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Influence of erbium on structural,and charged particles,photons,and neutrons shielding properties of Ba_(1-x)Er_(x)SnO_(3) perovskite ceramics

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Journal of Rare Earths 2024年第4期42卷 724-732页

作者： m.K.h.Hamad Nidal Dwaikat m.H.A.mhareb m.I.Sayyed R.m.Hamad Y.S.m.Alajerami m.a.almessiere Gameel Saleh Ahmad Hussein Alomari K.A.Ziq Department of Basic Sciences School of Social and Basics SciencesAl Hussein Technical UniversityKing Abdullah II St 242Amman11831Jordan Department of Physics College of Engineering and PhysicsInterdisciplinary Research Center for Advanced MaterialsKing Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Basic and Applied Scientific Research Center Imam Abdulrahman Bin Faisal UniversityP0.Box 1982Dammam31441Saudi Arabia Department of Physics Faculty of ScienceIsra UniversityAmman11622Jordan Department of Nuclear medicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityPo.Box 1982Dammam31441Saudi Arabia medical Imaging Department Applied Medical Sciences FacultyAl Azhar University-Gaza CityPo.Box 1277Palestine Department of Biophysics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityPo.Box1982Dammam 31441Saudi Arabia Department of Biomedical Engineering College of EngineeringImam Abdulrahman Bin Faisal UniversityPo.Box 1982Dammam31441Saudi Energy&minerals Regulatory Commission Amman11821Jordan

Five perovskite ceramics samples of Ba_(1-x)Er_(x)SnO_(3) with x=0.00,0.05,0.10,0.15,and 0.20 were synthesized using the conventional solid-state reaction *** prepared samples were characterized by X-ray diffraction(XRD),Fourier transforms infrared(FTIR),and UV-Vis *** shielding properties against ionizing radiation were also *** XRD analysis shows the perovskite cubic structure as the major phase in all *** FTIR reveals a distinctive band around 614-620 cm^(-1) ascribed to the antisymmetric O-Sn-O ***-Vis spectroscopy was used to determine the bandgap according to diffuse reflectance,and the results display a fixed enhancement in the bandgap from 3.2 to 3.3 eV for all ***-ray shielding properties of the synthesized samples were experimentally measured and compared with XCOm computational *** relative differences(Δ,%)between experimental and theo retical values are low and fall within the 0.446%-7.10%*** addition of Er leads to the enhanced density,neutron,and gamma shielding *** contrast,charged particles’shielding parameters gradually reduce with rising Er *** results suggest that Ba_(1-x)Er_(x)SnO_(3) samples can be used in different radiation shielding applications.

关键词： Perovskite Ceramics Gamma ray shielding mass stopping power Rare earths

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Unique structural and magnetic traits of Nd3+-substituted Co-Zn nanoferrites

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Journal of Rare Earths 2019年第10期37卷 1108-1115页

作者： m.a.almessiere Department of Physics College of Science Imam Abdulrahman Bin Faisal University Department of Nano-medicine Research Institute for Research & Medical Consultations (IRMC) Imam Abdulrahman Bin Faisal University

Because of the technological potential of magnetic spinel nanoferrites, we prepared neodymium ion(Nd3+)-substituted cobalt-zinc ferrites(CZFs) with the form Co0.5 Zn0.5 NdxFe2 exO4(0.03≤x≤0.05) via a hydrothermal method. The as-prepared samples were thoroughly characterized using various analytical techniques. XRD, FTIR and FESEm analyses confirm the formation of a cubic spinel phase of the CZFNPs(CZF nanoparticles). A decrease in the lattice parameter due to the substitution of Fe3+by Nd3+in the lattice structures is manifested in the XRD refinement data. The magnetic properties of the proposed CZFNPs were evaluated in terms of the saturation magnetization, remanence, coercivity, squareness ratio and magnetic moment. These CZFNPs exhibit superparamagnetic behaviors at room ***, the Nd3+inclusion does not significantly affect the measured magnetizations and coercivities of the CZFNPs. Samples containing 0.01 and 0.03 Nd3+exhibit lower saturation magnetizations than that of the pristine product. The squareness ratios much less than 0.53 are ascribed to surface spin disordering. The unique magnetic traits of the synthesized CZFNPs are primarily attributed to the substitution of Fe3+ions, with smaller ionic radii, by Nd3+ions, with larger ionic radii. The proposed CZFNPs may be useful for diverse magneto-optic applications.

关键词： Spinel nanoferrites Neodymium magnetic properties Optical properties Superparamagnetism Rare earths

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Structural,morphological and magnetic properties of(Ni_(0.5)Co_(0.5))[Ga_(x)Gd_(x)Fe_(2-2x)]O_(4)nanoparticles prepared via sonochemical approach

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Journal of Rare Earths 2023年第4期41卷 561-571页

作者： Y.Slimani m.a.almessiere A.Demir Korkmaz A.Baykal m.A.Gondal H.Güngünes Sagar E.Shirsath A.manikandan Department of Biophysics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Department of Chemistry Istanbul Medeniyet UniversityUskudarIstanbul34700Turkey Department of Nanomedicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Laser Research Group Physics DepartmentIRC-Hydrogen&Energy StorageKing Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia K.A.CARE Energy Research and Innovation Center King Fahd University of Petroleum&MineralsDhahran 31261Saudi Arabia Department of Physics Hitit University19030Cevre Yolu BulvarCorumTurkey School of materials Science and Engineering University of New South WalesKensingtonSydneyNSW2052Australia Department of Chemistry Bharath Institute of Higher Education and Research(BIHER)Bharath UniversityChennaiTamil Nadu600073India Center for Catalysis and Renewable Energy Bharath Institute of Higher Education and Research(BIHER)ChennaiTamil Nadu600073India

The impact of Ga^(3+)and Gd^(3+)co-substitution on different types of behavior of Ni-Co nanospinel ferrites(NSFs),(Ni_(0.5)Co_(0.5))[Ga_(x)Gd_(x)Fe_(2-2x)]O_(4)(0.000≤x≤0.025),was *** were fabricated through ultrasound *** structure,composition,and spherical morphology of all products were verified by numerous characterization techniques such as X-ray diffraction(XRD),scanning and transmission electron microscopes(SEm and TEm),and selected area electron diffraction(SAED).mossbauer spectra are composed of two ferromagnetic sextets and one paramagnetic *** spectra were fitted to extract hyperfine parameters of the doped *** sublattices'hyperfine magnetic field decreases with *** isomer shift values show that the mossbauer spectra are composed of magnetic Fe^(3+)*** magnetization measurements at variable magnetic field(m-H)were investigated via a vibrating sample magnetometer(VSm)at temperatures(T)from 300 to 10 *** NSFs disclose ferrimagnetic behavior at both 300 and 10 K at which they are soft and hard,*** determined that the remanence magnetization(m_(r)),saturation magnetization(m_(s)),and magneton number(n_(B))decrease with increasing Ga^(3+)and Gd^(3+)ions *** reduction in these values is predominantly recognized to be the impact of cation redistribution and surface spins on tetrahedral(T_(d))and octahedral(O_(h))*** the Ga^(3+)and Gd^(3+)contents increase,the coercivity(H_(c))is also found to decrease.

关键词： Spinel ferrites Rare earth substitution Sonochemical synthesis mossbauer analysis magnetic properties

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Electrical and dielectric properties of Ni_(0.5)Co_(0.5)Ga_(x)Fe_(1.8-x)O_(4)(x≤1.0)spinel ferrite microspheres

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Journal of Rare Earths 2023年第2期41卷 259-267页

作者： S.Akhtar m.a.almessiere B.Unal A.Demir Korkmaz Y.Slimani N.Tashkandi A.Baykal A.Ul-Hamid A.manikandan Department of Biophysics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Institute of Forensic Sciences and Legal medicine Istanbul University-CerrahpasaBuyukcekmece CampusBuyukcekmece-Istanbul34500Turkey Department of Chemistry Istanbul Medeniyet UniversityUskudar/Istanbul34700Turkey Department of Nanomedicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Core Research Facilities King Fahd University of Petroleum&MineralsDhahran13261Saudi Arabia Department of Chemistry Bharath Institute of Higher Education and Research(BIHER)Bharath UniversityChennaiTamil Nadu600073India Center for Catalysis and Renewable Energy Bharath Institute of Higher Education and Research(BIHER)ChennaiTamil Nadu600073India

microspheres of Ni_(0.5)Co_(0.5)Ga_(x)Fe_(2-x)O_(4)(x≤1.0)microsphere spinel ferrites(NiCoGaFe-mSFs)and carbon spheres were prepared via a hydrothermal *** micro structure of microspheres was investigated through scanning and transmission electron microscopy(SEm and TEm),respectively,and X-ray diffraction(XRD).The electrical and dielectric properties of NiCoGaFe-mSF at temperatures ranging from20 to 120℃(between 293,1×10^(3)and 393.1×10^(3))for f≤3.0 mHz were systematically studied as a result of 3D graphical drawing of the data obtained from an impedance *** parameters such as ac/dc conductivity,dielectric loss,dielectric constant,activation energy,dissipation factor and Cole-Cole impedance spectra were extensively evaluated for various Ga ion mole ratios in the substitution where x≤*** notice that the ac conductivity mostly obeys exponential power law rules,which vary significantly with the substitution ratios of Ga *** analyses confirm that differences in conduction mechanisms in NiCoGaFe-mSFs are mainly due to grain-to-grain boundaries related to Ga ion substitution *** change in dielectric constant of NiCoGaFe-mSFs is strongly dependent on the substitution rates and results in a normal dielectric distribution with *** tangential loss for all micro spheres is observed to vary with measured temperatures and their frequency dependencies can be attributed to the conduction mechanism similar to Koop’s phenomenological *** is clearly seen that the formation of semicircles is dominated by all the NiCoGaFe-mSFs and the diameter of the semicircles mostly decreases with increasing temperature,as evidence of a temperaturedependent relaxation mechanism.

关键词： Spinel ferrites microspheres Electrical properties Ac/dc conductivity Dielectric properties Rare earths

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AC susceptibility and FC-ZFC magnetic properties of SrTb_(x)Fe_(12-x)O_(19) and SrTm_(x)Fe_(12-x)O_(19) hexaferrites:a comparative study

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Journal of Rare Earths 2021年第8期39卷 1003-1009页

作者： Y.Slimani m.a.almessiere A.Demir Korkmaz A.Baykal I.Ercan Department of Biophysics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.0.Box 198231441 DammamSaudi Arabia Department of Chemistry Istanbul Medeniyet University34700 UskudarIstanbulTurkey Department of Nanomedicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia

In this comparative study,Tb and Tm substituted Sr-hexafe rrites(HFs) with the chemical compositions of SrTb_(x)Fe_(12-x)O_(19) and SrTm_(x)Fe_(12-x)O_(19)(x=0.00,0.02 and 0.04) were fabricated via citrate sol-gel *** AC susceptibility and FC-ZFC magnetization were *** product structure and morphologies were also investigated via XRD,TEm and SEm along with *** of temperature dependence of magnetization m-T and AC magnetic susceptibility versus temperature were carried *** various synthesized HFs displayed ferrimagnetic behavior within 10-325 *** lower temperatures,super-spin glass-like behavior was ***-Arrhenius and Vogel-Fulcher models were employed to explore the experimental data of AC susceptibility.

关键词： m-type hexaferrites magnetic properties AC susceptibility FC/ZFC Rare earths

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morphology and magnetic traits of strontium nanohexaferrites:Effects of manganese/yttrium co-substitution

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Journal of Rare Earths 2019年第7期37卷 732-740页

作者： m.a.almessiere Y.Slimani H.S.El Sayed A.Baykal Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia Department of Nano-medicine Research Institute for Research&Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia Department of Biophysics Institute for Research&Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia

Doped strontium(Sr) hexaferrites appeared potential candidates for microwave absorber *** by this idea, we examined the influence of manganese(mn) and yttrium(Y) co-substitution on the microstructures,morphology and magnetic properties of Sr nanohexaferrites(Sr1-xmnxFe12-yYyO19,where 0.0 ≤ x = y ≤ 0.5) synthesized via citrate sol-gel auto-combustion technique. As-prepared samples were thoroughly characterized using diverse analytical tools. X-ray diffraction pattern reveals a single mhexagonal crystalline phase. FE-SEm, TEm, HR-TEm show a hexagonal platelet-like structure. The magnetic hysteresis loops(measured at room and low temperature) of the as-prepared nanohexaferrites exhibit ferromagnetic(Fm) behavior. magnetic parameters including the saturation magnetization,remanence, coercive and magneto-crystalline anisotropy field are found to decrease with the increase in mn2+ and Y3+ contents. Zero-and normal-field cooled magnetization measurements in the range of 2-400 K display the complete absence of blocking temperature, confirming the characteristic ferromagnetic behavior of the proposed composition.

关键词： Strontium hexaferrite Sol-gel auto-combustion microstructure morphology magnetic properties Rare earths

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Tb^(3+)substituted strontium hexaferrites:Structural,magnetic and optical investigation and cation distribution

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Journal of Rare Earths 2020年第4期38卷 402-410页

作者： m.a.almessiere Y.Slimani H.Gungunes m.Sertkol m.Nawaz N.A.Algarou A.Baykal I.Ercan Department of Biophysics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia Department of Physics Hitit University19030Cevre Yolu Bulvari-CorumTurkey Deanship of Preparatory Year Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia Department of Nanomedicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441 DammamSaudi Arabia

In this study,SrFe12-xTbxO19(0.00≤x≤0.1)hexaferrites(HFs)were prepared successfully by citrate solgel approach.X-ray powder diffraction analyses affirm the hexagonal structure of *** phase starts to appear for x≥*** crystallites sizes were estimated to be in the range of 33-46 *** the products exhibit inhomogeneous distribution of grain size detected through *** analyses of magnetization versus applied magnetic field,m(H),were *** measurements were done at room(300 K;RT)and low(10 K)*** different magnetic parameters including saturation magnetization ms,remanence mr,squareness ratio(SQR=mr/ms),coercivity Hc,and magnetic moment nB are deduced and discussed in *** both considered temperatures,m(H)results show ferrimagnetic nature for all *** is shown that the Tb substitutions significantly affect m(H)data.A significant increase in the ms,mr,and nB is observed for x=0.02 *** SQR values are around 0.5 indicating the single domain nature with uniaxial *** obtained magnetic results were investigated deeply with relation to structural and microstructural *** spectroscopy results were also *** to mossbauer results,the Tb3+ions preferentially occupy 12 k and 4f2 sites.

关键词： m-type hexaferrites Structure mossbauer spectroscopy Optical properties magnetization Rare earths

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Co-substitution of zirconium and neodymium on hyperfine interactions and AC susceptibility of SrFe12O19 nanohexaferrites

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Journal of Rare Earths 2020年第3期38卷 265-273页

作者： m.A.Almessere Y.Slimani H.Güngünes A.Baykal Department of Physics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 198231441DammamSaudi Arabia Department of Biophysics Institute for Research&Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441DammamSaudi Arabia Department of Physics Hitit University19030Cevre Yolu Bulvan-CorumTurkey Department of Nano-medicine Research Institute for Research&Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityP.O.Box 198231441DammamSaudi Arabia

This study presents the influence of Zn and Nd co-substitution on structure,morphology,AC susceptibility and ZFC-FC magnetizations of Sr nanohexaferrites(NHFs),SrFe12-x(Zn,Nd)xO19(0.0≤x≤1.0),which was produced by sol-gel *** powder patterns,scanning electron microscopy(SEm) and high-resolution transmission electron spectroscopy(HR-TEm) approve the synthesis of Sr m-type *** spectra show that Zn^2+ions occupy 2 b and 4f1 sites while Nd3+ions locate at 2 a,4f2 and 12 k *** magnetic properties of the produced Sr-NHFs were investigated also by ZFC-FC magnetizations and AC *** to the mFC-mZFC results(between 2 and 400 K),no blocking temperature was detected which indicates the ferromagnetic(Fm) behavior of *** lower temperatures,a super-spin glass like behavior is *** AC susceptibility indicates that the magnetic interactions are improved due to the inclusion of low content(x=0.1) of Nd^3+and Zn^2+ions into the ***,with further increasing the Nd^3+and Zn^2+contents(x=0.9),the magnetic interactions are weakened.

关键词： Sr hexaferrites Rare earths mossbauer spectroscopy AC susceptibility ZFC-FC

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Frequency-dependent viscoelasticity effects on the wave attenuation performance of multi-layered periodic foundations

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Applied mathematics and mechanics(English Edition) 2024年第3期45卷 407-424页

作者： m.SAFI m.VAKILIFARD m.J.mAHmOODI Faculty of Civil Water&Environmental EngineeringShahid Beheshti UniversityTehran ***Iran Faculty of mechanical and Energy Engineering Shahid Beheshti UniversityTehran ***Iran

In this paper,layered periodic foundations(LPFs)are numerically examined for their responses to longitudinal and transverse modes in the time and frequency *** different unit-cells,i.e.,2-layer,4-layer,and 6-layer unit-cells,comprising concrete/rubber,concrete/rubber/steel/rubber,and concrete/rubber/steel/rubber/lead/rubber materials,respectively,are taken into ***,the viscoelasticity behavior of the rubber is modeled with two factors,i.e.,a frequency-independent(FI)loss factor and a linear frequency-dependent(FD)loss *** the extraction of the complex dispersion curves and the identification of the band gaps(BGs),the simulations of wave transmission in the time and frequency domains are performed using the COmSOL *** parametric studies evaluate the effects of the rubber viscoelasticity models on the dispersion curves and the wave transmission for the longitudinal and transverse *** results show that considering the rubber viscoelasticity enhances the wave attenuation ***,the transverse-mode damping is more sensitive to the viscoelasticity model than its longitudinal *** 6-layer unit-cell LPF exhibits the lowest BG,ranging from 4.8 Hz to 6.5 Hz.

关键词： layered metamaterial periodic foundation complex dispersion curve wave transmission diagram

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Engineering of efficient visible light photocatalysts:Ti_(1-x+y)Cu_(x)La_(y)O_(2)(x=0.03;y=0,0.005,0.01) compositions

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Journal of Rare Earths 2024年第3期42卷 497-505,I0003页

作者： S.m.Yakout A.m.Youssef Inorganic Chemistry Department National Research Centre(NRC)El Buhouth StDokkiCairo12622Egypt

In dye-photocatalysis, widening the wavelengths absorption range of catalysts as well as aborting the recombination of the photoexcited charge carriers(electrons-holes pairs) are of paramount *** the current study, we report the photocatalytic characteristics of four compositions composed of TiO_(2),Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders for two harmful dyes(Congo red and methylene blue). The X-ray diffraction technique verified the configuration of mixed anatase and rutile phases in pure TiO_(2)and Ti_(0.97)Cu_(0.03)O_(2)powders while Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders possess anatase phase only. The changes of the band gap structure and dimensions of the unit cell volume of TiO_(2)confirm the substitution of Ti^(4+)sites by Cu^(2+)and La^(3+)ions. Remarkable widening of wavelengths absorption with formation of long absorption tails were found in TiO_(2)(3.13 e V) through insertion of La^(3+)plus Cu^(2+)ions. Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)samples exhibit a visible light band gap of 2.3 and 2.7 e V, respectively. Based on SEm images, incorporation of Cu^(2+)and La^(3+)ions influences the surface morphology of TiO_(2). The resulting Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders present enhanced photocatalytic activity towards Congo red dye degradation compared to pure one under natural solar spectrum. The best Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst exhibits superior photocatalytic activity of 96% for 10 ppm CR dye in 20 min as well as above average photocatalytic efficiency of 63% for 30 ppm CR dye in 120 min. As well, it showed acceptable photodegradation activity of 52% for 30 ppm mB solution in 140 min of sunlight irradiation. The heightened photodegradation efficiency of Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst can be clarified in terms of higher ch

关键词： Semiconductor TiO_(2) Rare earths Congo red methylene blue Solar spectrum Photodegradation

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