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SO3H-Functionalized Ionic Liquids： Green, Efficient and Reusable Catalysts for the Facile Dehydration of Aldoximes into Nitriles

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Chinese Journal of Chemistry 2011年第5期29卷 978-982页

作者： Davoodnia Abolghasem Khojastehnezhad Amir Bakavoli mehdi tavakoli-Hoseini Niloofar Department of Chemistry Faculty of Sciences Mashhad Branch Islamic Azad University Mashhad Iran

Easily synthesized aldoximes have been converted to the corresponding nitriles under very mild conditions by a simple reaction using two halogen-free SO3H-functionalized ionic liquids, 3-methyl-l-（4-sulfonic acid）butylimidazolium hydrogen sulfate [MIM（CH2）aSO3H][HSO4] and 1-（4-sulfonic acid）butylpyridinium hydrogen sulfate [PY（CH2）4SO3H][HSO4], as catalyst and reaction medium without any additional organic solvent. The method was equally effective for aromatic aldoximes bearing electron-donating and electron-withdrawing substituents. Taking into account environmental and economical consideration, the protocol presented here has the merits of environmentally friendly, simple operation, easy work-up and very good yields. The catalysts could be recycled and reused for several times without noticeably decreasing in their catalytic activities.

关键词： ionic liquid aldoxime nitrile dehydration

Silica Gel-Supported Polyphosphoric Acid （PPA/SiO2）： An Efficient and Reusable Heterogeneous Catalyst for Facile Synthesis of 14-Aryl-14H-dibenzo[aj]xanthenes under Solvent-free Conditions

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Chinese Journal of Chemistry 2011年第2期29卷 297-302页

作者： Khojastehnezhad Amir Davoodnia Abolghasem Bakavoli mehdi tavakoli-Hoseini Niloofar Zeinali-Dastmalbaf Mohsen Department of Chemistry Faculty of Sciences Islamic Azad University Mashhad Branch Mashhad Iran

A simple, efficient and green method for the synthesis of 14-aryl-14H-dibenzo[aj]xanthenes by a one-pot condensation reaction of β-naphthol and aryl aldehydes using silica gel-supported polyphosphoric acid （PPA/SiO2）, an effective and reusable catalyst, under solvent-free conditions is described. The present methodology offers several advantages, such as a simple procedure with an easy work-up, short reaction times, high yields, and the absence of any volatile and hazardous organic solvents.

关键词： 14-Aryl-14H-dibenzo[a,j]xanthenes PPA/SiO2 heterogeneous catalysis green chemistry solvent-flee conditions

A CFD study on the hydrodynamic response of a small-scale ice floe induced by a passing ship

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Journal of Hydrodynamics 2024年第2期36卷 290-299页

作者： Zongyu Jiang Spyros Hirdaris Sasan tavakoli Mikko Suominen Pentti Kujala Marine and Arctic Technology Department of Mechanical EngineeringAalto UniversityEspooFinland Global Ship Systems Centre ABS Hellenic SM LLC.AthensGreece Department of Infrastructure Engineering The University of MelbourneMelbourneAustralia

A Reynolds averaged Navier-Stokes(RANS)computational fluid dynamics(CFD)model is built to investigate the hydrodynamic response of a circular ice floe under the influence of a passing ship in calm *** ship,mirroring the KRISO Container Ship’s hull design,progresses near an ice floe whose diameter is 30%of the ship’s length and its thickness is 3 *** ship advances at a constant speed,which is handled by using the overset mesh *** study focuses on the ice floe’s motions and the hydrodynamic forces induced by three speeds and three transverse distances of the passing *** reveal that ship-generated wakes notably influence the ice floe’s motions,with a greater influence on sway than ***,the ship’s speed and proximity distinctly affect the ice floe’s motions.

关键词： Hydrodynamics ship-ice interactions ice floe Reynolds averaged Navier-Stokes(RANS)computational fluid dynamics(CFD)

Thin-film flow technology in controlling the organization of materials and their properties Special Collection:Distinguished Australian Researchers

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Aggregate 2024年第1期5卷 115-129页

作者： Clarence Chuah Xuan Luo Javad tavakoli Youhong Tang Colin L.Raston Flinders Institute for Nanoscale Science and Technology College of Science and EngineeringFlinders UniversityAdelaideSouth AustraliaAustralia Centre for Health Technologies School of Biomedical EngineeringFaculty of Engineering and Information TechnologyUniversity of Technology SydneySydneyNew South WalesAustralia

Centrifugal and shear forces are produced when solids or liquids *** systems and devices that use these forces,such as dynamic thin-film flow technology,are evolving continuously,improve material structure-property relationships at the nanoscale,representing a rapidly thriving and expanding field of research high with green chemistry metrics,consolidated at the inception of *** vortex fluidic device(VFD)provides many advantages over conventional batch processing,with fluidic waves causing high shear and producing large surface areas for micro-mixing as well as rapid mass and heat transfer,enabling reactions beyond diffusion *** these abilities allows for a green and innovative approach to altering materials for various research and industry applications by controlling small-scale flows and regulating molecular and macromolecular chemical reactivity,self-organization phenomena,and the synthesis of novel *** review highlights the aptitude of the VFD as clean technology,with an increase in efficiency for a diversity of top-down,bottom-up,and novel material transformations which benefit from effective vortex-based processing to control material structure-property relationships.

关键词： material nanoscale structure-property relationship thin film flow technology vortex fluidic device

Nurses'critical thinking disposition and professional commitment:a cross-sectional study

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Frontiers of Nursing 2024年第1期11卷 119-126页

作者： Mahtab Allah tavakoli Golnaz Foroughameri Jamileh Farokhzadian Sedigheh Khodabandeh Shahraki Nursing Research Center Kerman University of Medical SciencesKerman ***Iran Reproductive Health Family and Population Research CenterKerman University of Medical SciencesKerman ***Iran

Objective:High-quality and successful nursing care delivery in a variety of situations requires critical thinking training and professional *** present study aimed to investigate critical thinking disposition,professional commitment,and the relationship between these 2 variables among ***:As a result of stratified random sampling,201 nurses were enrolled in the present cross-sectional *** were gathered using a socio-demographic form,the Critical Thinking Disposition Inventory(CTDI),and the Nurses'Professional Commitment Scale(NPCS).Results:Although the critical thinking disposition scores were at a moderate level(115.70±13.55),the mean score for professional commitment was high(91.37±11.77).A positive correlation was found between critical thinking disposition and professional commitment(r=0.67,P=0.001).Conclusions:Nursing managers are urged to employ strategies to enhance nurses'critical thinking disposition and professional commitment.

关键词： critical thinking nursing education professional commitment skills strategies

Isoimperatorin alleviates acetic acid-induced colitis in rats

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Asian Pacific Journal of Tropical Biomedicine 2024年第4期14卷 147-153页

作者： Saied Goodarzi Amir Hossein Abdolghaffari Behnaz Najafi Mostafa Pirali Hamedani Saeed tavakoli Mahshad Marvi Maryam Baeeri Narguess Yassa Abbas Hadjiakhoondi Mohammad Abdollahi Zahra Tofighi Medicinal Plants Research Center Faculty of PharmacyTehran University of Medical SciencesTehranIran Department of Toxicology and Pharmacology Faculty of PharmacyTehran Medical SciencesIslamic Azad UniversityTehranIran Department of Pharmacognosy Faculty of PharmacyTehran University of Medical SciencesTehranIran Medicinal Plants Research Center Institute of Medicinal PlantsACECRKarajIran International Campus School of Pharmacy Tehran University of Medical SciencesTehranIran Toxicology and Diseases group The Pharmaceutical Sciences Research CenterTehran University of Medical SciencesTehranIran Department of Toxicology and Pharmacology Faculty of PharmacyTehran University of Medical SciencesTehranIran

Objective:To investigate the effect of isoimperatorin on histopathological and biochemical changes in acetic acid-induced colitis ***:Colitis was induced by intracolonic administration of acetic acid solution(4%v/v)in *** were divided into six groups including the sham group,the negative control group,the dexamethasone-treated group,and the groups treated with isoimperatorin(0.1,1,and 10 mg/kg/d by gavage).The treatments were administered for three days and then colonic status was assessed by macroscopic,histopathological,and biochemical ***:Isoimperatorin significantly alleviated colonic damage in a dose-dependent manner and improved histological changes in rats with acetic acid-induced *** also significantly reduced myeloperoxidase,TNF-α,IL-1β,and malodialdehyde ***:Isoimperatorin alleviates acetic acid-induced colitis in rats and may be a potential therapeutic agent for the treatment of colitis.

关键词： Isoimperatorin Inflammatory bowel disease Acetic acid Colitis TNF-α IL-1β

Neuroprotective potential of traditional Ayurvedic Kadha:age-related neurological disorders:a comprehensive literature review

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Traditional Medicine Research 2024年第9期9卷 51-77页

作者： Sarvin Sadreddini Mohammad Javad Emami Kazemabad Sogand Sheikholeslami Kosar Chitzan-Zadeh Mohammad Taha Kouchaki Midia Rashidi Amir Abbas Ghayerin Shahin Sabaghi Ghazal tavakoli Sepehr Nanbakhsh Tina Mansourian Arefeh Tabashiri Fariba Arbab Mojeni Mohammed Namiq Amin Zahra Taheri Seyed Esmaeil Sedighi Taraneh Tarkashvand Parham Amirazodi Mobina Fathi Shirin Yaghoobpoor Niloofar Deravi School of Medicine Tabriz University of Medical SciencesTabriz ***Iran School of Medicine Qom University of Medical SciencesQom ***Iran School of Medicine Hamadan University of Medical SciencesHamadan ***Iran School of Medicine Ahvaz Jundishapur University of Medical SciencesAhvaz ***Iran Faculty of Medicine Tabriz University of Medical SciencesTabriz ***Iran School of Medicine Iran University of Medical SciencesTehran ***Iran School of Medicine Shahid Beheshti University of Medical SciencesTehran ***Iran School of Medicine Mazandaran University of Medical SciencesSari ***Iran School of Medicine Kermanshah University of Medical SciencesKermanshah ***Iran Faculty of Pharmacy Pharmaceutical Sciences BranchIslamic Azad UniversityTehran ***Iran Department of Biology Faculty of SciencePayamNoor UniversityTehran ***Iran Faculty of Medicine Islamic Azad University of Medical ScienceTehran 193951495Iran International Campus Shahid Sadoughi University of Medical SciencesYazd ***Iran

Despite modern medicine’s advancements,age-related neurological diseases like Alzheimer’s disease and Parkinson’s disease remain challenging due to high costs,side effects,and limited ***,a traditional Indian medicine system,offers Kadha tea as a potential herbal *** review explores Kadha’s components(basil(Ocimum basilicum L.),black pepper(Piper nigrum L.),Cinnamon(Cinnamomum verum ***),ginger(Zingiber officinale Roscoe),and raisin(Vitis vinifera L.))and their interaction with various neurological *** suggest Kadha exhibits anti-inflammatory,antioxidant,and antiviral properties,potentially impacting Alzheimer’s disease,Parkinson’s disease,neurotoxicity,neuroinflammation,and brain *** focusing on specific disease mechanisms and Kadha’s intergrade effects,this review aims to elucidate its potential role in managing age-related neurological disorders.

关键词： Ayurveda Kadha neuroprotective neurological disorders traditional medicine

Evolution of seasonal land surface temperature trend in pond-breeding newt (Neurergus derjugini) in western Iran and eastern Iraq

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Ecological Processes 2023年第2期12卷 3-17页

作者： Peyman Karami Sajad tavakoli Mina Esmaeili Department of Environmental Sciences Faculty of Natural Resources and Environment Sciences Malayer University Department of Environmental and Forest Science Faculty of Natural Resources and Environment Science and Research Branch Islamic Azad University Department of Biology Faculty of Science Razi University

Background Temperature, as one of the effective environmental stimuli in many aspects of species life and ecosystems, can affect amphibians in many ways. Knowing and predicting temperature change and its possible effects on the habitat suitability and movements of amphibians have led many researchers to use climate change scenarios and species distribution models(SDMs). One of the important remote-sensing products that received less attention of conservation biologists is the land surface temperature(LST). Due to the small difference between LST and air temperature, this component can be used to investigate and monitor the daily and seasonal changes of habitats. This study aims to investigate the seasonal trend of LST in the habitat suitability and connectivity of the critically endangered newt(Neurergus derjugini) in its small distribution range, using the MODIS LST time series(2003 to 2021) and with the help of SDMs, Mann–Kendall(MK) and Pettitt non-parametric *** In the last decade, the increasing trend of LST versus its decreasing trends is obvious. Based on MK and Pettitt tests, in the winter and spring, with the decrease in latitude of 35.45° and increase in longitude of 46.14°, the core populations which are located in the southeast have experienced an increase in temperature. Considering the period time of breeding and overwintering, the continuity of winter and spring can be effective on the survival of adult newts as well as larvae in the microclimate. Linkages with the highest current flow between core populations in the winter and summer are the most likely to be vulnerable. At the level of habitat, the increase in LST is proportional to the trend of thermal landscape changes, and all seasons have had an increase in LST, but in winter and summer, the largest area of the habitat has been involved. By continuing the current trend, many high-altitude southern habitats in Iran will be endangered, and the species will be at risk of local extinction.

关键词： Seasonal change Local extinction Climate refuge Amphibian

Composition, environment, and economic value of the Permian to Cretaceous coated grains from Zagros and the Persian Gulf

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International Journal of Sediment Research 2023年第3期38卷 316-334页

作者： Mehrangiz Naderi-Khujin Vahid tavakoli Pars Oil and Gas Company School of Geology College of Science University of Tehran

Ooid grainstone/packstone carbonate facies of the Dalan, Kangan, and Arab formations are the main hydrocarbon reservoirs in the Persian Gulf. Based on detailed petrographic and petrophysical analyses,sedimentological and mineralogical features of the Permian to Late Cretaceous carbonate and iron-rich coated grains from Zagros and the Persian Gulf were investigated. Frequent ooids in these formations indicate a high-energy environment and a wave-dominated shallow carbonate platform. Because of wide-spread Permian-Triassic epiric seas and long-lasting periods of arid and hot climate, Permian-Triassic carbonate ooids have more vertical and lateral distribution in comparison with Late Jurassic carbonate ooids. Dolomite, calcite, and anhydrite are the major minerals of carbonate ooid grains. Early Cretaceous iron-rich ooids have been deposited above a major Late Aptian disconformity during the highstand systems tract. Ooid ironstone bulk sample X-ray diffraction(XRD) analysis shows that goethite,siderite, fluorapatite, calcite, quartz, and pyrite are the major phases of ooid ironstone deposits. This layer of iron bearing ooids could have economic importance in its outcrops in the Zagros area. Late Cretaceous iron-rich coated grains(pisoid-oncoids) were deposited above the Sarvak exposure surface during the Late Cretaceous, long-lasting sea-level fall on the Arabian Plate. Boehmite, diaspore, hematite, and goethite are the main minerals of these kind of iron-rich deposits. Late Cretaceous karst-type bauxite deposits have also been reported from different sections of the Zagros area and have economic value for mining.

关键词： Coated grains Depositional conditions Permian Cretaceous Bauxite