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Impact of Polymer matrix.on Polymer Mechanochromism from Ex.ited State Intramolecular Proton Transfer

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Chinese Journal of Chemistry 2024年第6期42卷 611-616页

作者： Yu Wu x.n Cheng Huan Hu Shui Hu Zhimin ma Zhiyong ma Beijing Advanced Innovation Center for Soft matter Science and Engineering Beijing State Key Laboratory of Organic-Inorganic CompositesCollege of Chemical EngineeringBeijing University of Chemical TechnologyBeijing100029 China Center of Advanced Elastomer materials College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing100029 China College of Engineering Peking UniversityBeijing100871 China

Mechanochromic polymers based on non-covalent changes have attracted much attention ***,we report the impact of inter/intramolecular hydrogen bonds on polymer mechanochromism from the ex.ited state intramolecular proton transfer (ESIPT) ***-NH2-OH and PhMz=2A are designed and obtained by simple and high-yield synthesis,and are connected into polyurethane and poly(methyl acrylate-co-2-ethylhex.l acrylate),*** the initial state,the PhMz-NH2-OH@PU sample shows blue fluorescence from the ex.ited enol form (E*) ex.itons,owing to intermolecular hydrogen bonds that interrupt the ESIPT reactions but the PhMz=2A@Pma-2-EA sample ex.resses cyan fluorescence belonging to the ex.ited keto form (K*) emission,implying that the intramolecular hydrogen bonds ***,under stretching,ex.ernal force can tune the emission of the PhMz=2A@Pma-2-EA sample from K* to E* *** ex.ernal force can putatively still promote a bond rotation,ESIPT reactions remain equivalently interrupted in both the relax.d and stressed states in a hydrogen-bond donating *** calculation confirms the force-induced increase in dihedral angle for the transition of ESIPT-on/***,PhMz-NH2-OH@PU and PhMz=2A@Pma-2-EA showed disparate initial ESIPT states and further different responses/sensitivity to *** study reports a novel and efficient strategy for enriching mechanochromic investigation and ex.ending the applications of ESIPT reactions.

关键词： Polymer mechanochromism Ex.ited state intramolecular proton transfer Hydrogen bonding Supramolecular chemistry Elastomers

A rigorous real-time acoustic positioning method for ocean bottom seismic ex.loration

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Satellite Navigation 2024年第1期5卷 168-190页

作者： Jinye ma Shouchuan Fang Jianhu Zhao School of Geodesy and Geomatics Wuhan University129 Luoyu RoadWuhan430079China Institute of marine Science and Technology Wuhan UniversityWuhan430079China Surveying Service Center BGP Inc.CNPCZhuozhou072751HebeiChina

The conventional technique for positioning seafloor geophones in ocean bottom seismic ex.loration encounters several challenges,including the significant impact of outliers on positioning results,underutilization of high-precision observations,and low efficiency in real-time data *** issues inevitably affect the quality of seismic ex.loration *** address these challenges and enhance the accuracy of geophone positioning,this paper proposes a rigorous real-time acoustic positioning method for geophones based on sequential adjustment and Baarda's outlier detection *** proposed method comprises three key steps:grouping the original acoustic observations,constructing the intra-group acoustic positioning model,and synthesizing the positioning results across the different *** validity and practicality of this approach are confirmed through a simulation ex.eriment as well as the field ex.eriment conducted in the Bohai Sea,*** results demonstrate that the proposed method effectively eliminates outliers in the original observations and max.mizes the utilization of high-quality *** to traditional acoustic positioning methods,it significantly reduces positioning errors from meters to decimeters,and in some cases can achieve centimeter-level *** the sound velocity profile in the operating sea area is measured,the method can attain the posterior standard deviation at the millimeter level and positioning errors within 10 *** the sound velocity profile is unknown,the method can achieve the posterior standard deviation at centimeter-level and positioning errors of approx.mately 20 cm.

关键词： Ocean bottom seismic ex.loration Geophone positioning Acoustic positioning method Sequential adjustment Outlier detection

A Parameter Adaptive Method for Image Smoothing

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Tsinghua Science and Technology 2024年第4期29卷 1138-1151页

作者： Suwei Wang x.ang ma x.emei Li School of Computer Science and Technology Shandong UniversityJinan 250101China School of Software Shandong UniversityJinan 250101China

Edge is the key information in the process of image smoothing. Some edges, especially the weak edges, are difficult to maintain, which result in the local area being over-smoothed. For the protection of weak edges, we propose an image smoothing algorithm based on global sparse structure and parameter adaptation. The algorithm decomposes the image into high frequency and low frequency part based on global sparse structure. The low frequency part contains less tex.ure information which is relatively easy to smoothen. The high frequency part is more sensitive to edge information so it is more suitable for the selection of smoothing parameters. To reduce the computational complex.ty and improve the effect, we propose a bicubic polynomial fitting method to fit all the sample values into a surface. Finally, we use Alternating Direction Method of Multipliers (ADMM) to unify the whole algorithm and obtain the smoothed results by iterative optimization. Compared with traditional methods and deep learning methods, as well as the application tasks of edge ex.raction, image abstraction, pseudo-boundary removal, and image enhancement, it shows that our algorithm can preserve the local weak edge of the image more effectively, and the visual effect of smoothed results is better.

关键词： image smoothing parameter adaptation bicubic interpolation polynomial fitting

Bionic soft robotic gripper with feedback control for adaptive grasping and capturing applications

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Frontiers of Mechanical Engineering 2024年第1期19卷 129-148页

作者： Tingke WU Zhuyong LIU Ziqi ma Boyang WANG Daolin ma Hex. YU Department of Engineering Mechanics School of Ocean and Civil EngineeringShanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Ocean Engineering Shanghai Jiao Tong UniversityShanghai 200240China MOE Key Laboratory of Hydrodynamics Shanghai Jiao Tong UniversityShanghai 200240China

Robots are playing an increasingly important role in engineering *** robots have promising applications in several fields due to their inherent advantages of compliance,low density,and soft interactions.A soft gripper based on bio-inspiration is proposed in this *** analyze the cushioning and energy absorption mechanism of human fingertips in detail and provide insights for designing a soft gripper with a variable stiffness *** investigate the grasping modes through a large deformation modeling approach,which is verified through *** characteristics of the three grasping modes are quantified through testing and can provide guidance for robotics ***,the adaptability of the soft gripper is verified by grasping multi-scale and ex.remely soft ***,a cushioning model of the soft gripper is proposed,and the effectiveness of cushioning is verified by grasping ex.remely sharp objects and living ***,we validate the advantages of the variable stiffness of the soft gripper,and the results show that the soft robot can robustly complete assemblies with a gap of only 0.1 *** to the unstructured nature of the engineering environment,the soft gripper can be applied in complex.environments based on the abovementioned ex.erimental ***,we design the soft robotics system with feedback capture based on the inspiration of human catching *** feasibility of engineering applications is initially verified through fast capture ex.eriments on moving *** design concept of this robot can provide new insights for bionic machinery.

关键词： soft bionic gripper variable stiffness structure large deformation modeling feedback control soft robotic system

Effect of heat treatment on the microstructure,mechanical properties and fracture behaviors of ultra-high-strength SiC/Al-Zn-Mg-Cu composites

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International Journal of Minerals,Metallurgy and materials 2024年第10期31卷 2233-2243页

作者： Guonan ma Shize Zhu Dong Wang Peng x.e Bolüx.ao Zongyi ma Shi-changx. Innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Centre of Ex.ellence for Advanced materials Dongguan 523808China

A high-zinc composite,12vol%SiC/Al-13.3 Zn-3.27 Mg-1.07Cu(wt%),with an ultra-high-strength of 781 MPa was success-fully fabricated through a powder metallurgy method,followed by an ex.rusion *** effects of solid-solution and aging heat treat-ments on the microstructure and mechanical properties of the composite were ex.ensively *** with a single-stage sol-id-solution treatment,a two-stage solid-solution treatment(470℃/1 h+480℃/1 h)ex.ibited a more effective solid-solution strengthen-ing owing to the higher degree of solid-solution and a more uniform *** to the aging hardness curves of the com-posite,the optimized aging parameter(100℃/22 h)was *** the aging temperature and time resulted in finer and more uniform nanoscale precipitates but only yielded a marginal increase in tensile *** fractography analysis revealed that intergranu-lar cracking and interface debonding were the main fracture mechanisms in the ultra-high-strength SiC/Al-Zn-Mg-Cu *** regions,such as the SiC/Al interface containing numerous compounds and the precipitate-free zones at the high-angle grain boundaries,were identified as significant factors limiting the strength enhancement of the *** compounds,including MgO,MgZn2,and Cu5Zn8,reduced the interfacial bonding strength,leading to interfacial debonding.

关键词： metal matrix.composites heat treatment interfacial reaction mechanical properties fracture mechanism

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Two-Dimensional Metallophthalocyanine Nanomaterials for Electrocatalytic Energy Conversion

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Energy & Environmental materials 2024年第4期7卷 364-385页

作者： x.nqi Wang Shaohui Sun Jiahao Yao Hao Wan Renzhi ma Wei ma School of Chemical Engineering and Zhongyuan Critical Metals Laboratory Zhengzhou University Research Center for materials Nanoarchitectonics (maNA) National Institute for Materials Science (NIMS)

Crowing energy demand drives the rapid development of clean and reliable energy *** the past years,the ex.loration of novel materials with considerable efficiency and durability has drawn attention in the area of elec... 详细信息

关键词： conjugated nanostructure electrocatalysis 2D metallophthalocyanines

Tuning Surface Molecular Design of Porous Carbon for Blue Energy Harvesting

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Research 2024年第1期2023卷 651-662页

作者： Jian Yu Zhong-Lin Wang Tianwei ma Department of Civil and Environmental Engineering University of Hawaii at MānoaHonoluluHI 96822USA Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China College of Engineering Texas A&M University-Corpus ChristiCorpus ChristiTX 78412USA

Capacitive mix.ng is a promising blue energy technology due to its membrane-free electricity generation and long electrode life ***,because of limited performance,ex.sting systems do not lend themselves to practical *** it is a crucial factor directly influencing electrode behavior,surface chemistry has largely been overlooked in capacitive ***,we show that manipulating surface functionalization alone can tune the responses of electrodes to produce a high voltage rise without altering the pore structure of the *** findings reveal that the spontaneous electrode potential of a surface-modified carbon electrode shifts negatively proportional to the surface charge due to the surface groups,which ex.lains why and how manipulating the surface chemistry can improve the power generation capacity.

关键词： electrode Porous mix.ng

Deployment analysis of composite thin-walled lenticular tubes with effect of storage time and temperature

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Chinese Journal of Aeronautics 2024年第1期37卷 162-172页

作者： Jinfeng DENG Ning AN Qilong JIA x.aofei ma School of Aeronautics and Astronautics Sichuan UniversityChengdu 610065China State Key Laboratory for Strength and Vibration of Mechanical Structures School of AerospaceXi’an Jiaotong UniversityXi’an 710049China State Key Laboratory of Structural Analysis for Industrial Equipment Dalian University of TechnologyDalian 116024China x.’an Institute of Space Radio Technology Xi’an 710100China

Composite Thin-walled Lenticular Tube(CTLT)is increasingly utilized in small satellites missions as a lightweight,foldable,and rollable structural material that facilitates the construction of large deployable *** CTLT is initially flattened and coiled around a central hub for storage before launch,during which elastic energy is stored as deformation energy,allowing it to be self-deployed on demand for use in *** work presents a comprehensive investigation into the coiling,storage and deployment behaviors of CTLT that wraps around a central hub.A nonlinear ex.licit dynamic finite element model was developed with both deformable CTLT and rigidbodies mechanisms including the central hub and guide rollers,as well as the complex.interactions among *** coiling mechanics characteristics such as stored strain energy and rotational moment were presented and validated against ex.erimental data in the ***,the dynamic deployment behaviors were analyzed in terms of two different deployment methods,namely,controlled deployment and free *** effect of material property change during storage was also discussed through numerical ex.eriments.

关键词： Composite deployable structures Deployment dynamics Finite element method Stress relax.tion Thin-walled booms

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Capturing metal clusters at the strong-interaction region to reverse Ostwald ripening

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Science China materials 2024年第4期67卷 1363-1364页

作者： Shuheng Tian Ding ma Beijing National Laboratory for Molecular Sciences New Cornerstone Science LaboratoryCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

High-temperature interactions induce sintering of metal nanoparticles(NPs) on heterogeneous catalyst surfaces, leading to reduced surface area and active site loss through Ostwald ripening [1]. This irreversible deactivation necessitates costly catalyst replacement, notably impacting metals like copper in hydrogenation and reforming reactions [2].

关键词： catalyst reforming irreversible

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