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Science china chemistry 2010年第3期53卷 618-624页

作者： liu jiangtao1,liu ShaoPu2 & liu zhongfang2.1school of chemistry,chongqing normal university,chongqing 400300,china 2school of chemistry and Chemical Engineering,Southwest university,chongqing 400715,china school of chemistry Chongqing Normal University Chongqing China school of chemistry and Chemical Engineering Southwest University Chongqing China

The forming of bleomycinA2-Cu(Ⅱ) cationic chelate and the interaction of the chelate with DNA have been investigated by using resonance Rayleigh scattering(RRS),molecular absorption and fluorescence *** result shows that in aqueous solution,bleomycinA2(BLMA2) can react with Cu(Ⅱ) to form 1:1 cationic chelate which contributes to the changes of the absorption spectra and the quenched fluorescence of *** the cationic chelate further bound with DNA to form ternary ion-association complexes,the remarkable enhancement of the RRS intensity was *** this work,the optimum conditions for the coordination reaction of BLMA2 with Cu(Ⅱ) and some influencing factors have been *** reaction mechanism of BLMA2-Cu(Ⅱ) binding with DNA was suggested and a binding model was *** addition,the fluorescence quenching type of BLMA2 was investigated.A highly sensitive,simple and rapid new method for the determination of DNA by using BLMA2-Cu(Ⅱ) as RRS probe has been *** detection limits(3σ) are 7.2 ng/mL for ctDNA,7.1 ng/mL for sDNA and 18 ng/mL for *** method can be applied to the determination of trace amounts of DNA.

关键词： bleomycinA2 Cu(Ⅱ) DNA resonance Rayleigh scattering fluorescence quenching

Mo_(2)P Monolayer as a Superior Electrocatalyst for Urea Synthesis from Nitrogen and Carbon Dioxide Fixation:A Computational Study

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Energy & Environmental Materials 2024年第1期7卷 207-214页

作者： Dongxu Jiao Zhongxu Wang Yuejie liu Qinghai Cai Jingxiang Zhao Carlos R.Cabrera zhongfang Chen College of chemistry and Chemical Engineering and Key Laboratory of Photonic and Electronic Bandgap Materials Ministry of EducationHarbin Normal UniversityHarbin 150025China Modern Experiment Center Harbin Normal UniversityHarbin 150025China Heilongjiang Province Collaborative Innovation Center of Cold Region Ecological Safety Harbin 150025China Department of chemistry and Biochemistry The University of Texas at El PasoEl Paso TX 79968USA Department of chemistry University of Puerto RicoRio Piedras CampusSan JuanPuerto Rico 00931USA

Urea synthesis through the simultaneous electrocatalytic reduction of N_(2)and CO_(2)molecules under ambient conditions holds great promises as a sustainable alternative to its industrial production,in which the development of stable,highly efficient,and highly selective catalysts to boost the chemisorption,activation,and coupling of inert N_(2)and CO_(2)molecules remains rather ***,by means of density functional theory computations,we proposed a new class of two-dimensional nanomaterials,namely,transition-metal phosphide monolayers(TM_(2)P,TM=Ti,Fe,Zr,Mo,and W),as the potential electrocatalysts for urea *** results showed that these TM_(2)P materials exhibit outstanding stability and excellent metallic ***,the Mo_(2)P monolayer was screened out as the best catalyst for urea synthesis due to its small kinetic energy barrier(0.35 eV)for C-N coupling,low limiting potential(-0.39 V),and significant suppressing effects on the competing side *** outstanding catalytic activity of the Mo_(2)P monolayer can be ascribed to its optimal adsorption strength with the key^(*)NCON species due to its moderate positive charges on the Mo active *** findings not only propose a novel catalyst with high-efficiency and high-selectivity for urea production but also further widen the potential applications of metal phosphides in electrocatalysis.

关键词： C-N coupling density functional theory Mo_(2)P monolayer urea synthesis

Resonance Rayleigh scattering study of the interaction of bleomycinA_5 with nucleic acids and its analytical application

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Science china chemistry 2007年第5期50卷 629-637页

作者： liu jiangtao1,2, liu {2.1 & liu ShaoPu1 1 school of chemistry and Chemical Engineering, Southwest university, chongqing 400715, china 2 Department of chemistry, Fuling normal university, chongqing 408000, china school of chemistry and Chemical Engineering Southwest UniversityChongqing400715China Department of chemistry Fuling Normal UniversityChongqing 408000China

The interaction of bleomycinA5 with nucleic acids has been investigated byusing resonance Rayleigh scattering (RRS),molecular absorption and fluorescence *** resultshows that in near pH 2.2 buffer medium and absence of any metal ions,nucleic acids are capable ofbinding with bleomycinA5 (BLMA5) to form complexes which can remarkably enhance the RRS intensityand result in batho-chromic and hyperchromic molecular absorption of nucleic acids and fluorescencequenching of *** RRS spectral characteristics for the binding products of bleomycinA5with various DNA and RNA are similar,and the maximum RRS peaks are at 301 nm for ctDNA and sDNA,370nm for hsDNA,310 nm for RNAtypeVI and RNAtypelll,*** increments of RRS intensity aregreatly different in which DNA enhances greatly and RNA enhances *** this work,the optimumconditions of the interaction and some influencing factors have been *** reactionmechanism and a binding model for the interaction of BLMA5 with the nucleic acids are ***,a highly sensitive,simple and rapid new method for the determination of DNA has *** detection limits (3 sigma) are 5.7 ng/mL for ctDNA,7.4 ng/mL for sDNA and 9.2 ng/mLfor hsDNA,*** method can be applied to determination of trace amounts of DNA.

关键词： bleomycinA5, nucleic acids, resonance Rayleigh scattering, fluorescence quenching, absorption spectrum.

A combinatorial synthesis method for identification of orally bioavailable cyclic peptide

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Science china chemistry 2024年第8期67卷 2429-2430页

作者： Zhenzhen liu Li liu Bo Tang College of chemistry Chemical Engineering and Materials ScienceKey Laboratory of Molecular and Nano ProbesMinistry of EducationCollaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of ShandongInstitutes of Biomedical SciencesShandong Normal UniversityJinan 250014China Laoshan Laboratory Qingdao 266237China

Cyclic peptides are a type of polypeptide with macrocyclic structure formed by canonical and non-canonical amino *** to their rigid conformation and large surface area,cyclic peptides typically exhibit high binding affinity and specificity with target proteins,particularly those considered undruggable by traditional small molecule drugs,such as protein-protein interactions[1].Additionally,they are convenient to be chemical modified to improve the pharmacological or pharmacokinetic properties.

关键词： properties. canonical synthesis

A REFINEMENT OF THE SCHWARZ-PICK ESTIMATES AND THE CARATHéODORY METRIC IN SEVERAL COMPLEX VARIABLES

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Acta Mathematica Scientia 2024年第4期44卷 1337-1346页

作者： Xiaosong liu Taishun liu school of Mathematics and Statistics Lingnan Normal UniversityZhanjiang 524048China Department of Mathematics Huzhou UniversityHuzhou 313000China

In this article,we first establish an asymptotically sharp result on the higher order Fréchet derivatives for bounded holomorphic mappings f(x)=f(0)+∞∑s=1Dskf(0)(x^(sk))/(sk)!:B_(X)→B_(Y),where B_X is the unit ball of *** next give a sharp result on the first order Fréchet derivative for bounded holomorphic mappings F(X)=F(0+)∞∑s=KD^(s)f(0)(x^(8)/s!):B_(X)→B_(Y),where B_(X)is the unit ball of *** results that we derive include some results in several complex variables,and extend the classical result in one complex variable to several complex variables.

关键词： refined Schwarz-Pick estimate bounded holomorphic mapping Carathéodory metric first order Fréchet derivative higher order Fréchet derivatives

The important role of Turbidity Maximum Zone in sedimentary dynamic of estuarine mangrove swamp

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Frontiers of Earth Science 2024年第1期18卷 219-226页

作者： Tao liu Ying liu Baoqing HU Key laboratory of Environment Change and Resources Use in Beibu Gulf(Ministry of Education) Nanning Normal UniversityNanning 530001China school of Civil Engineering and Architecture Guangxi UniversityNanning 530004China

Sedimentation is a key process affecting wetland sustainability and carbon burial *** context of sea level rise,climate change and human activities,further understanding about the sedimentary dynamic in wetland is critical in predicting the landscape evolution or the change in carbon burial *** this study,based on the field hydrological observation in a mangrove system in the Nanliu River estuary,we found the net flux of suspended sediment to mangrove is 39−72 kg/m in tidal cycles with Turbidity Maximum Zone(TMZ)forming in surface layer and only is 9−18 kg/m in tidal cycles without *** higher net flux of suspended sediment to mangrove in tidal cycles with TMZ forming in surface layer is attributed to high SSC in rising tide and intense flocculation in *** significant discrepancy in sedimentation rate in the mangrove patches also can be explained by the probability of TMZ forming in the surface layer of *** future,rapid sea level rising may lead to the change of TMZ pattern in estuary,which will result in non-negligible variation in sedimentation rate in *** to the present data of sedimentation rate in wetlands,the fragility of wetlands in river estuary may be miscalculated.

关键词： mangrove wetland sedimentation Turbidity Maximum Zone Nanliu River

Changes of china’s Status in the Global System and Its Influencing Factors:A Multiple Contact Networks Perspective

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Chinese Geographical Science 2024年第2期34卷 265-279页

作者： liu Jian liu Jibin YANG Qingshan CAI Sikai liu Jie school of Geographical Sciences Northeast Normal UniversityChangchun 130024China Key Laboratory of Geographical Processes and Ecological Security of Changbai Mountains Ministry of EducationChangchun 130024China school of Architecture and Planning Jilin Jianzhu UniversityChangchun 130118China school of Geographical Sciences Liaoning Normal UniversityDalian 116029China

Clarifying china’s position in the global system is an important logical basis for developing national *** much research has been done on china’s development status,most studies have been based on country comparisons or institutional *** today’s networked era in which the global economy,trade,personnel,and information are closely connected,studies on china’s global position and its status changes and influencing factors in multiple contact networks are still *** this study,from the perspective of diverse global contact networks,we constructed economic,cultural,and political influence indices to explore the changes and influencing factors on china’s status in the global system from 2005 to *** results show that during the study period,china’s global influence in the fields of economic ties,cultural exchanges,and political contacts increased significantly,but its influ-ence in the fields of cultural exchanges and political contacts lagged far economic *** pattern of china’s economic influence on various economies around the world has shown a transformation from an‘upright pyramid’to an‘inverted pyramid’*** proportion of these economies in low-influence zones has decreased from more than 60%in 2005 to less than 20%in ***’s cultural and political influence on various economies around the world has increased significantly;however,for the former,the percentage of high-influence areas is still less than 20%,whereas for the latter the percentage of these economies in medium-and high-influence areas is still less than 50%.Analyses such as a scatter plot matrix show that geographical proximity,economic globalization,close cooperation with developing countries,and a proactive and peaceful foreign policy are important factors in improving china’s status in the diverse global network system.

关键词： global system economic ties cultural exchanges political contacts multiple contact networks china’s status

Input-to-State Stability of Impulsive Switched Systems Involving Uncertain Impulse-Switching Moments

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IEEE/CAA Journal of Automatica Sinica 2024年第6期11卷 1515-1517页

作者： Chang liu Wenlu liu Tengda Wei Xiaodi Li school of Mathematical and Statistics Shandong Normal UniversityJinan 250014China

Dear Editor,This letter studies the input-to-state stability(ISS)for a class of impulsive switched systems,where uncertain impulse-switching moments are *** robustness of ISS with respect to the perturbations of the occurrence time of impulse-switching moments is revealed by several less conservative dwell-time conditions for the uncertain impulse-switching moments combined with Lyapunov ***,the Lyapunov conditions have multiple coefficients at discrete time so as to handle the hybrid effect of impulse-switching moments,and the case that time derivative of Lyapunov function is indefinite is also taken into ***,a numerical example is proposed to illustrate the effectiveness of the theoretical results.

关键词： letter conservative derivative

A study on vector mediator top-philic dark matter

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Communications in Theoretical Physics 2024年第8期76卷 67-78页

作者： Yanyan Hu Yandong liu Yuanyuan liu College of Nuclear Science and Technology Beijing Normal UniversityJoint Laboratory of Jinping Ultra-low Radiation Background Measurement of Ministry of Ecology and EnvironmentJinping Deep Underground Frontier Science and Dark Matter Key Laboratory of Sichuan ProvinceKey Laboratory of Beam Technology of Ministry of EducationBeijing 100875China Beijing Radiation Center Beijing 100875China

We conducted a study on a simplified dark matter model that introduces a vector-like intermediate particle,facilitating exclusive interactions between dark matter and the top quark in the Standard *** analysis focused on the relic density of Dirac-type fermion dark matter and highlighted the complementary role of direct detection in constraining the dark matter ***,in instances when dark matter mass is small,the tree-level two-body annihilation process experiences *** such scenarios,the contributions of the threebody process(χχ→tbW-)and the one-loop process(χχ→gg)dominate the relic *** regard to direct detection,calculations were performed for the two-loop contribution to the dark-matter-gluon interaction,yielding the corresponding spin-independent scattering cross section.

关键词： dark matter new physics effective field theory

Stable hydrogen-bonded organic frameworks and their photo-and electro-responses

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Nano Research 2024年第8期17卷 7675-7699页

作者： Ying Hou Xin-Song Huang Sheng-Hao Gong Chen liu Yangyang liu Tian-Fu liu State Key Laboratory of Structural chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China university of Chinese Academy of Sciences Beijing 100049China Department of chemistry and Biochemistry California State UniversityLos AngelesCalifornia 90032USA College of chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China

Hydrogen-bonded organic frameworks(HOFs)are a recent class of porous materials that have garnered considerable research interest owing to their distinctive *** can be constructed through judicious selection of H-bonding motifs,which are further enforced by other weak intermolecular interactions such asπ–πstacking,van der Waals forces,and framework *** advantage of these interactions,we can expand the functional field of HOFs by introducing active ***,researchers have made substantial advancements in using HOFs for chemical sensing,catalysis,proton conduction,biological applications,and *** low bonding energy of H-bonds allows for precise control over the concentration of ligands in solvents,forming diverse HOF *** varied structures offer significant advantages for producing HOFs with photo-responsive and electro-responsive ***,the presence of H-bonds in HOFs results in their inherent lower stability compared to metal-organic frameworks(MOFs)and covalent-organic frameworks(COFs)formed via coordination and covalent bonds,*** a result,the pursuit of stable and innovative HOF materials with novel functional sites remains an ongoing *** review provides an overview of recent research progress in the development of new strategies for stable HOF synthesis and applications of HOFs with stimuli-responsive *** first classified all synthetic methods reported to date and discussed the stable HOFs synthesized,as well as their unique properties and *** addition,we summarized the applications of HOFs utilizing their synergistic responses to external stimuli,including photo,electrical,pressure,and chemical *** systematically reviewed stable HOF synthesis and applications,which may lead to a deeper understanding of the structure–activity relationship for these materials and guide future HOF design.

关键词： stable hydrogen-bonded organic frameworks(HOFs) photo-response electro-response photoelectric synergistic response