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Rare earth metal as a dopant element:Cerium ion as an articulator in hexavalent chromium removal by magnetic iron oxides

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Journal of Rare Earths 2023年第10期41卷 1616-1626,I0006页

作者： Pricila maria Batista Chagas Maísa M.M.Lima Aline Aparecida Caetano Lucas Bragança Carvalho Nayra maria de Abreu Piva maria eduarda resende luiz Iara do Rosário Guimarães Laboratory of Environmental Catalysis and New Materials Department of ChemistryFederal University of LavrasCEP 37200-900LavrasMGBrazil Department of Viticulture&Enology University of CaliforniaDavisCA95616USA Institute of Science and Technology São Paulo State University18087-180SorocabaBrazil

This study highlights introducing the rare earth metal cerium(Ce(Ⅳ))into the structure of magnetite(Fe_(3)O_(4))to achieve enhanced adsorptive properties for the removal of chromium(Cr(VI))from an aqueous *** ratios of Ce(Ⅳ)were introduced into the iron oxide matrix,termed FeCe-5,FeCe-10,and *** numerical values correspond to the nominal content of the dopant element added to the synthesis *** solid materials were characterized for morphology and chemical structure,and N_(2)physical adsorption/desorption measurements were *** solid materials doped with Ce(IV)have a high surface area compared to Fe_(3)O_(4),and the solid material with the highest content of the dopant ion(Ce(IV))has a 4-fold greater surface *** increase in the dopant content in the iron oxide structure leads to a total chromium removal of 93.3%.Isotherms studies on the solid materials show that chromium adsorption follows the Langmuir *** adsorption capacity to Fe_(3)O_(4)is 12.59 mg/g and FeCe-10 is 22.49 mg/g at 35℃.By fitting the kinetic and isothermal models,it is found that for the Fe_(3)O_(4)and FeCe-10 materials Cr(VI)removal occurs in very different ways,attributed to the different surface areas and compositions of the oxide,with the formation of the goethite(α-FeOOH)*** FeCe-10reuse process was performed and the removal capacity the Cr(VI)is reduced after the first *** result is attributed to a strong and irreversible adsorption of Cr(VI)on the FeCe-10.

关键词： Bimetallic oxides Fe-Ce interaction Oxygen vacancies Adsorption Cr(Ⅵ) Rare earths

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Operative Technique for Correction of Gigantomastia,Using the Superior Pedicle,with Special Care for the Nipple-Papillary Grafts:A 13-Year Retrospective Study

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Modern Plastic Surgery 2015年第3期5卷 34-46页

作者： Jose Humberto Cardoso resende Lucilia Feliciano Marques di Carlantonio luiz Celio Martins Freitas Teresa Tonini Nebia maria Almeida de Figueiredo luiz Carlos Santiago Nursing and Biosciences Federal University of Rio de Janeiro State(UNIRIO)Rio de JaneiroBrazil Member of the Brazilian Society of Plastic Surgery(SBCP) Rio de JaneiroBrazil Brazilian College of Surgeons(CBC) Rio de JaneiroBrazil President of the Catheters committee of the National Cancer Institute(INCa) Rio de JaneiroBrazil Public Health from State of Rio de Janeiro University(UERJ) Rio de JaneiroBrazil Coordinator of the Post-graduate Program in Nursing and Bioscience of UNIRIO Rio de JaneiroBrazil Nursing Federal University of Rio de Janeiro State(UNIRIO)Rio de JaneiroBrazil

This is a retrospective study on gigantomastia correction in obesity facing the technique of nipple-areolar grafts and its complexity. The main question is the technical-surgical care during its execution aiming to achieve reparative results that can return to these women the desire to live with better quality of life and health. Method: We performed a retrospective study of all obese patients with severe gigantomastia who underwent reduction mammaplasty with an operative technique using the superior pedicle, with special care for the nipple-papillary grafts. The study was carried out at a single institution between 2001 and 2013, in a total of 30 cases. This operative technique was presented at first time in 1980, with no changes up to now. We emphasized the perfect decortication of the areola and nipples until they were translucent after the maneuvers of Schwartzman and subsequent grafts operated in both breasts. Results: Results were considered satisfactory, from the reparative and aesthetic point of view, emphasizing the degree of improvement observed in women undergoing technique. Discussion: We can say that during all this time of aesthetic and therapeutic-restorative surgery, due to its realization in a single surgical time, there was big impact on the aesthetics of patients and on their families, even taking into account possible complications in the post-operative. Conclusion: The superior pedicle technique, performed as described here, is a safe and reliable procedure in patients with severe gigantomastia.

关键词： Mammoplasty Gigantomastia resende’s Technique Surgical Flaps Bariatric Surgery Obesity

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The Body Suffering and Care Possibilities: A Reflective Look from the Health Economics

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Health 2016年第4期8卷 285-292页

作者： José Humberto Cardoso resende Allan Peixoto de Assis Lucilia Feliciano Marques di Carlantônio luiz Célio Martins Freitas Teresa Tonini Nébia maria Almeida de Figueiredo luiz Carlos Santiago Universidade Federal do Estado do Rio de Janeiro (UNIRIO) Rio de Janeiro Brazil

This article aimed to show ideas about the themes: body suffering, nursing and Medical care, and Health Economics. To this end, we tried to put together a kaleidoscope of references that converged on the promotion of autonomy and empowerment and, as a strategy for action, and then we can think of what to do to alleviate the suffering of patients.

关键词： Health Economics Nursing Medicine

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Scientific Articles and Patent Applications on Biodiesel Production from Lignocellulosic Biomass

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Journal of Environmental Protection 2021年第6期12卷 371-390页

作者： Edgar Gutiérrez Infante Argimiro resende Secchi Luis Fernando Leite Adelaide maria de Souza Antunes Programa de Doutorado em Engenharia de Processos Químicos e Bioquímicos Universidade Federal do Rio de Janeiro Rio de Janeiro Brazil Instituto Alberto luiz Coimbra de Pós-Graduaç ã o e Pesquisa de Engenharia Universidade Federal do Rio de Janeiro Rio de Janeiro Brazil Escola de Química Centro de Tecnologia Universidade Federal do Rio de Janeiro Rio de Janeiro Brazil Instituto Nacional da Propriedade Industrial INPI Rio de Janeiro Brazil

This document was conducted to identify trends in research activity (published articles) and technology (patent applications) on the production of biodiesel from lignocellulosic biomass. The Web of Science, Compendex, and Scopus databases were used to retrieve articles and Derwent Innovation was used to search for patent applications;300 articles and 169 patent applications were retrieved. The most common research goals (microbial lipid production, acid pretreatment, and pyrolysis) were identified from an analysis of the author’s keywords. The countries most involved in research are China (96 articles), United States (68), and India (19). The top countries in international partnerships research were United States (22), China (16), and Germany (11). Bioresource Technology (54), Biotechnology for Biofuels (18), and Green Chemistry (13) are the journals with the most published articles. United States (84) is the leader on patent applications, followed by China (15) and Japan (5).

关键词： Biodiesel Lignocellulosic Biomass Research Articles Patent Applications

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Do Cytokines Play a Role in Predicting Some Features and Outcome in Infective Endocarditis?

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Advances in Infectious Diseases 2013年第2期3卷 115-119页

作者： maria Carmo Pereira Nunes Izabella Rodrigues de Araújo Andréa Teixeira de Carvalho Letícia Alves Andrade Marcio Henrique Lima resende José luiz Padilha da Silva Teresa Cristina Abreu Ferrari Universidade Federal de Minas Gerais Faculdade de Medicina Departamento de Clínica Médica Belo Horizonte Brazil

Objective: This study aimed to measure the serum concentrations of several cytokines in patients with infective endocarditis (IE), and correlate them with the C-reactive protein serum levels, echocardiographic findings and infecting microorganisms. Methods: Forty-five patients with definite IE according to the Duke’s criteria were included in the study. Ten healthy blood donors formed the control group. Serum levels of interleukin (IL) 1β, IL-6, IL-8, IL-10, IL-12 and tumor necrosis factor-α (TNF-α) were measured and compared between the groups, and also with some clinical and laboratory parameters of IE. Results: Patients with IE had significantly higher serum concentrations of the inflammatory mediators than the control patients. Median IL-12 and IL-1β levels were higher in staphylococcal than streptococcal IE. Except for TNF-α, the levels of all the other cytokines correlated with the C-reactive protein concentrations. In multivariate analysis, IL-10 and IL-12 serum levels remained as independent factors associated with the C-reactive protein concentrations. There was a significant correlation between IL-10 concentration and vegetation length. Conclusion: The inflammatory serum cytokines levels were elevated in IE in comparison to healthy controls. C-reactive protein concentrations correlated with cytokines levels. IL-1β and IL-12 serum concentrations were higher in staphylococcal when compared to streptococcal IE. IL-10 levels were associated with vegetation size.

关键词： Infective Endocarditis Inflammatory Cytokines C-Reactive Protein

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LUCC （Land Use and Cover Change） and the Environmental-Economic Accounts System in Brazil

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Journal of Earth Science and Engineering 2013年第12期3卷 840-844页

作者： Rodrigo de Campos Macedo Mauricio Zacharias Moreira Eloisa Domingues Angela maria resende Couto Gama Fabio Eduardo de Giusti Sanson Felipe Wolk Teixeira Fernando Peres Dias Femando Yutaka Yamaguchi luiz Roberto de Campos Jacintho National Institute of Spatial Research Seo Jose dos Campos-SP 12227-010 Brazil Brazilian Institute of Geography and Statistics Florianepolis-SC 88015-600 Brazil

The objective of this work is to produce statistics that are going to show changes occurred in Brazil＇s ecosystems and these statistics are going to join the SEEA （Environmental-Economic Accounts System）. It is based by a SEEA＇s methodology, diffused by UN （United Nations）, which aims an approach between economic and environmental statistics, producing international comparability and conceptual uniformity to evaluate change process in land cover and land use that occurs in several countries. It is necessary to verifying the suitability of methodological procedures to Brazilian reality and the access to all information and files needed. The first step was analysing MODIS （Moderate Resolution Imaging Spectroradiometer） as orbital instrument on the purposed classification method. The choice of this sensor was made because of the product＇s quality and its capacity to generate images of a large area, though the challenge is to identify accurate Land usage＇s categories in images with a spatial resolution of approximately 250 m. After the final classification, the next step is to make a quantification and comparison of data from these different years using a 1 km2 grids, as proposed in an already used methodology by the European Environment Agency. This procedure will allow evaluate and identify the process of changing in each grid of the land cover and land use, and provide historical series of the chosen years.

关键词： Remote sensing land use and cover change environmental statistics geoprocessing.

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Phytochemical Screening, Extraction of Essential Oils and Antioxidant Activity of Five Species of Unconventional Vegetables

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American Journal of Plant Sciences 2015年第16期6卷 2632-2639页

作者： Marcos Schleiden Sousa Carvalho maria das Gracas Cardoso Luciane Vilela resende Marcos de Souza Gomes luiz Roberto Marques Albuquerque Anni Cristini Silvestri Gomes Thaís Aparecida Sales Karen Caroline Camargo David Lee Nelson Gabriele Mikami Costa mariana Araújo Espósito Luis Felipe Lima e Silva Department of Agriculture Federal University of Lavras Lavras Brazil Department of Chemistry Federal University of Lavras Lavras Brazil Federal University of Vales de Jequitinhonha e Mucuri Unaí Brazil Federal University of Vales de Jequitinhonha e Mucuri Diamantina Brazil

Unconventional vegetables, in general, are plants that have been largely consumed by the population at some point and, because of changes in eating behavior, now present reduced economic and social expression and have lost ground to other vegetables. The objectives of this study were to perform phytochemical screening of the ethanol extracts of Rumex acetosa L., Tropaeolum majus L., Solanum muricatum, Stachys byzantina K. Koch and Solanum betaceum Cav. and evaluate their antioxidant potentials via the methods involving scavaging of the DPPH free radical and the ABTS radical, phosphomolybdenum and reducing power. In phytochemical screening, five species of unconventional vegetables tested positive for tannins;for sesquiterpene, lactones and other lactones. These tests were positive for Tropaeolum majus L. and Rumex acetosa L., Solanum betaceum Cav. and Solanum muricatum tested negative for steroids. Only Solanum betaceum Cav. gave positive tests for flavonoids. Among the five plant species studied, Stachys byzantina K. Koch presented the greatest antioxidant potential in all the methods evaluated.

关键词： Rumex acetosa L. Tropaeolum majus L. Stachys byzantina K.Koch Reducing Power

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