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Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Chinese Journal of Chemical Engineering 2021年第8期34卷 199-222页

作者： mohamed A.El-Nemr Ibrahim m.a.ismail Nabil m.Abdelmonem Ahmed El Nemr Safaa Ragab Department of Chemical Engineering Faculty of EngineeringCairo UniversityGizaEgypt Renewable Energy Program Zewail City of Science and TechnologyEgypt Environmental Division National Institute of Oceanography and FisheriesKayet BeyEl-AnfoushyAlexandriaEgypt

Watermelon peel residues were used to produce a new biochar by dehydration *** new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI)ions from aqueous solution has been *** biochars,melon-B,melon-BO-NH_(2) and melon-BO-TETA,were made from watermelon peel via dehydration with 50%sulfuric acid to give melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give melon-BO-NH_(2) or Triethylenetetramine(TETA)to give *** prepared biochars were characterized by BET,BJH,SEm,FT-IR,TGA,DSC and EDAX *** highest removal percentage of Cr(VI)ions was 69%for melon-B,98%for melon-BO-NH_(2) and 99%for melon-BO-TETA biochars of 100 mg·L^(−1) Cr(VI)ions initial concentration and 1.0 g·L^(−1) adsorbents *** unmodified biochar(melon-B)and modified biochars(melon-BO-NH_(2) and melon-BO-TETA)had maximum adsorption capacities(Q_(m))of 72.46,123.46,and 333.33 mg·g^(−1),*** amination of biochar reduced the pore size of modified biochar,whereas the surface area was *** obtained data of isotherm models were tested using different error function *** Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of melon-B,melon-BO-NH_(2) and melon-BO-TETA,*** adsorption rate was primarily controlled by pseudo-second–order rate ***,the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption *** adsorption for the melon-B,melon-BO-NH_(2) and melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.

关键词： Waste treatment Powder technology Citrullus lanatus Hexavalent chromium Biochar amination Adsorption

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A Q-Switched Erbium-Doped Fiber Laser with a Carbon Nanotube Based Saturable Absorber

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Chinese Physics Letters 2012年第11期29卷 67-69页

作者： S.W.Harun m.a.ismail F.Ahmad m.F.ismail R.m.Nor N.R.Zulkepely H.Ahmad Department of Electrical Engineering University of Malaya 50603 Kuala LumpurMalaysia Photonics Research Center Department of PhysicsUniversity of Malaya50603 Kuala LumpurMalaysia Department of Physics University of Malaya50603 Kuala LumpurMalaysia

We demonstrate a simple,compact and low cost Q-switched erbium-doped fiber laser(EDFL)using single-wall carbon nanotubes(CNTs)as a saturable absorber for possible applications in metrology,sensing,and medical *** EDFL operates at around 1560 nm with repetition rates of 16.1 kHz and 6.4 kHz with saturable absorbers SA1 and SA2 at a pump power of 120 *** absorbers are constructed by optically driven deposition and normal deposition *** is observed that the optical deposition method produces a Q-switched EDFL with a lower threshold of 70 mW and better Q-switching performance compared to that of the normal deposition *** EDFL also has pulse energy of 90.3 nJ and pulse width of 11.6μs at 120 mW pump power.

关键词： pump switched Erbium

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Performance Comparison of mode-Locked Erbium-Doped Fiber Laser with Nonlinear Polarization Rotation and Saturable Absorber Approaches

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Chinese Physics Letters 2012年第5期29卷 154-156页

作者： m.a.ismail S.J.Tan N.S.Shahabuddin S.W.Harun H.Arof H.Ahmad Department of Electrical Engineering Faculty of EngineeringUniversity of Malaya50603 Kuala LumpurMalaysia Photonics Research Center Department of PhysicsUniversity of Malaya50603 Kuala LumpurMalaysia

A mode-locked erbium-doped fiber laser (EDFL) is demonstrated using a highly concentrated erbium-doped fiber (EDF) as the gain medium in a ring configuration with and without a saturable absorber (SA).Without the SA,the proposed laser generates soliton pulses with a repetition rate of 12 mHz,pulse width of 1.11 ps and energy pulse of *** incorporating SA in the ring cavity,the optical output of the laser changes from soliton to stretched pulses due to the slight change in the group velocity *** the SA,a cleaner pulse is obtained with a repetition rate of 11.3 mHz,a pulse width of 0.58ps and a pulse energy of 2.3pJ.

关键词： pulse fiber Erbium

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Targeting oral-gut microbial transmission in diabetic coronary heart disease:unveiling key pathogenic mechanisms

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Science China(Life Sciences) 2024年第10期67卷 2287-2288页

作者： ismail Cimen Aab Cardiovascular Research Institute Department of MedicineUniversity of Rochester School of Medicine and DentistryRochester 14642USA

Diabetes significantly exacerbates the occurrence and adverse prognosis of coronary heart disease(CHD),emphasizing the importance of focusing on the prevention and management of diabetesrelated *** study identifies and verifies for the first time a distinctive oral-gut microbiota profile in patients with diabetic coronary heart disease(DCHD),marked by an increased abundance of oral Fusobacterium nucleatum and gut Lactobacillus.

关键词： coronary prevention diabetic

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Spatiotemporal landscape pattern changes and their effects on land surface temperature in greenbelt with semi-arid climate:A case study of the Erbil City,Iraq

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Journal of Arid Land 2024年第9期16卷 1214-1231页

作者： Suzan ismail Hamid mALIKI Department of Architecture College of EngineeringSalahaddin UniversityErbil 44002Iraq

Urban expansion of cities has caused changes in land use and land cover(LULC)in addition to transformations in the spatial characteristics of landscape *** alterations have generated heat islands and rise of land surface temperature(LST),which consequently have caused a variety of environmental issues and threated the sustainable development of urban *** are employed as an urban planning containment policy to regulate urban expansion,safeguard natural open spaces,and serve adaptation and mitigation *** they are regarded as a powerful measure for enhancing urban environmental *** the fact that,the relation between landscape structure change and variation of LST has been examined thoroughly in many studies,but there is a limitation concerning this relation in semi-arid climate and in greenbelts as well,with the lacking of comprehensive research combing both ***,this study investigated the spatiotemporal changes of landscape pattern of LULC and their relationship with variation of LST within an inner greenbelt in the semi-arid Erbil City of northern *** study utilized remote sensing data to retrieve LST,classified LULC,and calculated landscape metrics for analyzing spatial changes during the study *** results indicated that both composition and configuration of LULC had an impact on the variation of LST in the study *** Pearson's correlation showed the significant effect of Vegetation 1 type(VH),cultivated land(CU),and bare soil(BS)on LST,as increase of LST was related to the decrease of VH and the increases of CU and BS,while,neither Vegetation 2 type(VL)nor built-up(BU)had any ***,the spatial distribution of LULC also exhibited significant effects on LST,as LST was strongly correlated with landscape indices for VH,CU,and ***,for BU,only aggregation index metric affected LST,while none of VL metrics had a *** study provides insights for landscape pla

关键词： land use and land cover change landscape pattern land surface temperature greenbelt remote sensing

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Assembly of functional carboxymethyl cellulose/polyethylene oxide/anatase TiO_(2) nanocomposites and tuning the dielectric relaxation, optical, and photoluminescence performances

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Journal of Semiconductors 2024年第7期45卷 26-38页

作者： Asmaa m.ismail Abeer A.Reffaee Fawzy G.El Desouky Spectroscopy Department Physics Research InstituteNational Research CentreGizaCairo 12622Egypt microwave Physics and Dielectrics Department National Research CentreDokkiCairoEgypt Solid State Physics Department Physics Research InstituteNational Research CentreGizaCairo 12622Egypt

Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CmC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting ***2 nanocrystals were effectively incorporated into CmC/PEO polymers,as shown by X-ray diffraction(XRD)and attenuated total reflectance fourier transform infrared(ATR-FTIR)*** roughness growth is at high levels of TO nanocrystals(TO NCs),which means increasing active sites and defects in CmC/*** differential scanning calorimetry(DSC)thermograms,the change in glass transition temperature(Tg)val-ues verifies that the polymer blend interacts with TO *** increment proportions of TO NCs have a notable impact on the dielectric performances of the nanocomposites,as *** electrical properties of the CmC/PEO/TO nanocomposite undergo significant *** nanocomposite films exhibit a red alteration in the absorption edge as the concentration of TO NCs increases in the polymer *** decline in the energy gap is readily apparent as the weight percentage of TO NCs *** photoluminescence(PL)emission spectra indicate that the sites of the luminescence peak maximums show slight variation;peaks get wider,while their intensities decrease dramatically as the concentration of TO *** nanocomposite materials show potential for multifunctional applications including optoelectronics,antireflection coatings,pho-tocatalysis,light emitting diodes,and solid polymer electrolytes.

关键词： anatase TiO_(2) CmC/PEO nanocomposites optical photoluminescent electrical optoelectronics

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High resolution sequence stratigraphy of the mishrif Formation(Cenomanian-Early Turonian)at zubair oilfield(al-rafdhiah dome),southern Iraq

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Petroleum Research 2024年第1期9卷 61-71页

作者： Aymen A.Lazim maher J.ismail maher m.mahdi Geoscience Department Zubair Field Operation DivisionBasra Oil CompanyIraq Basrah Oil Company WQ1 FODBasrahIraq University of Basrah College of ScienceGeology Dept.BasrahIraq

The mishrif Formation(Cenomanian-E Turonian)is one of the most important geological formations in the middle East and Iraq because it contains enormous petroleum *** is considered to be the first reservoir in the region,and is still being studied because of its economic *** carbonate of the mishrif Formation derives from a variety of depositional settings,including mid-ramp,shoal,lagoon,and *** five main microfacies discussed in this paper are wackestone,packstone,grainstone,floatstone,and *** most frequent fossilised components found in the mishrif Formation are rudists,benthic foraminifera,echinoderms,burrows molluscs,and *** to the microfacies and analysed wireline log data,the sequence stratigraphy of the studied formation is composed of two regression *** parasequences of transgressive-regressive cycles make up the depositional sequence of the mishrif *** standard depositional environments seem to demonstrate a gradual regression,beginning with a short period of the outer ramp,then a steady period of the mid-ramp,and ending in the intertidal ***,the study recorded two regional maximum flooding surfaces:K-135 and *** former is present in the lowermost part of the formation,while the other lies in the *** study shows a close relationship between facies(environments)and hydrocarbon *** increased accumulation focuses on the lower part of the studied formation,and seems to be lower in the upper part of the formation as a result of changes in the environment of deposition.

关键词： mishrif formation Cenomanian Sequence stratigraphy Zubair oilfield Iraq

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Shear Let Transform Residual Learning Approach for Single-Image Super-Resolution

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Computers, materials & Continua 2024年第5期79卷 3193-3209页

作者： Israa ismail Ghada Eltaweel mohamed meselhy Eltoukhy Department of Computer Science Faculty of Computers and InformaticsSuez Canal UniversityIsmailia51422Egypt Department of Information Technology College of Computing and Information Technology at KhulaisUniversity of JeddahJeddahSaudi Arabia

Super-resolution techniques are employed to enhance image resolution by reconstructing high-resolution images from one or more low-resolution ***-resolution is of paramount importance in the context of remote sensing,satellite,aerial,security and surveillance ***-resolution remote sensing imagery is essential for surveillance and security purposes,enabling authorities to monitor remote or sensitive areas with greater *** study introduces a single-image super-resolution approach for remote sensing images,utilizing deep shearlet residual learning in the shearlet transform domain,and incorporating the Enhanced Deep Super-Resolution network(EDSR).Unlike conventional approaches that estimate residuals between high and low-resolution images,the proposed approach calculates the shearlet coefficients for the desired high-resolution image using the provided low-resolution image instead of estimating a residual image between the high-and low-resolution *** shearlet transform is chosen for its excellent sparse approximation ***,remote sensing images are transformed into the shearlet domain,which divides the input image into low and high *** shearlet coefficients are fed into the EDSR *** high-resolution image is subsequently reconstructed using the inverse shearlet *** incorporation of the EDSR network enhances training stability,leading to improved generated *** experimental results from the Deep Shearlet Residual Learning approach demonstrate its superior performance in remote sensing image recovery,effectively restoring both global topology and local edge detail information,thereby enhancing image *** to other networks,our proposed approach outperforms the state-of-the-art in terms of image quality,achieving an average peak signal-to-noise ratio of 35 and a structural similarity index measure of approximately 0.9.

关键词： Super-resolution shearlet transform shearlet coefficients enhanced deep super-resolution network

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Inclusion of CoTiO_(3) to ameliorate the re/dehydrogenation properties of the mg–Na–Al system

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Journal of magnesium and Alloys 2024年第3期12卷 1215-1226页

作者： N.A.Ali N.Y.Yusnizam N.A.Sazelee Sami-ullah Rather Haizhen Liu m.ismail Energy Storage Research Group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Department of Chemical and materials Engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia Guangxi Novel Battery materials Research Center of Engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured metal materials and Life-Cycle Safety for Composite Structures Nanning 530004China

For the first time,the mgH_(2)–NaAlH_(4)(ratio 4:1)destabilized system with CoTiO_(3) addition has been *** CoTiO_(3)-doped mgH_(2)–NaAlH_(4) sample begins to dehydrogenate at 130℃,which is declined by 40℃ compared to the undoped mgH_(2)–NaAlH_(4).moreover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped mgH_(2)–NaAlH_(4) were greatly *** the inclusion of CoTiO_(3),the mgH_(2)–NaAlH_(4) composite absorbed 5.2 wt.%H_(2),higher than undoped mgH_(2)–NaAlH_(4).In the context of dehydrogenation,the CoTiO_(3)-doped mgH_(2)–NaAlH_(4) sample desorbed 2.6 wt.%H_(2),almost doubled compared to the amount of hydrogen desorbed from the undoped mgH_(2)–NaAlH_(4) *** activation energy obtained by the Kissinger analysis for mgH_(2) decomposition was significantly lower by 35.9 kJ/mol than the undoped mgH_(2)–NaAlH_(4) *** reaction mechanism demonstrated that new phases of mgCo and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized mgH_(2)–NaAlH_(4) system with the inclusion of CoTiO_(3).

关键词： Destabilize system magnesium hydride Sodium alanate Hydrogen storage Additive.

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Complex Decision modeling Framework with Fairly Operators and Quaternion Numbers under Intuitionistic Fuzzy Rough Context

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Computer modeling in Engineering & Sciences 2024年第5期139卷 1893-1932页

作者： Nadeem Salamat muhammad Kamran Shahzaib Ashraf manal Elzain mohammed Abdulla Rashad ismail mohammed m.Al-Shamiri Institute of mathematics Khwaja Fareed University of Engineering&Information TechnologyRahim Yar Khan64200Pakistan Department of mathematics Thal University BhakkarPunjab30000Pakistan Department of mathematics Faculty of Science and ArtsKing Khalid UniversityMuhayl Assir61913Saudi Arabia

The main goal of informal computing is to overcome the limitations of hypersensitivity to defects and uncertainty while maintaining a balance between high accuracy,accessibility,and *** paper investigates the potential applications of intuitionistic fuzzy sets(IFS)with rough sets in the context of sparse *** it comes to capture uncertain information emanating fromboth upper and lower approximations,these intuitionistic fuzzy rough numbers(IFRNs)are superior to intuitionistic fuzzy sets and pythagorean fuzzy sets,*** use rough sets in conjunction with IFSs to develop several fairly aggregation operators and analyze their underlying *** present numerous impartial laws that incorporate the idea of proportionate dispersion in order to ensure that the membership and non-membership activities of IFRNs are treated equally within these *** operations lead to the development of the intuitionistic fuzzy rough weighted fairly aggregation operator(IFRWFA)and intuitionistic fuzzy rough ordered weighted fairly aggregation operator(IFRFOWA).These operators successfully adjust to membership and non-membership categories with fairness and *** highlight the unique qualities of these suggested aggregation operators and investigate their use in the multiattribute decision-making *** use the intuitionistic fuzzy rough environment’s architecture to create a novel strategy in situation involving several decision-makers and non-weighted ***,we developed a novel technique by combining the IFSs with quaternion *** establish a unique connection between alternatives and qualities by using intuitionistic fuzzy quaternion numbers(IFQNs).With the help of this framework,we can simulate uncertainty in real-world situations and address a number of decision-making *** the examples we have released,we offer a sophisticated and systematically constructed illustrative scenario that is intricately wo

关键词： Intuitionistic fuzzy set quaternion numbers fuzzy logic decision-making rough set

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