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Aggregation-induced emission and thermally activated delayed fluorescence of 2,6-diaminobenzophenones

Science China Chemistry 2018年第8期61卷 925-931页

作者： masaki Shimizu masaki nakatani Kenta Nishimura Faculty of Molecular Chemistry and Engineering Kyoto Institute of Technology

Exploration of novel organic luminophores that exhibit thermally activated delayed fluorescence(TADF) in the aggregated state is very crucial for advance of delayed luminescence-based applications such as time-gated bio-sensing and temperature *** report herein that synthesis, photophysical properties, molecular and crystal structures, and theoretical calculations of 2,6-bis(diarylamino)benzophenones. Absorption spectra in solution and calculations using density functional theory(DFT) method revealed that the optical excitation took place through intramolecular charge-transfer from one diarylamino moiety to an aroyl group. While the benzophenones did not luminesce in solution, the solids of the benzophenones emitted green light with moderate-to-good quantum yields. Thus, the benzophenones exhibit aggregation-induced emission. Based on the lifetime measurement, the green emission of the solids was found to include TADF. The emergence of the TADF is supported by the small energy gap between the excited singlet and triplet states, which was estimated by time-dependent DFT calculations. Thin films of poly(methyl methacrylate) doped by the benzophenones also showed green prompt and delayed fluorescence whose lifetimes were in the order of microseconds. Linear correlation between logarithm value of TADF lifetime and temperature was observed with the benzophenone in powder, suggesting that the benzophenones can serve as molecular thermometers workable under aqueous conditions.

关键词： donor-acceptor system delayed fluorescence temperature sensor

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G-Quadruplex Binding of Sanguinarine:A Novel Model of Ligand Binding to Beads-on-a-String Structure of Human Telomeric DNA

G-Quadruplex Binding of Sanguinarine:A Novel Model of Ligand...

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第五届全国化学生物学学术会议

作者： Li-Ping Bai~1 masaki Hagihara~2 Kazuhiko nakatani~2 Zhi-Hong Jiang~(1*) 1 School of Chinese Medicine,Hong Kong Baptist University,Hong Kong 2 Institute of Scientific and Industrial Research,Osaka University,Japan

＜正＞We recently investigated G-quadruplex binding property of sanguinarine by using Taq DNA polymerase stop assays,circular dichroism（CD）spectroscopy and UV-melting *** polymerase stop assays using DNA template containing 4 human telomeric repeats TTAGGG showed that sanguinarine produced the same concentration-dependent paused bands as that of TMPyP4 by

关键词： G-quadruplex telomere sanguinarine DNA polymerase stop assay circular dichroism

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