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Nuclear Science and Techniques 2023年第5期34卷 47-55页

作者： Fatemeh Mansourzadeh mohammad Mahdi Shadman Javad karimi Sabet Valiyollah Ghazanfari Nuclear Fuel Cycle Research School Nuclear Science and Technology Research InstituteTehranIran

The thermal diffusion column represents one method of separating stable *** method is advantageous for smallscale operations because of the simplicity of the apparatus and small inventory,especially in gas-phase ***,it has attracted attention for its applicability in tritium and noble gas separation *** this study,the R cascade was used to design and determine the number of columns.A square cascade was adopted for the final design because of its flexibility,and calculations were performed to separate 20Ne and 22Ne *** the R cascades that enriched the Ne isotopes by more than 99%were investigated,the number of columns was determined,and the square cascade parameters were optimized using the specified ***,a calculation code“RSQ_CASCADE”was developed.A unit separation factor of three was considered,and the number of studied stages ranged from 10 to *** results showed that the column separation power,relative total flow rate,and required number of columns were linearly related to the number of *** separation power and relative total flow decreased and the number of columns increased as the stage number ***,a cascade of 85 columns is recommended to separate the stable Ne *** calculations yielded a 17-stage square cascade with five columns in each *** changing the stage cut,feed point,and cascade feed flow rate,the best parameters for the square cascade were determined according to the cascade and column separation *** the column separation power had a maximum value in cascade feed 50,it was selected for separating Ne isotopes.

关键词： Stable isotope Thermal diffusion Cascade Separation Neon

Electrocatalytic oxidation of hydrazine with alizarin red S as a homogenous mediator on the glassy carbon electrode

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Science China Chemistry 2010年第5期53卷 1194-1200页

作者： mohammad Mazloum-Ardakani Roya Mazidi mohammad Hossein Mashhadizadeh Parvanah Rahimi mohammad Ali karimi Department of Chemistry Faculty of ScienceYazd University Department of Chemistry Payam Noor UniversityArdakan Center Department of Chemistry Faculty of ScienceTarbiat Moalem University Department of Chemistry Faculty of SciencePayam Noor UniversitySirjan Center

Electro-catalytic oxidation and detection of hydrazine on a glassy carbon electrode,at pH 6.0,was studied by using alizarin red S as a homogeneous *** overall number of electrons involved in the catalytic oxidation of hydrazine and that involved in the rate-determining step were four and one,*** interfering effect of some cations,anions and organic compounds were *** current for this process varied linearly with the square root of the scan *** kinetic parameters,such as the electron transfer coefficient(α) and catalytic rate constant(k) ,were determined using cyclic voltammetry,linear sweep voltammetry and *** electro-catalytic response was optimized with regards to the pH,scan rate,hydrazine concentration and other variables.

关键词： alizarin red S hydrazine glassy carbon electrode electro-catalytic oxidation voltammetry

Stripping voltammetric determination of Cd(Ⅱ)based on multiwalled carbon nanotube functionalized with 1-(2-pyridylazo)-2-naphthol

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Chinese Chemical Letters 2011年第12期22卷 1469-1472页

作者： Alireza Mohadesi Hadi Beitollahi mohammad Ali karimi Department of Chemistry Payame Noor UniversityTehran 19395-4697Iran Department of Chemistry Payame Noor University(PNU)P.O.Box 76175-559KermanIran Environmental Department Research Institute of Environmental SciencesInternational Center for SciencesHigh Technology and Environmental SciencesKermanIran Department of Chemistry & Nanoscience and Nanotechnology Research Laboratory(NNRL) Payame Noor University(PNU)SirjanIran

The present work has focused on the modification of multiwalled carbon nanotube with a ligand,l-（2-pyridylazo）-2-naphthol, and its potential application for the development of a new,simple and selective modified glassy carbon electrode for stripping voltammetric determination of Cd（Ⅱ）.The analytical curve for Cd（Ⅱ） ions covered the linear range varying from 0.8 up to 220.4μgL^（-1）.The limit of detection was found to be 0.1μgL^（-1）,while the relative standard deviation（RSD） at 50.0μgL^（-1） was 1.8%（n=5）.This modified electrode was successfully applied for determination of Cd（Ⅱ） in some water samples.

关键词： Multiwalled carbon nanotube 1-(2-Pyridylazo)-2-naphthol Cadmium(Ⅱ) Stripping voltammetry

The role of the fiber ply configurations on the biomechanics of the hip prosthesis

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International Journal of Modeling, Simulation, and Scientific Computing 2022年第3期13卷 149-160页

作者： Kamran Hassani mohammad Nikkhoo Alireza karimi Department of Biomedical Engineering Science and Research Branch Islamic Azad University TehranIran Department of Ophthalmology and Visual Sciences University of Alabama at Birmingham Birmingham ALUSA

The total hip replacement is the only approved procedure for restoring a degenerated hip joint through *** life span of a prosthesis could depend on the geometry and material properties of the *** study aims to analyze the biomechanics of the carbon/polyetheretherketone(PEEK)composite prosthesis having three different fiber ply configurations compared to traditional stainless steel(SS)*** implant-bone system was established and subjected to a load from the head of the femur and abductor muscle *** stresses and strains in the implant-bone systems were calculated and *** results revealed lower stresses and strains in composite prostheses compared to SS *** fiber ply orientation of the carbon/PEEK composite prosthesis is shown to be a key asset in stress and strain distribution of the 13 implant-bone *** fiber plies which orientated multidirectionally with−45 and+45 degrees exhibited uniform stress and strain *** results suggested the advantage of using composite prostheses in implant designs as they not only invoke lower stresses and strains in the implant-bone system but also amplify the life span of implants in the body.

关键词： Prosthesis hip joint composite stress strain finite element

Complexation of Sm^(3+) and pamidronate: A DFT study

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Journal of Rare Earths 2015年第3期33卷 310-319页

作者： Masoud Arabieh mohammad Hassan Khodabandeh mohammad Hossein karimi-Jafari Carlos Platas-Iglesias Karim Zare Computational Chemistry Laboratory NSTRI 11365-8486 Tehran Iran Department of Chemistry Faculty of Science Shahid Beheshti University G.C. Evin 19839-63113 Tehran Iran Department of Bioinformatics Institute of Biochemistry and Biophysics University of Tehran 13145-1384 Tehran Iran Departamento de Química Fundamental Universidade da Coru?a Campus da Zapateira-Rúa da Fraga 10 15008 A Coru?a Spain

We reported a quantum mechanical study of the complexes formed between Sm3＋ and the bisphosphonate ligand pamidronate in aqueous solution. According to available experimental p K a values pamidronate was expected to exist in aqueous solution, at physiologically relevant p H, in its di- and tri-protonated forms（denoted by H3 L and H2L）. The most stable structures of the ligands and Sm3＋ complexes were found by using a detailed analysis of the conformational space with semiempirical and DFT methods. The results showed that both H2 L and H3 L bisphosphonates acted as a tridentate ligands in their complexes with Sm3＋. The addition of explicit water molecules to the coordination sphere of the metal not only gave different coordination numbers for H2 L and H3 L complexes（CN=9 and 10）, but also provided different trends in stabilization energies. The results highlighted the importance of considering not only an explicit first coordination shell, but also a second hydration shell, for an adequate description of this type of complexes in aqueous solution.

关键词： samarium radiopharmaceutical bisphosphonates solvent effects rare earths

Multidisciplinary design optimization of a dual-spin guided vehicle

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Tris(hydrogensulfato) boron as a solid heterogeneous catalyst for the rapid synthesis of α,α'-benzylidene bis(4-hydroxycoumarin) derivatives

Defence technology 2024年第7期 133页

作者： Jalal karimi mohammad Reza Rajabi Seyed Hossein Sadati Seyed Mahid Hosseini

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Chinese Chemical Letters 2012年第7期23卷 781-784页

作者： Zahed karimi-Jaberi mohammad Reza Nazarifar Baharak Pooladian Department of Chemistry Firoozabad BranchIslamic Azad UniversityP.O.Box 74715-117 FiroozabadFarsIran

α, α＇-Benzylidene bis（4-hydroxycoumarin） derivatives were readily prepared in a few minutes with good yields through the reaction of an aromatic aldehyde and 4-hydroxycoumarin in aqueous media in the presence of ... 详细信息

关键词： Biscoumarin 4-Hydroxycoumarin Tris(hydrogensulfato)boron Heterogeneous catalyst

Shoreline spatial and temporal response to natural and human effects in Boujagh National Park, Iran

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International Journal of Sediment Research 2021年第5期36卷 582-592页

作者： Morteza karimi Jamal mohammad Vali Samani Mehdi Mazaheri Department of Water Structures Tarbiat Modares University Academic Center for Education Culture and Research (ACECR) Environmental Research Institute

Shoreline variation and river deltas are among the most dynamic systems in marine environments. The related different variations in spatial and temporal scales play significant roles in land planning and different management applications. Modeling the dynamics of seashore of Boujagh National Park(BNP)which is located on the southern coast of the Caspian Sea in the Sefidrud Delta(SD), considering natural and anthropogenic factors, was the main objective of the current study. To achieve this goal, a combination of remote sensing data, historical data, and numerical simulations was utilized. The BNP covers an area of 3,270 ha and includes two international wetlands, Boujagh and Kiashahr. In earlier periods, this area faced severe morphological changes whereas recently its shoreline has experienced gradual variations. Accordingly, at the first stage, the shoreline variation from 2006 to 2017 was extracted by processing and classifying Operational Land Imager(OLI) and Thematic Mapper(TM) images from Landsat satellites using the Maximum Likelihood approach. In the second stage, the two dimensional MIKE21 model was utilized to identify wave and coastal current patterns and parameters for the year ***, the results showed that, the shoreline of the BNP is affected by several natural and anthropogenic factors. Seaward advancement of the shoreline occurred in zones A(east zone) and C(west zone) due to Caspian Sea Level drop and sedimentation while retreating occurred at Zone B(north zone) influenced by wave and current patterns and reduction of the Sefidrud River flows. Also, the results imply that maintaining the existing conditions results in the disappearance of a considerable part of the ecological area in the BNP. Hence, to manage and preserve the coastline of the BNP complying with the current anthropogenic and natural factors, it is vital to take necessary management measures.

关键词： Shoreline dynamics Boujagh National Park Remote sensing MIKE21 Wave and current

Cobalt(Ⅱ) chloride accelerated one-pot three-component synthesis of α-aminophosphonates at room temperature

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Chinese Chemical Letters 2011年第5期22卷 559-562页

作者： Zahed karimi-Jaberi Hassan Zare mohammad Amiri Naghmeh Sadeghi Department of Chemistry Islamic Azad UniversityFiroozabad BranchP.O.Box 74715-117FiroozabadFarsIran

A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presence of CoCl_2-6H_2O under solvent-free ***α-aminophosphonates were synthesized relatively quickly in good yields at room temperature.

关键词： α-Aminophosphonates Cobalt(Ⅱ) chloride Trimethyl phosphite Room temperature Solvent-free

Fischer-Tropsch synthesis over ruthenium-promoted Co/Al_2O_3 catalyst with different reduction procedures

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Journal of Natural Gas Chemistry 2010年第5期19卷 503-508页

作者： Ali karimi Ali Nakhaei Pour Farshad Torabi Behnam Hatami Ahmad Tavasoli mohammad Reza Alaei mohammad Irani Research Institute of Petroleum Industry (RIPI) Gas Research Division

The effect of reduction procedure on catalyst properties, activity and products selectivity of ruthenium-promoted Co/γ-Al2O3 catalyst in Fischer-Tropsch synthesis （FTS） was investigated. Catalyst samples were reduced with different reduction gas compositions and passivated before being characterized by TPR and XRD techniques. Different activity and product selectivity analyses were also performed. These results showed that the catalyst dispersion, particle size, and the degree of reduction changed with different reduction gas compositions, which were resulted from the water partial pressures in reduction process that give varying degrees of interaction with the support. It has been suggested that the FTS activity of cobalt catalyst was directly dependent on the catalyst reducibility. A reduction gas with a molar ratio of H2Prle = 1 was used to prevent the formation of Co-support compound during catalyst reduction.

关键词： Fischer-Tropsch synthesis cobalt reducibility activity C5+ selectivity