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Nano Research 2024年第4期17卷 3413-3422页

作者： Huimei Chen yan yang Chi Jiao Zhiwen zhuo Junjie Mao yan Liu Key Laboratory of Functional Molecular Solids Ministry of EducationCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241002China

The electrocatalytic nitrogen reduction reaction(e-NRR)is a promising alternative method for the Haber–Bosch ***,it still faces many challenges in searching for high activity,stability,and selectivity catalysts and ascertaining the catalytic mechanism with complete ***,a series of graphene-based N-bridged dual-atom catalysts(M1-N-M2/NC)are systematically investigated via first-principle calculation and a high-throughput screening *** result unveils that N_(2) adsorption on M1-N-M2/NC in bridge-on adsorption mode can effectively break the scaling relationship on single-atom catalysts(SACs).Moreover,V-N-Ru/NC and V-N-Os/NC are systematically screened out as promising e-NRR catalysts,with extremely low limiting potentials of-0.20 and-0.18 V,***,the adsorption site competition between*N_(2) and*H,as well as the competitive twin reactions of hydrogen evolution reaction(HER)on intermediates(N_(n)H_(m))during the e-NRR process,is systematically evaluated to form a remodeling insight for the reactions in mechanism,and the e-NRR of new proposed dual-atom catalysts(DACs)is strategically optimized for its high-efficiency performance potential via our remolding insight in e-NRR *** work provides new ideas and insights for the design and mechanism of e-NRR catalysts and an effective strategy for rapidly screening highly efficient e-NRR catalysts.

关键词： nitrogen reduction dual-atom catalysts high-throughput screening hydrogen evolution reaction density functional theory calculations

Constitutionally adaptive crown ether-based macrocyclic bolaamphiphile with redox-responsive switching of lower critical solution temperature behaviors

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Chinese Chemical Letters 2021年第12期32卷 4024-4028页

作者： Qiangqiang Xu Zhiliyu Cui Jizhen Yao Bo Li Ping lv Xin Shen zhuo Yu yan Ge Zhenhui Qi Sino-German Joint Research Lab for Space Biomaterials and Translational Technology Synergetic Innovation Center of Biological Optoelectronics and Healthcare Engineering(BOHE)Xi'an 710072China

Constitutionally adaptive chemistry of selenium-containing crown ethers(CEs) offers a new platform for controlling/switching the hydration of bolaamphiphile skeletons in water in an effective and simple manner by the virtue of covalent bonding. The adaptive behaviour of the macrocyclic bolaamphiphiles(transformations between C7SeBola and C7SeOBola) in response to redox environment was found to be a decisive factor.

关键词： Macrocycle Crown ether Bola Amphiphiles Selenium

Multiplicative forms on Poisson groupoids

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Science China Mathematics 2025年第1期 169-206页

作者： zhuo Chen Honglei Lang Zhangju Liu Department of Mathematical Sciences Tsinghua University College of Science China Agricultural University School of Mathematics and Statistics Henan University

First,we prove a decomposition formula for any multiplicative differential form on a Lie groupoid ***,we prove that if G is a Poisson Lie groupoid,then the space ?mult·（G） of multiplicative forms on G has a differential graded Lie algebra（DGLA） ***,when combined with ?·（M）,which is the space of forms on the base manifold M of G,?mult·（G） forms a canonical DGLA crossed *** supplements a previously known fact that multiplicative multi-vector fields on G form a DGLA crossed module with the Schouten algebra Γ（∧·A） stemming from the Lie algebroid A of G.

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Ubiquitiformal Crack Extension in Quasi-Brittle Materials

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Acta Mechanica Solida Sinica 2020年第5期33卷 674-691页

作者： zhuo-Cheng Ou Yi-Bo Ju Jing-yan Li zhuo-Ping Duan Feng-Lei Huang State Key Laboratory of Explosion Science and Technology School of MechatronicsBeijing Institute of TechnologyBeijing100081China

Based on the concept of ubiquitiform,a ubiquitiformal crack extension model is developed for quasi-brittle *** simulations are carried out using the ABAQUS software with the XFEM-based cohesive segments method to determine the ubiquitiformal crack extension path or fracture surface profile of the material under quasi-static *** a ubiquitiformal crack model removes the singularity of a fractal crack;for the latter,the boundary value problem cannot be uniquely *** the simulation,the material properties,e.g.,the tensile strength,are assumed to obey the Weibull *** meso-element equivalent method is used to determine the correlation between the Weibull distribution parameters and the aggregate gradation of concrete *** numerical results show that the complexities of the ubiquitiformal crack configurations are in good agreement with the previous experimental *** the numerical simulation,it is further demonstrated that the complexity of a ubiquitiformal crack is insensitive to the random spatial distribution of the aggregates,but more dependent on the Weibull distribution parameters which reflect the heterogeneity of the concrete.

关键词： Ubiquitiformal crack Complexity Quasi-brittle materials Random distribution of tensile strength Weibull distribution parameters

Magnetic Transport Properties of Fe-Phthalocyanine Dimer with Carbon Nanotube Electrodes

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Chinese Physics Letters 2017年第4期34卷 79-82页

作者： Yu-zhuo lv Peng Zhao De-Sheng Liu School of Physics and Technology University of Jinan Jinan 250022 School of Physics Shandong University Jinan 250100 Department of Physics Jining University Qufu 273155

Based on the non-equilibrium Green＇s method and density functional theory, the magnetic transport of Fe- phthMocyanine dimers with two armchair single-wailed carbon nanotube electrodes is investigated. The results show that the system can present high-performance spin filtering, magnetoresistance, and low-bias spin negative differential resistance effects by tuning the external magnetic field. These results show that the Fe-phthalocyanine dimer has the potential to design future molecular spintronic devices.

关键词： Magnetic Transport Properties of Fe-Phthalocyanine Dimer with Carbon Nanotube Electrodes Fe AP NDR CSR

A prediction method for ground-based stellar occultations by ellipsoidal solar system bodies and its application

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Research in Astronomy and Astrophysics 2017年第5期17卷 65-78页

作者： Ye Yuan yan-Ning Fu zhuo Cheng Purple Mountain Observatory Chinese Academy of Sciences Nanjing 210008 China University of Chinese Academy of Sciences Beijing 100049 China

A new programmable prediction method is developed to refine the occultation band by taking into consideration the triaxiality of an occulting body, as well as two more factors, namely, the barycenter offset of an occulting planet from the relevant planetary satellite system and the gravitational deflection of light rays due to an occulting planet. Although these factors can be neglected in most cases, it is shown that there are cases when these factors can cause a variation ranging from several tens to thousands of kilometers in the boundaries of occultation bands. Knowledge of analytic geometry simplifies the process of derivation and computation. This method is applied to long-term predictions of Jovian and Saturnian events.

关键词： shadow stellar Saturn Jupiter uncertainty programmable planet offset derivation refine

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基于BIM的智慧农业温室大棚建模分析

农机化研究 2025年第3期47卷 217-221页

作者：李祯庄卓河南工业职业技术学院河南南阳473000

智慧农业是当前农业发展的趋势,而温室大棚作为重要的农业生产设施,对其进行建模分析具有重要意义。为此,基于BIM技术,对Venlo智慧农业温室大棚进行了建模分析。首先,对温室大棚的设计流程进行分析;然后,对BIM工作流做介绍和分析,并对... 详细信息

智慧农业是当前农业发展的趋势,而温室大棚作为重要的农业生产设施,对其进行建模分析具有重要意义。为此,基于BIM技术,对Venlo智慧农业温室大棚进行了建模分析。首先,对温室大棚的设计流程进行分析;然后,对BIM工作流做介绍和分析,并对建筑结构和节点进行深化分析;最后,设计了一栋智慧农业温室大棚,并利用BIM软件对其进行三维建模和分析。实例设计表明:基于BIM技术的智慧农业温室大棚建模分析具有较高的准确性和可操作性,可为农业生产提供重要支持。

关键词：智慧农业 Venlo温室大棚 BIM技术建筑结构三维建模

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Reinforcement learning based edge computing in B5G

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Digital Communications and Networks 2024年第1期10卷 1-6页

作者： Jiachen yang Yiwen Sun Yutian Lei zhuo Zhang yang Li Yongjun Bao Zhihan lv School of Electrical and Information Engineering Tianjin UniversityTianjin300072China Technology and Data Center ***Beijing100176China School of Data Science and Software Engineering Qingdao UniversityQingdao266101China

The development of communication technology will promote the application of Internet of Things,and Beyond 5G will become a new technology *** the same time,Beyond 5G will become one of the important supports for the development of edge computing *** paper proposes a communication task allocation algorithm based on deep reinforcement learning for vehicle-to-pedestrian communication scenarios in edge *** trial and error learning of agent,the optimal spectrum and power can be determined for transmission without global information,so as to balance the communication between vehicle-to-pedestrian and *** results show that the agent can effectively improve vehicle-to-infrastructure communication rate as well as meeting the delay constraints on the vehicle-to-pedestrian link.

关键词： Reinforcement learning Edge computing Beyond 5G Vehicle-to-pedestrian

Numerical Forecasting of Icing on Structural Components of Offshore Platforms in Polar Regions

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China Ocean Engineering 2021年第4期35卷 588-597页

作者： BAI Xu SHEN Jie XUE yan-zhuo SHU Yuan-chao School of Naval Architecture&Ocean Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China College of Shipbuilding Engineering Harbin Engineering UniversityHarbin 150001China

The Polar Regions are rich in natural resources but experience an extremely cold *** surfaces of offshore platforms operating in the Polar Regions are prone to *** develop solutions to this problem of surface icing,the influence of both the liquid water concentration of the surrounding atmosphere and the average water droplet diameter on the formation of ice on two major structural components of offshore platforms was analyzed using a combination of Fluent and *** showed that at a wind speed of 7 m/s,as the concentration of liquid water in the air increases from 0.05 to 0.25 g/m3,the amount and thickness of the icing on the surfaces of the two structural components increase *** a wind speed of 7 m/s and when the size of the average water droplet diameter is 20–30(30–35)μm,as the average water droplet diameter increases,the amount and thickness of the icing on the surfaces of the two structural components increase(decrease)gradually.

关键词： offshore platform in cold regions icing numerical analysis icing thermodynamic model icing calculation process

Influence of environmental factors on arsenic accumulation and biotransformation using the aquatic plant species Hydrilla verticillata

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Journal of Environmental Sciences 2020年第4期32卷 244-252页

作者： Yuan Zhao zhuo Zhen Zhenhong Wang Liqing Zeng Changzhou yan Key Laboratory of Urban Environment and Health Fujian Key Laboratory of Watershed EcologyInstitute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China School of Chemistry and Environment Fujian Province Key Laboratory of Modern Analytical Science and Separation TechnologyMinnan Normal UniversityZhangzhou 363000China

Hydrilla verticillata(waterthyme)has been successfully used for phytoremediation in arsenic(As)contaminated *** evaluate the effects of environmental factors on phytoremediation,this study conducted a series of orthogonal design experiments to determine optimal conditions,including phosphorus(P),nitrogen(N),and arsenate(As(Ⅴ))concentrations and initial pH levels,for As accumulation and biotransformation using this aquatic plant species,while also analyzing As species transformation in culture media after 96-hr *** of variance and the signal-to-noise ratio were used to identify both the effects of these environmental factors and their optimal conditions for this *** indicated that both N and P significantly impacted accumulation,and N was essential in As species *** N and intermediate P levels were critical to As accumulation and biotransformation by ***,while high N and low P levels were beneficial to As species transformation in culture *** highest total arsenic accumulation was(197.2±17.4)μg/g dry weight when As(V)was at level 3(375μg/L),N at level 2(4 mg/L),P at level 1(0.02 mg/L),and pH at level 2(7).Although *** is highly efficient in removing As(Ⅴ)from aquatic environments,its use could be potentially harmful to both humans and the natural environment due to its release of highly toxic *** cost-effective and ecofriendly phytoremediation of As-contaminated water,both N and P are helpful in regulating As accumulation and transformation in plants.

关键词： Phytoremediation Orthogonal design pH Phosphorus Nitrogen