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Journal of Energy Chemistry 2025年第1期100卷 637-645页

作者： Chunliu Zhu Huanyu Liang Ping Li Chenglong Qiu Jingyi wu Jingwei Chen Weiqian Tian Yue Zhu Zhi Li Huanlei Wang School of materials Science and Engineering Ocean University of China Department of Chemical and materials Engineering University of Alberta

Zinc-ion hybrid capacitors （ZIHCs） have received increasing attention as energy storage devices owing to their low cost,high safety,and environmental ***,their progress has been hampered by low energy and power density,as well as unsatisfactory long-cycle stability,mainly due to the lack of suitable electrode *** this context,we have developed manganese single atoms implanted in nitrogen-doped porous carbon nanosheets （mnSAs/NCNs） using a metal salt template method as cathodes for *** metal salt serves a dual purpose in the synthesis process:It facilitates the uniform dispersion of mn atoms within the carbon matrix and acts as an activating agent to create the porous *** applied in ZIHCs,the mnSAs/NCNs electrode demonstrates exceptional performance,including a high capacity of 203 m Ah g-1,an energy density of 138 Wh kg-1at 68 W kg-1,and excellent cycle stability with 91%retention over 10,000 *** calculations indicate that the introduced mn atoms modulate the local charge distribution of carbon materials,thereby improving the electrochemical *** work demonstrates the significant potential of carbon materials with metal atoms in zinc-ion hybrid capacitors,not only in enhancing electrochemical performance but also in providing new insights and methods for developing high-performance energy storage devices.

关键词： Zinc ion hybrid capacitors Cathodes Carbon materials Heteroatoms Single atoms

Boosting cationic and anionic redox activity of Li-rich layered oxide cathodes via Li/Ni disordered regulation

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Journal of Energy Chemistry 2025年第1期100卷 533-543页

作者： Zewen Liu Zhen wu Hao Wang xudong Zhang Yuanzhen Chen Yongning Liu Shengwu Guo Shenghua Chen Yanli Nan Yan Liu State Key Laboratory for mechanical Behavior of materials Xi'an Jiaotong University School of materials Science and Engineering Xi'an University of Architecture and Technology Hefei Advanced Computing Center Operation management Corp Ltd Network Information Center Xi'an Jiaotong University

Lithium-rich layered oxides （LLOs） are increasingly recognized as promising cathode materials for nextgeneration high-energy-density lithium-ion batteries （LIBs）.However,they suffer from voltage decay and low initial Coulombic efficiency （ICE） due to severe structural degradation caused by irreversible O ***,we introduce a three-in-one strategy of increasing Ni and mn content,along with Li/Ni disordering and Tm–O covalency regulation to boost cationic and anionic redox activity simultaneously and thus enhance the electrochemical activity of *** target material,Li1.2Ni0.168mn0.558Co0.074O2（L1）,exhibits an improved ICE of 87.2%and specific capacity of 293.2 mA h g-1and minimal voltage decay of less than 0.53 m V cycle-1over 300 cycles at 1C,compared to Li1.2Ni0.13mn0.54Co0.13O2（Ls）(274.4 mA h g-1for initial capacity,73.8%for ICE and voltage decay of 0.84 mV/cycle over 300 cycles at 1C).Theoretical calculations reveal that the density of states （DOS） area near the Fermi energy level for L1 is larger than that of Ls,indicating higher anionic and cationic redox reactivity than ***,L1 exhibits increased O-vacancy formation energy due to higher Li/Ni disordering of 4.76%（quantified by x-ray diffraction Rietveld refinement） and enhanced Tm–O covalency,making lattice O release more difficult and thus improving electrochemical *** increased Li/Ni disordering also leads to more Ni2+presence in the Li layer,which acts as a pillar during Li+de-embedding,improving structural *** research not only presents a viable approach to designing low-Co LLOs with enhanced capacity and ICE but also contributes significantly to the fundamental understanding of structural regulation in high-performance LIB cathodes.

关键词： Ice

mechanism of wavy vortex and sign laws in flow past a bluff body:vortex-induced vortex

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Acta mechanica Sinica 2019年第1期35卷 1-14,I0001页

作者： L.m.Lin S.Y.Shi x.F.Zhong Y.x.wu Key Laboratory for mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Sciences University of Chinese Academy of SciencesBeijing 100049China

As reported in a previous work by Lin et al.(Acta meeh Sin, 2018. https://***/10.1007/s 10409-018-0758-z), an interesting phenomenon was discovered based on the analysis of wavy vortex and vorticity distribution in the shear layers and near wake of a peak-perforated conic shroud, and two sign laws were summarized. In the present paper, the theory of a vortex-induced vortex is introduced to explore mechanisms in a wavy vortex and applicable sign laws for uniform and incompressible flow past a fixed bluff body. Based on the analysis of the nearest-wall How, two vortex-induced models for streamwise and vertical vortex pairs, respectively, are proposed under two boundary cases, denoting the induced vorticity introduced or distributed on and near the walls. As a result, the first sign law, for only streamwise and vertical components of vorticity, and the second sign law, for three components of vorticity, are obtained under their own particular conditions. The first sign law reveals the intrinsic physical relationship between streamwise and vertical vorticities, independent of the distribution of spanwise vortices in the whole flow field. It is also confirmed that the spanwise vortices, as well as the shear layers and wake width, distributed wavily across the span, are attributed to the introduced streamwise or vertical vortices. The two sign laws for vorticity are independent of the disturbed spanwise wavelength and the Reynolds number. Through the analysis of flow past the conic shroud, the two sign laws are successfully used to summarize typical spacial distributions of vorticity in three flow regions: on and near the front cylinder surfaces, the separated shear layers and the near wake.

关键词： Wavy vortex Sign law Vortex-induced vortex Wake Bluff body

Ultrahigh strength mg-Y-Ni alloys obtained by regulating second phases

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Journal of materials Science & Technology 2020年第10期42卷 117-124页

作者： S.Z.wu x.G.Qiao m.Y.Zheng School of materials Science and Engineering Harbin Institute of TechnologyHarbin150001China

mg-Y-Ni alloys with different second phases were designed by changing Y/Ni atomic ratio from 1.5 to *** microstructure and mechanical properties of as-cast and as-extruded alloys were *** as-cast mg-Y-Ni alloy with Y/Ni ratio of 1.5 is composed ofα-mg and long period stacking ordered(LPSO)*** Y/Ni ratio is equal to 1,nanoscale lamellarγ’phase and eutectic mg2Ni phase are formed in addition to LPSO *** Y/Ni ratio decreases further,the amount of eutectic mg2Ni phase increases,while the amount of LPSO phase *** extrusion,the LPSO andγ’phases are distributed along the extrusion direction,while eutectic mg2Ni phase is broken and dispersed in the as-extruded *** phase and mg2Ni phase in the alloys promote dynamic recrystallization(DRx)during extrusion,whileγ’phase inhibits ***,the mg96Y2Ni2(at.%)alloy with LPSO phase andγ’phase as the main second phases shows the strongest basal texture after *** tensile yield strength of the as-extruded mg-Y-Ni alloys increases first and then decreases with decreasing Y/Ni *** as-extruded mg96Y2Ni2(at.%)alloy with Y/Ni=1 exhibits excellent mechanical properties with tensile yield strength of 465 mPa,ultimate tensile strength of 510 mPa and elongation to failure of 7.2%,which is attributed to the synergistic effect of bulk LPSO phase and nanoscaleγ’phase.

关键词： mg-Y-Ni alloys LPSO γ’Phase mg2Ni mechanical properties

measurement and Prediction of Insertion Force for the mosquito Fascicle Penetrating into Human Skin

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Journal of Bionic Engineering 2009年第2期6卷 143-152页

作者： x Q Kong C W wu State Key Laboratory of Structural Analysis for Industrial Equipment Department of Engineering MechanicsDalian University of Technology

mosquitoes are exceptional in their ability to pierce into human skin with a natural ultimate painless microneedle, named fascicle. Here the structure of the Aedes albopictus mosquito fascicle is obtained using a Scanning Electron microscope (SEm), and the whole process of the fascicle inserting into human skin is observed using a high-speed video imaging technique. Direct measurements of the insertion force for mosquito fascicle to penetrate into human skin are reported. Results show that the mosquito uses a very low force (average 18 μN) to penetrate into the skin. This force is at least three orders of magnitude smaller than the reported lowest insertion force for an artificial microneedle with an ultra sharp tip to insert into the human skin. In order to understand the piercing mechanism of mosquito fascicle tip into human multilayer skin tissue, a numerical simulation is conducted to analyze the insertion process using a nonlinear finite element method. A good agreement occurs between the numerical results and the experimental measurements.

关键词： biomimetic microneedle mosquito fascicle mechanics penetration

BEHAVIOR OF SHORT FATIGUE CRACKS AT BLUNT NOTCHES IN A mEDIUm CARBON STEEL

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Acta metallurgica Sinica(English Letters) 1997年第5期10卷 430-436页

作者： wu, Z.x. Sun, x.F. Southwest Jiaotong Univ Chengdu China

The behavior of part-through and through short cracks in single edge blunt notched specimens of a medium carbon steel was investigated by a replication method. It is found that the fatigue failure of these notched specimens is caused mainly by the growth of short surface cracks originating from the surface of notch root. more than 70% of the fatigue life is spent in the regimes in which short surface cracks initiate and propagate as part-through cracks before joining up to form a single through-thickness crack. The effect of original crack profile which is formed through the coalescence of multiple part-through cracks is the main reason causing the 'anomalous' propagation behavior of the through-thickness crack in its early stage.

关键词： Carbon steel Crack initiation Crack propagation Fatigue of materials Fracture mechanics Surfaces

Application of kernel ridge regression in predicting neutron-capture reaction cross-sections

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Communications in Theoretical Physics 2022年第9期74卷 98-104页

作者： T x Huang x H wu P W Zhao State Key Laboratory of Nuclear Physics and Technology School of PhysicsPeking UniversityBeijing 100871China

This article provides the first application of the machine-learning approach in the study of the cross-sections for neutron-capture reactions with the kernel ridge regression(KRR)*** is found that the KRR approach can reduce the root-mean-square(rms)deviation of the relative errors between the experimental data of the maxwellian-averaged(n,γ)cross-sections and the corresponding theoretical predictions from 69.8%to 35.4%.By including the data with different temperatures in the training set,the rms deviation can be further significantly reduced to 2.0%.moreover,the extrapolation performance of the KRR approach along different temperatures is found to be effective and reliable.

关键词： kernel ridge regression machine learning neutron-capture reaction

moS2 synaptic transistor with one-step manufacture

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Science China(Information Sciences) 2025年第1期68卷 357-365页

作者： Yihao GUO Yang WANG Wenjie DENG Yi wu Jingtao LI Kexin LI Yuehui ZHAO Songlin YU xiaoting WANG Yongzhe ZHANG Hui YAN Key Laboratory of Optoelectronics Technology of Education ministry of China Faculty of Information TechnologyBeijing University of Technology Key Laboratory of Advanced Functional materials Ministry of Education Faculty of Materials and ManufacturingBeijing University of Technology The 11th Research Institute of Electronics Technology Group Corporation

The synaptic transistor,which is a neuromorphic device with brain-like functions,has garnered significant attention due to characteristics such as low energy consumption,high integration,multiple functions,and high computational ***,the current synaptic transistor possesses a complicated structure and involves complex manufacturing steps,which is not conducive to low-cost,large-scale bionic ***,we introduce a simple moS2synaptic transistor exhibiting robust synaptic *** transistor utilizes magnetron sputtering manufacture to combine the process of device metal electrode deposition and the introduction of defect states,which helps streamline the manufacturing process into a single *** long-term potentiation and long-term depression in photoelectric coordination are initially ***,biological functions,such as double pulse facilitation and the transformation behavior of short-term memory to long-term memory,are thoroughly evaluated,along with learning-forgetting-relearning ***,the device exhibits robust synaptic plasticity until incident light angles down to 30° to imitate the multi-to-one axon-cellular ***,a classical simulation of Pavlov's dog conditioned reflex is demonstrated along with the multiview extraction *** experimental results demonstrate a promising synaptic transistor with a simple structure,manufacturing technique,and excellent *** further indicates the potential for large-scale integration of bionic neuromorphic systems.

关键词： process optimization artificial synaptic device one-stepmanufacture synaptic plasticity bionic simulation

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g-C_(3)N_(4)nanosheets coupled with CoSe_(2)as co-catalyst for efficient photooxidation of xylose to xylonic acid

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Green Energy & Environment 2025年第1期10卷 231-238页

作者： Qi Hao Yijun Liu Ren Zou Ge Shi Shilian Yang Linxin Zhonga wu Yang xiao Chi Yunpeng Liu Shimelis Admassie xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou510641GuangdongChina Hainan Key Laboratory of Storage&Processing of Fruits and Vegetables Agricultural Products Processing Research InstituteChinese Academy of Tropical Agricultural SciencesZhanjiangGuangdong524001China Department of Chemistry and Centre for Advanced 2D materials(CA2Dm)National University of Singapore 3 Science Drive 3 Singapore117543Singapore School of materials Science and Hydrogen Energy Foshan UniversityFoshan528231GuangdongChina Department of Chemistry Addis Ababa UniversityPO BOX 1176Addis AbabaEthiopia

Photocatalysis has emerged as an effective approach to sustainably convert biomass into value-added ***_(2)is a promising nonprecious,efficient cocatalyst for photooxidation,which can facilitate the separation of photogenerated electron–holes,increase the reaction rates,and enhance photocatalytic *** this work,we synthesized a stable and efficient photocatalysis system of CoSe_(2)/g-C_(3)N_(4)through attaching CoSe_(2)on g-C_(3)N_(4)sheets,with a yield of 50.12%for the selective photooxidation of xylose to xylonic *** light illumination,the photogenerated electrons were prone to migrating from g-C_(3)N_(4)to CoSe_(2)due to the higher work function of CoSe_(2),resulting in the accelerated separation of photogenerated electron–holes and the promoted ***,this study reveals the unique function of CoSe_(2),which can significantly promote oxygen adsorption,work as an electron sink and accelerate the generation of$O2-,thereby improving the selectivity toward xylonic acid over other *** work provides useful insights into the design of selective photocatalysts by engineering g-C_(3)N_(4)for biomass high-value utilization.

关键词： Biomass photooxidation Hemicelluloses xylose g-C_(3)N_(4) xylonic acid

mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： mingdong Sun Wenwen Guan Cailing Chen Chao wu xiaoling Liu Biao meng Tao Chen Yu Han Jun Wang Shibo xi Yu Zhou State Key Laboratory of materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced membranes and Porous materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge x-ray absorption near-edge structure （xANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Activation energy