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Microwave-Assisted Confining Growth and Liquid Exfoliation of sp3-Hybrid Carbon Nitride Nano/Micro-Crystals

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ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 399-408页

作者： Shen, Chenglong lou, qing Liu, Kaikai Zheng, Guangsong Song, Runwei Zang, Jinhao Yang, Xigui Li, Xing Dong, Lin Shan, Chongxin Zhengzhou Univ Minist Educ Sch Phys & Lab Zhongyuan Light Henan Key Lab Diamond Optoelect Mat & DevicesKey Zhengzhou 450052 Peoples R China

As one promising carbon-based material, sp(3)-hybrid carbon nitride has been predicted with various novel physicochemical properties. However, the synthesis of sp(3)-hybrid carbon nitride is still limited by the nanaoscale, low crystallinity, complex source, and expensive instruments. Herein, we have presented a facile approach to the sp(3)-hybrid carbon nitride nano/micro-crystals with microwave-assisted confining growth and liquid exfoliation. Actually, the carbon nitride nano/micro-crystals can spontaneously emerge and grow in the microwave-assisted polymerization of citric acid and urea, and the liquid exfoliation can break the bulk disorder polymer to retrieve the highly crystalline carbon nitride nano/micro-crystals. The obtained carbon nitride nano/micro-crystals present superior blue light absorption strength and surprising photoluminescence quantum yields of 57.96% in ethanol and 18.05% in solid state. The experimental characterizations and density functional theory calculations reveal that the interface-trapped localized exciton may contribute to the excellent intrinsic light emission capability of carbon nitride nano/micro-crystals and the interparticle staggered stacking will prevent the aggregation-caused-quenching partially. Finally, the carbon nitride nano/micro-crystals are demonstrated to be potentially useful as the phosphor medium in light-emitting-diode for interrupting blue light-induced eye damage. This work paves new light on the synthesis strategy of sp(3)-hybrid carbon nitride materials and thus may push forward the development of multiple carbon nitride research.

关键词： confining growth density functional theory liquid exfoliation luminescence sp(3)-hybrid carbon nitride BETA-C3N4 FLUORESCENT FILMS NANODOTS DRIVEN ROUTE DOTS CNX

Rational design multi-color-emissive chemiluminescent carbon nanodots in a single solvothermal reaction

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Nano Research 2024年第6期17卷 4651-4660页

作者： Guang-Song Zheng Cheng-Long Shen Yuan Deng Kai-Kai Liu Jin-Hao Zang Lin Dong qing lou Chong-Xin Shan Henan Key Laboratory of Diamond Optoelectronic Materials and Devices Key Laboratory of Materials PhysicsMinistry of Educationand School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China

Recently,the chemiluminescence(CL)induced by carbon nanodots(CDs)has intrigued researchers’extensive interests in various applications due to its special light emission ***,the difficulty of synthesizing chemiluminescent CDs with full-spectrum emission severely hinders the further regulation of the CL emission ***,the multi-color-emissive chemiluminescent CDs are rational designed and further synthesized by regulating the sp2-hybrid core and sp3-hybrid surface from the citrate-ammonia molecular in a single solvothermal *** experimental characterizations and density functional theory calculations reveal that the higher temperature can promote the crosslinking polymerization/carbonization of carbon core and the higher protonation of solvent can determine the core size of final CDs,resulting in the variant CL emission from molecular-,crosslinking-and ***,the CL emission of the CDs can be further synthesized by tuning the luminescence chromophores in the formation process via regulating the temperature and solvent,enabling the applications of the CL CDs in illumination and information *** study paves a new technology to understand the luminescence of CDs and affords an industry translational potential over traditional chemiluminescent molecular.

关键词： carbon nanodots chemiluminescence regulation energy level alignment mechanism

Sensitive humidity sensor based on moisture-driven energy generation

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Nano Research 2024年第6期17卷 5578-5586页

作者： qingchao Ni qing lou Chenglong Shen Guangsong Zheng Runwei Song Jingnan Hao Jialu Liu Jinyang Zhu Jinhao Zang Lin Dong Chong-Xin Shan Henan Key Laboratory of Diamond Optoelectronic Materials and Devices Key Laboratory of Materials PhysicsMinistry of Educationand School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China State Centre for International Cooperation on Designer Low-Carbon&Environmental Materials and School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China

The emergence of novel self-powered humidity sensors has attracted considerable attention in the fields of smart electronic devices and personal ***,self-powered humidity sensors have been fabricated using a moisture-driven energy generation(MEG)device based on asymmetric tubular graphitic carbon nitride(g-CN)films prepared on anodized aluminum(AAO)*** a relative humidity(RH)of 96%,the MEG device can provide an open-circuit voltage of 0.47 V and a short-circuit current of 3.51μA,with a maximum output power of 0.08μ*** inherent self-powered ability and humidity response via current variation,an extraordinary response of 1.78×106%(41%-96%RH)can be gained from the MEG *** possible power generation mechanism is that g-CN/AAO heterostructure can form ion gradient and diffusion under the action of moisture to convert chemical potential into electrical potential,evoking a connaturally sensitive response to ***-powered respiration monitoring device based on the sensor is designed to monitor human movement(sitting,warming up,and running)and sleep status(normal,snoring,and apnea),maintaining excellent stability during cumulative 12-h respiration *** self-powered humidity sensing technology has promising potential for extensive integration into smart electronic and round-the-clock health monitoring devices.

关键词： graphitic carbon nitride moisture-driven energy generation humidity sensor respiration monitoring

温度影响下Anammox-DAMO系统N2O产消机制及调控

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中国环境科学 2024年第3期44卷 1324-1334页

作者：韩梦茹楼菊青徐帆浙江工商大学环境科学与工程学院浙江杭州310018

以厌氧氨氧化-反硝化厌氧甲烷氧化(Anammox-DAMO)系统为研究对象,考察了不同温度对该系统性能和N_(2)O产消的影响,建立了该过程的酶动力学模型.结果表明,在40℃的高温胁迫下系统性能明显恶化且积累了更多的N_(2)O,Acidovorax和Thauera... 详细信息

以厌氧氨氧化-反硝化厌氧甲烷氧化(Anammox-DAMO)系统为研究对象,考察了不同温度对该系统性能和N_(2)O产消的影响,建立了该过程的酶动力学模型.结果表明,在40℃的高温胁迫下系统性能明显恶化且积累了更多的N_(2)O,Acidovorax和Thauera属丰度在高温条件下显著降低,而Bacillus属丰度则上升,N_(2)O还原酶活性的抑制是N_(2)O排放量增加的主要因素.酶动力学拟合结果表明35℃时可以最大程度地实现N_(2)O减排.

关键词：温度 Anammox-DAMO系统 N_(2)O 调控策略

不同补料方式对好氧颗粒污泥合成PHA的影响

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中国环境科学 2024年第3期44卷 1286-1295页

作者：陈淞苑泉娄雨晴张艳萍孙迎雪北京工商大学生态环境学院北京100048

为提高好氧颗粒污泥(AGS)合成聚羟基脂肪酸酯(PHA)的产量,探究了4种不同补料方式(未补料、好氧0h补料、好氧0.5h补料和好氧1h补料)对AGS合成PHA的影响,同时考察了此过程中AGS的碳氮磷去除效能以及微生物群落结构变化.结果表明,补料能够... 详细信息

为提高好氧颗粒污泥(AGS)合成聚羟基脂肪酸酯(PHA)的产量,探究了4种不同补料方式(未补料、好氧0h补料、好氧0.5h补料和好氧1h补料)对AGS合成PHA的影响,同时考察了此过程中AGS的碳氮磷去除效能以及微生物群落结构变化.结果表明,补料能够提高AGS合成PHA的含量,在好氧1h补料时AGS合成PHA的含量最高,为125.06mg/g;同时补料时间会影响AGS的脱氮除磷性能,当补料时间由好氧0h延迟至好氧1h时,AGS的总氮去除率由(87.49±5.49)%降至(67.60±16.24)%,溶解性正磷酸盐(SOP)去除率由(94.08±1.42)%降至(62.91±15.33)%.且不同补料时间条件下,AGS的微生物群落结构变化较大,合成PHA的优势菌群差异较大,在未补料和好氧0h补料条件下,优势菌为既能合成PHA同时能够脱氮或除磷的不动杆菌属(Acinetobacter);在好氧1h补料条件下中,优势菌为能合成PHA的噬氢菌属(Hydrogenophaga)和黄杆菌属(Flavobacterium).

关键词：好氧颗粒污泥聚羟基脂肪酸酯(PHA) 脱氮除磷补料时间影响

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基于电导率质量平衡法的基流分割方法研究

吉林建筑大学学报 2024年第3期41卷 35-39,68页

作者：王琰楼青云吕航吉林建筑大学测绘与勘查工程学院长春130118

本研究通过综合运用电导率质量平衡法(CMB)、数字滤波法、ECK滤波法、HYSEP法以及BFI法对科罗拉多河流域的典型水文站点进行基流分割计算,并根据电导率质量平衡法的结果对其他的基流分割方法进行参数修正。结果表明:(1)以CMB法为标准,EC... 详细信息

本研究通过综合运用电导率质量平衡法(CMB)、数字滤波法、ECK滤波法、HYSEP法以及BFI法对科罗拉多河流域的典型水文站点进行基流分割计算,并根据电导率质量平衡法的结果对其他的基流分割方法进行参数修正。结果表明:(1)以CMB法为标准,ECK滤波法和数字滤波法的结果比HYSEP法以及BFI法更为准确;(2)根据CMB法对其他方法进行参数修正,2个水文站修正后结果准确性分别提高了5%~40%和10%~50%;(3)综合评定最适合科罗拉多河流域的基流分割方法是经过CMB法参数修正后的ECK滤波法,2个水文站经过修正后的ECK法相较于CMB法结果的误差百分比分别为1.836%和2.506%。

关键词：基流分割电导率质量平衡法数字滤波法

不同基座高度对沥青混凝土心墙堆石坝受力特性的影响研究

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水电能源科学 2024年第4期42卷 119-122,84页

作者：姚夏繁赵二峰娄一青河海大学水利水电学院江苏南京210098 温州市水利电力勘测设计院有限公司浙江温州325000

为研究不同基座高度对沥青混凝土心墙坝受力特性的影响,采用邓肯-张E-B模型作为坝体及心墙的本构模型,对大坝施工和蓄水过程进行模拟,并依据基座与心墙的高度关系拟定5种计算方案,对比不同基座高度下堆石体和心墙的受力特性。结果表明,... 详细信息

为研究不同基座高度对沥青混凝土心墙坝受力特性的影响,采用邓肯-张E-B模型作为坝体及心墙的本构模型,对大坝施工和蓄水过程进行模拟,并依据基座与心墙的高度关系拟定5种计算方案,对比不同基座高度下堆石体和心墙的受力特性。结果表明,基座越高,大坝堆石体竖向位移及第一、三主应力越小,而心墙第一、三主应力越大,竖向位移则随基座增高而减小。在此基础上,利用熵值法构建了基座影响定权模型,量化了基座高度变化对大坝不同部位的影响程度:基座高度变化对心墙的影响(权重56.06%)最显著,建议工程设计和安全评价需要考虑基座高度发生变化时对心墙第一主应力状态的影响。研究成果可为沥青混凝土心墙堆石坝工程设计和施工提供参考依据。

关键词：沥青混凝土心墙坝心墙基座有限元分析熵值法

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醋/涤面料的染色同色性

上海纺织科技 2024年第8期52卷 32-37页

作者：张京彬刘淑云娄晴宁慧国家先进印染技术创新中心山东泰安271000 山东中康国创先进印染技术研究院有限公司山东泰安271000

针对醋酯纤维与涤纶染色同色性差的问题,从染色温度、染液pH值、染色浴比、保温时间、染料用量等方面研究了分散染料对醋涤面料染色性能的影响,并对染色工艺进行了优化。优化后的染色工艺为:染色温度120℃、pH值4.0、浴比1∶20、保温时... 详细信息

针对醋酯纤维与涤纶染色同色性差的问题,从染色温度、染液pH值、染色浴比、保温时间、染料用量等方面研究了分散染料对醋涤面料染色性能的影响,并对染色工艺进行了优化。优化后的染色工艺为:染色温度120℃、pH值4.0、浴比1∶20、保温时间40 min。随染料用量的增加,黄AC-RL、红玉AC-GFN、藏青AC-3R染料染色平衡指数先逐渐增大后逐渐降低,最后趋于稳定;黑AC-BS染色平衡指数逐渐增大。染色后面料的耐皂洗色牢度均在4级以上,能够满足服装面料对色牢度的要求。

关键词：染色醋酯涤纶同色性分散染料色牢度

Fabry-Perot interference and piezo-phototronic effect enhanced flexible MoS_(2) photodetector

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Nano Research 2022年第5期15卷 4395-4402页

作者： Xuexia Chen Xun Yang qing lou Yuan Zhang Yancheng Chen Yacong Lu Lin Dong Chong-Xin Shan Henan Key Laboratory of Diamond Optoelectronic Materials and Devices Key Laboratory of Materials PhysicsMinistry of Educationand School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China

Flexible photodetectors(PDs)are indispensable components for next-generation wearable ***,two-dimensional(2D)materials have been implemented as functional flexible optoelectronic devices due to their characteristics of atomically thin layers,excellent flexibility,and strain *** this work,we developed a flexible photodetector based on MoS_(2)/NiO heterojunction,and Fabry-Perot(F-P)and piezo-phototronic effect have been employed to enhance the responsivity(R)and external quantum efficiency(EQE)of the *** F-P effect is utilized to improve the optical absorption of the MoS_(2),resulting in an enhancement in the photoluminescence(PL)of monolayer MoS_(2) and the EQE of the photodetector by 30 and 130 times,*** flexible photodetector exhibits an ultrahigh detectivity(D*)of 2.6×10^(14) Jones,which is the highest value ever reported for flexible MoS_(2) *** piezo-potential of monolayer MoS_(2) decreases the valence band offset at the interface of MoS_(2)/NiO,which increases the transfer efficiency of the photon-generated carriers *** 1.17%tensile strain,the R of the flexible photodetector can be enhanced by 271%.This research may provide a universal strategy for the design and performance optimization of 2D materials heterostructures for flexible optoelectronics.

关键词： flexible photodetector MoS_(2) Fabry-Perot(F-P)interference piezo-phototronic effect