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Performance and Application of Double-layered Microcapsule Corrosion Inhibitors

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Journal of Wuhan University of Technology(Materials Science) 2024年第4期39卷 845-853页

作者：余海燕 WANG Yingxiang WANG Ruizhi HU lintong WANG Tianlei School of Materials Science and Engineering Tianjin Chengjian UniversityTianjin 300384China Tianjin Key Laboratory of Building Green Functional Materials Tianjin Chengjian UniversityTianjin 300384China

Double-layered microcapsule corrosion inhibitors were developed by sodium monofluorophosphate as the core material,polymethyl methacrylate as the inner wall material,and polyvinyl alcohol as the outer wall material combining the solvent evaporation method and spray drying *** protection by the outer capsule wall was used to prolong the service life of the corrosion *** dispersion,encapsulation,thermal stability of microcapsules,and the degradation rate of capsule wall in concrete pore solution were analyzed by ultra-deep field microscopy,scanning electron microscopy,thermal analyzer,and sodium ion release rate *** microcapsules were incorporated into mortar samples containing steel reinforcement,and the effects of double-layered microcapsule corrosion inhibitors on the performance of the cement matrix and the actual corrosion-inhibiting effect were *** experimental results show that the double-layered microcapsules have a moderate particle size and uniform distribution,and the capsules were completely *** microcapsules as a whole have good thermal stability below 230 ℃.The monolayer membrane structure microcapsules completely broke within 1 day in the simulated concrete pore solution,and the double-layer membrane structure prolonged the service life of the microcapsules to 80 days in the simulated concrete pore solution before the core material was completely *** mortar samples containing steel reinforcement incorporated with the double-layered microcapsule corrosion inhibitors still maintained a higher corrosion potential than the monolayer microcapsule corrosion inhibitors control group at 60 *** incorporation of double-layered microcapsules into the cement matrix has no significant adverse effect on the setting time and early strength.

关键词： corrosion inhibitors microcapsule double-layer structure potentiodynamic polarization curve

Synergistically constructed lamination-like network of redox-active polyimide and MXene via π-π interactions for aqueous NH_(4)^(+) storage

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Chinese Journal of Chemical Engineering 2024年第7期71卷 217-224页

作者： Jing He Hongye Xuan Jing Jin Ke Yu Changyao Liyang lintong Hu Minjie Shi Chao Yan School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China Jiangsu New Yangzi Shipbuilding Co. LtdJingjiang 214532China

As a nonmetallic charge carrier,ammonium ion(NH_(4)^(+))has garnered significant attention in the construction of aqueous batteries due to its advantages of low molar mass,small hydration size and rapid diffusion in aqueous *** are a kind of potential electro-active materials for aqueous NH_(4)^(+)***,traditional polymer electrodes are typically created by covering the bulky collectors with excessive additives,which could lead to low volume capacity and unsatisfactory ***,a nanoparticle-like polyimide(PI)was synthesized and then combined with MXene nanosheets to synergistically construct an additive-free and self-standing PI@MXene composite ***,the redox-active PI nanoparticles are enclosed between conductive MXene flakes to create a 3D lamination-like network that promotes electron transmission,while theπ-πinteractions existing between PI and MXene contribute to the enhanced structural integrity and stability within the composite *** such,it delivers superior aqueous NH_(4)^(+)storage behaviors in terms of a notable specific capacity of 110.7 mA·h·cm^(–3) and a long lifespan with only 0.0064%drop each ***,in-situ Raman and UV–Vis examinations provide evidence of reversible and stable redox mechanism of the PI@MXene composite electrode during NH_(4)^(+)uptake/removal,highlighting its significance in the area of electrochemical energy storage.

关键词： Synergetic coupling Composite materials Polyimide Energy storage Aqueous ammonium ion batteries

Mechanical and magnetocaloric adjustable properties of Fe3O4/PET deformed nanoparticle film

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Chinese Physics B 2024年第3期33卷 589-595页

作者：范凤国段林彤 School of Physics and Electrical Information Shangqiu Normal UniversityShangqiu 476000China

The flexibility of nanoparticle films is a topic of rapidly growing interest in both scientific and engineering researches due to their numerous potential applications in a broad range of wearable electronics and biomedical *** article presents the elucidation of the properties of nanoparticle ***,a flexible film is fabricated based on polyethylene terephthalate(PET)and magnetic iron oxide at the nanoscale using layer-by-layer *** 2D thin flexible film material can be bent at different angles from 0°to 360°.With an increase in elastic deformation angles,the magnetocaloric effect of the film gradually increases in the alternating magnetic *** test results from a vibrating sample magnetometer and a low-frequency impedance analyzer demonstrate that the film has a good magnetic response and *** magnetocaloric effect and magnetic induction effect are controlled by deformation,providing a new idea for the application of elastic *** combines the flexibility of the nanoparticle PET substrate and,in the future,it may be used for skin adhesion for administration and magnetic stimulation control.

关键词： nanoparticle film deformation magnetic properties flexible substrates

Broadband high-efficiency dielectric metalenses based on quasi-continuous nanostrips

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Opto-Electronic Advances 2024年第5期7卷 43-51页

作者： Xiaohu Zhang Qinmiao Chen Dongliang Tang Kaifeng Liu Haimo Zhang lintong Shi Mengyao He Yongcai Guo Shumin Xiao Key Laboratory of optoelectronic Technology and Systems of the Education Ministry of China Chongqing UniversityChongqing 400044China Ministry of Industry and Information Technology Key Lab of Micro-Nano Optoelectronic Information System Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic SystemsHarbin Institute of TechnologyShenzhen 518055China Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education&Hunan Provincial Key Laboratory of Low-Dimensional Structural Physics and Devices School of Physics and ElectronicsHunan UniversityChangsha 410082China

Benefiting from the abrupt phase changes within subwavelength thicknesses,metasurfaces have been widely applied for lightweight and compact optical *** broadband and high-efficiency characteristics are highly attractive for the practical implementation of ***,current metasurface devices mostly adopt discrete micro/nano structures,which rarely realize both merits *** this paper,dielectric metasurfaces composed of quasi-continuous nanostrips are proposed to overcome this *** quasi-continuous nanostrips metasurface,a normal focusing metalens and a superoscillatory lens overcoming the diffraction limit are designed and experimentally *** quasi-continuous metadevices can operate in a broadband wavelength ranging from 450 nm to 1000nm and keep a high power *** average efficiency of the fabricated metalens reaches 54.24%,showing a significant improvement compared to the previously reported metalenses with the same *** proposed methodology can be easily extended to design other metadevices with the advantages of broadband and high-efficiency in practical optical systems.

关键词： broadband high-efficiency metalens sub-diffraction quasi-continuous

Runoff change in the Yellow River Basin of China from 1960 to 2020 and its driving factors

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Journal of Arid Land 2024年第2期16卷 168-194页

作者： WANG Baoliang WANG Hongxiang JIAO Xuyang HUANG lintong CHEN Hao GUO Wenxian School of Water Conservancy North China University of Water Resources and Electric PowerZhengzhou 450046China College of Water Resources North China University of Water Resources and Electric PowerZhengzhou 450046China

Analysing runoff changes and how these are affected by climate change and human activities is deemed crucial to elucidate the ecological and hydrological response mechanisms of *** Indicators of Hydrologic Alteration and the Range of Variability Approach(IHA-RVA)method,as well as the ecological indicator method,were employed to quantitatively assess the degree of hydrologic change and ecological response processes in the Yellow River Basin from 1960 to *** Budyko's water heat coupling balance theory,the relative contributions of various driving factors(such as precipitation,potential evapotranspiration,and underlying surface)to runoff changes in the Yellow River Basin were quantitatively *** results show that the annual average runoff and precipitation in the Yellow River Basin had a downwards trend,whereas the potential evapotranspiration exhibited an upwards trend from 1960 to *** approximately 1985,it was reported that the hydrological regime of the main stream underwent an abrupt *** degree of hydrological change was observed to gradually increase from upstream to downstream,with a range of 34.00%-54.00%,all of which are moderate ***,significant differences have been noted among different ecological indicators,with a fluctuation index of 90.00%at the outlet of downstream hydrological stations,reaching a high level of *** the mutation,the biodiversity index of flow in the middle and lower reaches of the Yellow River was generally lower than that in the base *** research results also indicate that the driving factor for runoff changes in the upper reach of the Yellow River Basin is mainly precipitation,with a contribution rate of 39.31%-54.70%.Moreover,the driving factor for runoff changes in the middle and lower reaches is mainly human activities,having a contribution rate of 63.70%-84.37%.These results can serve as a basis to strengthen the protection and restoration efforts in the Yellow River Basin

关键词： Budyko theory hydrological regime attribution analysis ecological responses Yellow River climate change human activity runoff

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析出相对稀土镁合金腐蚀行为的影响

中国材料进展 2024年第4期43卷 336-343页

作者：柯静郭林通西安建筑科技大学冶金工程学院陕西西安710055

镁合金由于密度低、比强度高、电磁屏蔽性能良好而广泛应用在航空航天、汽车、数码等重要领域,但其较差的腐蚀性能使进一步应用受到限制。稀土元素原子的晶体结构与Mg原子相同,在α-Mg中具有较大的固溶度,形成的金属间化合物第二相可细... 详细信息

镁合金由于密度低、比强度高、电磁屏蔽性能良好而广泛应用在航空航天、汽车、数码等重要领域,但其较差的腐蚀性能使进一步应用受到限制。稀土元素原子的晶体结构与Mg原子相同,在α-Mg中具有较大的固溶度,形成的金属间化合物第二相可细化合金晶粒,同时加入稀土元素可改变腐蚀层结构,进而可以有效地改善镁合金的耐腐蚀性能。通过X射线荧光光谱仪、光学显微镜、扫描电子显微镜、电化学站测试、原子力显微镜等测试设备,表征了Mg-3.4Y-3.6Sm-2.6Zn-0.8Zr合金在3.5%NaCl溶液(质量分数)中的腐蚀速率和腐蚀形貌,研究了析出相对稀土镁合金腐蚀行为的影响。结果表明,稀土元素Y和Sm在镁合金中形成了(Mg,Zn)_(3)(Y,Sm)和Mg_(12)(Y,Sm)Zn 2种析出相,在合金腐蚀过程中(Mg,Zn)_(3)(Y,Sm)相最先被腐蚀,随后是α-Mg基体和Mg_(12)(Y,Sm)Zn相。析出相在合金腐蚀过程中形成了均匀的腐蚀产物膜层,增大了合金的电化学阻抗值,腐蚀产物膜层对合金起到了保护作用,有效地降低了合金的腐蚀速率。

关键词： Mg-Y-Sm-Zn-Zr镁合金析出相微观组织腐蚀行为腐蚀膜层

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数字金融对企业技术创新的影响及空间效应

科研管理 2024年第6期45卷 72-82页

作者：高粼彤孟霏田启波山东工商学院经济学院山东烟台264005 深圳大学中国经济特区研究中心广东深圳518000

在数字经济时代背景下,如何提升金融服务实体经济能力是一个值得深入探究的重要议题。本文基于2011-2020年中国30个省(区、市)1804家上市企业面板数据,将企业微观数据与各省域宏观数据相匹配,综合运用空间杜宾模型、中介效应模型和门槛... 详细信息

在数字经济时代背景下,如何提升金融服务实体经济能力是一个值得深入探究的重要议题。本文基于2011-2020年中国30个省(区、市)1804家上市企业面板数据,将企业微观数据与各省域宏观数据相匹配,综合运用空间杜宾模型、中介效应模型和门槛模型等,从内在逻辑和空间关联双重维度实证考察了数字金融对企业技术创新的内在作用机制和空间影响机理。研究发现:(1)数字金融和企业技术创新均存在明显的正向空间相关性;(2)数字金融对企业技术创新既存在显著的直接促进作用,又存在显著的负向空间溢出效应;(3)融资约束和信息约束是数字金融发挥企业技术创新激励效应的重要传导机制;(4)数字金融对企业技术创新的激励效应具有“先正后负”的倒U型非线性特征。本研究丰富了企业技术创新驱动因素和数字金融经济后果的相关文献,对于如何为企业技术创新提供有效的金融支持,以及加快落实创新驱动发展战略、助推经济高质量发展具有重要的启示意义。

关键词：数字金融企业技术创新空间效应门槛效应

激光选区熔化Al-Si合金组织特征及腐蚀行为研究进展

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稀有金属材料与工程 2024年第3期53卷 870-881页

作者：郭林通王文礼杨海鸥刘文强西安建筑科技大学冶金工程学院陕西西安710055 西北工业大学凝固技术国家重点实验室陕西西安710072 北京科技大学工程技术研究院北京100083

激光选区熔化(selective laser melting,SLM)制备的Al-Si合金在航空航天材料定制化和轻量化的发展中有着巨大潜力。然而,影响SLM成形件寿命的腐蚀行为研究尚有不足。本文结合当前文献报道,根据SLM过程中的凝固特征分析了冶金缺陷和微观... 详细信息

激光选区熔化(selective laser melting,SLM)制备的Al-Si合金在航空航天材料定制化和轻量化的发展中有着巨大潜力。然而,影响SLM成形件寿命的腐蚀行为研究尚有不足。本文结合当前文献报道,根据SLM过程中的凝固特征分析了冶金缺陷和微观组织的形成原因,论述了SLM制备的Al-Si合金的腐蚀机制,归纳总结了冶金缺陷、微观组织和热处理工艺对于腐蚀行为的影响。发现试样的致密度,表面状态(粗糙度)和共晶Si的含量、形态及分布对腐蚀性能有重要影响。在此基础上,指出了目前SLM工艺下Al-Si合金腐蚀研究中存在的工艺参数不够系统,忽视Mg、Fe等元素的作用,研究手段和范围不够完善等不足以及未来进一步发展的方向。

关键词：激光选区熔化 Al-Si合金腐蚀行为冶金缺陷微观组织

译林牛津版高中英语教材对教师教学模式的影响研究

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英语教师 2024年第17期24卷 33-35页

作者：张琳童江苏省南通市小海中学江苏南通226000

探讨译林牛津版高中英语教材对教师教学模式的影响。通过对教材编写案例的分析,发现该版本教材在词汇学习单元、文化背景阅读、听力训练、写作技巧和语法点强化等方面采用了独特的设计理念。这些案例对教学模式产生了深远影响,鼓励教师... 详细信息

探讨译林牛津版高中英语教材对教师教学模式的影响。通过对教材编写案例的分析,发现该版本教材在词汇学习单元、文化背景阅读、听力训练、写作技巧和语法点强化等方面采用了独特的设计理念。这些案例对教学模式产生了深远影响,鼓励教师采用更加多样和灵活的教学方法,包括联系上下文式教学、跨文化交际、听力训练、写作技巧教学及系统的语法讲解。认为将译林牛津版高中英语教材的设计理念与教学实践相结合,能为英语教师提供新的教学模式,并有望对学生的综合语言运用能力产生积极影响。

关键词：高中英语教材编写教学模式教学影响