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Zoological Research 2024年第1期45卷 226-229页

作者： Ming Zhang Cai-Hui Wang Yu-Xin Zheng Qi-Gao Jiangzuo Ye-Mao Hou Peng Cao Qing-Yan Dai Ruo-Wei Yang Feng Liu Xiao-Tian Feng Lin-Heng mo qiao-Mei Fu China-Central Asia"the Belt and Road"Joint Laboratory on Human and Environment Research Key Laboratory of Cultural Heritage Research and ConservationSchool of Culture HeritageNorthwest UniversityXi’anShaanxi 710127China Shanghai Qi Zhi Institute Shanghai 200232China College of Life Sciences Northwest UniversityXi’anShaanxi 710127China Key Laboratory of Vertebrate Evolution and Human Origins Institute of Vertebrate Paleontology and PaleoanthropologyCenter for Excellence in Life and PaleoenvironmentChinese Academy of SciencesBeijing 100044China Cultural Relics and Archaeology Institute of Hunan ChangshaHunan 410083China University of the Chinese Academy of Sciences Beijing 100049China

DEAR EDITOR,The Laosicheng site in Yongshun County,Hunan Province,China,plays an important role in elucidating the animal population composition of the region prior to the middle Qing Dynasty(approximately 300 years ago).This site has yielded a substantial number of animal bones,11960 of which have been identified to the species level,serving as direct evidence of ancient animal populations(Hunan Provincial Institute of Cultural Relics and Archaeology,2018).

关键词： Hunan Ancient insight

Rehabilitation care for pain in elderly knee replacement patients

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World Journal of Clinical Cases 2024年第4期12卷 721-728页

作者： Li Liu qiao-Zhen Guan Li-Fang Wang Wuhan Fourth Hospital Wuhan 430033Hubei ProvinceChina Department of Orthopaedics Wuhan Third HospitalWuhan 430074Hubei ProvinceChina

BACKGROUND Total knee arthroplasty(TKA)is recognized as the most effective surgical intervention for relieving pain and improving joint mobility and deformity in patients with knee osteoarthritis and other synovial diseases.The application of accelerated postoperative rehabilitation(enhanced recovery after surgery)has demonstrated its efficacy in improving patient outcomes,and early postoperative joint function exercise has become a key prognostic factor in knee replacement.The unexpected appearance of limb pain and swelling hindered the patient’s tendency for early mobilization,leading in prolonged hospitalization,delayed functional recovery and negative psychological responses.A retrospective analysis was conducted on a cohort of 116 patients who under-went TKA at our hospital between July 2019 and July 2021.The patients were divided into two groups:A control group(n=58)receiving programmatic nur-sing,and an observed group(n=58)receiving programmed nursing combined with a collaborative nursing model.A pain management team consisting of attending physicians,head nurses,and responsible nurses was established.Outcome measures included visual analogue scale(VAS)scores,activities of daily living(ADL)scale scores,and functional scores.The ADL scores of patients in both groups exhibited a continuous increase.However,there was no statistically significant difference in the ADL scores between the two groups at 48 h and the 7th d post-surgery(P>0.05).Upon reexamination at the 3rd mo,the observation group demonstrated higher ADL scores compared to the control group(67.48±14.69 vs 59.40±16.06,P0.05).The functional status of patients in both groups exhibited a gradual increase prior to intervention and at the 1st,2nd,and 3rd month following discharge(Pmonth after dis

关键词： Programmed pain nursing Collaborative nursing Total knee arthroplasty

Cu/mo2C synthesized through Anderson-type polyoxometalates modulate interfacial water structure to achieve hydrogen evolution at high current density

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Nano Research 2024年第4期17卷 2546-2554页

作者： Dunyuan Jin Fen qiao Yan Zhou Junfeng Wang Kecheng Cao Jing Yang Jikang Zhao Lei Zhou Haitao Li School of Energy and Power Engineering Jiangsu UniversityZhenjiang 212013China School of Physical Science and Technology and Shanghai Key Laboratory of High-resolution Electron Microscopy ShanghaiTech UniversityShanghai 201210China Institute for Energy Research Jiangsu UniversityZhenjiang 212013China

The development of efficient non-precious metal catalysts is important for the large-scale application of alkaline hydrogen evolution reaction(HER).Here,we synthesized a composite catalyst of Cu and mo_(2)C(Cu/mo_(2)C)using Anderson-type polyoxometalates(POMs)synthesized by the facile soaking method as precursors.The electronic interaction between Cu and mo_(2)C drives the positive charge of Cu,alleviating the strong adsorption of hydrogen at the mo site by modulating the d-band center of mo_(2)C.By studying the interfacial water structure using in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy(ATR-SEIRAS),we determined that the positively charged Cu crystals have the function of activating water molecules and optimizing the interfacial water structure.The interfacial water of Cu/mo_(2)C contains a large amount of free water,which could facilitate the transport of reaction intermediates.Due to activated water molecules and optimized interfacial water structure and hydrogen adsorption energy,the overpotential of Cu/mo_(2)C is 24 mV at a current density of 10 mA·cm^(-2) and 178 mV at a current density of 1000 mA·cm^(-2).This work improves catalyst performance in terms of interfacial water structure optimization and deepens the understanding of water-mediated catalysis.

关键词： electrocatalytic hydrogen production interfacial water charge transport d band center in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy(ATR-SEIRAS)

In-doping collaboratively controlling back interface and bulk defects to achieve efficient flexible CZTSSe solar cells

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Journal of Energy Chemistry 2024年第2期89卷 10-17,I0002页

作者： Quanzhen Sun Yifan Li Caixia Zhang Shunli Du Weihao Xie Jionghua Wu qiao Zheng Hui Deng Shuying Cheng Institute of Micro-Nano Devices and Solar Cells College of Physics and Information EngineeringFuzhou UniversityFuzhou 350108FujianChina Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108FujianChina Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering Changzhou 213164JiangsuChina

Focusing on the low open circuit voltage(V_(OC))and fill factor(FF)in flexible Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)solar cells,indium(In)ions are introduced into the CZTSSe absorbers near mo foils to modify the back interface and passivate deep level defects in CZTSSe bulk concurrently for improving the performance of flexible device.The results show that In doping effectively inhibits the formation of secondary phase(Cu(S,Se)_(2))and VSndefects.Further studies demonstrate that the barrier height at the back interface is decreased and the deep level defects(Cu_(Sn)defects)in CZTSSe bulk are passivated.moreover,the carrier concentration is increased and the V_(OC) deficit(V_(OC,def))is decreased significantly due to In doping.Finally,the flexible CZTSSe solar cell with 10.01%power conversion efficiency(PCE)has been obtained.The synergistic strategy of interface modification and bulk defects passivation through In incorporation provides a new thought for the fabrication of efficient flexible kesterite-based solar cells.

关键词： Flexible solar cells Cu_(2)ZnSn(S,Se)_(4) Back interface Deep level defects Barrier height

Hard carbon derived from rice husk as low cost negative electrodes in Na-ion batteries

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Journal of Energy Chemistry 2019年第2期28卷 17-22页

作者： Maria K.Rybarczyk Yunming Li mo qiao Yong-Sheng Hu Maria-Magdalena Titirici Marek Lieder Gdansk University of Technology Chemical Faculty Key Laboratory for Renewable Energy Beijing Key Laboratory for New Energy Materials and DevicesNational Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of Sciences Queen Mary University London School of Materials Science & Engineering

Here,we report the synthesis of hard carbon materials(RH) made from natural rice husk through a single pyrolysis process and their application as an anode in sodium-ion batteries.The studies show that the electrochemical properties of RHs are affected by the treatment temperatures,which determine the materials morphology,in particular,their degree of graphitization and extent of continuous channels(nanovoids).The latter are accessible to sodium ions and significantly contribute to charge storage capacity of the produced anodes.The RHs obtained at 1600 °C deliver the highest reversible capacity of276 mAh g^(-1) mainly due to insertion of sodium ions into the nanovoids.This work deepens the basic understanding of the influence of the carbonization temperature on the sodium storage mechanism.

关键词： Nanovoids in rice husk Sustainable energy storage Na-ion batteries

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油气比变化对燃烧室流场影响试验研究

热能动力工程 2024年第4期39卷 19-24页

作者：党新宪王新桥杨元模南昌职业大学航空发动机研究所江西南昌330500 宿州航空职业学院安徽宿州234000

为解决油气比变化时航空发动机燃烧稳定性问题,针对某型航空发动机短环形燃烧室在不同油气比下进行试验研究,利用PIV测速仪对不同油气比下燃烧室内液雾燃烧流场进行测量;利用温度传感器对燃烧室出口温度分布进行测量,分析了油气比对燃... 详细信息

为解决油气比变化时航空发动机燃烧稳定性问题,针对某型航空发动机短环形燃烧室在不同油气比下进行试验研究,利用PIV测速仪对不同油气比下燃烧室内液雾燃烧流场进行测量;利用温度传感器对燃烧室出口温度分布进行测量,分析了油气比对燃烧室内燃烧流场和出口温度分布影响规律。研究结果表明:随着油气比的增加,燃烧室回流区长度缩短,回流区涡心分别向火焰筒上下壁面靠拢,涡心距离增大;燃烧室内气流紊流度增大,速度轴向分量Urms增大;燃烧室出口各点的温度T相应升高。油气比靠近熄火边界时,燃烧流场稳定性减弱。

关键词：航空、航天推进系统环形燃烧室液雾燃烧流场 PIV测量

基于SWAT模型的渠江流域径流侵蚀功率时空规律分析

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中国水土保持科学 2024年第2期22卷 25-33页

作者：黄幸莫淑红李平治乔殿新李斌斌河海大学水文水资源学院南京210098 西安理工大学省部共建西北旱区生态水利国家重点实验室西安710048 水利部水土保持监测中心北京100053

探明流域径流侵蚀功率的演变规律对重点侵蚀区识别和土壤侵蚀防治至关重要。以嘉陵江右岸支流渠江流域为研究区,基于SWAT模型模拟计算流域径流侵蚀功率,分析其时空分布特征与空间尺度效应,并通过聚类分析、相关性分析揭示其对流域气象... 详细信息

探明流域径流侵蚀功率的演变规律对重点侵蚀区识别和土壤侵蚀防治至关重要。以嘉陵江右岸支流渠江流域为研究区,基于SWAT模型模拟计算流域径流侵蚀功率,分析其时空分布特征与空间尺度效应,并通过聚类分析、相关性分析揭示其对流域气象、地形、土壤等因素的关系。结果表明:渠江流域年尺度的径流侵蚀功率大于季尺度,其中第3季度为土壤侵蚀重点防治时段;全年和第3季度的多年平均径流侵蚀功率均呈现出北部大南部小、西部大东部小、上游大下游小的空间分布特征;渠江干流与其支流大通江的多年平均径流侵蚀功率和流域控制面积之间均呈幂指数关系,且其变化规律存在空间阈值,在年尺度干流和大通江的阈值面积分别为8549.4和8504.4 km^(2),在第3季度干流和大通江的阈值面积分别为4834.9和6223.5 km^(2);气象因子、地形因子和流域形态因子为渠江流域径流侵蚀功率的主要影响因素。研究结果可为制订渠江流域土壤侵蚀治理方案提供决策依据。

关键词： SWAT模型径流侵蚀功率时空分布空间尺度效应渠江流域

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A silylene-stabilized distannavinylidene with a highly labile substituent

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Science China Chemistry 2023年第12期66卷 3555-3561页

作者： Zihao qiao Ming Chen Zhenbo mo State Key Laboratory and Institute of Elemento-Organic Chemistry Frontiers Science Center for New Organic MatterCollege of ChemistryNankai UniversityTianjin 300071China

Vinylidene and its heavier analogues are fundamentally important in synthetic chemistry,but their stabilization and structural characterization remains extremely challenging.Herein we describe that the reduction of an NHSi-stabilized stannyl-stannylene(2)with one molar equivalent of[(^(Mes)Nacnac)Mg]_(2)affords an NHSi-stabilized distannavinylidene(3).Single-crystal X-ray crystallography and density functional theory(DFT)calculations show that compound 3 features a pronounced Sn=Sn double bond and one lone pair of electrons at the two-coordinate Sn atom.most strikingly,3 undergoes an interconversion with distannyne(4)upon the addition and removal of one molar equivalent of N-heterocyclic carbene.Compound 3 readily reacts with Ph_(2)C=C=O,Ad C≡P and(Al Cp^(*))_(4)to give the structurally interesting stannacycles(5,6)and an aluminyl distannyne(7),demonstrating its unique reactivity derived from the high substituent lability.

关键词： distannavinylidene silylenes stannacycles distannyne carboranes

“Grafting from”法制备高载量大孔弱阳离子交换层析介质

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高等学校化学学报 2024年第3期45卷 64-72页

作者：郭旺姜泽平马磊乔娟莫文清靳海波何广湘黄永东张荣月北京石油化工学院新材料与化工学院燃料清洁化及高效催化减排技术北京市重点实验室北京102617 中国科学院过程工程研究所生化工程国家重点实验室北京100190

针对大孔聚合物层析介质孔径大、比表面积低而导致的蛋白结合容量低的问题,采用“graftingfrom”策略,以大孔聚丙烯酸酯微球为基质,通过氧化还原引发甲基丙烯酸在微球表面接枝聚合,制备了高载量弱阳离子交换层析介质.研究了单体浓度、... 详细信息

针对大孔聚合物层析介质孔径大、比表面积低而导致的蛋白结合容量低的问题,采用“graftingfrom”策略,以大孔聚丙烯酸酯微球为基质,通过氧化还原引发甲基丙烯酸在微球表面接枝聚合,制备了高载量弱阳离子交换层析介质.研究了单体浓度、过硫酸钾浓度及反应温度等因素对蛋白结合容量的影响.所得介质的蛋白静态结合容量和动态结合容量分别达到252.21和157.25mg/mL;同时发现具有一定离子交换容量的该类介质能够在0.2 mol/L NaCl缓冲液中保持100 mg/mL的蛋白结合容量.将该层析介质用于鸡卵清中溶菌酶的纯化,获得了较高的纯化效率.

关键词：弱阳离子交换层析介质大孔聚合物蛋白结合容量 Grafting from法分离纯化

Qualitative analysis of aromatic compounds via 1D TOCSY techniques

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Magnetic Resonance Letters 2024年第1期4卷 21-27页

作者： Wenbo Dong Qi Zhao Jiancheng Zhao Jiarong Zhang Yingxiong Wang Yan qiao State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of Sciences27 South Taoyuan RoadTaiyuan030001China Graduate University of Chinese Academy of Sciences Beijing100049China Marine Biomedical Research Institution Guangdong Medical UniversityZhanjiang524023China College of Chemistry Taiyuan University of Technology79 Yingze West StreetWanbailin DistrictTaiyuan030024China

The aromatic compounds,including o-xylene,m-xylene,p-xylene,and ethylbenzene,primarily originate from the catalytic reforming of crude oil,and have a wide variety of applications.However,because of similar physical and chemical properties,these compounds are difficult to be identified by gas chromatography(GC)without standard samples.With the development of modern nuclear magnetic resonance(NMR)techniques,NMR has emerged as a powerful and efficient tool for the rapid analysis of complex and crude mixtures without purification.In this study,the parameters of one-dimensional(1D)total correlation spectroscopy(TOCSY)NMR techniques,including 1D selective gradient TOCSY and 1D chemicalshift-selective filtration(CSSF)with TOCSY,were optimized to obtain comprehensive molecular structure information.The results indicate that the overlapped signals in NMR spectra of nonpolar aromatic compounds(including o-xylene,m-xylene,p-xylene and ethylbenzene),polar aromatic compounds(benzyl alcohol,benzaldehyde,benzoic acid),and aromatic compounds with additional conjugated bonds(styrene)can be resolved in 1D TOCSY.more importantly,full molecular structures can be clearly distinguished by setting appropriate mixing time in 1D TOCSY.This approach simplifies the NMR spectra,provides structural information of entire molecules,and can be applied for the analysis of other structural isomers.

关键词： 1D TOCSY NMR technologies Xylenes Aromatic compounds Structure information of entire molecular Qualitative analysis