Light-driven dry reforming of methane toward syngas presents a proper solution for alleviating climate change and for the sustainable supply of transportation fuels and ***,Rh/InGaN1-xOxnanowires supported by silicon ...
Light-driven dry reforming of methane toward syngas presents a proper solution for alleviating climate change and for the sustainable supply of transportation fuels and ***,Rh/InGaN1-xOxnanowires supported by silicon wafer are explored as an ideal platform for loading Rh nano particles,thus assembling a new nanoarchitecture for this grand *** combination with the remarkable photothermal synergy,the O atoms in Rh/InGaN1-xOxcan significantly lower the apparent activation energy of dry reforming of methane from 2.96 eV downward to 1.70 *** as-designed Rh/InGaN1-xOxNWs nanoarchitecture thus demonstrates a measurable syngas evolution rate of 180.9 mmol gcat-1h-1with a marked selectivity of 96.3% under concentrated light illumination of 6 W *** is more,a high turnover number(TON) of 4182 mol syngas per mole Rh has been realized after six reuse cycles without obvious activity *** correlative18O isotope labeling experiments,in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS) and in-situ diffuse reflectance Fourier transform infrared spectroscopy characterizations,as well as density functional theory calculations reveal that under light illumination,Rh/InGaN1-xOxNWs facilitate releasing*CH3and H+from CH4by holes,followed by H2evolution from H+reduction with ***,the O atoms in Rh/InGaN1-xOxcan directly participate in CO generation by reacting with the*C species from CH4dehydrogenation and contributes to the coke elimination,in concurrent formation of O *** resultant O vacancies are then replenished by CO2,showing an ideal chemical *** work presents a green strategy for syngas production via light-driven dry reforming of methane.
Previously,it was found that several proteins of Haemonchus contortus were involved in the stimulation of the host immune ***,the information about the selection of superlative antigens with immunogenic efficacies on ...
Previously,it was found that several proteins of Haemonchus contortus were involved in the stimulation of the host immune ***,the information about the selection of superlative antigens with immunogenic efficacies on host DCs is *** the current study,the stimulatory effects of five recombinant proteins(elongation factor-1α,arginine kinase,ES-15,ES-24,and ADP-ribosylation factor 1) of *** on the maturation of goat monocyte-derived dendritic cells(md.DCs) were *** proteins were purified separately in *** expression and incubated with isolated goat peripheral blood mononuclear cells(PBMC).Immunofluorescence assay(IFA) results confirmed the binding of these molecules to the md.DC’s surface as compared to control *** the flow cytometry analysis,recombinant proteins induced md.DC stimulation via the up-regulation of the expression of the costimulatory molecule(CD80) and MHC-Ⅱ.Quantitative RT-PCR data showed a significant increase in the expression of specific genes of the WNT and toll-like receptor(TLR) signaling *** result of ELISA indicated the higher levels of cytokine(IL-10,IL-12,IFN-y,and TNF-α) secretion in the md.DC compared to the negative(pET-32 a His-Tag) and blank(PBS)control *** data gives valuable support in the selection of potential antigens for future studies on the immunomodulation of the host against the infection of ***.
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