检索结果-南通市图书馆

Synthesis of luminescent KY_3F_(10) nanopowder multi-doped with lanthanide ions by a co-precipitation method

在线全文

学校读者我要写书评

暂无评论

引用

Journal of Rare Earths 2016年第8期34卷 808-813页

作者： Szymon Goderski marcin runowski Stefan Lis Department of Rare Earths Faculty of Chemistry Adam Mickiewicz University

A series of KY3F10 nanophosphors doped with Gd3＋, Ce3＋ and Eu3＋ ions were obtained with the use of a co-precipitation method. The resulting products were white precipitates, consisting of spherical particles with diameter about 150-200 nm, which was confirmed using transmission electron microscopy （TEM） technique. Powder X-ray diffraction （XRD） and energy dispersive X-ray analysis （EDX） measurements confirmed appropriate structures of the nanoparticles obtained. Spectroscopic properties of the prod- ucts were examined on the basis of the measured excitation/emission spectra and luminescence decay curves. The synthesized sam- ples showed orange-red luminescence, characteristic for Eu3＋ ions. The reaction process was performed in required alkaline pH ad- justed with the use of ethylenediaminetetraacetic acid （EDTA） and potassium hydroxide. The samples containing large amounts of Gd3＋ dooant ions exhibited a tendencv to form nroducts with different momhologies.

关键词： : fluorides co-precipitation nanophosphors luminescence nanopowders Ce3+/Gd3+/Eu3+ doping rare earths

Synthesis, structural and spectroscopic studies on GdBO_3:Yb^(3+)/Tb^(3+)@SiO_2 core-shell nanostructures

在线全文

学校读者我要写书评

暂无评论

引用

Journal of Rare Earths 2015年第11期33卷 1148-1154页

作者： Konrad Kubasiewicz marcin runowski Stefan Lis Agata Szczeszak Department of Rare Earths Faculty of Chemistry Adam Mickiewicz University

The presented study concerned up-converting core/shell type nanomaterials based on lanthanide（Ⅲ） ions, Ln（Ⅲ）, doped orthoborates. The system studied composed of the GdBO3 doped with Yb^3＋/Tb^3＋ luminescent core ensured an effective cooperative sensitization up-conversion, resulting in a bright green luminescence. The silica coating process was performed by a modified St？ber method, which resulted in the formation of core-shell nanostructures, making them suitable for bioapplications. The nanophosphors and nanocomposites were obtained by various methods, such as co-precipitation in the presence of Triton X-100 and micelle synthesis with ethylenediaminetetraacetic acid（EDTA） as organic modifiers/surfactants. The synthesized nanomaterials were characterized with the use of powder X-ray diffraction（XRD）, infrared light absorption with Fourier transform FT-IR spectra, transmission electron microscopy（TEM）, up-conversion emission spectra under IR light, as well as excitation spectra, emission spectra and fluorescence lifetimes under UV light, and their photophysical properties were compared.

关键词： Ln(Ⅲ) ions GdB O3 silica coating core-shell nanocomposites up-conversion cooperative sensitization rare earths

Luminescent-plasmonic core-shell microspheres,doped with Nd3+ and modified with gold nanoparticles,exhibiting whispering gallery modes and SERS activity

在线全文

学校读者我要写书评

暂无评论

引用

Journal of Rare Earths 2019年第11期37卷 1152-1156页

作者： marcin runowski Inocencio R.Martin Vladimir N.Sigaev Vitaliy I.Savinkov Georgiy Yu.Shakhgildyan Stefan Lis Faculty of Chemistry Adam Mickiewicz UniversityUniwersytetu Poznanskiego 861-614 PoznanPoland Departamento de Fisica Instituto de Materiales y Nanotecnologia(IMN)Universidad de La LagunaApdo.456E-38200 San Cristobal de La LagunaSanta Cruz de TenerifeSpain D.Mendeleev University of Chemical Technology Miusskaya Sq.9125047 MoscowRussia

Multifunctional core/shell type,luminescent-plasmonic material composed of lanthanide doped microspheres(≈50μm)and gold nanoparticles(Au NPs;≈10-20 nm)deposited onto their surface,were successfully prepared(Nd^3+:YAS@Au).The material was synthesized to combine the luminescence properties of the Nd^3+-doped microspheres,*** resonance with plasmonic activity of the surface Au NPs,*** enhanced Raman scattering(SERS)effect,within a single,micro-sized *** luminescent-plasmonic microspheres were used as the active SERS substrate for detection of the organic probe,and for generation of Whispering Gallery Modes(WGM),which red-shift together with increasing laser power(temperature elevation).The products obtained were analysed with optical,scanning and transmission electron microscopy(SEM and TEM),as well as by Raman,absorption and photoluminescence spectroscopies.

关键词： Luminescence Gold NPs-SPR Surface enhanced Raman scattering Microsphere resonators-WGM Lanthanide ions Optical sensors