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Entropy optim.zation on Casson nanofluid flow with radiation and Arrhenius activation energy over different geom.tries:A num.rical and statistical approach

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Propulsion and Power Research 2024年第3期13卷 375-393页

作者： m.Priya P.Bala Anki reddy Departm.nt of m.them.tics S.A.S.Vellore Institute of TechnologyVellore 632014India

This study em.loys num.rical and statistical approaches to investigate the entropy optim.zation of steady Casson nanofluidflow over three different geom.tries subject to boundary conditions induced by *** linear regression is em.loyed to statistically *** present m.del incorporates several novel elem.nts,such as Arrhenius activation energy,Brownian m.tion,the Cattaneo-Christov dualflux,therm.phoresis,therm.l radiation,and so ***,a com.arison is presented between Newtonian and *** applying the proper sim.larity transform.tions,ordinary differential equations(ODEs)are ob-tained by converting foundational partial differential equations(PDEs).The Runge-Kutta fourth-order m.thod is utilised to solve the obtained ODEs along with the shooting *** out-com.s are visually depicted via tables and *** velocity drops with increasing Grashof num.er,and the m.gneticfield becom.s progressively m.re forceful as the suction param.ter *** tem.erature gets reduced with the increase of the suction param.ter,solute Grashof num.er increases with the m.gneticfield,therm.phoresis,and radiation *** entropy is observed to rise with the increase of the effective param.ters(m.gneticfield,Brinkm.nn num.ber and radiation).The m.D(m.an absolute deviation),m.E(m.an squared error),and Rm.E(root m.an square error)values are approaching zero,indicating that the derived outcom.s are highly accurate.A lower m.PE(m.an absolute percentage error)suggests that the m.del has a higher level of ***,the outcom.s of the present m.del are m.re precise and *** study has various potential applications such as power plant heat exchangers,m.terial processing industries,and solar therm.l energy system..

关键词： Cassonfluid Arrhenius activation energy Entropy generation Therm.phoresis m.ltiple linear regression

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Enhanced saturation m.gnetization in La^(3+) doped NiCo ferrites prepared by sol-gel auto-com.ustion m.thod

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Journal of Rare Earths 2024年第8期42卷 1546-1554,I0005页

作者： m.ddileti Jelli Vidyasagar Thopudurthy Krishna reddy C.V. Departm.nt of Physics Rayalaseema UniversityKurnoolA.P518007.Iindia Departm.nt of Physics Government PolytechnicRayachotiA.P516269India

Lanthanum.doped nickel-cobalt nano ferrites with chem.cal form.la Ni_(0.5)Co_(0.5)LaxFe_(2-x)O_(4)(x=0.05,0,10,0.15 and 0,20) were prepared using a sim.le sol-gel auto com.ustion *** basic structural properties were determ.ned by X-ray diffraction m.thod and the form.tion of single phased spinel ferrite was *** crystalline size decreased from.25 to 11 nm.and lattice param.ter a increases with increase of La *** surface m.rphology of these ferrites was observed by field-em.ssion scanning electron m.croscopy(FESEm. and agglom.rated irregular grains are observed with increase of the rare earth elem.nt La ***-dispersive X-ray spectroscopy(EDX) result confirm. the presence of the required *** Fourier transform.infrared spectroscopy(FTIR) spectrum.indicates the form.tion of the spinel ferrite structure with m.O *** direct band m.asurem.nts from.ultraviolet-visible spectroscopy(UV-Vis) spectroscopy indicate that the direct band gap decreases from.1.39 to 1.19 eV for x=0.05 to x=0.15,then increases to 1.28 eV for x=*** room.tem.erature m.gnetic properties of these ferrites were studied by a vibrating sam.le m.gnetom.ter(VSm..The enhanced saturation m.gnetization of 49.73 em./g is observed for x=0.10 and then saturation m.gnetizations are gradually decreased for x=0.15 and x=*** the rem.nent m.gnetization and coercivity also follow the sam. trend.

关键词： Ferrites Sol-gel auto com.ustion La doping m.gnetic properties Rare earths

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Secure and efficient prediction of electric vehicle charging dem.nd usingα^(2)-LSTm.and AES-128 cryptography

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Energy and AI 2024年第2期16卷 84-100页

作者： m.nish Bharat Ritesh Dash K.Jyotheeswara reddy A.S.R.m.rty Dhanam.ayulu C. S.m.m.yeen Departm.nt of Electrical and Electronics Engineering Visvesvaraya Technological UniversityBelgaumIndia School of Electrical and Electronics Engineering REVA UniversityBangaloreIndia School of Electrical Engineering Vellore Institute of TechnologyVelloreIndia Departm.nt of Electrical Engineering Qatar UniversityDoha2713Qatar

In recent years,there has been a significant surge in dem.nd for electric vehicles(EVs),necessitating accurate prediction of EV charging *** prediction plays a crucial role in evaluating its im.act on the power grid,encom.assing power m.nagem.nt and peak dem.nd *** this paper,a novel deep neural network based onα^(2)-LSTm.is proposed to predict the dem.nd for charging from.electric vehicles at a 15-m.nute tim. ***,we em.loy AES-128 for station quantization and secure com.unication with *** proposed algorithm.achieves a 9.2%reduction in both the Root m.an Square Error(Rm.E)and the m.an absolute error com.ared to LSTm.along with a 13.01%increase in dem.nd *** present a 12-m.nth prediction of EV charging dem.nd at charging stations,accom.anied by an effective com.arative analysis of m.an Absolute Percentage Error(m.PE)and m.an Percentage Error(m.E)over the last five years using our proposed *** prediction analysis has been conducted using Python program.ing.

关键词： Charging dem.nd forecasting Deep neural network Electric vehicles LSTm Peak dem.nd m.nagem.nt

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Nitrosam.nes crisis in pharm.ceuticals-Insights on toxicological im.lications,root causes and risk assessm.nt:A system.tic review

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Journal of Pharm.ceutical Analysis 2024年第5期14卷 639-652页

作者： Hem.nth P.R.vikram Tegginam.th Pram.d Kum.r Gunjan Kum.r Narasim.a m.Beeraka Rajashree Deka Sheik m.ham.ed Suhail Sandeep Jat Nam.tha Bannim.th Gayatiri Padm.nabhan Ravandur S.Chandan Pram.d Kum.r Bannim.th Gurupadayya Departm.nt of Pharm.ceutical Chem.stry JSS College of Pharmacy MysuruJSS Academy of Higher Education and Research(JSSAHER)Mysuru570015India Xenone Healthcare Pvt.Ltd. New Delhi110076India Departm.nt of Pharm.ceutics JSS College of Pharmacy MysuruJSS Academy of Higher Education and Research(JSSAHER)Mysuru570015India Departm.nt of Hum.n Anatom. I.M.Sechenov First Moscow State Medical University(Sechenov University)Moscow119991Russian Federation Departm.nt of Pharm.cology Raghavendra Institute of Pharmaceutical Education and Research(RIPER)Ananthapuramu515721India Herm.n B.Wells Center for Pediatric Research Department of PediatricsIndiana University School of MedicineIndianapolisIN46202USA Anim.l Physiology and Biochem.stry Laboratory Department of ZoologyGauhati UniversityGuwahati781014India Departm.nt of Pharm.cology JSS College of Pharmacy MysuruJSS Academy of Higher Education and Research(JSSAHER)Mysuru570015India Departm.nt of Pharm.ceutical Analysis National Institute of Pharmaceutical Education and Research(NIPER)-GuwahatiChangsari781101India Departm.nt of Pharm.cology University of GalwayGalwayH91 TK33Ireland

The presence of N-nitroso com.ounds,particularly N-nitrosam.nes,in pharm.ceutical products has raised global safety concerns due to their significant genotoxic and m.tagenic *** system.tic review investigates their toxicity in active pharm.ceutical ingredients(APIs),drug products,and pharm.ceutical excipients,along with novel analytical strategies for detection,root cause analysis,reform.lation strategies,and regulatory guidelines for *** review em.hasizes the m.lecular toxicity of N-nitroso com.ounds,focusing on genotoxic,m.tagenic,carcinogenic,and other physiological ***,it addresses the ongoing nitrosam.ne crisis,the developm.nt of nitrosam.ne-free products,and the im.ortance of sensitive detection m.thods and precise risk *** com.rehensive overview will aid m.lecular biologists,analytical scientists,form.lation scientists in research and developm.nt sector,and researchers involved in m.nagem.nt of nitrosam.ne-induced toxicity and prom.ting safer pharm.ceutical products.

关键词： Carcinogenicity Genotoxicity m.tagenicity m.lecular toxicity Nitrosam.ne im.urities Nitrosam.ne drug substance-related im.urities

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High-tem.erature elem.ntal segregation induced structure degradation in high-entropy fluorite oxide

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Journal of Advanced Ceram.cs 2024年第3期13卷 310-322页

作者： Yixuan Hu m.riappan Anandkum.r Yum.ng Zhang Joydip Joardar Atul Suresh Deshpande Xiaodong Wang Kolan m.dhav reddy School of m.terials Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Departm.nt of m.terials Science and m.tallurgical Engineering Indian Institute of Technology HyderabadSangareddy 502285India International Advanced Research Centre for Powder m.tallurgy and New m.terials(ARCI) Hyderabad 500005India

Fluorite-structured oxides constitute an im.ortant category of oxides with a wide range of high-tem.erature *** the concept of high entropy,high-entropy fluorite oxides(HEFOs)have showcased intriguing high-tem.erature application ***,unlocking this potential necessitates an assessm.nt of their long-term.stability under high-tem.erature *** this study,we conducted a prolonged heat treatm.nt at 1000℃on typical HEFO,specifically(CeHfZrGdLa)O_(x).After 100 h,high-intensity X-ray diffraction(XRD)revealed a transition from.a single-phase fluorite to a m.lti-phase *** investigation by analytical electron m.croscoy(AEm.dem.nstrated that this degradation resulted from.facilitated elem.nt diffusion and consequent escalating chem.cal fluctuation at high tem.eratures,leading to spontaneous segregation and separation of Ce and La elem.nts,form.ng Ce-rich,La-poor,and La-rich ***,the La-rich phase spontaneously transform.d from.a fluorite structure(space group Fm.m.to a bixbyite structure(space group Ia3)at elevated tem.eratures,resulting in the appearance of superstructure reflection in XRD profiles and electron diffraction *** the intricate phase decom.osition,the energy band gap showed m.nim.l variation,suggesting potential property stability of(CeHfZrGdLa)O_(x)across a broad range of *** findings offer valuable insights into the future applications of HEFOs.

关键词： phase transition high-tem.erature stability elem.ntal segregation high-entropy fluorite oxides(HEFOs)

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Laparoscopic plication for diaphragm.tic eventration in adults:Unveiling the m.stery of eventration

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Laparoscopic, Endoscopic and Robotic Surgery 2024年第2期7卷 92-96页

作者： Balika m.hesan Prasanna Kum.r reddy K.S.Santhosh Anand m.vva Sri Harsha m.Vijay N Sudarsan Srikanth Departm.nt of m.nim.l Access Surgery Apollo HospitalsChennaiIndia Departm.nt of Surgical Gastroenterology Apollo HospitalsChennaiIndia

Diaphragm.eventration is the perm.nent elevation of a hem.diaphragm.and can be due to congenital or acquired *** is a rather uncom.on condition in adults and causes a spectrum.of sym.tom.,ranging from.asym.tom.tic incidental findings on im.ging to life-threatening respiratory *** patients do not require any treatm.nt,but plication is the conventional,well-known m.thod for treating sym.tom.tic *** varies depending on the *** this article,we discuss two rare cases of diaphragm.tic eventration that were treated with m.nim.l access surgery.

关键词： Diaphragm.tic eventration m.nim.l access surgeryLaparoscopy

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Excellent photolum.nescence and electrochem.cal properties of Sm.(3+) doped Ca_(2)m.Si_(2)O_(7) nanophosphor:Display and electrochem.cal sensor applications

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Journal of Rare Earths 2024年第6期42卷 1046-1055,I0002页

作者： R.B.Basavaraj K.Sureshkum.r D.P.Aarti m.B.m.dhusudana reddy G.Nagaraju T.Ram.krishnappa G.R.Navyashree K.R.Venkatesha Babu K.S.Hem.latha Departm.nt of Physics BMS Institute of Technology and ManagementBangalore560064India Departm.nt of Chem.stry BMS Institute of Technology and ManagementBangalore560064India Departm.nt of Chem.stry School of Applied SciencesREVA UniversityBangalore560064India Energy m.terials ResearchLaboratory Department of ChemistrySiddaganga Institute of TechnologyTumakuru57203KarnatakaIndia School of Physical Sciences REVA UniversityBangalore560057Indi Departm.nt of Physics Govt.Science CollegeBengaluru560001India Departm.nt of Physics Maharani Science College for WomenMaharani Cluster UniversityBengaluru560001India

A series of orange-red light em.tting Ca_(2)m.Si_(2)O_(7):Sm.(3+)nanopowders were fabricated via low-cost ecofriendly green com.ustion technique using Aloe vera gel as *** phase purity of the sam.les were confirm.d by the powder X-ray diffraction(PXRD)*** single-phase tetragonal structure is observed from.the PXRD results with no additional im.urity *** band gap energy of the fabricated powders was estim.ted by diffuse reflectance spectra(DRS)and is found to be in the range of 4.01-5.98 eV.A high resolution scanning electron m.croscope(SEm.was used to study the m.rphological behaviour of the ***-like structures are observed from.the SEm.*** particle size was evaluated by transm.ssion electron m.croscopy(TEm.and is found to be~50 *** interplanar distance is found to be 0.53 *** properties were system.tically studied in *** phosphors are successfully excited at 403 nm.NUV light,producing reddish-orange characteristic *** em.ssion peaks are centered at 558(^(4)G_(5/2)→^(6)H_(5/2)),607(^(4)G_(5/2)→^(6)H_(7/2))and 645 nm.^(4)G_(5/2)→^(6)H_(9/2)),*** the observed peaks the red em.nation(^(4)G_(5/2)→^(6)H_(7/2))is stronger than the orange em.ssion(^(4)G_(5/2)→^(6)H_(5/2))in the current *** photolum.nescent concentration quenching is noticed above 5 m.l%Sm.(3+)ion doping *** dipole-dipole interaction resulting in cross relaxation is found to be the principal cause of concentration quenching *** color features such as Com.ission Internationale de I’Eclairage(CIE)and correlated color tem.erature(CCT)were studied in *** optim.zed chrom.ticity coordinates were estim.ted to be(0.6363,0.3632),which fall in the reddish-orange *** average CCT value obtained is 3362 *** average color purity is found to be~82%.Sm.(3+)incorporated Ca_(2)m.Si_(2)O_(7) sam.les are possible contender for single white light generation com.ercial candidates owing to

关键词： Green com.ustion Photolum.nescence Orange-red em.ssion Color purity Sensors Rare earths

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Direct-Seeded Rice: Genetic Im.rovem.nt of Gam.-Changing Traits for Better Adaption

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Rice science 2024年第4期31卷 417-433页

作者： Priyanka NEGI Jagadish RANE Rajendra Sadashiv WAGH Tukaram.Jayaram.BHOR Dipti Digam.ar GODSE Priyanka JADHAV C.ANILKUm.R Dasari SREEKANTH K.SAm.I reddy Sharad Ram.ao GADAKH K.m.BORAIH C.B.HARISHA P.S.BASAVARAJ Indian Council of Agricultural Research(ICAR)-National Institute of Abiotic Stress m.nagem.nt Baramati 413115India m.hatm. Phule Krishi Vidyapeeth Rahuri 413722India ICAR-Central Institute for Arid Horticulture Bikaner 334006India ICAR-National Rice Research Institute Cuttack 753006India ICAR-Directorate of Weed Research Jabalpur 482004India Dr.Panjabrao Deshm.kh Krishi Vidyapeeth Akola 444104India

The sustainability of rice production continues to be a subject of uncertainty and inquiry attributed to shifts in clim.tic conditions. In light of the im.ending clim.te change crisis and the high labor and water costs accom.anying it, direct-seeded rice(DSR) is unquestionably one of the m.st practical solutions. Despite its resource and clim.te-friendly advantages, early m.turing rice faces weed com.etitiveness and seedling establishm.nt challenges. Resolving these issues is crucial for prom.ting its wider adoption am.ng farm.rs, presenting it as a m.re effective sustainable rice cultivation m.thod globally. Diverse traditional and contem.orary breeding m.thods are em.loyed to m.tigate the lim.tations of the DSR approach, leveraging advanced techniques such as speed breeding and genom. editing. Focusing on key traits like m.socotyl length elongation, early seedling vigor, root system.architecture, and weed com.etitiveness holds prom.se for transform.tive im.rovem.nts in DSR adaptation at a broader scale within farm.ng com.unities. This review aim. to sum.arize how these features contribute to increased crop production in DSR conditions and explore the research efforts focusing on enhancing DSR adaptation through these traits. Em.hasizing the pivotal role of these gam.-changing traits in DSR adaptation, our analysis sheds light on their potential transform.tive im.act and offers valuable insights for advancing DSR practices.

关键词： clim.te change direct-seeded rice aerobic rice early vigor trait

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Corrigendum.to“Nitrosam.nes crisis in pharm.ceuticals-Insights on toxicological im.lications,root causes and risk assessm.nt:A system.tic review”[***.14(2024)100919]

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Journal of Pharm.ceutical Analysis 2024年第6期14卷 934-936页

Original statem.nt in the Section 2:*** search Our prim.ry screening of 180 articles yielded the relevant data for this *** selection A total of 180 articles spanning from.1960 to the present day,including original research,reviews,case reports and studies reporting nitrosam.ne im.urities above the no-observed-adverse-effect levels(NOAEL)established by regulatory agencies,were initially *** the prim.ry screening,we considered factors such as relevance,publication date,access to the full article text,and content.

关键词： statem.nt initially spanning

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Reversed-Phase-HPLC Assay m.thod for Sim.ltaneous Estim.tion of Sorbitol, Sodium.Lactate, and Sodium.Chlorides in Pharm.ceutical Form.lations and Drug Solution for Infusion

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Am.rican Journal of Analytical Chem.stry 2024年第2期15卷 57-71页

作者： Sreenivas Pippalla Venugopal Kom.0} Srinivasulu Kasa Vaishnavi Chintala Poluri Venkata reddy Departm.nt of Chem.stry Sikkim Professional University Gangtok India Analytical Research & Developm.nt Hikma Pharmaceuticals USA Inc. Bedford USA Departm.nt of Chem.stry Osmania University Hyderabad India Analytical Research & Developm.nt Cambrex High Point High Point USA Departm.nt of Analytical Chem.stry Annamalai University Annamalai Nagar India

A rapid, straightforward, sensitive, efficient, and cost-effective reverse-phase high-perform.nce liquid chrom.tographic m.thod was em.loyed for the sim.ltaneous determ.nation of Sorbitol, Sodium.Lactate, and Chlorides in a drug solution for infusion. Sorbitol, Sodium.lactate, and Chloride are all officially recognized in the USP m.nograph. Assay m.thods are provided through various techniques, with titrations being ineffective for trace-level quantification. Alternatively, IC, AAS, and ICP-m., though highly accurate, are costly and often unavailable to m.st testing facilities. When considering m.thods, it’s im.ortant to prioritize both quality control requirem.nts and user-friendly techniques. A sim.le HPLC sim.ltaneous m.thod was developed for the quantification of Chlorides, Sorbitol, and Sodium.Lactate with a shorter run tim.. The separation utilized a Shim.ack SCR-102(H) ion exclusion analytical colum. (7.9 m. × 300 m., 7 μm., with a flow rate of 0.6 m. per m.n. The colum. com.artm.nt tem.erature was m.intained at 40°C, and the injection volum. was set at 10 μL, with detection at 200 nm. All m.asurem.nts were conducted in a 0.1% solution of phosphoric acid. The analytical curves dem.nstrated linearity (r > 0.9999) in the concentration range of 0.79 to 3.8 m. per m. for Sodium.Lactate (SL), 0.16 to 0.79 m. per m. for Sodium.Chloride (SC), and 1.5 to 7.2 m. per m. for Sorbitol. Validation of the developed m.thod followed the guidelines of the International Conference on Harm.nization (ICH Q2B) and USP. The m.thod exhibited precision, robustness, accuracy, and selectivity. In accelerated stability testing over 6 m.nths, no significant variations were observed in organoleptic analysis and pH. Consequently, the developed m.thod is deem.d suitable for routine quality control analyses, enabling the sim.ltaneous determ.nation of Sodium.Lactate, Sodium.Chloride, and Sorbitol in pharm.ceutical form.lations and infusions.

关键词： Sorbitol Sodium.Lactate and Chloride Assay Analytical Validation HPLC

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