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Probing the interaction between asphaltene-wax and its effects on the crystallization behavior of waxes in heavy oil via molecular dynamics simulation

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Petroleum Science 2024年第4期21卷 2839-2848页

作者： Yong Hu Xi Lu Hai-Bo Wang Ji-chao fang Yi-Ning Wu Jian fang Sun SINOPEc Petroleum Exploration and Production Research Institute Shandong Key Laboratory of Oilfield chemistry School of Petroleum Engineering China University of Petroleum (East China)

High content of asphaltenes and waxes leads to the high pour point and the poor flowability of heavy oil,which is adverse to its efficient development and its transportation in *** the interaction mechanism between asphaltene-wax is crucial to solve these problems,but it is still *** this paper,molecular dynamics simulation was used to investigate the interaction between asphaltenewax and its effects on the crystallization behavior of waxes in heavy *** show that molecules in pure wax are arranged in a paralleled *** wax molecules in heavy oil,which are close to the surface of asphaltene aggregates,are bent and arranged *** the mass fraction of asphaltenes in asphaltene-wax system(ωasp) is 0-25 wt%,the attraction among wax molecules decreases and the bend degree of wax molecules increases with the increase of ω*** ωaspincreases from 0 to 25 wt%,and the attraction between asphaltene-wax is stronger than that among *** causes that the wax precipitation point changes from 353 to 333 *** the ωaspincreases to 50 wt%,wax molecules are more dispersed owing to the steric hindrance of asphaltene aggregates,and the interaction among wax molecules transforms from attraction to *** causes that the ordered crystal structure of waxes can't be formed at normal ***,the asphaltene,with the higher molecular weight or the more hetero atoms,has more obvious inhibition to the formation of wax ***,resins also have an obvious inhibition on the wax crystal due to the formation of asphalteneresin aggregates with a larger *** results reveal the interaction mechanism between asphaltene-wax,and provide useful guidelines for the development of heavy oil.

关键词： Heavy oil Interaction mechanism Asphaltenes Waxes Molecular dynamics

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The Extended Hybrid carrier-Based Multiple Access Technology for High Mobility Scenarios

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china communications 2024年第1期21卷 53-68页

作者： Ge Song Xiaojie fang Xuejun Sha School of Electronics and Information Engineering Harbin Institute of TechnologyHarbin 150001China

The hybrid carrier(Hc)system rooted in the carrier fusion concept is gradually garnering *** this paper,we study the extended hybrid carrier(EHc)multiple access scheme to ensure reliable wireless *** employing the EHc modulation,a power layered multiplexing framework is realized,which exhibits enhanced interference suppression capability owing to the more uniform energy distribution *** implementation method and advantage mechanism are explicated respectively for the uplink and downlink,and the performance analysis under varying channel conditions is *** addition,considering the connectivity demand,we explore the non-orthogonal multiple access(NOMA)method of the EHc system and develop the EHc sparse code multiple access *** proposed scheme melds the energy spread superiority of EHc with the access capacity of NOMA,facilitating superior support for massive connectivity in high mobility *** results have verified the feasibility and advantages of the proposed *** with existing Hc multiple access schemes,the proposed scheme exhibits robust bit error rate performance and can better guarantee multiple access performance in complex scenarios of nextgeneration communications.

关键词： extended hybrid carrier system high mo-Received:Jun.09,2023 Revised:Nov.20,2023 Editor:Yuanwei Liu bility communications multiple access

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Physical informed memory networks for solving PDEs:implementation and applications

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communications in Theoretical Physics 2024年第2期76卷 51-61页

作者： Jiuyun Sun Huanhe Dong Yong fang college of Mathematics and Systems Science Shandong University of Science and TechnologyQingdao 266590China

With the advent of physics informed neural networks(PINNs),deep learning has gained interest for solving nonlinear partial differential equations(PDEs)in recent *** this paper,physics informed memory networks(PIMNs)are proposed as a new approach to solving PDEs by using physical laws and dynamic behavior of *** the fully connected structure of the PINNs,the PIMNs construct the long-term dependence of the dynamics behavior with the help of the long short-term memory ***,the PDEs residuals are approximated using difference schemes in the form of convolution filter,which avoids information loss at the neighborhood of the sampling ***,the performance of the PIMNs is assessed by solving the Kd V equation and the nonlinear Schr?dinger equation,and the effects of difference schemes,boundary conditions,network structure and mesh size on the solutions are *** show that the PIMNs are insensitive to boundary conditions and have excellent solution accuracy even with only the initial conditions.

关键词： nonlinear partial differential equations physics informed memory networks physics informed neural networks numerical solution

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Intracellular RNA Labeling Technologies for the Analysis of RNA Biology

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chinese Journal of chemistry 2024年第7期42卷 790-801页

作者： Ruiqi Zhao Xin fang Xiaocheng Weng Department of clinical Laboratory Center for Gene DiagnosisDepartment of NeurosurgeryZhongnan Hospital of Wuhan UniversityWuhanHubei 430071China college of chemistryand Molecular Sciences Key Laboratory of Biomedical Polymers-Ministry of EducationWuhan UniversityWuhan Hubei 430072China

As a cornerstone of the central dogma of molecular biology,RNA plays vital roles in living *** the past few decades,many RNA labeling technologies have been developed to elucidate the biological function of *** technologies have signifi-cantly advanced our understanding of RNA secondary structure,localization,and ***,taking advantage of these innovative RNA labeling approaches,plenty of tool kits have been devised for the regulation of RNA-related biological process,such as gene expression and gene *** this review,we primarily focus on an array of intracellular RNA labeling methods,encom-passing chemical probes-based labeling,metabolic labeling,and proximity-dependent *** also provide a brief overview of their applications in the research of RNA ***,the perspectives of RNA labeling are also discussed.

关键词： RNA chemical probes Metabolic labeling Proximity-dependent labeling RNA structures Gene sequencing RNA recognition

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Sufficient conditions for Amalgamated 3-Manifolds to be ∂-Irreducible

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chinese Annals of Mathematics,Series B 2024年第2期45卷 161-172页

作者： Bing fang Fengchun LEI Liang LIANG School of Mathematical Sciences Dalian University of TechnologyDalian 116024LiaoningChina School of Mathematics Liaoning Normal UniversityDalian 116029LiaoningChina

In this paper,the authors give some sufficient conditions for an amalgamated 3-manifold along a compact connected surface F with boundary to be ∂-irreducible in terms of distances between some kinds of vertex subsets ... 详细信息

关键词： ∂-Irreducibility Irreducibility Amalgamated 3-manifold curve complex Arc complex

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Thermo-hydro-mechanical (THM) coupled simulation of the land subsidence due to aquifer thermal energy storage (ATES) system in soft soils

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 1952-1966页

作者： Yang Wang Fengshou Zhang fang Liu Department of Geotechnical Engineering College of Civil EngineeringTongji UniversityShanghai200092China Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education Tongji UniversityShanghai200092China Shanghai Engineering and Technology Research center of Shallow Geothermal Energy Shanghai200072China

Aquifer thermal energy storage(ATES)system has received attention for heating or cooling ***,it is well known that land subsidence becomes a major environmental concern for ATES ***,the effect of temperature on land subsidence has received practically no attention in the *** paper presents a thermo-hydro-mechanical(THM)coupled numerical study on an ATES system in Shanghai,*** water wells were installed for seasonal heating and cooling of an agriculture *** target aquifer at a depth of 74e104.5 m consisted of alternating layers of sand and silty sand and was covered with *** level,temperature,and land subsidence data from 2015 to 2017 were collected using field monitoring *** by data,we constructed a field scale three-dimensional(3D)model using TOUGH(Transport of Unsaturated Groundwater and Heat)and FLAc3D(Fast Lagrangian Analysis of continua)equipped with a thermo-elastoplastic constitutive *** effectiveness of the numerical model was validated by field *** model was used to reproduce groundwater flow,heat transfer,and mechanical responses in porous media over three years and capture the thermo-and pressure-induced land *** results show that the maximum thermoinduced land subsidence accounts for about 60%of the total *** thermo-induced subsidence is slightly greater in winter than that in summer,and more pronounced near the cold well area than the hot well *** study provides some valuable guidelines for controlling land subsidence caused by ATES systems installed in soft soils.

关键词： Aquifer thermal energy storage(ATES) Land subsidence TOUGH-FLAc3D Thermo-elastoplastic constitutive model

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Performance of iron-air battery with iron nanoparticle-encapsulated c-N composite electrode

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Frontiers in Energy 2024年第1期18卷 42-53页

作者： can fang Xiangmei TANG Jiaoyan WANG Qingfeng YI School of chemistry and chemical Engineering Hunan University of Science and TechnologyXiangtan 411201China Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and conversion Xiangtan 411201China

Highly efficient and stable iron electrodes are of great significant to the development of iron-air battery(IAB).In this paper,iron nanoparticle-encapsulated c–N composite(NanoFe@cN)was synthesized by pyrolysis using polyaniline as the c–N *** performance of the NanoFe@cN in different electrolytes(alkaline,neutral,and quasi-neutral)was investigated via cyclic voltammetry(cV).The IAB was assembled with NanoFe@cN as the anode and IrO_(2)+Pt/c as the *** effects of different discharging/charging current densities and electrolytes on the battery performance were also *** K_(2)SO_(4)electrolyte can effectively suppress the passivation of iron electrode,and the battery showed a good cycling stability during 180 charging/discharging *** to the pure nano-iron(NanoFe)battery,the NanoFe@cN battery has a more stable cycling stability either in KOH or NH_(4)cl+Kcl electrolyte.

关键词： energy storage and conversion metallic composites nanocomposites iron-air battery iron anode

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capturability-based Fuzzy Footstep Planner for a Biped Robot with centroidal compliance

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Journal of Bionic Engineering 2024年第1期21卷 84-100页

作者： Zihan Xu Qin fang Yong Ren chengju Liu Robot and Artificial Intelligence Lab(RAIL) College of Electronic and Information EngineeringTongji UniversityShanghai 201804China Applied Technology college Soochow UniversitySuzhou 215000China

compliance motion and footstep adjustment are active balance control strategies from learning human subconscious *** force estimation without direct end-actuator force measurement and the optimal footsteps based on complex analytical calculation are still challenging tasks for elementary and kid-size position-controlled *** this paper,an online compliant controller with Gravity Projection Observer(GPO),which can express the external force condition of perturbations by the estimated Projection of Gravity(PoG)with estimation covariance,is proposed for the realization of disturbance absorption,with which the robustness of the humanoid contact with environments can be *** fuzzy footstep planner based on capturability analysis is proposed,and the Model Predictive control(MPc)is applied to generate the desired *** fuzzification rules are well-designed and give the corresponding control output responding to complex and changeable external *** validate the presented methods,a series of experiments on a real humanoid robot are *** results verify the effectiveness of the proposed balance control framework.

关键词： Biped walking centroidal compliance Gravity projection observer Fuzzy footstep planner

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Kinetic model of vibration screening for granular materials based on biological neural network

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Particuology 2024年第5期88卷 98-106页

作者： Zhan Zhao Yan Zhang fang Qin Mingzhi Jin School of Agricultural Engineering Jiangsu UniversityZhenjiang212013China Shandong Academy of Agricultural Machinery Sciences Ji'nan250100China

The kinetic model is the theoretical basis for optimizing the structure and operation performance of vibration screening *** this paper,a biological neurodynamic equation and neural connections were established according to the motion and interaction properties of the material under vibration *** material feeding to the screen and the material passing through apertures were considered as excitatory and inhibitory inputs,respectively,and the generated stable neural activity landscape was used to describe the material distribution on the 2D screen *** dynamic process of material vibration screening was simulated using discrete element method(DEM).By comparing the similarity between the material distribution established using biological neural network(BNN)and that obtained using DEM simulation,the optimum coefficients of BNN model under a certain screening parameter were determined,that is,one relationship between the BNN model coefficients and the screening operation parameters was *** screening parameters were randomly selected,and the corresponding relationships were established as a ***,with straw/grain ratio,aperture diameter,inclination angle,vibration strength in normal and tangential directions as inputs,five independent adaptive neuro-fuzzy inference systems(ANFIS)were established to predict the optimum BNN model coefficients,*** training results indicated that ANFIS models had good stability and *** flexibility and adaptability of the proposed BNN method was demonstrated by modeling material distribution under complex feeding conditions such as multiple regions and non-uniform rate.

关键词： Kinetic model Material distribution Vibration screening Biological neural network DEM simulation Adaptive neuro-fuzzy inference systems

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Discontinuous phase diagram of amorphous carbons

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National Science Review 2024年第4期11卷 164-171页

作者： YinBo Zhu ZhouYu fang ZhongTing Zhang HengAn Wu cAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern MechanicsUniversity of Science and Technology of China State Key Laboratory of Nonlinear Mechanics Institute of Mechanics Chinese Academy of Sciences

The short-range order and medium-range order of amorphous carbons demonstrated in experiments allow us to rethink whether there exist intrinsic properties hidden by atomic disordering. Here we presented six representative phases of amorphous carbons（0.1–3.4 g/cm3）, namely, disordered graphene network（DGN）, high-density amorphous carbon（HDAc）, amorphous diaphite（a-DG）, amorphous diamond（a-D）, paracrystalline diamond（p-D）, and nano-polycrystalline diamond（NPD）, respectively, classified by their topological features and microstructural characterizations that are comparable with experiments. To achieve a comprehensive physical landscape for amorphous carbons, a phase diagram was plotted in the sp3/sp2versus density plane, in which the counterintuitive discontinuity originates from the inherent difference in topological microstructures, further guiding us to discover a variety of phase transitions among different amorphous carbons. Intriguingly, the power law, log（sp3/sp2） ∝ ρn, hints at intrinsic topology and hidden order in amorphous carbons, providing an insightful perspective to reacquaint atomic disorder in non-crystalline carbons.

关键词： amorphous carbons disordered carbons phase diagram microstructural topology phase transition

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