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Journal of Energy Chemistry 2025年第1期100卷 578-604页

作者： Caixia Li Wenwu Liu Shiji Da lingbin kong Fen Ran State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of Technology School of Materials Science and Engineering Lanzhou University of Technology

Photovoltaic metal halide perovskite solar cells(PSCs) convert light to electricity more efficiently than crystalline silicon cells, and the cost of materials used to make them is lower than that of silicon *** efficiency is not a core issue affecting the application of perovskite solar cells in special *** present, stability is the major technical encounters that hinders its further commercial development. Microstrain in PSCs is currently a significant factor responsible for the device's instability. Strain-induced ion migration is widely believed to accelerate perovskite degradation even when external stimuli are ***, it is imperative to study strain to enhance the stability of PSCs. This paper reviews recent developments to understand strain's origin and effect mechanisms on performance of PSCs, including ion migration,failure behavior, defect formation, and its effect on photoelectric properties, stability, and ***, several well-known strain management strategies are systematically introduced based on the strain effect mechanism and strain engineering on the film, providing more clues for further preparation with increased stability. The manipulation of external physical strain applied from films to entire devices has been extensively studied. Furthermore, recommendations for future research directions and chemical approaches have been provided. It is emphasized that strain engineering plays a crucial role in improving the efficiency and longevity of PSCs. Tensile strain causes rapid degradation, while moderate compressive strain and external strain control could improve properties and stability. Efforts should focus on controlling compressive strain to mitigate residual tensile strain and introducing it in a controlled manner. Future research endeavors may focus on exploring these pathways to improve the efficiency and lifespan of PSCs.

关键词： Halide perovskite solar cells Strain origins Strain effects Strain management

Synthesis of 2-aryl-5-alkyl-7-methoxylbenzo[b]furan derivatives

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Chinese Chemical Letters 2007年第4期18卷 380-382页

作者： xue Fei Yang ling Yi kong Department of Natural Medicinal Chemistry China Pharmaceutical University Nanjing 210009 China

A series of 2-aryl-5-alkyl-7-methoxylbenzo[b]furan derivatives have been synthesized by utilizing the coupling of methyl 3- methoxy-4hydroxy-5-bromocinnamate with cuprous phenylacetylide as the key step. The structures of the new compounds were confirmed by 1H NMR, IR and MS. The structure of compound 14 was further confirmed by single crystal X-ray. Compound 17 showed cytotoxic activity against human lung carcinoma A549.

关键词： 2-Aryl-5-alkyl-7-methoxylbenzo[b]furan Neolignans Synthesis Cytotoxicity

Structure and Thermochromic Property of a Silver(I) Complex Based on Dicyanamide and Phosphine Ligands

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Chinese Journal of Structural Chemistry 2020年第7期39卷 1301-1306页

作者： XU Bo YANG Xiao-Dong kong ling-xue School of Chemistry and Chemical Engineering University of JinanJinan 250022China

A new silver(I)complex{Ag2(dppm)2[N(CN)2]}2[μ-N(CN)2]2(1)with chelate ligand bis(diphenylphosphino)methane(dppm)and bridging ligand dicyanamide(N(CN)2)was carefully synthesized and fully characterized by single-crystal X-ray crystallography,IR spectrometry,high-resolution mass spectrometry,thermal analysis and 1H *** to the crystal structure analysis,this complex could be considered as two binucleate moieties{Ag2(dppm)2[N(CN)2]}+linked by two bridging anionic ligands N(CN)2-.It exhibits thermochromic property in solid *** dependence of color or emission of substance on temperature is known as *** temperature luminescences of complex 1 are *** with the reduction of temperature from 298 K to 77 K,a noticeable emission enhancement as well as lifetime extension is observed.

关键词： silver complex crystal structure dicyanamide bis(diphenylphosphino)methane thermochromic property

Numerical analysis of carbon saving potential in a top gas recycling oxygen blast furnace

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Journal of Iron and Steel Research International 2017年第6期24卷 608-616页

作者： xue-feng She Xiu-wei An Jing-song Wang Qing-guo xue ling-tan kong State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Beijing 100083 China Qingdao Special Steel Company Limited Shandong Qingdao 266409 Shandong China

Aiming at the current characteristics of blast furnace （BF） process, carbon saving potential of blast furnace was investigated from the perspective of the relationship between degree of direct reduction and carbon consumption. A new relationship chart between carbon consumption and degree of direct reduction, which can reflect more real situation of blast furnace operation, was established. Further- more, the carbon saving potential of hydrogen-rich oxygen blast furnace （OBF） process was ana- lyzed. Then, the policy implications based on this relationship chart established were suggested. On this basis, the method of improving the carbon saving potential of blast furnace was recycling the top gas with removal of CO2 and H2O or increasing hydrogen in BF gas and full oxygen blast. The results show that the carbon saving potential in traditional blast furnace （TBF） is only 38 56 kg · t ^-1 while that in OBF is 138 kg · t ^-1. Theoretically, the lowest carbon consumpt!on of OBF is 261 kg · t ^-1 and the corresponding degree of direct reduction is 0.04. In addition, the theoretical lowest carbon consumption of hydrogen-rich OBF is 257 kg · t ^-1. The modeling analysis can be used to estimate the carbon savings potential in new ironmaking process and its related CO2 emissions.

关键词： Blast furnace processDirect reduction degreeCarbon consumptionDirect reductionCarbon saving potentiaOxygen blast furnace

Steroids from the Roots of Asparagus officinalis and Their Cytotoxic Activity

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Journal of Integrative Plant Biology 2008年第6期50卷 717-722页

作者： xue-Feng Huang Yu-Ying Lin ling-Yi kong Department of Natural Medicinal Chemistry China Pharmaceutical University Nanjing 210009 China

One new （Sarsasapogenin O） and seven known steroids were isolated from the roots of Asparagus offlcinalis L. Their structures were elucidated on the basis of spectroscopic analysis, including various 2D-NMR techniques, hydrolysis, and by comparison of spectral data of known compounds. These compounds together with nine steroids which were previously isolated from this plant, were tested for cytotoxic activity. Among them, eight compounds displayed significant cytotoxiciUes against human A2780, HO-8910, Eca-109, MGC-803, CNE, LTEP-a-2, KB and mouse L1210 tumor cells.

关键词： Asparagus officinalis cytotoxic activity Sarsasapogenin O steroid

Effects of iron precursors on the structure and catalytic performance of iron molybdate prepared by mechanochemical route for methanol to formaldehyde

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Chinese Journal of Chemical Engineering 2020年第6期28卷 1603-1611页

作者： lingtao kong Shengtao Xu xue Liu Chaofan Liu Dandan Zhang ling Zhao Key Laboratory of Coal Clean Conversion&Chemical Engineering Process College of Chemistry and Chemical EngineeringXinjiang UniversityUrumqi 830046China Key Laboratory of Oil and Gas Fine Chemicals of Education College of Chemistry and Chemical EngineeringXinjiang UniversityUrumqi 830046China

Mechanochemical synthesis has been applied for many novel material preparations and gained more and more attention due to green and high-efficiency recently. In order to explore the influences of iron precursors on structure and performance of iron molybdate catalyst prepared by mechanochemical route, three typical and cheap iron precursors have been used in preparation of iron molybdate catalyst. Many characterization methods have been employed to obtain the physical and chemical properties of iron molybdate catalyst. Results indicate that iron precursors have the significant impact on the phase composition, crystal morphology and catalytic performance in the conversion of methanol to formaldehyde. It is hard to regulate the phase composition by changing Mo/Fe mole ratios for Fe2(SO4)3 as iron precursor. In addition, as for Fe2(SO4)3, the formaldehyde yield is lower than that from iron molybdate catalyst prepared with Fe(NO3)3·9H2O due to the reduction in Fe2(MoO4)3 phase as active phase. Based on mechanochemical and coprecipitation method, the solvent water could be a key factor for the formation of MoO3 and Fe2(MoO4) for FeCl3·6H2O and Fe2(SO4)3 as precursors. Iron molybdate catalyst prepared with Fe(NO3)3·9H2O by mechanochemical route, shows the best methanol conversion and formaldehyde yield in this reaction.

关键词： Iron precursors Mechanochemical route Iron molybdate catalyst Methanol oxidation

The School that Changes Mindsets

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China Today 2025年第1期74卷 62-64页

作者： GUO QING kong SIQI 不详

China’s highest-altitude primary school is not only teaching children of farmers and herders but their parents as *** Sinopec Primary School in Nagqu,a city in Xizang Autonomous Region in southwest China,is known as the school“the closest to the sky”due to its high-altitude location-a breathtaking 4,700 meters above sea *** by oil and gas giant Sinopec as part of its corporate social responsibility,the school opened in 2012 and has since become a microcosm of China’s drive for education,especially in remote and rural areas,to ensure that no one is left behind.

关键词： altitude farmers southwest

Promoting amorphization of commercial TiO_(2) upon sodiation to boost the sodium storage performance

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Journal of Energy Chemistry 2023年第6期81卷 379-388,I0009页

作者： Tao Li ling-Yun kong xue Bai Yan-Xiang Wang Yong-Xin Qi Key Laboratory of Liquid-Solid Structural Evolution and Processing of Materials of Ministry of Education State Key Laboratory of Crystal MaterialsShandong UniversityJinan 250061ShandongChina School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590ShandongChina

Anatase TiO_(2) is a promising anode material for sodium-ion batteries,yet the low electronic and ionic conductivities are the main obstacles for its practical *** though the amorphization of TiO_(2) upon sodiation has already been observed,its underneath mechanisms are not fully ***,a low-cost nitrogen-containing carbon source of polyacrylonitrile is adopted to modify commercial anatase TiO_(2) by a convenient and nontoxic ball-milling technique combined with subsequent annealing *** particular,the employment of a nitrogen-doping approach accompanied by nitrogendoped carbon coating,results in a greatly improved conductivity,overall leading to a high reversible capacity of about 260 m A h g^(-1)at 25 m A g^(-1),superior rate capabilities,and an ultra-stable capacity of about 186 m A h g^(-1)after 1600 cycles at 500 m A g^(-1).Detailed characterizations denote that the improved conductivity as well as the small size of the synthesized TiO_(2) grains play a key role in the TiO_(2) amorphization upon sodiation,with the TiO_(2)/C nanocomposite undergoing a complete amorphization in just few ***,the irreversible amorphization of TiO_(2) is confirmed to be a crucial ingredient facilitating the Na+diffusion kinetics and pseudocapacitive behavior,thus boosting the sodium storage performance.

关键词： Commercial TiO_(2) Anode material Amorphization Nitrogen doping Sodium-ion battery

Neurons-system-like structured SnS_(2)/CNTs composite for high-performance sodium-ion battery anode

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Rare Metals 2021年第6期40卷 1383-1390页

作者： ling Zhu xue-Xian Yang Yan-Hong Xiang Peng kong Xian-Wen Wu School of Physics and Electromechanical Engineering Jishou UniversityJishou 416000China School of Chemistry and Chemical Engineering Jishou UniversityJishou 416000China

Sodium-ion batteries(SIBs)have attracted significant attention with respect to renewable energy power generation systems because of the abundant reserves of sodium on ***,anode materials are presently limited by low energy density,poor rate performance and inferior cycling *** recent years,tin disulfide(SnS_(2))with a particular layered structure has been considered as a promising anode material for SIBs due to its high theoretical capacity and low ***,a nervoussystem-like structured SnS_(2)/CNTs composite was successfully synthesized via a hydrothermal *** SnS_(2)sheets were strung with carbon nanotubes(CNTs)to form a hierarchical porous structure,which is effective for electrolyte diffusion and electronic *** large distance of the(001)plane(0.5899 nm)of SnS_(2)favors Na+insertion-extraction *** from these structural characteristics,SnS_(2)/CNTs electrodes exhibit high specific capacity,excellent rate performance and superior cycling stability.A high charge capacity of 642 mAh·g^(-1)was released at 0.2 A·g^(-1),and then,a high reversible capacity of 427 mAh·g^(-1)was retained after 100 *** charged at 2 A·g^(-1),the SnS_(2)/CNTS electrode maintained a capacity of 282 mAh·g^(-1).The nervous-system-like structure of the SnS_(2)/CNTs composite provides a novel strategy for the development of SIBs with high electrochemical performance.

关键词： SnS_(2)/CNTs Sodium-ion batteries Anode Composite Rate capability