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Structure and defect dual-engineering of cobalt oxides for lowtemperature Zn-air batteries

Nano Research 2024年第5期17卷 4108-4117页

作者： Hang Lei Zhuowen Huangfu Liangjun Chen Xuelin Yang Zilong Wang wenjie mai Hubei Provincial Collaborative Innovation Center for New Energy Microgrid College of Electrical Engineering&New EnergyChina Three Gorges UniversityYichang 443002China Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632China

The exploration of bifunctional electrocatalysts with high catalytic activity and long-term durability for low-temperature Zn-air batteries(ZABs)is an ongoing ***,quintet-shelled hollow spheres,P-doped multi-layer Co_(3)O_(4)(PM-Co_(3)O_(4)),with enriched oxygen vacancies are prepared by thermally induced mass relocation and a simple phosphating *** advanced characterizations reveal P anion-induced effects on internal electronic structure and local coordination *** finite element method elucidates that the complex multi-layer spherical nanostructure is conducive to the transport and diffusion of OH-and O_(2).Benefiting from its unique structural features and abundant oxygen vacancies,the well-designed PM-Co_(3)O_(4) presents small reversible oxygen overpotential for catalyzing oxygen reduction/evolution ***,the fabricated low-temperature ZABs based on PM-Co_(3)O_(4) as air-cathode exhibit high power density(20.8 mW·cm^(-2))and long-term stability(over 600 cycles)at the ultra-low temperature of-40℃,outperforming state-of-art Pt/C+IrO_(2)-based ***,the dynamic evolution mechanism of cobalt oxide catalysts during ZAB operation is *** work provides a guideline to design efficient electrocatalysts with regulated electronic configurations and exquisite nano-/microstructures for ZABs under extreme working conditions.

关键词： Zn-air batteries electrocatalysts low temperature hollow spheres oxygen vacancies

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Online soft measurement for wastewater treatment system based on hybrid deep learning

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Frontiers of Environmental Science & Engineering 2024年第2期18卷 77-89页

作者： wenjie mai Zhenguo Chen Xiaoyong Li Xiaohui Yi Yingzhong Zhao Xinzhong He Xiang Xu Mingzhi Huang SCNU Environmental Research Institute Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of EnvironmentSchool of EnvironmentSouth China Normal UniversityGuangzhou 510006China Fujian Environmental Protection Design Institute Co.Ltd. Fuzhou 350000China Huashi(Fujian)Environment Technology Co.Ltd. Quanzhou362001China SCNU Qingyuan Institute of Science and Technology Innovation Co.Ltd. Qingyuan 511517China Econ Technology Co.Ltd. Yantai 265503China

The existing automated wastewater treatment control systems encounter challenges such as the utilization of specialized testing instruments, equipment repair complications, high operational costs, substantial operational errors, and low detection accuracy. An effective soft measure model offers a viable approach for real-time monitoring and the development of automated control in the wastewater treatment process. Consequently, a novel hybrid deep learning CNN-BNLSTM-Attention (CBNLSMA) model, which incorporates convolutional neural networks (CNN), bidirectional nested long and short-term memory neural networks (BNLSTM), attention mechanisms (AM), and Tree-structure Parzen Estimators (TPE), has been developed for monitoring effluent water quality during the wastewater treatment process. The CBNLSMA model is divided into four stages: the CNN module for feature extraction and data filtering to expedite operations;the BNLSTM module for temporal data’s temporal information extraction;the AM module for model weight reassignment;and the TPE optimization algorithm for the CBNLSMA model’s hyperparameter search optimization. In comparison with other models (TPE-CNN-BNLSTM, TPE-BNLSTM-AM, TPE-CNN-AM, PSO-CBNLSTMA), the CBNLSMA model reduced the RMSE for effluent COD prediction by 25.4%, decreased the MAPE by 32.9%, and enhanced the R2 by 14.9%. For the effluent SS prediction, the CBNLSMA model reduced the RMSE by 26.4%, the MAPE by 21.0%, and improved the R2 by 35.7% compared to other models. The simulation results demonstrate that the proposed CBNLSMA model holds significant potential for real-time effluent quality monitoring, indicating its high potential for automated control in wastewater treatment processes.

关键词： Prediction model Soft measurement CNN-BNLSTM-AM model TPE optimization algorithm

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In situ induced cation-vacancies in metal sulfides as dynamic electrocatalyst accelerating polysulfides conversion for Li-S battery

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Journal of Energy Chemistry 2022年第12期75卷 74-82,I0003页

作者： Rongrong Li Hao Sun Caiyun Chang Yuan Yao Xiong Pu wenjie mai Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632GuangdongChina CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro-Nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 101400China State Key Laboratory of Power Transmission Equipment and System Security and New Technology School of Electrical EngineeringChongqing UniversityChongqing 400044China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Cation vacancy engineering is considered to be one of the effective methods to solve the issues of shuttling and sluggish redox kinetics of Li PSs owing to the intrinsic tunability of electronic ***,cation vacancies are few studied in the Li-S realm due to their complex and rigid preparation *** this work,one-step pyrolysis is reported to in situ introduce Fe-vacancies into iron sulfide(Fe_(0.96)S)as a sulfur *** this host structure,Fe_(0.96)S is first employed as an adsorbent and catalyst in Li-S *** the carbonization process,a tight contact structure of Fe_(0.96)S crystal and carbon network(Fe_(0.96)S@C)is in situ constructed,and the carbon layer as a conductor provides smooth electrons transfer pathways for redox ***,due to the introduction of Fe-vacancies in Fe S crystal,the adsorption capability and catalytic effect for Li PSs have been substantially ***,the presence of Fe_(0.96)S crystal favors the mobility of electron and diffusion of Li+,which is revealed by the experiments and theoretical *** synergy respective advantages effect of Fe_(0.96)S and carbon,the Fe_(0.96)S@C-S cathode delivers high-rate capability at 5.0 C and stable long-life *** under a high sulfur loading of 3.5 mg/cm^(2),the durable cyclic stability is still exhibited with the capacity retention of 93%over 400 cycles at 1.0 C,and the coulombic efficiency is≥98%.Noting that this strategy greatly simplifies the synthetic process of currently known cation-vacancy materials and furnishes a universal mentality for designing both divinable and astonishing new cation-vacancy materials.

关键词： Cation vacancy Fe_(0.96)S@C structure Catalytic conversion Lithium-sulfur battery

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Manipulating Interfacial Stability Via Absorption-Competition Mechanism for Long-Lifespan Zn Anode

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Nano-Micro Letters 2022年第2期14卷 161-173页

作者： Meijia Qiu Liang Ma Peng Sun Zilong Wang Guofeng Cui wenjie mai Key Laboratory for Polymeric Composite&Functional Materials of Ministry of Education School of ChemistryKey Laboratory of Low-Carbon Chemistry&Energy Conservation of Guangdong ProvinceSun Yat-Sen UniversityGuangzhou 510275People’s Republic of China Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsGuangzhou Key Laboratory of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangdong 510632People’s Republic of China

The stability of Zn anode in various Znbased energy storage devices is the key problem to be ***,aromatic aldehyde additives are selected to modulate the interface reactions between the Zn anode and *** comprehensively considering electrochemical measurements,DFT calculations and FEA simulations,novel mechanisms of one kind of aromatic aldehyde,veratraldehyde in inhibiting Zn dendrite/by-products can be *** additive prefers to absorb on the Zn surface than H_(2)O molecules and Zn^(2+),while competes with hydrogen evolution reaction and Zn plating/stripping proces s via redox reactions,thus preventing the decomposition of active H_(2)O near the interface and uncontrollable Zn dendrite growth via a synactic absorption-competition *** a result,Zn-Zn symmetric cells with the veratraldehyde additive realize an excellent cycling life of 3200 h under 1 mA cm^(-2)/1 mAh cm^(-2)and over 800 h even under 5 mA cm^(-2)/5 mAh cm^(-2).Moreover,Zn-Ti and Zn-MnO_(2)cells with the veratraldehyde additive both obtain elevated performance than that with pure ZnSO_(4)***,two more aromatic aldehyde additives are chosen to prove their universality in stabilizing Zn anodes.

关键词： Aromatic aldehyde Absorption-competition mechanism Zn anode Interfacial stability

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Self-powered and broadband germanium/PEDOT:PSS heterojunction photodetectors for near-infrared biomedical imaging applications

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Science China(Technological Sciences) 2021年第11期64卷 2523-2531页

作者： WU QiuYue LIU YuJin HUANG XinYue ZHENG Xu HE JieZhong JI Zhong mai wenjie Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632China

To develop high-performance photodetectors(PDs) as near-infrared(NIR) imaging sensors, researchers have either proposed new photoelectric materials, introduced complicated interface-processing steps, or created complex optical structures. In this study, we introduce a solution-processed organic material, PEDOT:PSS(PEDOT corresponds to a polymer of 3,4-ethylene dioxythiophene(EDOT), and PSS corresponds to a polystyrene sulfonate), to germanium(Ge) wafers using a convenient spincoating method to improve the photoresponse performance of Ge-based PDs. The Ge wafers and PEDOT:PSS form a heterojunction that reduces the dark current when compared with the Ge Schottky PD(Au/Ge/Ag PD). The experimental results show that the Au/PEDOT:PSS/Ge/Ag heterojunction PD with a bias voltage of 0 V at 1550 nm exhibits a responsivity(R) of 0.26 A/W,a detectivity(D*) of 6.5×1011 Jones, a linear dynamic range(LDR) of 124 d B, and a bandwidth(-3 dB) of 10 k Hz. This implies that the performance of the PD is comparable to that of previously reported Ge-based PDs. Subsequently, a biomedical imaging application of the PD is successfully demonstrated through foreign-body detection. Therefore, it is expected that the selfpowered Au/PEDOT:PSS/Ge/Ag PD will be highly suitable for NIR imaging.

关键词： gemanium photodetectors PEDOT:PSS heterojunction self-powered photodetectors near-infrared biomedical imaging

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Graphite Anode for Potassium Ion Batteries: Current Status and Perspective

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Energy & Environmental Materials 2022年第2期5卷 458-469页

作者： Xiaodan Li Jinliang Li Liang Ma Caiyan Yu Zhong Ji Likun Pan wenjie mai Department of Physics Siyuan LaboratoryGuangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsJinan UniversityGuangzhou 510632China nternational Joint Laboratory of Renewable Energy Materials and Devices of Henan Province School of Physics&ElectronicsHenan UniversityKaifeng 475004China Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200062China

With the increased demand from the storage of renewable energy sources,some safe and inexpensive energy storage technologies instead of Li-ion batteries become urgently ***,K-ion batteries(KIBs)have attracted much attention and evolved significant development because of the low price,safety,and similar property compared with Li-ion *** to the high reversibility,stability,and low potential plateau,graphite becomes a current research focus and is regarded as one of the most promising KIB’s anode *** this review,we mainly discuss the electrochemical reaction mechanism of graphite during potassiation-depotassiation process and analyze the effects of electrode/electrolyte interface on graphite for Kion ***,we summarize several kinds of methods to improve the performance of graphite for KIBs,including the design of graphite structure,selection of appropriate binder,solvent chemistry,and salt ***,a concept of“relative energy density”is raised,which can be more accurate to evaluate the genuine electrochemical performance of graphite anode involving the specific capacity and *** addition,we also summarize the considerable challenges to current graphite anode in KIBs and we believe our work will offer alterative solutions to further explore high-performance graphite anode of K-ion storage.

关键词： electrochemical reaction mechanism graphite anode K-ion batteries methods to improve performance

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甲状腺癌“低位领”式与“L”型切口淋巴结清扫术的比较

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实用癌症杂志 2024年第4期39卷 554-557页

作者：李旭张建辉买文洁叶晓红河南省郑州市第二人民医院 450000

目的比较“低位领”式与“L”型切口淋巴结清扫术治疗甲状腺癌的临床效果。方法选取80例甲状腺癌患者,按随机数字表法分为2组,各40例。对照组采取“L”型切口淋巴结清扫术,观察组施行“低位领”式淋巴结清扫术,观察至术后3个月。对比2... 详细信息

目的比较“低位领”式与“L”型切口淋巴结清扫术治疗甲状腺癌的临床效果。方法选取80例甲状腺癌患者,按随机数字表法分为2组,各40例。对照组采取“L”型切口淋巴结清扫术,观察组施行“低位领”式淋巴结清扫术,观察至术后3个月。对比2组手术相关指标、切口满意度、颈肩部疼痛程度与心理状态、生活质量、并发症。结果观察组术中出血量[(40.53±4.26)ml]少于对照组[(58.75±6.31)ml],手术时间[(118.79±10.53)min]与住院时间[(6.35±1.03)d]短于对照组[(146.35±12.69)min、(9.42±1.69)d],切口满意度[95.00%(38/40)]高于对照组[80.00%(32/40)],视觉模拟疼痛评估量表(VAS)评分[(3.56±0.48)分]与焦虑自评量表(SAS)评分[(39.46±4.33)分]、抑郁自评量表(SDS)评分[(40.63±5.20)分]低于对照组[(5.23±0.79)分、(47.53±6.36)分、(48.56±6.48)分],有统计学差异(P0.05)。结论与“L”型切口相比,“低位领”式淋巴结清扫术治疗甲状腺癌效果更佳,术中出血量更少,手术及术后住院时间更短,并能够减轻患者颈肩部疼痛,改善心理状态及生活质量,且无严重并发症。

关键词：淋巴结清扫术甲状腺癌 “低位领”式切口 “L”型切口疼痛程度并发症

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In Situ Monitoring the Potassium‑Ion Storage Enhancement in Iron Selenide with Ether‑Based Electrolyte

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Nano-Micro Letters 2021年第11期13卷 294-307页

作者： Xiaodan Li Jinliang Li Wenchen Zhuo Zhibin Li Liang Ma Zhong Ji Likun Pan wenjie mai Siyuan Laboratory Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy MaterialsGuangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New MaterialsDepartment of PhysicsJinan UniversityGuangzhouGuangdong 510632People’s Republic of China Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241People’s Republic of China

As one of the promising anode materials,iron selenide has received much attention for potassium-ion batteries(KIBs).Nevertheless,volume expansion and sluggish kinetics of iron selenide result in the poor reversibility and stability during potassiation–depotassiation *** this work,we develop iron selenide composite matching ether-based electrolyte for KIBs,which presents a reversible specific capacity of 356 mAh g^(−1) at 200 mA g^(−1) after 75 *** to the measurement of mechanical properties,it is found that iron selenide composite also exhibits robust and elastic solid electrolyte interphase layer in ether-based electrolyte,contributing to the improvement in reversibility and stability for *** further investigate the electrochemical enhancement mechanism of ether-based electrolyte in KIBs,we also utilize in situ visualization technique to monitor the potassiation–depotassiation *** comparison,iron selenide composite matching carbonate-based electrolyte presents vast morphology change during potassiation–depotassiation *** changing to ether-based electrolyte,a few minor morphology changes can be *** phenomenon indicates an occurrence of homogeneous electrochemical reaction in ether-based electrolyte,which results in a stable performance for potassium-ion(K-ion)*** believe that our work will provide a new perspective to visually monitor the potassium-ion storage process and guide the improvement in electrode material performance.

关键词： Iron selenide Ether-based electrolyte In situ visualization technique Potassium-ion batteries

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Coordination and interface engineering to boost catalytic property of two-dimensional ZIFs for wearable Zn-air batteries

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Journal of Energy Chemistry 2022年第5期31卷 78-86页

作者： Hang Lei Shangjing Yang Qixiang Wan Liang Ma Muhammad Sufyan Javed Shaozao Tan Zilong Wang wenjie mai Guangdong Engineering&Technology Research Centre of Graphene-Like Materials and Products Department of ChemistryCollege of Chemistry and Materials ScienceJinan UniversityGuangzhou 510632GuangdongChina Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632GuangdongChina School of Physical Science and Technology Lanzhou UniversityLanzhou 730000GansuChina

Metal organic frameworks(MOFs) have been considered as compelling precursor for miscellaneous applications. However, their unsatisfied electrocatalytic performance limits their direct application as electrocatalyst. Herein, by incorporating the cobalt-oxide bonds and polyaniline(PANI) with two-dimension zeolitic imidazolate frameworks(ZIFs), a novel bifunctional catalyst(Co-O-ZIF/PANI) for Zn-air battery was designed based on a facile and eco-friendly method. This Co-O-ZIF/PANI with optimized surface adsorption effect and suitable Co^(3+)/Co^(2+)ratio, exhibits eminent electrocatalytic activity toward both oxygen reduction and evolution reaction. The as-assembled liquid ZABs based on Co-O-ZIF/PANI achieves a remarkable maximum power density of 123.1 m W cm^(-2) and low discharge-charge voltage gap of 0.81 V at 5 m A cm^(-2) for over 300 cycles. Operando Raman spectroscopy reveals that the excellent performance origins from the optimized surface chemisorption property of O_(2) and H_(2)O brought by Co–O bonds and PANI. This work provides a novel prospect to develop efficient MOF derived bifunctional electrocatalysts by optimizing surface chemisorption properties.

关键词： Zn-air batteries Wearable batteries Bifunctional electrocatalyst Operando Raman Zeolitic imidazolate frameworks

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All-inorganic lead-free NiO_(x)/Cs_(3)Bi_(2)Br_(9) perovskite heterojunction photodetectors for ultraviolet multispectral imaging

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Nano Research 2022年第2期15卷 1094-1101页

作者： Yujin Liu Yuxin Gao Jingyi Zhi Rongqing Huang Wanjun Li Xinyue Huang Genghua Yan Zhong Ji wenjie mai Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632China.

Bismuth-based perovskites are considered to be promising candidates to substitute the toxic lead-based perovskite in optoelectronics due to their excellent optoelectronic properties,high environmental friendliness,and(moisture,light,and heat)***,there are still few reports about high performance bismuth-based perovskite ultraviolet photodetectors,and is more lacking in ultraviolet imaging ***,we reported a self-powered NiO_(x)/Cs_(3)Bi_(2)Br_(9) heterojunction photodetector with excellent photodetection performance by electrochemical depositing NiOx as the hole transport *** optimized NiO_(x)/CsaBi_(2)Brg heterojunction photodetector exhibits excellent ultraviolet detection performance with a fast response speed of 3.04/4.65 ms,wide linear dynamic range of 116.6 dB,decent responsivity of 4.33 mA·W^(-1) at 0 V bias,and high detectivity of 1.3×10^(11) *** outstanding performance of the optimized NiO_(x)/Cs_(3)Bi_(2)Br_(9) heterojunction photodetector is enough to meet the high-quality ultraviolet ***,we further integrated the optimized NiO_(x)/Cs_(3)Bi_(2)Br_(9) heterojunction photodetector to the transmission mode ultraviolet multispectral imaging system,achieving admirable imaging results at weak light *** work will play a positive role in promoting the development of bismuth-based ultraviolet photodetection and ultraviolet multispectral imaging.

关键词： bismuth perovskites heterojunction photodetectors multispectral imaging

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