite 2,and barite 2 with calcite and minor quartz and *** Merguechoum ore deposits have never been *** study was the first contribution that studied the genesis of fluorite and *** ore occurs as dissemination within granite intrusion and also fills the NE-SWtrending meter-sized fractures and *** values of the total Rare Earth Elements and Yttrium(REY)and the ratios of LREY/HREY,Y/Ho,Tb/Ca,and Tb/La indicate that the Merguechoum fluorite precipitated from hydrothermal fluids,likely basinal brines,which interacted with the Hercynian *** REY data indicate that the ore-forming fluids of the early stage have intensely interacted with the Hercynian granite compared to those of the late ore *** gradual decrease in the europium(Eu/Eu^(*)),yttrium(Y/Y^(*)),and cerium(Ce/Ce^(*))anomalies and a low concentration ofΣREY observed in the second ore stage compared to the first ore stage suggest an increase in p H and fO_(2)and by inference a decrease in temperature during the evolution of the hydrothermal *** evolution could be explained by fluid mixing between the ascending basinal hydrothermal fluids and the diluted sulfate-rich meteoric water barite separates from selected samples reveal that the dissolved sulfates(SO_(4)^(2-))were derived from Permian–Triassic sulfates and/or coeval poreseawater *** proposed fluid mixing triggered the precipitation of an early-stage F-Ba assemblage followed by the second-stage F-Ba *** fieldwork,REY inventories,and isotope data point to the ore genesis during the Permian–Triassic extensional tectonic activity concerning the Pangea *** extensional tectonic environment is likely the driving force that mobilized a large amount of the ore

关键词： Fluorite-barite veins Geochemistry of REY and trace elements O–S isotopes Late hercynian granite Pangea rifting Merguechoum Eastern Meseta of Moroccan

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