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Recent advances in catalytic systems for CO_(2) conversion to substitute natural gas(SNG):Perspective and challenges

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Journal of Energy Chemistry 2021年第11期30卷 377-407,I0008页

作者： I.Hussain A.A.Jalil N.S.hassan m.Y.S.Hamid Department of Chemistry Faculty of ScienceUniversiti Teknologi Malaysia81310 UTM Johor BahruJohorMalaysia School of Chemical and Energy Engineering Faculty of EngineeringUniversiti Teknologi Malaysia81310 UTM Johor BahruJohorMalaysia Centre of Hydrogen Energy Institute of Future Energy81310 UTM Johor BahruJohorMalaysia

It has been well established that carbon dioxide(CO_(2))is one of the main greenhouse gasses and a leading driver of climate *** chemical conversion of CO_(2) to substitute natural gas(SNG)in the presence of renewable hydrogen is one of the most promising solutions by a well-known process called CO_(2) *** have been comprehensive efforts in developing effective and efficient CO_(2) methanation catalytic ***,the choice of competitive and stable catalysts is still a monumental obstruction and a great challenge towards the commercialization and industrialization of CO_(2) *** is necessary to emphasize the critical understandings of intrinsic and extrinsic interactions of catalyst components(active metal,support,promoter,etc.)for enhanced catalytic performance and stability during CO_(2) *** study reviews the up-to-date developments on CO_(2) methanation catalysts and the optimal synergistic relationship between active metals,support,and promoters during the catalytic *** existing catalysts and their novel properties for enhanced CO_(2) methanation were elucidated using the state-of-the-art experimental and theoretical *** selection of an appropriate synthesis method,catalytic activity for CO_(2) methanation,deactivation of the catalysts,and reaction mechanisms studies,have been explicitly compared and ***,future efforts should be directed towards the sustainable developments of catalytic configurations for successful industrial applications of CO_(2) utilization to SNG using CO_(2) methanation.

关键词： CO_(2)utilization CO_(2)methanation SNG Catalytic systems Deactivation mechanism

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Advanced Functional Electromagnetic Shielding materials:A Review Based on micro‑Nano Structure Interface Control of Biomass Cell Walls

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Nano-micro Letters 2025年第1期17卷 98-134页

作者： Yang Shi mingjun Wu Shengbo Ge Jianzhang Li Anoud Saud Alshammari Jing Luo mohammed A.Amin Hua Qiu Jinxuan Jiang Yazeed m.Asiri Runzhou Huang Hua Hou Zeinhom m.El‑Bahy Zhanhu Guo Chong Jia Kaimeng Xu Xiangmeng Chen Co‑Innovation Center of Efficient Processing and Utilization of Forest Resources College of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037People’s Republic of China State Key Laboratory of Efficient Production of Forest Resourced Beijing Forestry UniversityQinghua East Road 35Haidian DistrictBeijing 100083People’s Republic of China Department of Physics Faculty of Sciences‑ArarNorthern Border UniversityArar 91431Saudi Arabia Department of Chemistry College of ScienceTaif UniversityP.O.Box 1109921944 TaifSaudi Arabia Shaanxi Key Laboratory of macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’anShaanxi 710072People’s Republic of China Integrated Composites Lab Department of Mechanical and Construction EngineeringNorthumbria UniversityNewcastle Upon Tyne NE18STUK College of materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024People’s Republic of China Department of Chemistry Faculty of ScienceAl-Azhar UniversityNasr CityCairo 11884Egypt Yunnan Provincial Key Laboratory of Wood Adhesives and Glued Products International Joint Research Center for Biomass MaterialsSouthwest Forestry UniversityKunming 650224People’s Republic of China School of Science Henan Agricultural UniversityZhengzhou 450002People’s Republic of China

Research efforts on electromagnetic interference(EmI)shielding materials have begun to converge on green and sustainable biomass *** materials offer numerous advantages such as being lightweight,porous,and *** to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EmI shielding *** concerted efforts on the EmI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EmI shielding *** particular,a more comprehensive study and summary of the factors influencing biomass EmI shielding materials including the pore structure adjustment,preparation process,and micro-control would be *** preparation methods and characteristics of wood,bamboo,cellulose and lignin in EmI shielding field are critically discussed in this paper,and similar biomass EmI materials are summarized and *** composite methods and fillers of various biomass materials were *** paper also highlights the mechanism of EmI shielding as well as existing prospects and challenges for development trends in this field.

关键词： Biomass materials Electromagnetic interference shielding micro-nano structure interface control Conductivity

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Liver stiffness as a predictor of hepatocellular carcinoma behavior in patients with hepatitis C related liver cirrhosis

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Hepatobiliary & Pancreatic Diseases International 2020年第1期19卷 22-28页

作者： Sameh A Lashen mohamed m Elshafei Fahmy H Hablass Eman A Alsayed Asmaa A hassan Department of Internal medicine Faculty of MedicineUniversity of AlexandriaAlexandriaEgypt Department of Radiology Faculty of MedicineUniversity of AlexandriaAlexandriaEgypt Department of Biomedical Informatics and medical Statistics Medical Research InstituteUniversity of AlexandriaAlexandriaEgypt

Background: Risk strati cation and prognostication of hepatocellular carcinoma (HCC) help to improve patient outcome. Herein we investigated the role of liver stiffness measurement (LSm) in the prediction of HCC behavior. methods: Totally 121 na ve patients with HCC were included. HCC radiological evaluation and staging were done. LSm was measured using virtual touch quanti cation. Patients were divided into early to intermediate HCC (BCLC-0, A and B) and late HCC (BCLCC and D). HCC was treated according to the BCLC stage. HCC recurrence-free interval was estimated. Results: The mean LSm inside the tumor was signi cantly lower than the peri-tumoral area and the cirrhotic non-cancerous liver parts (Pmean LSm inside the tumor and in the peri-tumoral tissue was lower than the corresponding values in the early to intermediate HCCs stage (Pm inside the tumor and in the peri-tumoral tissue negatively correlated with serum AFP, tumor vascular invasion, and stage (Pm inside the tumor and inversely to LSm in cirrhotic non tumorous liver part. Kaplan-meier analysis showed that the recurrence-free interval was signi cantly longer in patients with LSm inside the tumor of ≥1.25m/s compared to those with LSm inside the tumor ofm/s. Conclusions: LSm can serve as a potential non-invasive predictor for HCC clinical behavior and the recurrence-free interval following loco-regional treatments.

关键词： Fibrosis Hepatitis C Hepatocellular carcinoma Point shear wave Liver cirrhosis

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Growth of monodisperse nanospheres of mnFe_2O_4 with enhanced magnetic and optical properties

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Chinese Physics B 2013年第10期22卷 453-459页

作者： m.Yasir Rafique 潘礼庆 Qurat-ul-ain Javed m.Zubair Iqbal 邱红梅 m.hassan Farooq 郭振刚 m.Tanveer College of Science and Research Institute for New Energy China Three Gorges University Department of Physics University of Science and Technology of Beijing School of material Science and Engineering University of Science and Technology of Beijing Research Center of materials Science Beijing Institute of Technology

Highly dispersive nanospheres of mnFe204 are prepared by template free hydrothermal method. The nanospheres have 47.3-nm average diameter, narrow size distribution, and good crystallinity with average crystallite size about 22 nm. The reaction temperature strongly affects the morphology, and high temperature is found to be responsible for growth of uniform nanospheres. Raman spectroscopy reveals high purity of prepared nanospheres. High saturation magnetization （78.3 emu/g）, low coercivity （45 Oe, 10e = 79.5775 ***-1）, low remanence （5.32 emu/g）, and high anisotropy constant 2.84 × 10^4 J/m3 （10 times larger than bulk） are observed at room temperatures. The nearly snperparamagnetic behavior is ~ spin due to comparable size of nanospheres with superparamagnetic critical thameter Dcr spm The high value of Keff may be due to coupling between the pinned moment in the amorphous shell and the magnetic moment in the core of the nanospheres. The nanospheres show prominent optical absorption in the visible region, and the indirect band gap is estimated to be 0.98 eV from the transmission spectrum. The prepared mn ferrite has potential applications in biomedicine and photocatalysis.

关键词： mn ferrite magnetic materials hydrothermal method superparamagnetic Raman spectroscopy

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A review of hydrogen technologies and engineering solutions for railway vehicle design and operations

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Railway Engineering Science 2021年第3期29卷 212-232页

作者： Yan Sun m.Anwar N.m.S.hassan maksym Spiryagin Colin Cole Centre for Railway Engineering Central Queensland UniversityRockhamptonQLDAustralia

Interest in hydrogen-powered rail vehicles has gradually increased worldwide over recent decades due to the global pressure on reduction in greenhouse gas emissions,technology availability,and multiple options of power *** the past,research and development have been primarily focusing on light rail and regional trains,but the interest in hydrogen-powered freight and heavy haul trains is also *** review shows that some technical feasibility has been demonstrated from the research and experiments on proof-of-concept *** rail vehicles powered by hydrogen either are currently operating or are the subject of experimental *** paper identifies that fuel cell technology is well developed and has obvious application in providing electrical traction power,while hydrogen combustion in traditional IC engines and gas turbines is not yet well *** need for on-board energy storage is discussed along with the benefits of energy management and control systems.

关键词： Hydrogen Fuel cells Hybrid power Rail vehicles Greenhouse gas emissions

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multiphysics simulation of VVER-1200 fuel performance during normal operating conditions

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Nuclear Science and Techniques 2023年第2期34卷 139-152页

作者： Khaled m.Yassin mohamed H.hassan mohammad m.Ghoneim mostafa S.Elkolil Adel Alyan Said A.Agamy Nuclear Research Center Egyptian Atomic Energy AuthorityAbo Zaabal 13759CairoEgypt Department of Nuclear and Radiological Engineering Faculty of EngineeringAlexandria UniversityAlexandria 21544Egypt Faculty of Engineering Egyptian Russian UniversityBadr 11829Egypt

Nuclear fuel performance modeling and simulation are critical tasks for nuclear fuel design optimization and safety analysis under normal and transient *** performance is a complicated phenomenon that involves thermal,mechanical,and irradiation mechanisms and requires special multiphysics *** this study,a fuel performance model was developed using the COmSOL multiphysics *** modeling was performed for a 2D axis-symmetric geometry of a UO2fuel pellet in the E110 clad for VVER-1200 *** modeling considers all relevant phenomena,including heat generation and conduction,gap heat transfer,elastic strain,mechanical contact,thermal expansion,grain growth,densification,fission gas generation and release,fission product swelling,gap/plenum pressure,and cladding thermal and irradiation *** model was validated using a code-to-code evaluation of the fuel pellet centerline and surface temperatures in the case of constant power,in addition to validation of fission gas release(FGR)*** prediction proved that the model could perform according to previously published VVER nuclear fuel performance parameters.A sensitivity study was also conducted to assess the effects of uncertainty on some of the model *** model was then used to predict the VVER-1200 fuel performance parameters as a function of burnup,including the temperature profiles,gap width,fission gas release,and plenum pressure.A compilation of related material and thermomechanical models was conducted and included in the modeling to allow the user to investigate different material/performance *** the model was developed for normal operating conditions,it can be modified to include off-normal operating conditions.

关键词： VVER-1200 Fuel performance COmSOL code Zr-1%Nb cladding UO2 fuel rod

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Targeting harmful effects of non-excitatory amino acids as an alternative therapeutic strategy to reduce ischemic damage

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Neural Regeneration Research 2025年第9期20卷 2454-2463页

作者： Victoria Jiménez Carretero IrisÁlvarez-merz Jorge Hernández-Campano Sergei A.Kirov Jesús m.Hernández-Guijo Department of Pharmacology and Therapeutic School of MedicineUniv.Autónoma de MadridMadridSpain Ramón y Cajal Institute for Health Research(IRYCIS) Neurobiology-Research ServiceHospital Ramón y CajalMadridSpain Institute of Neurobiology Faculty of Mathematics and Natural SciencesHeinrich Heine University DüsseldorfDüsseldorfGermany Department of Neuroscience and Regenerative medicine&Department of Neurosurgery Medical College of Georgia at Augusta UniversityAugustaGAUSA

The involvement of the excitatory amino acids glutamate and aspartate in ce rebral ischemia and excitotoxicity is ***,the role of non-excitatory amino acids in brain damage following a stroke or brain trauma remains largely *** release of amino acids by necrotic cells in the ischemic core may contribute to the expansion of the *** findings indicated that the reversible loss of field excitato ry postsynaptic potentials caused by transient hypoxia became irreversible when exposed to a mixture of just four non-excitatory amino acids(L-alanine,glycine,L-glutamine,and L-serine)at their plasma *** amino acids induce swelling in the somas of neurons and astrocytes during hypoxia,along with permanent dendritic damage mediated by N-methyl-D-aspartate *** N-methyl-D-aspartate receptors prevented neuronal damage in the presence of these amino acids during *** is likely that astroglial swelling caused by the accumulation of these amino acids via the alanine-serine-cysteine transporter 2 exchanger and system N transporters activates volume-regulated anion channels,leading to the release of excitotoxins and subsequent neuronal damage through N-methyl-D-aspartate receptor ***,previously unrecognized mechanisms involving non-excitatory amino acids may contribute to the progression and expansion of brain injury in neurological emergencies such as stroke and traumatic brain *** these pathways co uld highlight new therapeutic targets to mitigate brain injury.

关键词： cell swelling N-methyl-D-aspartate receptor non-excitatory amino acids stroke synaptic transmission

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Robust Switch Selection in Radial Distribution Systems Using Combinatorial Optimization

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CSEE Journal of Power and Energy Systems 2022年第3期8卷 933-940页

作者： Hani mavalizadeh Omid Homaee Reza Dashti Josep m.Guerrero hassan Haes Alhelou Pierluigi Siano Fanavaran moj Khatam Tehran 16844Iran School of Electrical Engineering Iran University of Science and TechnologyTehran 16844Iran School of Advanced Technologies Iran University of Science and TechnologyTehran 16844Iran Department of Energy Technology Aalborg UniversityAalborg 9220Denmark Department of Electrical Power Engineering Faculty of Mechanical and Electrical EngineeringTishreen UniversityLattakia 2230Syria Department of management&Innovation Systems University of SalernoFisciano 84084Italy

Selecting the best type of equipment among available switches with different prices and reliability levels is a significant challenge in distribution system *** this paper,the optimal type of switches in a radial distribution system is selected by considering the total cost and reliability criterion and using the weighted augmented epsilon constraint method and combinatorial optimization.A new index is calculated to assess the robustness of each Pareto ***,for each failure,repair time is considered based on historical *** Carlo simulations are used to consider the switch failure uncertainty and fault repair time uncertainty in the *** proposed framework is applied to an RTBS Bus-2 test ***,the model is also applied to an industrial system to verify the proposed method’s excellent performance in larger practical engineering problems.

关键词： Combinatorial optimization monte Carlo Simulation multi-objective optimization radial distribution system reliability robustness

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Rapid sequence induction(RSI) in trauma patients: Insights from healthcare providers

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World Journal of Emergency medicine 2019年第1期10卷 19-26页

作者： Bianca m.Wahlen Ayman El-menyar mohammad Asim hassan Al-Thani Department of Anesthesia Hamad General Hospital Clinical Research Trauma & Vascular Surgery Hamad General Hospital Clinical medicine Weill Cornell Medical College Department of Surgery Trauma Surgery Hamad General Hospital

BACKGROUND: We aimed to describe the current practice of emergency physicians and anaesthesiologists in the selection of drugs for rapid-sequence induction(RSI) among trauma ***: A prospective survey audit was conducted based on a self-administered questionnaire among two intubating specialties. The preferred type and dose of hypnotics, opioids, and muscle relaxants used for RSI in trauma patients were sought in the questionnaire. Data were compared for the use of induction agent, opioid use and muscle relaxant among stable and unstable trauma patients by the intubating ***: A total of 102 participants were included; 47 were anaesthetists and 55 were emergency physicians. Propofol(74.5%) and Etomidate(50.0%) were the most frequently used induction agents. Significantly higher proportion of anesthesiologist used Propofol whereas, Etomidate was commonly used by emergency physicians in stable patients(P=0.001). Emergency physicians preferred Etomidate(63.6%) and Ketamine(20.0%) in unstable patients. The two groups were comparable for opioid use for stable patients. In unstable patients, use of opioid differed significantly by intubating specialties. The relation between rocuronium and suxamethonium use did change among the anaesthetists. Emergency physicians used more suxamethonium(55.6% vs. 27.7%, P=0.01) in stable as well as unstable(43.4 % vs. 27.7%, P=0.08) ***: There is variability in the use of drugs for RSI in trauma patients amongst emergency physicians and anaesthesiologists. There is a need to develop an RSI protocol using standardized types and dose of these agents to deliver an effective airway management for trauma patients.

关键词： Rapid-sequence induction Trauma Emergency physicians Anaesthetists Drugs

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One-pot multicomponent Synthesis, Spectroscopy, Crystal Structures and Theoretical Calculations of 3-Cyano-4-(4-hydroxy-3-methoxyphenyl)-6-phenyl-2(1H)-pyridinone and 3-Cyano-4-chlorophenyl-6-(4-tolyl)-2(1H)-pyridinone

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Chinese Journal of Structural Chemistry 2019年第3期38卷 448-463页

作者： mUHAmmAD Nadeem Arshad hassan m.Faidallah ABDULLAH m.Asiri OSmAN I.Osman FAISAL m.S.Aqlan Chemistry Department Faculty of Science King Abdulaziz University Centre of Excellence for Advanced materials Research (CEAmR) King Abdulaziz University Department of Chemistry University of Jeddah Department of Chemistry University of IBB

Pyridinone derivatives are of great interest in medicinal chemistry where they were found to be potent to various diseases. Their metal complexes added more value to their applications. Here, we have synthesized two 2-pyridinone derivatives(3-cyano-4-(4-hydroxy-3-methoxyphenyl)-6-phenyl-2(1 H)-pyridinone and 3-cyano-4-chlorophenyl-6-(4-tolyl)-2(1 H)-pyridinone) using one-pot multicomponent system. They were well characterized using spectroscopic techniques like nuclear magnetic resonance(NmR-1 H & 13 C), Fourier transform infrared(FT-IR) and UV/Vis spectroscopy. The final structures were determined using single-crystal X-ray diffraction technique which helps us to determine their geometries. Density functional theory(DFT) and time-dependent density functional theory(TD-DFT) with suitable basis-sets of calculations have correctly simulated these spectroscopic parameters. The intramolecular charge transfer(ICT) of both substrates has been discussed using natural bond orbital(NBO) technique. molecular electrostatic potential(mEP) surfaces showed their reactive locations for intermolecular charge transfer. Compared to p-nitroaniline(pNA), both substrates were shown to have substantial molecular hyperpolarizability.

关键词： crystal structures NBO one-pot multicomponent system 2-pyridinone TD-DFT

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