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Timing the termination of the doushantuo negative carbon isotope excursion: evidence from U-Pb ages from the dengying and Liuchapo formations,South China

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Science Bulletin 2018年第21期63卷 1431-1438页

作者： Mingzhong Zhou Taiyi Luo Warren d.huff Zhiqing Yang Guanghong Zhou Tian Gan Hua Yang di Zhang School of Geographical and Environmental Sciences Guizhou Normal University State Key Laboratory of Ore deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences department of Geology University of Cincinnati Beijing SHRIMP Center Chinese Academy of Geological Sciences School of Geography and Tourism Guizhou Education University College of Earth Sciences University of Chinese Academy of Sciences

The doushantuo negative carbon isotope excursion(dOUNCE) is the largest known marine inorganic carbon isotope anomaly. The origin of this pronounced negative excursion is still an enigmatic issue that attracts geologists. Time constraints on the excursion are the critical information that would provide insight into its genesis. In previous decades, the timing of its termination has been constrained by the widely cited zircon U-Pb age of 550.5 ± 0.8 Ma for the tuff at the top of the Miaohe Member at the Jiuqunao section in the Yangtze Gorges area, South China. However, results of recent studies indicate that the reliability of this time constraint needs to be re-evaluated. Here, a geochronological study was carried out using two K-bentonites from Fanglong in South China. A K-bentonite in the lower dengying Formation yielded a U-Pb age of 557 ± 3 Ma, while a K-bentonite in the basal Liuchapo Formation yielded an age of 550 ± 3 Ma. Based on regional correlations between the Ediacaran successions in South China,the age(557 ± 3 Ma) for the K-bentonite in the lower dengying Formation may serve as a second critical timing constraint for the ending of the dOUNCE. Combined with available estimates of the dOUNCE duration, our new data indicate that the dOUNCE has a maximum onset age ～570 Ma.

关键词： doushantuo formation dengying formation Shuram carbon isotope excursion South China

华南五峰组-龙马溪组黑色岩系时空展布的主控因素及其启示

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地球科学（中国地质大学学报） 2007年第6期32卷 819-827页

作者：苏文博李志明 Frank R.Ettensohn Markes E.Johnson Warren d.huff 王巍马超李录张磊赵慧静中国地质大学地球科学与资源学院北京100083 中国地质大学地球科学学院湖北武汉430074 dept .of Earth &Environ .Sciences University of Kentucky dept .of Geosciences Williams College dept .of Geology University of Cincinnati

在回顾五峰组-龙马溪组两个地层单位沿革并重申其定义与划分基础上,重建了华南五峰组-龙马溪组及其相关地层序列的区域地层框架.根据这一框架中奥陶-志留纪黑色笔石岩系的穿时性、以及相关地层序列纵向演化特征与岩石圈板块挠曲模式的联... 详细信息

在回顾五峰组-龙马溪组两个地层单位沿革并重申其定义与划分基础上,重建了华南五峰组-龙马溪组及其相关地层序列的区域地层框架.根据这一框架中奥陶-志留纪黑色笔石岩系的穿时性、以及相关地层序列纵向演化特征与岩石圈板块挠曲模式的联系,结合所发现钾质斑脱岩源岩的板块汇聚背景,以及该阶段海平面升降与黑色岩系对应关系,提出控制该阶段华南黑色岩系的时空展布格局的主要因素有两个,即该阶段自南东向北西的华夏地块与扬子地块幕式汇聚过程所产生的岩石圈板块挠曲-周缘前陆盆地的同向迁移,以及该阶段两次全球性的三级海平面变化快速上升阶段所导致的缺氧及欠补偿水体.本文认为,要在华南奥陶-志留纪(包括其他断代)寻找其他可能的烃源岩层位,可能要首先考虑类似背景下这两种因素综合作用所导致的快速沉降及深水缺氧的沉积环境.

关键词：奥陶-志留纪烃源岩黑色页岩岩石圈挠曲全球海平面变化华南板块汇聚

Implications of a new, biostratigraphically well-controlled, radio-isotopic age for the lower Telychian Stage of the Llandovery Series （Lower Silurian, Sweden）

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Episodes 2008年第3期31卷 309-314页

作者： Stig M. Bergstrom Funda Ozlem Toprak Warren d. huff Roland Mundil School of Earth Sciences Division of Geological Sciences The Ohio State University 155 S. Oval Mall Columbus Ohio 43210 USA. department of Geoiogy University of Cincinnati Cincinnati Ohio 45221 USA Berkeley Geochronology Center 2455 Ridge Road Berkeley California 94709 USA.

Radio-isotopic analysis of single zircons from two early Telychian K-bentonites, one of which is among the most widespread Lower Paleozoic volcanic ash falls in north- ern Europe, yields overlapping weighted mean 206pb/238U ages of 438. 7± 1.0 Ma and 437.8 ± 0.5 Ma, respectively. The former age is from zircons of the Osmundsberg K-bentonite from the type locality at Osmundsberget in the Siljan area of central Sweden where it occurs in the lower part of the Spirograptus tur- riculatus Graptolite Zone and in the lower part of the Angochitina longicollis Chitinozoan Zone. Zircons giv- ing the latter age are from a bed previously identified as the Osmundsberg K-bentonite at the Kallholn Quarry in the same area. Based on new biostratigraphic data, the latter bed is now considered to be slightly younger than the Osmundsberg K-bentonite. The dated stratigraphic level of the ash layers is slightly younger than the base of the Telychian Stage and thus represents a minimum age for the Aeronian/Telychian Stage boundary. A U-Pb age of 〉 438 Ma for the base of this stage, however, is older and in conflict with estimates in the most recent compilation of the Silurian time scale. In view of the fact that only three radio-isotopic dates from the entire Llan- dovery have been previously accepted, this new and biostratigraphically exceptionally well-controlled radio-isotopic date fills an important gap in the Lower Silurian geochronology.

关键词：无线电同位素蓝达夫里阶志留纪

SHRIMP U-Pb dating for a K-bentonite bed in the Tieling Formation,North China

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Chinese Science Bulletin 2010年第29期55卷 3312-3323页

作者： SU WenBo LI HuaiKun huff W d ETTENSOHN F R ZHANG ShiHong ZHOU HongYing WAN YuSheng School of Earth Sciences and Resources China University ofGeosciences (Beijing) Beijing 100083 China Tianjin Institute of Geology and Mineral Resources China Geological Survey Tianjin 300170 China department of Geology University of Cincinnati Cincinnati OH 45221-0013 USA department of Earth and Environment Sciences University of Kentucky Lexington KY 40506-0053 USA Beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China

A SHRIMP U-Pb zircon age of 1437±21 Ma was obtained for a recently discovered K-bentonite bed in the Tieling Formation,situated northeast of Beijing at the boundary between Liaoning and Hebei provinces,on the northern margin of the North China Craton(NCC).The SHRIMP U-Pb age places Tieling Formation near the end of the Calymmian Period of the early Mesoproterozoic *** addition,a SHRIMP U-Pb zircon date of 1372±18 Ma was acquired for K-bentonite beds in the overlying,dark-shale-dominated Xiamaling Formation from the same location northeast of *** date assigns a similar Mid-Mesoproterozoic(Ectasian Period) age for the Xiamaling Formation,as have previously determined dates from other sections northwest of *** dates indicate that the Tieling and Xiamaling formations,as well as the related succession in the eastern part of the Yanshan Mountains,represented by the well-known Meso-to Neoproterozoic standard section in Jixian,can be correlated well with sections northwest of Beijing in the western part of the Yanshan *** other words,the boundary between the Calymmian and Ectasian periods in the northern parts of the NCC is marked by the unconformity between the Tieling and Xiamaling formations in the northern *** boundary was previously ascribed to the "Qinyu Orogeny" and thought to be of Grenville *** this regard,the conventional "Qinyu Orogeny" should now be regarded as a short-lived regional uplift during Early Mesoproterozoic time,rather than a result from the Grenvillian assembly of the NCC to the Rodinia Supercontinent(～1.0 Ga).

关键词： SHRIMP 铁岭组膨润土 Pb 锆石中国 Rodinia超大陆中元古代早期

The Global Stratotype Section and Point （GSSP） for the base of the Katian Stage of the Upper Ordovician Series at Black Knob Ridge, Southeastern Oklahoma, USA

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Episodes 2007年第4期30卷 258-270页

作者： daniel Goldman Stephen A. Leslie Jaak Nōlvak Seth Young Stig M. Bergstroem Warren d. huff department of Geology University of Dayton 300 College Park Dayton Ohio 45469 USA deparment of Geology and Environmental Science James Madison University MSC 6903 Harrisonburg VA 22807 USA Institute of Geology at Tallinn University of Technology Ehitajate tee 5 19086 Tallinn Estonia School of Earth Sciences Division of Geological Sciences The Ohio State University 155 S. Oval Mall Columbus Ohio 43210 USA department of Geology University of Cincinnati Cincinnati Ohio 45221 USA.

The Global Boundary Stratotype Section and Point （GSSP） for the Katian Stage of the Upper Ordovician Series is defined as the 4.0 m-level above the base of the Bigfork Chert in the Black Knob Ridge section, southeastern Oklahoma. This point in this section is coincident with the first appearance of the graptolite diplacanthograptus caudatus, which has proved to be a reliable datum for precise worldwide correlation. The FAd ofd. caudatus occurs very near the first occurrences of the graptolites d. lanceolatus, *** americanus, Orthograptus pageanus, O. quadrimucronatus, dicranograptus hians, and Neurograptus margaritatus. This rapid succession of fossil species appearance events provides a secure basis for identification of the base of the Katian Stage of the Upper Ordovician Series and for its global chronostratigraphic correlation.

关键词：层形断面奥陶纪俄克拉荷马州美国地质特点

中-新元古界标准剖面蓟县系首获高精度年龄制约——蓟县剖面雾迷山组和铁岭组斑脱岩锆石SHRIMP U-Pb同位素定年研究

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岩石学报 2014年第10期30卷 2999-3012页

作者：李怀坤苏文博周红英相振群田辉杨立公 Warren d.huff Frank R ETTENSOHN 中国地质调查局天津地质矿产研究所中国地质大学地球科学与资源学院天津市蓟县中上元古界国家自然保护区管理中心 department of Geology University of CincinnatiCincinnatiOH 45221-0013 department of Earth and Environment Sciences University of KentuckyLexingtonKY 40506-0053

近期在蓟县中-新元古界标准剖面铁岭组和雾迷山组首次发现斑脱岩、并测得其锆石SHRIMP U-Pb同位素年龄为～1440Ma（1439±14Ma）和～1485Ma（1483±13Ma和1487±16Ma）,这标志着这条传统的标准剖面上以碳酸盐岩为主体的蓟县系上部的两... 详细信息

近期在蓟县中-新元古界标准剖面铁岭组和雾迷山组首次发现斑脱岩、并测得其锆石SHRIMP U-Pb同位素年龄为～1440Ma（1439±14Ma）和～1485Ma（1483±13Ma和1487±16Ma）,这标志着这条传统的标准剖面上以碳酸盐岩为主体的蓟县系上部的两个重要组,从此也获得了直接的、高精度的锆石U-Pb同位素年龄约束。这是华北中-新元古界标准剖面蓟县系相关地层单位首次获得直接而精确的锆石U-Pb同位素年龄约束,也是在整个华北北缘燕山地区雾迷山组内部首次获得精确的直接定年。这一进展为闻名中外的天津蓟县剖面中-新元古界年代地层格架的正确厘定、以及今后继续作为华北该阶段的标准剖面,并与国内外其他地区相关地层的正确对比等,提供了新的、精确的年代学＂锚点＂,因而具有重要的科学和实际意义。

关键词：蓟县剖面斑脱岩铁岭组雾迷山组 SHRIMP U-Pb同位素测年中元古界华北克拉通

铁岭组钾质斑脱岩锆石SHRIMP U-Pb年代学研究及其地质意义

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科学通报 2010年第22期55卷 2197-2206页

作者：苏文博李怀坤 huff W d ETTENSOHN F R 张世红周红英万渝生中国地质大学(北京)地球科学与资源学院北京100083 中国地质调查局天津地质矿产研究所天津300170 department of Geology University of CincinnatiCincinnatiOH 45221-0013USA department of Earth and Environment Sciences University of KentuckyLexingtonKY 40506-0053USA 北京离子探针中心中国地质科学院地质研究所北京100037

最近在冀北-辽西以碳酸盐岩为主的铁岭组内发现了钾质斑脱岩,并获得其锆石SHRIMP U-Pb年龄——(1437±21)Ma,这一进展将铁岭组的时代确定为中元古代早期盖层纪(Calymmian Period)末期.与此同时,还在同一剖面获得了铁岭组的上覆地层——... 详细信息

最近在冀北-辽西以碳酸盐岩为主的铁岭组内发现了钾质斑脱岩,并获得其锆石SHRIMP U-Pb年龄——(1437±21)Ma,这一进展将铁岭组的时代确定为中元古代早期盖层纪(Calymmian Period)末期.与此同时,还在同一剖面获得了铁岭组的上覆地层——下马岭组碳硅质页岩里钾质斑脱岩锆石SHRIMPU-Pb年龄——(1372±18)Ma,这与稍早前在北京西北及其附近地区所获得的定年结果(～1380Ma)是一致的.这在肯定了该地区下马岭组应归入中元古代中期延展纪(Ectasian Period)早期的同时,也表明以蓟县剖面为代表的燕山东部地区铁岭组-下马岭组等相关序列,可与北京西山及燕山西部进行良好对比.换言之,华北北部从高于庄组到铁岭组的巨厚碳酸盐岩序列都应视为中元古界盖层系沉积,而铁岭组与下马岭组之间的不整合面可作为中元古界盖层系与延展系之间的物理性分界标志;早先以该不整合面命名的"芹峪上升"(或"芹峪运动")应属于一个时限短暂的中元古代早期的区域抬升,不能再视为华北克拉通对新元古代罗迪尼亚超大陆聚合事件(～1.0Ga)的响应.

关键词：锆石U-Pb年龄钾质斑脱岩铁岭组华北克拉通盖层纪中元古代

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欧洲稀燃缸内直接喷射汽油机车型的评估

汽车与新动力 2012年第6期 24-29页

作者： Chambon P huff S Norman K Edwards K d Thomas J Prikhodko V 陈荣峻

稀燃汽油缸内直接喷射燃烧是一种很有前途的燃烧技术,可在满足未来排放要求的情况下显著提高燃油效率。虽然在美国市场上部分车型已实现化学计量比汽油缸内直接喷射技术的商业化运作,却还没有稀燃汽油直接喷射车型出现,而这种车型已在... 详细信息

稀燃汽油缸内直接喷射燃烧是一种很有前途的燃烧技术,可在满足未来排放要求的情况下显著提高燃油效率。虽然在美国市场上部分车型已实现化学计量比汽油缸内直接喷射技术的商业化运作,却还没有稀燃汽油直接喷射车型出现,而这种车型已在欧洲市场上市。美国橡树岭国家试验室获得了1台配装2.0 L稀燃汽油直接喷射汽油机的欧洲产BMW 1系轿车,利用底盘测功器对其进行测量,分别在美国行驶循环(联邦测试循环)、公路燃油经济性测试循环和US06联邦增补测试循环,以及稳态脉谱下检测了发动机和排气后处理系统的性能和排放。在研究过程中,同时对车辆使用轻度混合动力技术(发动机起动-停车系统和交流电机智能控制)时的性能进行了评估。对试验数据作了分析,并根据美国市场对燃油经济性和排放所提出的要求,量化了稀燃汽油直接喷射与轻度混合动力技术的优缺点。这些数据经过整理后将用于开发和运用常规或先进的动力总成车辆的仿真。

关键词：稀燃缸内直接喷射燃油经济性排放发动机起动-停车系统交流电机智能控制

华南五峰组—龙马溪组与华北下马岭组的钾质斑脱岩及黑色岩系——两个地史转折期板块构造运动的沉积响应

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地学前缘 2006年第6期13卷 82-95页

作者：苏文博李志明史晓颖周洪瑞黄思骥刘晓茗陈晓雨张继恩杨红梅贾柳静 W.d.huff F.R.ETTENSOHN 中国地质大学(北京)地球科学与资源学院北京100083 中国地质大学(武汉)地球科学学院湖北武汉430074 北京市第五十四中学北京100013 中国科学院研究生院北京100049 美国辛辛那提大学地质学系辛辛那提oh452210013 美国肯塔基大学地球与环境科学系列克星顿ky405060053

华南奥陶—志留纪之交的五峰组—龙马溪组及华北新元古界下马岭组发现的钾质斑脱岩,都产自类似的黑色硅质-碳质页岩/板岩岩系。这两套黑色岩系与上、下地层的接触关系、岩性组成以及垂向序列所揭示的地质过程,具有良好的可对比性,都符合... 详细信息

华南奥陶—志留纪之交的五峰组—龙马溪组及华北新元古界下马岭组发现的钾质斑脱岩,都产自类似的黑色硅质-碳质页岩/板岩岩系。这两套黑色岩系与上、下地层的接触关系、岩性组成以及垂向序列所揭示的地质过程,具有良好的可对比性,都符合Ettensohn总结的黑色页岩与板块构造运动之间的成因关系模式。岩石元素地球化学研究表明,这两组不同时代的钾质斑脱岩具有相似的源岩岩浆背景,为中酸性的粗安岩-英安岩-流纹岩系列,源于同碰撞岛弧(synCOL-VA)背景的火山喷发活动,与板块边缘的俯冲碰撞密切相关。由于华南五峰组—龙马溪组内斑脱岩及黑色页岩沉积的形成与此间华夏地块与扬子地块的汇聚相关,华北下马岭组的黑色岩系与钾质斑脱岩的形成可能也和华北地块与相邻地块的碰撞相关。推测后者很可能为Rodinia超大陆或Pangea850Ma汇聚时的沉积-地层学响应。

关键词：钾质斑脱岩黑/暗色岩系板块汇聚早古生代新元古代华南和华北