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Synthesis of rod-like bis-ester liquid crystals and their influence on photoelectric properties of liquid crystalline materials

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Chinese Chemical Letters 2009年第5期20卷 549-553页

作者： min yan zheng Yong Sheng Wei Zhong Wei An Shan Wang Department of Chemistry Xianyang Normal University Xianyang 712000 China School of Chemistry & Material Science Shaanxi Normal University Xi'an 710062 China

Six novel rod-like magnetic liquid crystals have been prepared, in which trans-bicyclohexyl or trans-cyclohexylphenyl and biphenylcarboxylic acid phenyl ester mesogenic cores with n-propyl and n-pentyl substituents were terminated by 4-hydroxyl- TEMPO （TEMPO = 2,2,6,6-tetramethylpiperidine-l-oxy）. Their structures were confirmed by elemental analysis, IR and MS. Determined by SQUID, EPR, DSC and HS-POM （heat stage polarizing optical microscope）, the six compounds all have both magnetic and liquid crystalline properties; their temperature ranges of mesophase were from 16.0 to 24.8 ℃, and the magnetic liquid crystal molecules could obviously improve the response sensitivity of liquid crystal materials.

关键词： Liquid crystals Magnetic Photoelectric property Ester 4-OH-TEMPO

Amplitude-Squared Squeezing in a Kerr-Nonlinear Blackbody

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Communications in Theoretical Physics 2007年第5期47卷 933-936页

作者： WU Zi-Xia CHENG Ze ZHANG yan-min CHENG zheng-Ze Department of Physics Huazhong University of Science and Technology Wuhan 430074 China

We find that amplitude-squared squeezing of the photon field is present in a new blackbody, namely, a Kerr- nonlinear blackbody. The squeezing effect decreases as temperature T increases. The amount of the amplitude-squared squeezing in a Kerr-nonlinear blackbody is much larger than the corresponding squeezing in normal blackbody, and the degree of amplitude-squared squeezing is much larger than the amplitude squeezing for the same range of parameters in a Kerr-nonlinear blackbody.

关键词： Kerr-nonlinear blackbody amplitude-squared squeezing nonpolariton

Comparative proteomics analysis of human gastric cancer

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World Journal of Gastroenterology 2008年第37期14卷 5657-5664页

作者： Wei Li Jian-Fang Li Ying Qu Xue-Hua Chen Jian-min Qin Qin-Long Gu min yan zheng-Gang Zhu Bing-Ya liu Shanghai Key Laboratory of Diagnosis and Treatment for GastrointestinalCancer Department of Surgery Shanghai Institute of DigestiveSurgery Ruijin Hospital Shanghai Jiao Tong University Schoolof Medicine Shanghai 200025 China

AIM: To isolate and identify differentially expressed proteins between cancer and normal tissues of gastric cancer by two-dimensional electrophoresis (2-DE) and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). METHODS: Soluble fraction proteins of gastric cancer tissues and paired normal tissues were separated by 2-DE. The differentially expressed proteins were selected and identified by MALDI-TOF-MS and database search. RESULTS: 2-DE profiles with high resolution and reproducibility were obtained. Twenty-three protein spots were excised from sliver staining gel and digested in gel by trypsin, in which fifteen protein spots were identified successfully. Among the identified proteins, there were ten over-expressed and five under-expressed proteins in stomach cancer tissues compared with normal tissues. CONCLUSION: In this study, the well-resolved, reproducible 2-DE patterns of human gastric cancer tissue and paired normal tissue were established and optimized and certain differentially-expressed proteins were identified. The combined use of 2-DE and MS provides an effective approach to screen for potential tumor markers.

关键词： Proteome Two-dimensional polyacrylamide gel electrophoresis Mass spectrometry Gastric cancer Tumor markers

Synergistic promotion strategy of “dual-site” and “dual-path” to enhance the C–C coupling between CO2 and HCHO driven by photoelectrocatalysis

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Journal of Energy Chemistry 2025年第1期100卷 39-49页

作者： Hongqiang yang Jianfeng zheng Guoyu Wang Yifei Gao Yatao yang Jia Li Xiaojin Han yan Cui Zhanggen Huang National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal Institute of Coal Chemistry Chinese Academy of Science University of Chinese Academy of Science Shenyang University of Chemical Technology

Photoelectrocatalytic coupling CO2and volatile organic compounds （VOCs） is a promising green strategy for the synergistic conversion of the two carbon-containing resources to *** catalytic efficiency is always at the mercy of chemical inertness of CO2and the competitive hydrogen evolution of ***,a modified g-C3N4/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely *** Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol *** revealed by in-situ characterizations and density functional theory calculations,CO2and HCHO were absorbed at Zn site and N site,***,*CO generated from CO2and HCHO was converted to*CH3O and*CHO on the dual-active-site *** detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH3O in electrocatalysis *** from the“*CO+*CH3O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic *** selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO2and HCHO simultaneously driven by light and electricity.

关键词： Photoelectrocatalysis Z-scheme C–C coupling Ethanol

Hypoxia-preconditioned bone marrow-derived mesenchymal stem cells protect neurons from cardiac arrest-induced pyroptosis

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Neural Regeneration Research 2025年第4期20卷 1103-1123页

作者： Xiahong Tang Nan zheng Qingming Lin yan You zheng Gong yangping Zhuang Jiali Wu Yu Wang Hanlin Huang Jun Ke Feng Chen Shengli Clinical Medical College of Fujian Medical University Fujian Medical UniversityFuzhouFujian ProvinceChina Department of Emergency Fujian Provincial HospitalFuzhouFujian ProvinceChina Fujian Provincial Key Laboratory of Emergency Medicine FuzhouFujian ProvinceChina The Second Department of Intensive Care Unit Fujian Provincial Hospital South BranchFuzhouFujian ProvinceChina

Cardiac arrest can lead to severe neurological impairment as a result of inflammation,mitochondrial dysfunction,and post-cardiopulmonary resuscitation neurological *** preconditioning has been shown to improve migration and survival of bone marrow–derived mesenchymal stem cells and reduce pyroptosis after cardiac arrest,but the specific mechanisms by which hypoxia-preconditioned bone marrow–derived mesenchymal stem cells protect against brain injury after cardiac arrest are *** this end,we established an in vitro co-culture model of bone marrow–derived mesenchymal stem cells and oxygen–glucose deprived primary neurons and found that hypoxic preconditioning enhanced the protective effect of bone marrow stromal stem cells against neuronal pyroptosis,possibly through inhibition of the MAPK and nuclear factor κB ***,we transplanted hypoxia-preconditioned bone marrow–derived mesenchymal stem cells into the lateral ventricle after the return of spontaneous circulation in an 8-minute cardiac arrest rat model induced by *** results showed that hypoxia-preconditioned bone marrow–derived mesenchymal stem cells significantly reduced cardiac arrest–induced neuronal pyroptosis,oxidative stress,and mitochondrial damage,whereas knockdown of the liver isoform of phosphofructokinase in bone marrow–derived mesenchymal stem cells inhibited these *** conclude,hypoxia-preconditioned bone marrow–derived mesenchymal stem cells offer a promising therapeutic approach for neuronal injury following cardiac arrest,and their beneficial effects are potentially associated with increased expression of the liver isoform of phosphofructokinase following hypoxic preconditioning.

关键词： bone marrow–derived mesenchymal stem cells cardiac arrest cardiac resuscitation hypoxic preconditioning liver isoform of phosphofructokinase mitochondria neuroinflammation oxidative stress pyroptosis reactive oxygen species

Porous Organic Cage‑Based Quasi‑Solid‑State Electrolyte with Cavity‑Induced Anion‑Trapping Effect for Long‑Life Lithium Metal Batteries

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Nano-Micro Letters 2025年第2期17卷 376-386页

作者： Wei-min Qin Zhongliang Li Wen‑Xia Su Jia‑min Hu Hanqin Zou Zhixuan Wu Zhiqin Ruan Yue‑Peng Cai Kang Li Qifeng zheng School of Chemistry South China Normal UniversityGuangzhou 510006People’s Republic of China Key Laboratory of Functional Metal‑Organic Compounds of Hunan Province College of Chemistry and Material ScienceHengyang Normal UniversityHengyang 421008People’s Republic of China Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials Guangzhou 510006People’s Republic of China

Porous organic cages(POCs)with permanent porosity and excellent host–guest property hold great potentials in regulating ion transport behavior,yet their feasibility as solid-state electrolytes has never been testified in a practical ***,we design and fabricate a quasi-solid-state electrolyte(QSSE)based on a POC to enable the stable operation of Li-metal batteries(LMBs).Benefiting from the ordered channels and cavity-induced anion-trapping effect of POC,the resulting POC-based QSSE exhibits a high Li+transference number of 0.67 and a high ionic conductivity of 1.25×10^(−4) S cm^(−1) with a low activation energy of 0.17 *** allow for homogeneous Li deposition and highly reversible Li plating/stripping for over 2000 *** a proof of concept,the LMB assembled with POC-based QSSE demonstrates extremely stable cycling performance with 85%capacity retention after 1000 ***,our work demonstrates the practical applicability of POC as SSEs for LMBs and could be extended to other energy-storage systems,such as Na and K batteries.

关键词： Porous organic cage Cavity-induced anion-trapping Quasi-solid-state electrolyte Homogeneous Li+flux Lithium metal battery

Blocking optimized SIMD tree search on modern processors

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Journal of Shanghai University(English Edition) 2011年第5期15卷 437-444页

作者：张倬陆宇凡沈文枫徐炜民郑衍衡 School of Computer Engineering and Science Shanghai University

Tree search is a widely used fundamental algorithm. Modern processors provide tremendous computing power by integrating multiple cores, each with a vector processing unit. This paper reviews some studies on exploiting single instruction multiple date （SIMD） capacity of processors to improve the performance of tree search, and proposes several improvement methods on reported SIMD tree search algorithms. Based on blocking tree structure, blocking for memory alignment and dynamic blocking prefetch are proposed to optimize the overhead of memory access. Furthermore, as a way of non-linear loop unrolling, the search branch unwinding shows that the number of branches can exceed the data width of SIMD instructions in the SIMD search algorithm. The experiments suggest that blocking optimized SIMD tree search algorithm can achieve 1.6 times response speed faster than the un-optimized algorithm.

关键词： single instruction multiple date (SIMD) tree search binary search streaming SIMD extensions (SSE) Cell broadband engine (BE)

Small modifications of endo-functionalized cavities lead to large changes in molecular interaction in water

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Science China Chemistry 2025年第1期 369-376页

作者： Song-Meng Wang Hao Nian yan-Fang Wang Li-Shuo zheng Yu-Tao zheng Yi-Wei Dong Liping Huang Xiaoping Wang Wei Jiang Liu-Pan yang Department of Chemistry Southern University of Science and Technology School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesGuangxi Normal University School of Pharmaceutical Science Hengyang Medical School University of South China

Studying molecular recognition in aqueous environments is crucial for understanding biological processes. Herein, we present a series of N-doped endo-functionalized anthracene-based cavities by introducing inward-directed pyridine units. The subtle modifications can significantly affect the binding properties of these receptors, which is similar to the mutations in biological systems. Combining theoretical calculations and molecular recognition experiments demonstrated that these “mutations” have an impact on the hydrophobicity and charge distribution of the hosts, consequently significantly influencing molecular *** is crucial for understanding the intricate mechanisms of molecular-level interactions in biological receptors.

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地震综合信息显示与消息通告系统应用解析

山西地震 2009年第1期 31-33页

作者：赵晓云闫民正山西省地震局山西太原030021 太原大陆裂谷动力学国家野外科学观测研究站山西太原030025

"地震综合信息显示与消息通告系统"是中国数字地震观测网络信息分项应用软件之一。介绍了该系统架构,分析了该系统软件主要应用模块,为深入了解以及合理使用该系统提供一定的参考。

关键词：应用软件地震信息消息通告