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Porphyrins,phthalocyanines,and related covalent-organic frameworks in the photochemical and electrochemical water splitting:A review

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Particuology 2024年第7期90卷 236-265页

作者： Oxana V.Kharissova Yolanda Peña méndez Boris I.Kharisov Aleksandr LNikolaev Edith Luévano-Hipólito lucy T.González Universidad Autónoma de Nuevo León Ave.Universidad s/nSan Nicolás de los GarzaNuevo León66455Mexico Department of Chemistry Moscow State UniversityVorobievy HillsMoscowRussia CONACYT-Universidad Autónoma de Nuevo León Facultad de Ingeniería Civil-Departamento de Ecomateriales y EnergíaCd.UniversitariaC.P.66455San Nicolás de los GarzaNLMexico Tecnologico de monterrey Escuela de Ingeniería y CienciasMonterreyNuevo León 64890Mexico Tecnologico de monterrey Centro del AguaMonterreyNuevo León 64890Mexico

In this review,the possibilities of photochemical and electrochemical water splitting(WS)using porphyrins,phthalocyanines,related macrocycles,and their metal complexes are *** efforts are being carried out in order to develop novel and cheap methods for water decomposition to generate inexhaustible greener energy sources(molecular hydrogen)instead of oil and *** processes of WS in heterogeneous and homogeneous media require novel photo-and electrocatalysts,in particular those on macrocycle basis.A high WS efficiency has been observed for porphyrins and phthalocyanines,showing their suitability both for HER and OER processes are available using these relative compounds for WS *** can be used in photocatalytic and electrocatalytic WS processes both in their free forms or as metal porphyrins/porphyrinates,mainly loaded on various inorganic materials,such as Au NPs,C_(3)N_(4),GaP,KTaO_(3),GaP,and so on,as part of porphyrin-containing polymers or on electrode surface as modifying coatings,being sometimes better than commercial catalysts,such as Pt/*** H2 evolution can be considerably depended on the shape of porphyrin particles;in particular,porphyrin nanowires can yield up to 20 times more H2 than its *** certain cases,both HER and OER can be driven in the same electrolyte using metal *** capacity of metal porphyrins to generate ROS(in particular,singlet oxygen 1O_(2))under ultrasonic treatment is known and can be successfully used for H_(2)O_(2) and O_(2) *** can be used in similar processes in free form or as composites with inorganic or organic counterparts,being immobilized on nanocarbons,metal oxides and salts,or simply dissolved in water acting in a homogeneous *** additional use of ultrasound can lead to better results due to the synergistic effect of the sonochemical treatment and ***-organic frameworks are also applied for WS purposes and are mainly based

关键词： Porphyrins Phthalocyanines COFs Water splitting Photocatalysis Electrocatalysis

Hydroxyapatite composites with carbon allotropes:Preparation,properties,and applications

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Particuology 2024年第5期88卷 239-265页

作者： Boris I.Kharisov Oxana V.Kharissova lucy T.González Yolanda Peña méndez Igor E.Uflyand Idalia Gómez de la Fuente Universidad Autónoma de Nuevo León Ave.UniversidadCiudad UniversitariaSan Nicolás de los GarzaNuevo León 66455Mexico Tecnologico de monterrey Escuela de Ingeniería y CienciasMonterreyNuevo Leon 64890Mexico Department of Chemistry Southern Federal UniversityRostov-on-DonRussia

Hydroxyapatite(HA)and its composites with inorganic additives,dopants,and polymers is a rapidly developing branch in the materials *** particular,carbon allotropes are widely used in these composites being widely applied for medical *** a gap of insufficient generalization of recent achievements in the field of the HA/Carbon composites,in this review we present the state of the art of the field of HA composites and hybrids with classic carbon allotropes and *** composites are known for carbon nanotubes,nanofibers,graphene and its oxidized forms,as well as,in a lesser grade,for graphite,fullerenes,nanodiamonds,carbon nanofoams,*** composites can be fabricated by a variety of classic and less-common methods,such as co-precipitation(with or without ultrasonic treatment),CVD,hot isostatic pressing,hydrothermal,spark plasma sintering,biomimetic mineralization,thermal and plasma spray,electrochemical and electrophoretic deposition,self-assembling,3D printing,electrospinning,and lyophilisation,among *** of various synthesis techniques can be also carried out for composite *** or synthetic HA can be used as it is for further interaction with carbon allotropes or it can be first prepared and then reacted with carbon counterpart;similarly,carbon allotropes can be introduced into the interaction with HA directly or they can be first synthesized,in particular from *** biocompatible composites can be produced in the form of coatings,powders,and scaffolds and can additionally contain quantitative amounts of third phases,frequently natural or synthetic *** these composites,especially with O-containing functionalizing groups,HA disadvantages could be considerably decreased with simultaneous enhancement of mechanical properties,becoming similar to human bone,chemical stability and biocompatibility,as well as possessing antibacterial ***→G reduction and higher HA decoration were obs

关键词： Hydroxyapatite Carbon nanotubes Graphene Quantum dots Fullerenes Nanodiamonds

Forcing ocean model with atmospheric model outputs to simulate storm surge in the Bangladesh coast

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Tropical Cyclone Research and Review 2020年第2期9卷 117-134页

作者： Nabir mamnun lucy m.Bricheno md Rashed-Un-Nabi Nansen-Bangladesh International Centre for Coastal Ocean and Climate StudiesHouse 10Road 16AGulshanDhaka1212Bangladesh Faculty of marine Sciences and Fisheries University of ChittagongChattagram4331Bangladesh National Oceanography Centre Joseph Proudman BuildingBuilding6 Brownlow StreetLiverpoolL35DAUK

Tropical cyclones are devastating hazards and have been a major problem for the coastal population of B *** the advancements in atmospheric and oceanic prediction,accurate forecasting of storm surges is of specific interest due to their great potential to inflict loss of life and *** decades,the numerical model based storm surge prediction systems have been an important tool to reduce the loss of human lives and property *** order to improve the accuracy in predicting storm surge and coastal inundation,recent model development efforts tended to include more modeling components,such as meteorology model and surface wave model in storm surge *** this study,we used the outputs of an atmospheric model to force the ocean model for simulating storm surges in the Bay of Bengal with particular focus on the Bangladesh *** ability of the modeling system was investigated simulating water levels in the Bangladesh coast of two tropical cyclones Sidr(2007)and Aila(2009).The effectiveness of the model was verified through comparing the obtained computational outputs against tide gauge *** cyclone tracks and intensities reproduced by the atmospheric model were reasonable,though the model had a tendency to overestimate the cyclone intensity during peaks and also close to *** water levels are reproduced fairly well by the ocean model,although errors still *** root mean square errors in water level at different gauges range from 0.277 to 0.419 m with coefficient of correlation(R^2)between 0.64 and 0.97 in case of Sidr and0.209-0.581 m with R^20.62 to 0.98 for *** overall coupled modeling system is found to be useful with reasonable accuracy and precision,though there are spaces for ***-resolution modeling approaches are recommended to gain more skills.

关键词： Tropical cyclone Storm surge One-way coupling Bay of bengal

Health Emergency and Disaster Risk management: Five Years into Implementation of the Sendai Framework

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International Journal of Disaster Risk Science 2020年第2期11卷 206-217页

作者： Natalie Wright lucy Fagan Jostacio mLapitan Ryoma Kayano Jonathan Abrahams Qudsia Huda Virginia murray Global Public Health Public Health EnglandLondon SE18UGUK Disaster Risk management and Resilience Unit Health Security Preparedness DepartmentWorld Health OrganizationGeneva 1211Switzerland WHO Centre for Health Development(WHO Kobe Centre) KobeHyogo 651-0073Japan

The Sendai Framework for Disaster Risk Reduction 2015–2030 recognizes health at the heart of disaster risk management(DRm)at the global policy *** years on,it has catalyzed the rapid development of the field of Health Emergency and Disaster Risk management(Health EDRm)by providing a mandate for building partnerships as well as enhancing scientific *** milestones achieved include publication of the World Health Organization’s Health EDRm Framework,development of the WHO Thematic Platform for Health EDRm and the WHO Health EDRm Research Network,and further application of health information principles to ***,health actors at all levels have continued to engage in the Sendai Framework processes and have had a key role in its implementation and proposed *** have been significant gains made through the partnership of health and DRm,but the relationship has not been without its *** national,regional,and global initiatives continue to operate with a lack of consistency and of linkages to respond to the Sendai Framework’s call for embedding health resilience in DRm,and conversely,embedding DRm in health *** this hurdle is important,and doing so will be a key marker of success of the next 10 years of partnership under the Sendai Framework.

关键词： Data collection Disaster risk management Health emergencies Research networks Sendai Framework

Understanding acute burn injury as a chronic disease

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Burns & Trauma 2019年第1期7卷 213-221页

作者： lucy W.Barrett Vanessa S.Fear Jason C.Waithman Fiona m.Wood mark W.Fear Telethon Kids Institute University of Western AustraliaNorthern EntrancePerth Children’s Hospital15 Hospital AveNedlandsWA 6009Australia Institute for Respiratory Health Ground FloorE Block Sir Charles Gairdner HospitalHospital AvenueNedlandsWA 6009Australia Fiona Wood Foundation Fiona Stanley HospitalMNH(B)Main HospitalCD 15Level 4Burns Unit102-118 Murdoch DriveMurdochWA 6150Australia Burns Service of Western Australia WA Department of HealthNedlandsWA 6009Australia Burn injury research unit School of Biomedical SciencesUniversity of Western AustraliaCrawleyWA 6009Australia

While treatment for burn injury has improved significantly over the past few decades,reducing mortality and improving patient outcomes,recent evidence has revealed that burn injury is associated with a number of secondary pathologies,many of which arise long after the initial injury has *** studies have linked burn injury with increased risk of cancer,cardiovascular disease,nervous system disorders,diabetes,musculoskeletal disorders,gastrointestinal disease,infections,anxiety and *** wide range of secondary pathologies indicates that burn can cause sustained disruption of homeostasis,presenting new challenges for post-burn *** burn injury as a chronic disease will improve patient care,providing evidence for better long-term support and monitoring of *** focused research into the mechanisms underpinning long-term dysfunction,a better understanding of burn injury pathology may help with the development of preventative treatments to improve long-term health *** review will outline evidence of long-term health effects,possible mechanisms linking burn injury to long-term health and current research into burns as a chronic disease.

关键词： Burns Immune system Endocrine system Homeostasis Patient care Chronic disease

Towards an actionable One Health approach

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贫困所致传染病(英文) 2024年第2期13卷 77-82页

作者： Zhang Xiao-Xi Lederman Zohar Han Le-Fei Schurer Janna m. Xiao Li-Hua Zhang Zhi-Bing Chen Qiu-Lan Pfeiffer Dirk Ward michael P. Sripa Banchob Gabri?l Sarah Dhama Kuldeep Acharya Krishna Prasad Robertson lucy J. Deem Sharon L. Aenishaenslin Cécile Dantas-Torres Filipe Otranto Domenico Grace Delia Wang Yang Li Peng Fu Chao Poeta Patrícia Rahman md. Tanvir Kassegne Kokouvi Zhu Yong-Zhang Yin Kun Liu Jiming Wang Zhao-Jun Guo Xiao-Kui Gong Wen-Feng Schwartl?nder Bernhard Ren ming-Hui Zhou Xiao-Nong School of Global Health Chinese Center for Tropical Diseases Research Shanghai Jiao Tong University School of Medicine Shanghai People’s Republic of China Institute of One Health Shanghai Jiao Tong University Shanghai People’s Republic of China medical Ethics and Humanities Unit Hong Kong University Hong Kong People’s Republic of China Center for One Health University of Global Health Equity Butaro Rwanda College of Veterinary medicine South China Agricultural University Guangzhou People’s Republic of China School of Ecology and Environment Hainan University Haikou Hainan People’s Republic of China Branch of animal and vector-borne diseases Division of Infectious Disease Control Chinese Center for Disease Control and Prevention Beijing People’s Republic of China Centre for Applied One Health Research and Policy Advice Department of Infectious Diseases and Public Health Jockey Club College of Veterinary Medicine and Life Sciences City University of Hong Kong Hong Kong SAR People’s Republic of China Department of Pathobiology and Population Sciences Royal Veterinary College London United Kingdom Sydney School of Veterinary Science The University of Sydney Camden Australia Tropical Disease Research Center Department of Tropical Medicine Faculty of Medicine Khon Kaen University Khon Kaen Thailand Laboratory of foodborne parasitic zoonoses Department of translational physiology infectiology and public health Chair Faculty Committee on Internationalisation Faculty of Veterinary Medicine Ghent University Merelbeke Belgium Division of Pathology ICAR-Indian Veterinary Research Institute (IVRI) Bareilly Uttar Pradesh India Department of Livestock Services Animal Quarantine Office-Kathmandu Budhanilkantha Kathmandu Nepal Parasitology Department of Paraclinical Sciences Faculty of Veterinary Medicine Norwegian University of Life Sciences ?s Norway One Government Drive Saint Louis Zoo Institute for Conservation Medicine St. Louis USA Groupe de Recherche en épidémi

Background Despite the increasing focus on strengthening One Health capacity building on global level, challenges remain in devising and implementing real-world interventions particularly in the Asia-Pacific region. Recognizing these gaps, the One Health Action Commission (OHAC) was established as an academic community for One Health action with an emphasis on research agenda setting to identify actions for highest *** text This viewpoint describes the agenda of, and motivation for, the recently formed OHAC. Recognizing the urgent need for evidence to support the formulation of necessary action plans, OHAC advocates the adoption of both bottom-up and top-down approaches to identify the current gaps in combating zoonoses, antimicrobial resistance, addressing food safety, and to enhance capacity building for context-sensitive One Health *** By promoting broader engagement and connection of multidisciplinary stakeholders, OHAC envisions a collaborative global platform for the generation of innovative One Health knowledge, distilled practical experience and actionable policy advice, guided by strong ethical principles of One Health.

关键词： One Health Global Health One Health Action Commission Research agenda

Predicting disruptions to drug pharmacokinetics and the risk of adverse drug reactions in nonalcoholic steatohepatitis patients

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Acta Pharmaceutica Sinica B 2023年第1期13卷 1-28页

作者： Solène marie Kayla L.Frost Raymond K.Hau lucy martinez-Guerrero Jailyn m.Izu Cassandra m.myers Stephen H.Wright Nathan J.Cherrington College of Pharmacy Department of Pharmacology&ToxicologyUniversity of ArizonaTucsonAZ 85721USA College of medicine Department of PhysiologyUniversity of ArizonaTucsonAZ 85724USA

The liver plays a central role in the pharmacokinetics of drugs through drug metabolizing enzymes and ***-alcoholic steatohepatitis(NASH)causes disease-specific alterations to the absorption,distribution,metabolism,and excretion(ADmE)processes,including a decrease in protein expression of basolateral uptake transporters,an increase in efflux transporters,and modifications to enzyme *** can result in increased drug exposure and adverse drug reactions(ADRs).Our goal was to predict drugs that pose increased risks for ADRs in NASH *** research identified 71 drugs with reported ADRs in patients with liver disease,mainly non-alcoholic fatty liver disease(NAFLD),54 of which are known substrates of transporters and/or metabolizing *** NASH is the progressive form of NAFLD but is most frequently undiagnosed,we identified other drugs at risk based on NASH-specific alterations to ADmE ***,we present another list of 71 drugs at risk of pharmacokinetic disruption in NASH,based on their transport and/or metabolism *** encompasses drugs from various pharmacological classes for which ADRs may occur when used in NASH patients,especially when eliminated through multiple pathways altered by the ***,these results may inform clinicians regarding the selection of drugs for use in NASH patients.

关键词： Non-alcoholic steatohepatitis Hepatic elimination Transporter Enzyme Pharmacokinetics Drug-drug interaction Liver Adverse drug reaction

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Visit the Zoo

小学生导刊(高年级) 2016年第6期 46-46页

作者： lucy

Lily和爸爸妈妈一起去动物园玩。有两种动物给她留下了深刻印象。是谁呢?请你猜一猜。1I have sharp teeth in my big mouth,And I have short legs,But my tail is very *** in my eyes when I catch *** careful,I’m not kind.

关键词：动物 very

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中国大陆上地幔各向异性和壳幔变形模式

中国科学：地球科学 2014年第1期44卷 98-110页

作者：王椿镛常利军丁志峰刘琼林廖武林 lucy m FLESCH 中国地震局地球物理研究所北京100081 Purdue University West Lafayette IN 47907 USA

近10年来,中国布设的宽频带地震台站大幅度增加.宽频带地震记录中含有大量的剪切波分裂信息,它在揭示中国大陆上地幔的各向异性特征起重要作用.本文对这些台站的远震SKS和(或)SKKS记录,采用最小切向能量的分析方法,确定各台站剪切波分... 详细信息

近10年来,中国布设的宽频带地震台站大幅度增加.宽频带地震记录中含有大量的剪切波分裂信息,它在揭示中国大陆上地幔的各向异性特征起重要作用.本文对这些台站的远震SKS和(或)SKKS记录,采用最小切向能量的分析方法,确定各台站剪切波分裂的快波偏振方向和延迟时间.此外,还收集了前人在中国大陆及其周边地区的剪切波分裂研究的部分结果,形成拥有1020个剪切波分裂参数对的数据集.这些分裂参数展示了复杂的上地幔各向异性图像.统计分析表明,中国大陆存在较强的上地幔各向异性,平均的剪切波时间延迟为0.95 s,其中西部地区为1.01 s,东部地区为0.92 s.西部地区的各向异性强度略大于东部地区.在大尺度意义下,青藏高原及天山地区,其SKS波分裂和地表变形数据共同支持岩石圈变形模式,即地壳与岩石圈地幔是连贯变形的;东部地区的平均快波偏振方向近似平行于绝对板块运动方向,上地幔各向异性归因于软流圈流动.中部的鄂尔多斯至四川盆地一带为东、西部两种变形模式的过渡带,各向异性结构较为复杂,表现为"化石"各向异性和(或)双层各向异性.印度板块和欧亚板块的碰撞是中国大陆西部上地幔各向异性的主要影响因素,东部地区则与太平洋板块和菲律宾板块向欧亚板块俯冲有关.

关键词：剪切波分裂上地幔各向异性岩石圈变形软流圈流动绝对板块运动

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