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Experimental evaluation of eco-friendly flocculants prepared from date palm rachis

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Journal of Environmental Sciences 2010年第10期22卷 1539-1543页

作者： Ramzi Khiari Sonia Dridi-Dhaouadi Chadlia Aguir mohamed farouk Mhenni Research Unity of Applied Chemistry & Environment Department of Chemistry

Sodium carboxymethylcellulose （CMCNa） is an anionic water soluble polyelectrolyte widely used in many industrial sectors including food, textiles, papers, adhesives, paints, pharmaceuticals, cosmetics and mineral processing. CMCNa was produced by chemical modification of cellulose, and represents many advantages： natural, renewable, non-toxic and biodegradable. In this study, different kinds of CMCNa, prepared from an agricultural waste date palm rachis, were tested as eco-friendly flocculants for drinking water treatment and their performances as flocculants in turbidity removal enhancement were assessed. The prepared materials were characterized by the degree of substitution （DS） and polymerisation （DP）. The study of the effect of some experimental parameters on the coagulation-flocculation performance, using the prepared materials combined with aluminium sulphate （as coagulant）, showed that the best conditions for turbidity treatment were given for pH 8, coagulant dose 20 mg/L, flocculant concentration of 100 mg/L and stirring velocity （during the flocculation step） of 30 r/min. Under the optimum conditions, the turbidity removal using CMCNa, prepared from raw material, was about 95%. A comparison study between the flocculation performance of a commercial anionic flocculant （A100PWG： polyacrylamide） and that of the prepared CMCNa showed that the performance of the waste-based flocculant with a DS of 1.17 and a DP of 480 was 10% better than that achieved by the commercial one.

关键词： carboxymethylcellulose flocculants date palm rachis flocculation process

A Challenging Approach to Improve the Low Affinity of Acrylic Fibres to Be Successfully Dyed with a Bio-Colorant Extracted from Grape Marc

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Journal of Renewable Materials 2019年第3期7卷 289-300页

作者： Noureddine Baaka Manel Ben Ticha Wafa Haddar mohamed farouk Mhenni University of Monastir Faculty of Sciences of MonastirResearch Unity of Applied Chemistry and Environment5000 MonastirTunisia National Engineering School of Monastir 5019 MonastirTunisia Higher Institute of Technological Studies 5070Ksar HellalMonastirTunisia

Acrylic fibres are highly crystalline and non-polar polymers,which makes their dyeing a very difficult step that poses real technical *** order to overcome this concern,it is intended in this paper to modify acrylic fibers by different methods namely cationisation using the Crosscolor DRT then amidoximation using hydroxylamine hydrochloride and ammonium *** resulted samples were dyed then with the bio-colorant extracted from grape *** effect of the pretreatment on fibers fine structure using X-ray diffraction and the scanning electron microscope(SEM)images and its correlation with the colour strength of the dyed fabrics was *** dyeing parameters,such as dye bath pH and temperature on the performances of this dyeing process were *** dyeing qualities and new shades varying from brown to grey and dark green have been obtained following process optimization,mordanting and modification of acrylic fibers by the technique of cationisation.

关键词： Modified acrylic fibers grape marc bio-colorant mordant.

Structural Characterization and Antioxidant Activity of Lignin Extracted from Ficus Carica L.

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Journal of Renewable Materials 2019年第4期7卷 345-354页

作者： Ibtissem Moussa Ramzi Khiari Ali Moussa Gérard Mortha mohamed farouk Mhenni University of Monastir Faculty of SciencesUR13 ES 63-Research Unity of Applied Chemistry&EnvironmentAvenue of the environment5019 MonastirTunisia University of Monastir National Engineering School of MonastirStreet of Ibn El Jazzar5000 MonastirTunisia Higher Institute of Technological Studies of Ksar-Hellal Department of Textile-TunisiaAvenue of Hadj Ali Soua.5070 Ksar-HellalTunisia University of Grenoble Alpes CNRSGrenoble INPLGP2F-38000 GrenobleFrance

The most abundant phenolic biopolymer in the biosphere is the *** phenolic biopolymer commonly exists in combination with polysaccharides and other cell wall *** this study,the solvent system dioxane-water is used to extract lignin,which is considered as unaltered native *** dioxane lignin extracted from fig stems was characterized regarding to its structural feature,quantification of its functional groups,molecular weight,and evaluation of its thermal *** and molecular weight distribution of the studied lignin indicated that isolated lignin contained a low amount of sugar(c.a.19%)and had a high weight-average molecular weight(10068 ***-1).Lignin sample had approximately the same amounts of guaiacyl(G)and p-hydroxyphenyl(H)units with relatively fewer syringyl(S)*** isolated lignin revealed good antioxidant ***,it proved to have a high potential of application in new antioxidants formulations.

关键词： Ficus Carica L. lignin organosolv molecular weight NMR spectroscopy antioxidant activity

Application of Prunus amygdalus By-products in Eco-friendly Dyeing of Textile Fabrics

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Journal of Renewable Materials 2018年第1期6卷 55-67页

作者： Ibtissem Moussa Noureddine Baaka Ramzi Khiari Ali Moussa Gérard Mortha mohamed farouk Mhenni University of Monastir Faculty of SciencesUR13ES63-Research Unity of Applied Chemistry&Environment5000 MonastirTunisia Higher Institute of Technological Studies of Ksar Hellal Department of TextilesRue Hadj Ali Soua-B.P.n°68-5070 Ksar HellalTunisia Institute of Engineering University of Grenoble AlpesCNRSGrenoble INPLGP2F-38000 GrenobleFrance National Engineering School of Monastir 5019 MonastirTunisia

Natural dyes have become an interesting subject of study because of their better ecological properties in comparison to their synthetic *** article concerns the dyeing of wool,silk,and polyamide fabrics with natural dyes extracted from almond shells and *** developed method of dyeing by these extracts is interesting and very attractive for several reasons:firstly,the extracts used are the black liquor discharged from the industries of delignification,which is a chemical process for removing lignin from agricultural wastes to produce a cellulosic fiber;(ii)these natural dyes are renewable and available in large quantities;(iii)this method is economical;and(iv)lastly,the dyeing performances of the obtained dyed textiles are very *** color of each dyed material was investigated in terms of the CIELAB coordinates and their fastness properties measured by washing,rubbing,and light.

关键词： Almond shell almond stem fastness properties natural dyes residual lignin

Clinical outcomes of transepithelial photorefractive keratectomy versus femtosecond laser assisted keratomileusis for correction of high myopia in South Egyptian population

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International Journal of Ophthalmology(English edition) 2020年第1期13卷 129-134页

作者： Amr Mounir Engy mohamed Mostafa Hatem Ammar Osama Ali Mohammed Alahmady Hamad Alsmman Mahmoud mohamed farouk mohamed Gamal Elghobaier Department of Ophthalmology Sohag Faculty of MedicineSohag UniversitySohag 82524Egypt Egyptian Police Hospitals Cairo 11765Egypt

AIM: To evaluate the safety and efficacy of transepithelial photorefractive keratectomy(t-PRK) with adjuvant mitomycin C(MMC) versus femtosecond laser assisted keratomileusis(Femto-LASIK) in correction of high ***: Prospective randomized comparative study including 156 eyes of 156 patients with high myopia and a spherical equivalent refraction(SER) <-6.00 D. They were divided randomly into two groups: Group A included 72 eyes treated with t-PRK with adjuvant MMC and Group B included 84 eyes treated with Femto-LASIK. Visual acuity, SER, corneal topography, pachymetry and keratometry were assessed for 12 mo ***: The preoperative mean SER was-8.86±1.81 and-9.25±1.70 D in t-PRK MMC group and Femto-LASIK respectively(P=0.99) which improved to-0.65±0.43 D and-0.69±0.50 D at 12 mo follow up. Mean SER remained stable during the 12 mo of follow-up, with no statistically significant difference between the two groups(P=0.64). In t-PRK MMC group, only six eyes needed retreatment after six months of follow up. And two eyes showed haze(one reversible haze grade 2, while the other had dense irreversible haze grade 4).CONCLUSION: t-PRK MMC provides safe and satisfactory visual outcomes and acceptable risk as Femto-LASIK in patients with high myopia.

关键词： transepithelial photorefractive keratectomy femtosecond laser assisted keratomileusis high myopia corneal haze Egypt

An amorphous FeMoO_(4) nanorod array enabled high-efficiency oxygen evolution electrocatalysis in alkaline seawater

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Nano Research 2024年第4期17卷 2270-2275页

作者： Jie Tang Shengjun Sun Xun He Hui Zhang Chaoxin Yang Min Zhang Meng Yue Hefeng Wang Yuntong Sun Yonglan Luo Sulaiman Alfaifi Asmaa farouk mohamed S.Hamdy Xuping Sun Huiqing Wang Binwu Ying Department of Laboratory Medicine West China HospitalSichuan UniversityChengdu 610041China College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinan 250014China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Chemistry Department Faculty of ScienceKing Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Chemistry College of ScienceKing Khalid UniversityAbha 61413Saudi Arabia Medical Simulation Centre West China Second University HospitalSichuan UniversityChengdu 610041China

The development of highly efficient and durable oxygen evolution reaction(OER)catalysts for seawater electrolysis is of great importance for ***,an amorphous FeMoO_(4) nanorod array on Ni foam is reported as a highly active OER electrocatalyst in alkaline seawater,requiring only overpotentials of 303 and 332 mV to achieve 100 and 300 mA·cm^(-2),***,it shows strong long-term electrochemical durability for at least 50 h.

关键词： amorphous material FeMoO_(4) nanorod array electrocatalyst seawater electrolysis oxygen evolution reaction

Cauliflower-like Ni_(3)S_(2)foam for ultrastable oxygen evolution electrocatalysis in alkaline seawater

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Nano Research 2024年第8期17卷 6820-6825页

作者： Qiuying Dai Xun He Yongchao Yao Kai Dong Xuwei Liu Xiankun Guo Jie Chen Xiaoya Fan Dongdong Zheng Yongsong Luo Shengjun Sun Luming Li Wei Chu Asmaa farouk mohamed SHamdy Xuping Sun Bo Tang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinan 250014China Institute for Advanced Study Chengdu UniversityChengdu 610106China Department of Chemistry College of ScienceKing Khalid UniversityP.O.Box 900461413 AbhaSaudi Arabia Center for High Altitude Medicine West China HospitalSichuan UniversityChengdu 610041China Laoshan Laboratory Qingdao 266237China

It is of great importance to design and develop electrocatalysts that are both long-lasting and efficient for seawater ***,a three-dimensional porous cauliflower-like Ni_(3)S_(2)foam on Ni foam(Ni_(3)S_(2)foam/NF)is proposed as a high-performance electrocatalyst for the oxygen evolution reaction in alkaline *** as-synthesis Ni_(3)S_(2)foam/NF achieves exceptional efficacy,achieving a current density of 100 mA·cm^(−2)at mere overpotential of 369 ***,its electrocatalytic stability extends up to 1000 h at 500 mA·cm^(−2).

关键词： Ni_(3)S_(2)foam oxygen evolution reaction seawater electrolysis electrocatalyst

Cyclophosphamide and Etoposide as a Salvage Treatment in Metastatic Osteosarcoma Patients

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Journal of Cancer Therapy 2018年第7期9卷 529-537页

作者： Fatma MF Akl mohamed farouk Akl Clinical Oncology and Nuclear Medicine Department Mansoura University Mansoura Egypt

Background and Objective: Osteosarcoma is a rare bone cancer with approximately 30% - 35% of patients who will relapse either systemically or locally, with the lung being the commonest site of relapse. The objective of this trial was to evaluate the efficacy of cyclophosphamide and etoposide, in treatment of metastatic osteosarcoma patients progressed after one or more chemotherapy lines, with the progression free survival and treatment response as the primary endpoints, while the secondary endpoints were overall survival and treatment toxicity. Patients and Methods: Twenty seven metastatic osteosarcoma patients were enrolled into this trial and received cyclophosphamide and etoposide chemotherapy. Cyclophosphamide was given at a dose of 500 mg/m2 per day, I.V for 5 days and etoposide (100 mg/m2 per day I.V for 5 days). Response was assessed after 3 cycles according to Response Evaluation Criteria in Solid Tumors (RECIST) version 1.1. Chemotherapy Toxicity was graded according to the Common Terminology Criteria for Adverse Events (CTCAE). Results: The median overall survival time and progression-free survival were 12 months and 8 months, respectively. Four patients (14.8%) achieved partial response;14 patients (51.9%) had stationary disease (SD);and 9 (33.3%) expressed tumor progression. Hematologic toxicity was the main toxicity. None of the patients had G4 or life threatening toxicities. Conclusion: The combination of cyclophosphamide and etoposide represents an efficient and tolerable treatment option for patients with metastatic osteosarcoma.

关键词： Cyclophosphamide Etoposide Metastatic Osteosarcoma Salvage Chemotherapy

Analytical Solution for Acoustic Waves Propagation in Fluids

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World Journal of Mechanics 2011年第5期1卷 243-246页

作者： mohamed I. A. Othman mohamed Galal Sayed Ali Roushdi mohamed farouk 不详

This paper presents a mathematical model of linear acoustic wave propagation in fluids. The benefits of a mathematical model over a normal mode analysis are first discussed, then the mathematical model for acoustic propagation in the test medium is developed using computer simulations. The approach is based on a analytical solution to the homogeneous wave equation for fluid medium. A good agreement between the computational presented results with published data.

关键词： Acoustic Waves Normal Mode Analysis Fluid Medium