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solar-assisted photocatalytic water splitting using defective UiO-66 solids from modulated synthesis

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Nano Research 2024年第5期17卷 4134-4150页

作者： Celia M.Rueda-Navarro maría Cabrero-Antonino Paula escamilla Valentín Díez-Cabanes Dong Fan Pedro Atienzar Belén Ferrer Ignacio Vayá Guillaume Maurin Herme G.Baldoví sergio Navalón Departamento de Química Universitat Politècnica de ValènciaCamino de Vera s/nValencia 46022Spain Instituto de Ciencia Molecular(ICMOL) Universitat de ValènciaPaterna 46980Spain ICGM Univ.MontpellierCNRSENSCMMontpellier34095France Instituto de Tecnología Química(UPV-CsIC) Universitat Politècnica de ValènciaAvenida de los Naranjos s/nValencia 46022Spain

Metal-organic frameworks(MOFs)are attracting increasing interests as photocatalysts for solar-driven hydrogen production from *** paper reports on a comparative study of using either acetic acid(AA)or trifluoroacetic acid(TFA)as the representative UiO-66 organic modulators for synthesizing visible light responsive UiO-66(Zr)-X(X:NH_(2) or NO_(2))photocatalysts for water *** results show that photocatalytic hydrogen generation from a water/methanol mixture can be improved by varying the nature and amount of the modulator employed to prepare the different UiO-66(Zr)-X(X:NH_(2) or NO_(2))solid ***-66(Zr)-NH_(2) was the most active photocatalyst,followed by UiO-66(Zr)-NO_(2),both prepared with 12 equivalents of AA with respect to the organic *** UiO-66(Zr)-NH_(2) solid was more active than the parent MOF in photocatalytic overall water splitting(OWs)(H_(2) and O_(2) production of 450 and 160μmol·g^(-1),respectively,in 5 h;apparent quantum yield(AQY)at 400 nm of 0.06%)in the absence of methanol and compares favourably with analogous *** on the photocatalytic activity of the most active solids of both series was obtained by means of a series of techniques,including ultraviolet-visible(UV-vis)diffuse reflectance,X-ray photoelectron spectroscopy(XPs),laser flash photolysis(LFP),electron spin resonance(esR),photoluminescence and photoelectrochemical measurements together with density functional theory(DFT)*** results showed that organic acid modulators can be used to enhance the photocatalytic activity of missing linker UiO-66 defective materials in solar-powered water splitting.

关键词： heterogeneous photocatalysis metal-organic frameworks(MOFs) UiO-66 materials carboxylic acid modulators water splitting solar light

evaluation of Clinical Characteristics and Plasma Cortisol Concentrations in Individuals with COVID-19 and Post-COVID syndrome

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Case Reports in Clinical Medicine 2024年第1期13卷 12-24页

作者： David Alejandro García López stephania Ramos Hernández Yamile López-Hernández maría Argelia López Luna elena Donaji Ramírez Alvarado Rosa maría Ramírez santoyo sergio Hugo sánchez Rodríguez Laboratorio de Biología Celular y Neurobiología Universidad Autónoma de Zacatecas México Zacatecas Unidad Académica de Ciencias Químicas Universidad Autónoma de Zacatecas México Zacatecas Laboratorio de Metabolómica y Proteómica Universidad Autónoma de Zacatecas México Zacatecas Laboratorio de Bacterias y Hongos filamentosos Universidad Autónoma de Zacatecas México Zacatecas

COVID-19 generates systematic alterations in humans both in active stages of infection and over time, called post-COVID syndrome. Cortisol is a hormone that is overexpressed in inflammation and cellular stress processes. Its main function is to return to physiological homeostasis, so its evaluation together with other clinical parameters can allow us to determine the degree of systemic affectation by COVID-19. Objective: To evaluate changes in clinical parameters and plasma cortisol concentrations in patients with active COVID-19 and post-COVID syndrome. Material and Methods: Healthy patients, in stages of mild infection, critical and with post-COVID syndrome, were recruited, obtaining, through clinical diagnoses and interviews, their main clinical characteristics, in addition to plasma, in which cortisol concentrations were determined using competitive eLIsA. Results: The critical stage group had higher frequencies of comorbidities, clinical symptoms, as well as more altered laboratory parameters compared to the other subgroups. In the post-COVID syndrome group after the initial infection, most laboratory parameters recovered, however, several clinical symptoms remained latent over time. The determination of cortisol showed an increase in its concentration, being higher in patients in critical stage and with post-COVID syndrome. Conclusion: COVID-19 disease generates clinical alterations that trigger an increase in plasma cortisol. These alterations increase as the stages of infection become more severe and some of them remain altered in patients with post-COVID syndrome.

关键词： COVID-19 Cortisol Post-COVID syndrome

北美生活用纸市场重回正轨及面临的变化与挑战

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生活用纸 2024年第10期24卷 75-78页

作者： sanna sosa soile Kilpi AFRY管理咨询公司

行业变化在北美地区,生活用纸产品的需求增长已从之前新冠疫情期间的恐慌性抢购中稳定下来,并重新回到疫情前的轨道上。在2020年和2021年因新冠疫情出现需求激增之后,2022年和2023年,居家用生活用纸的需求量稳定在710万t左右,比疫情前... 详细信息

行业变化在北美地区,生活用纸产品的需求增长已从之前新冠疫情期间的恐慌性抢购中稳定下来,并重新回到疫情前的轨道上。在2020年和2021年因新冠疫情出现需求激增之后,2022年和2023年,居家用生活用纸的需求量稳定在710万t左右,比疫情前的年需求量水平高出4.5%。居家办公和对清洁与卫生的关注使居家用生活用纸的需求提升,超过了疫情前的消费水平。

关键词：消费水平生活用纸需求激增北美地区抢购疫情居家

effect of eu3+,Bi3+,and Li+ doping on luminescent property of GdNbO4

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Journal of Rare earths 2024年第1期42卷 66-75页

作者： s.W.Wi Y.s.Lee Department of Physics and Integrative Institute of Basic sciences Soongsil University

We investigated the emission properties of eu3+-doped GdNbO4-based oxide phosphors,aiming at improving the eu3+emission by codoping of Bi3+and Li+.eu3+singly doped,eu3+and Bi3+doubly doped,and eu3+,Bi3+,and Li+triply doped GdNbO4were prepared using a high-temperature solid-state reaction *** red-orange emissions from eu3+in the singly doped samples are significantly improved by the codoping of Bi3+,mainly due to the energy transfer from Bi3+to eu3+.The additional codoping of Li+is found to increase the eu3+emission *** improvement might be attributed to the increase in the photoluminescent quantum yield originating from larger grain sizes and better crystallinity.A detailed analysis of the X-ray diffraction pattern and the asymmetric ratio estimated from the photoluminescence spectra show that the local lattice environment around eu3+in GdNbO4does not change significantly with the codoping of Bi3+and Li+.Our results indicate that Li+doping is a promising way to improve the emission properties of rare-earth ion-doped GdNbO4phosphors.

关键词： eu 3+ GdNbO 4 Codoping of Li + Photoluminescence sensitizer Rare earths

enhancing high-temperature oxidation resistance(at 1000 °C) of nickel superalloy obtained by laser powder bed fusion via reactive electric spark treatment

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Transactions of Nonferrous Metals society of China 2024年

作者： s.K.MUKANOV M.I.PeTRZHIK A.e.KUDRYAsHOV e.A.NAUMOVA F.A.BAsKOV P.A.LOGINOV e.A.LeVAsHOV National University of science and Technology MIsIs

The high-temperature oxidation resistance of the nickel superalloy grown by the Laser Powder Bed Fusion (LPBF) has been significantly increased as a result of in-situ formation of a thermal barrier layer (α-Al2O3+ CaMoO4) during oxidative annealing of surface layers modified by electric spark treatment (esT). The reactive esT of the LPBF-built items based on nickel eP741NP alloy was carried out with low-melting Al-12%si， Al-6%Ca-0.6%si and Al-7%Ca-1%Mn electrodes. It was found that at esT done by Al-7%Ca-1%Mn electrode an intermetallic (β-NiAl + γ’-Ni3Al) 15 microns thick layer reinforced by spherical oxide (CaMe)O nanoparticles was formed. Formation of that structure increases the wear resistance of LPBF nickel superalloy by 4.5 times. Further oxidative annealing at 1000 °C lead to a formation of continuous two-layered coating with an inner layer of α-Al2O3and an outer layer of CaMoO4， which together act as an effective barrier preventing the diffusion of oxygen into the volume of the superalloy.

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FsCIL-eACA: Few-shot Class-Incremental Learning Network Based on embedding Augmentation and Classifier Adaptation for Image Classification

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Chinese Journal of electronics 2024年第1期33卷 139-152页

作者： Ruru ZHANG Haihong e Meina sONG school of Computer science Beijing University of Posts and Telecommunications education Department Information Network engineering Research Center Beijing University of Posts and Telecommunications

The ability to learn incrementally is critical to the long-term operation of AI systems. Benefiting from the power of few-shot class-incremental learning(FsCIL), deep learning models can continuously recognize new classes with only a few samples. The difficulty is that limited instances of new classes will lead to overfitting and exacerbate the catastrophic forgetting of the old classes. Most previous works alleviate the above problems by imposing strong constraints on the model structure or parameters, but ignoring embedding network transferability and classifier adaptation(CA), failing to guarantee the efficient utilization of visual features and establishing relationships between old and new classes. In this paper, we propose a simple and novel approach from two perspectives: embedding bias and classifier bias. The method learns an embedding augmented(eA) network with cross-class transfer and class-specific discriminative abilities based on self-supervised learning and modulated attention to alleviate embedding bias. Based on the adaptive incremental classifier learning scheme to realize incremental learning capability,guiding the adaptive update of prototypes and feature embeddings to alleviate classifier bias. We conduct extensive experiments on two popular natural image datasets and two medical datasets. The experiments show that our method is significantly better than the baseline and achieves state-of-the-art results.

关键词： Training Adaptation models Visualization Image recognition Prototypes self-supervised learning Power capacitors

Mast cell activation syndrome:An up-to-date review of literature

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World Journal of Clinical Pediatrics 2024年第2期13卷 104-113页

作者： ÖnerÖzdemir Gökçe Kasımoğlu Ayşegül Bak Hüseyin sütlüoğlu süreyya savaşan Department of Pediatric Allergy and Immunology Sakarya UniversitySakaryaAdapazarı54100Türkiye Department of Pediatrics Sakarya UniversitySakaryaAdapazarı54100Türkiye Department of Pediatrics Kocaeli City HospitalKocaeli 50123Türkiye Department of Pediatrics Children’s Hospital of MichiganHematology/OncologyCentral Michigan University College of MedicineMount PleasantMI 48859United States Barbara Ann Karmanos Cancer Institute Wayne State UniversityDetroitMI 12345United States

Mast cells are a subtype of white blood cells and are involved in the immune *** cells contain many chemical substances called mediators,which are involved in the allergic *** fact that mast cells play a role in many events that require urgent intervention,especially anaphylaxis,has led to a more detailed study of these *** diseases also caused by dysfunctions of mast cells have been examined in many *** instance,mast cell activation syndrome is known as an augmented number of cells due to decreased cell death,resulting in clinical symptoms affecting many *** main common symptoms include flushing,hypotension,urticaria,angioedema,headache,vomiting and *** the underlying mechanism is not yet clearly known,we aim to review the literature in a broad perspective and bring together the existing knowledge in the light of the literature due to the diversity of its involvement in the body and the fact that it is a little known syndrome.

关键词： Mast cell Mast cell activation syndrome Tryptase Histamine

The effect of the concentration of plastic waste on the formation of reaction products of the Ti–PeT system

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Blast injury risks to humans within a military trench

Green Chemical engineering 2024年第3期5卷 374-382页

作者： Aleksey e.Matveev Tomsk scientific Center of the siberian Branch of the Russian Academy of sciences

The paper presents research results of the synthesis, phase composition, and structure of products obtained by highly exothermic reactions between Ti and C10H8O4mixture components, depending on the plastic waste concentration and Ti powder dispersiveness, density of initial samples, and synthesis medium. The dependence of the phase composition and structure of the synthesis products on the concentration of the polymer（plastic）component in the initial Ti-PeT(C10H8O4) system was found. When the plastic waste content is 20 wt% to 25 wt%, synthesis products contain TiC0.5O0.5–TiC0.6–0.75particle agglomerates. Further growth in the polyethylene terephthalate content from 30 wt% to 45 wt% leads to the formation of synthesis products consisting of titanium carbide(TiC0.6–1.0). The gaseous byproduct composition of the exothermic reaction is investigated for the Ti–-C10H8O4mixture composition. It is found that the gaseous by-product mostly contains hydrogen and carbon monoxide as well as impurities of different hydrocarbons（methane, acetylene, ethane, ethene） and carbon dioxide. The maximum adiabatic temperature of the gas combustion temperature is 2080℃, which demonstrates the possibility of using gas as a fuel for energy generation devices. Based on the data obtained, it is possible to create a basis for a new plastic waste technology to fabricate carbide-containing materials.

关键词： Plastic waste Titanium carbide Green technology Hydrogen synthesis

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Defence Technology（防务技术） 2024年第10期40卷 91-104页

作者： Idan e.edri National Building Research Institute Technion-Israel Institute of TechnologyTechnion CityHaifa 32000Israel

In land warfare,trenches serve as vital defensive fortifications,offering protection to soldiers while engaging in ***,despite their protective function,soldiers often sustain injuries within these *** lack of corresponding blast data alongside empirical injury reports presents a significant knowledge gap,particularly concerning the blast pressures propagating within trench spaces following nearby *** absence hinders the correlation between blast parameters,trench geometry,and reported injury cases,limiting our understanding of blast-related risks within *** paper addresses the critical aspect of blast propagation within trench systems,essential for evaluating potential blast injury risks to individuals within these *** advanced computational fluid dynamics(CFD)simulations,the study comprehensively investigates blast injury risks resulting from explosions near military *** a sophisticated computational model,the research analyzes the dynamic blast effects within trenches,considering both geometrical parameters and blast characteristics influenced by explosive weight and scaled *** numerical simulations yield valuable insights into the impact of these parameters on blast injury risks,particularly focusing on eardrum rupture,lung injury,and traumatic brain injury levels within the *** findings elucidate distinct patterns of high-risk zones,highlighting unique characteristics of internal explosions due to confinement and venting dynamics along the *** study underscores the significance of detailed numerical modeling in assessing blast injury risks and provides a novel knowledge base for understanding risks associated with explosives detonating near military *** insights gained contribute to enhancing safety measures in both military and civilian contexts exposed to blast events near trench structures.

关键词： Trench Blast Injury risk eardrum rupture Lung injury Traumatic brain injury

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