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Anisotropic Inter-granular Corrosion Behaviors and microstructures of AlmgSiCu Alloy Sheets made by Thermal–mechanical Treatments

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Acta metallurgica Sinica(English Letters) 2022年第2期35卷 275-284页

作者： L.m.Liu Y.X.Lai C.L.wu z.zhang J.H.Chen Center for High-Resolution Electron microscopy College of Materials Science and EngineeringHunan UniversityChangsha 410082China

This study investigates the microstructure and local corrosion behavior of an Al-mg-Si-Cu alloy,which has been subjected to cold-rolling with different deformation strain ratios(DSRs)and followed by artificial *** corrosion tests show that peak-aged samples with a small DSR(5-10%)are sensitive to inter-granular corrosion(IGC)along both the normal and rolling *** the DSR increases to medium strength(20-40%),IGC sensitivity decreases along both directions and corrosion propagates *** the DSR is 60-80%,IGC sensitivity along the normal direction continues to decrease,but increases along the rolling direction,indicating pronounced corrosion *** characterization reveals the decreased IGC sensitivity is mainly attributed to a reduction in element segregation at high-angle grain boundaries and the kinked and discontinuous grain boundary corrosion *** increased IGC sensitivity along the rolling direction could be related to the significantly flattened grains.

关键词： Al alloys Local corrosion Anisotropy Transmission electron microscopy(TEm) Electron backscattering diffraction(EBSD)

The Effect of Non-Contact Conditions in a Splinted Fixed Partial Denture on the Load Sharing mechanism： A Finite Element Study

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Journal of Bionic Engineering 2012年第3期9卷 336-342页

作者： m. z. Bendjaballah Biomedical Technology Department College of Applied Medical Sciences King Saud University Riyadh Saudi Arabia

A computer-aided design model for a fixed partial denture was constructed and used in a finite element analysis to study the overall load sharing mechanism between the fixed partial denture and oral structures while the denture base rested on the al- veolar ridge. To investigate the consequences of non-contact conditions, three additional models were generated incorporating a uniform clearance of 0.125 mm, 0.25 mm, and 0.5 mm, respectively. A 100 N static load located at the free end of the prosthesis was applied while the distal portion of the jaw was set fixed. The results show that whilst releasing the ridge almost entirely, the presence of the clearance drastically increased the load on the splinting teeth. A pull-out force on the canine tooth of about 44 N was computed, accompanied by a mesio-distal moment of about 500 ***. The combination of which was similar to the tooth extraction maneuver performed by the dentist. In contrast, the second premolar was found to bear a push-in force of almost 115 N. The first molar, though barely solicited in the contact condition, became substantially loaded in non-contact conditions, which validates the choice of sacrificing three teeth to support the denture.

关键词： finite element analysis splinted fixed partial denture hygienic space load transfer mechanism contact problem

Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable zn‑Air Batteries

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Nano-micro Letters 2025年第1期17卷 176-190页

作者： Xiaohong zou Qian Lu mingcong Tang Jie wu Kouer zhang Wenzhi Li Yunxia Hu Xiaomin Xu Xiao zhang zongping Shao Liang An Department of mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Jiangsu Key Laboratory of Atmospheric Environment monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China Department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of mines:minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction zn-air batteries

The Novel mechanical Property of Tongue of a Woodpecker

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Journal of Bionic Engineering 2009年第3期6卷 214-218页

作者： P zhou X Q Kong C W wu z Chen National Key Laboratory for Structural Analysis of Industrial Equipment Dalian University of Technology Department of Civil and Environmental Engineering University of Missouri

Biomaterials such as bone,teeth,nacre and silk are known to have superior mechanical properties due to their specific nanocomposite *** we report that the woodpecker's tongue exhibits a novel strength and flexibility due to its special composite micro/*** tongue consists of a flexible cartilage-and-bone skeleton covered with a thin layer tissue of high strength and *** the interface between the cartilage-and-bone skeleton and the tissue layer,there is a hierarchical fiber-typed *** is this special design of the tongue that makes the woodpeckers efficient in catching the insects inside *** special micro/nanostructures of the woodpecker's tongue show us a potential method to enhance the interfacial connection between soft and hard material layers for bio-inspired composite system designs.

关键词： woodpeckcr hyoid cartllage multilevel structure tensile strength

Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation

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International Journal of minerals,metallurgy and materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du zhichen wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies Co. Ltd.Beijing 100085China

S and Co co-doped carbon catalysts were prepared via pyrolysis of mOF-71 and thiourea mixtures at 800℃at a mass ratio of mOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PmS)for methylene blue(mB)*** effects of two different mixing routes were identified on the mB degradation ***,the catalyst obtained by the alcohol solvent evaporation(mOF-AEP)mixing route could degrade 95.60%mB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(mOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of mOF-AEP(43.39at%)was less than that of mOF-DGP(54.73at%),and the proportion of C-S-C in mOF-AEP(13.56at%)was higher than that of mOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PmS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PmS compared with ***,the degradation parameters,including pH and mOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading mB.

关键词： advanced oxidation process alcohol solvent evaporation hydrogen bond S and Co co-doped carbon catalysts wastewater remediation

Novel Agents in the management of Hepatic Encephalopathy:A Review

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Journal of Clinical and Translational Hepatology 2021年第5期9卷 749-759页

作者： Leen z.Hasan George Y.wu Department of medicine Division of Gastroenterology-HepatologyUniversity of Connecticut Health CenterFarmingtonCTUSA

Hepatic encephalopathy is an often devastating complication of chronic liver disease,associated with high mortality and increased burden on patients and healthcare *** agents(such as nonabsorbable disaccharides and oral antibiotics)are often only partially effective and associated with unpleasant side *** our improved understanding of the pathophysiology of hepatic encephalopathy,multiple treatment modalities have emerged with promising results when used alone or as an adjunct to standard *** mechanisms of these agents vary greatly,and include the manipulation of gut microbial composition,reduction of oxidative stress,inhibition of inflammatory mediators,protection of endothelial integrity,modulation of neurotransmitter release and function,and other novel methods to reduce blood ammonia and *** their promising results,the studies assessing these treatment modalities are often limited by study design,sample size,outcome assessment heterogeneity,and paucity of data regarding their safety *** this article,we discuss these novel agents in depth and provide the best evidence supporting their use,along with a critical look at their limitations and future directions.

关键词： Hepatic encephalopathy Liver cirrhosis Ammonia

Fire hazard in transportation infrastructure:Review,assessment,and mitigation strategies

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Frontiers of Structural and Civil Engineering 2021年第1期15卷 46-60页

作者： Venkatesh KODUR m.z.NASER Department of Civil and Environmental Engineering Michigan State UniversityEast LansingMI 48824-1226USA Glenn Department of Civil Engineering Clemson UniversityClemsonSC 29634USA

This paper reviews the fire problem in critical transportation infrastructures such as bridges and *** magnitude of the fire problem is illustrated,and the recent increase in fire problems in bridges and tunnels is *** research undertaken to address fire problems in transportation structures is reviewed,as well as critical factors governing the performance of those ***,key strategies recommended for mitigating fire hazards in bridges and tunnels are presented,and their applicability to practical situations is demonstrated through a practical case ***,research needs and emerging trends for enhancing the“state-of-the-art”in this area are discussed.

关键词： fire hazard bridges tunnels fire resistance mitigation strategies transportation infrastructure

Production of porous silica by the combustion of rice husk ash for tundish lining

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Journal of University of Science and Technology Beijing 2008年第3期15卷 307-313页

作者： Y.m.z.Ahmed E.m.Ewais z.I.zaki Central metallurgical Research and Development Institute(CmRDI)

In order to study the production of porous silica compacts by the combustion of rice husk ash （RHA） for tundish lining, the experimental design technique was used to evaluate the effect of firing temperature, soaking time and compaction pressure on controlling both the porosity degree and compressive strength of rice husk ash compacts. The results revealed that while the porosity degree of the compacts decreased with the increase in the entire studied parameters, the compressive strength exhibited another trend especially at a lower soaking time. At a lower soaking time, the increase in firing temperature led to a slight decrease in compressive strength and then increasing thereafter. The porous silica compacts having 30% porosity and 〉 2.5 mPa compressive strength suitable for tundish lining could be obtained from the combustion of rice husk ash compacts.

关键词： porous silica rice husk ash tundish lining compressive strength porosity

HIGH-CURRENT PULSED ELECTRON BEAm: RAPID SURFACE ALLOYING AND WEAR RESISTANCE ImPROVEmENT

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Acta metallurgica Sinica(English Letters) 2003年第4期16卷 276-282页

作者： J.Xu H.W.Liu z.R.zhou C.Dong A.m.wu S.z.Hao A.m.zhang T.Xu TribologyResearchInstitute SouthwestJiaotongUniversityChengdu610031ChinaManuscriptreceived25November2002 StateKeyLab.formaterialsmodificationbyLaser IonandElectronBeamsDalianUniversityofTech-nologyDalian116024China StateKeyLaboratoryofSolidLubrication LanzhouInstituteofChemicalPhysicsTheChineseAcademyofSciencesLanzhou730000China

The present paper reports the rapid surface alloying induced by the bombardment of high-current pulsed electron beam. Two kinds of substrate materials were examined to show this effect. The first sample was a pure Al metal pre-coated with fine carbon powders prior to the bombardment, and the second alloy is the D2-Crl2molVl mould steel pre-coated with Cr, Ti, and TiN powders. The surface elements diffuse about several micrometers into the substrate materials only after several bombardments. Tribological behaviors of these samples were characterized and significant improvement in wear resistance was found. Finally, a TEm analysis reveals the presence of stress waves generated by coupled thermal and stress fields, which was considered as the main cause of the enhanced properties.

关键词： high-current pulsed electron beam surface alloying tribology fretting wear