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Transient synthesis of carbon-supported high-entropy alloy sulfide nanoparticles via flash Joule heating for efficient electrocatalytic hydrogen evolution

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Nano Research 2024年第4期17卷 3379-3389页

作者： Yuntian liao Rongtao Zhu Wenjun Zhang Haiyang Zhu Yang Sun Jiale chen Zhenhua Dong Ronghuan Lv School of Chemical Engineering and Technology China University of Mining and TechnologyXuzhou 221116China

High entropy alloys(HEA)are frequently employed as catalysts in electrocatalytic hydrogen ***,the traditional high entropy alloy synthesis methods are time-consuming,energy-intensive,and environmentally polluting,which limits their application in the hydrogen evolution reaction(HER).This study leveraged the capabilities of flash Joule heating(FJH)to synthesize carbon-supported high-entropy alloy sulfide nanoparticles(CC-S-HEA)on carbon cloth(CC)with good self-standing properties within 300 *** carbon thermal shock generated by the Joule heating could pyrolyze the sulfur source into gas,resulting in numerous pore structures and defects on CC,forming an S-doped carbon substrate(CC-S).Then the S atoms were used to stably anchor the metal atoms on CC-S to form high-density uniformly dispersed HEA *** electrochemical test results demonstrated that CC-S-HEA prepared at 60 V flash voltage had HER performance comparable to Pt/*** density functional theory(DFT)calculation indicated that the S atoms on CC-S accelerated the electron transfer between the carbon substrate and HEA ***,the unique electronic structure of CC-S-HEA was beneficial to H*adsorption and promoted catalytic *** simplicity and versatility of FJH synthesis are of great significance for optimizing the synthesis of HEA and improving the quality of HEA products,which provides a broad application prospect for the synthesis of nanocatalysts with efficient HER performance.

关键词： high entropy alloy flash Joule heating carbon thermal shock hydrogen evolution reaction density functional theory

Tumor necrosis factor-α： a new mechanism of ischemic ventricular fibrillation？

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Chinese Medical Journal 2008年第18期121卷 1848-1851页

作者： XIAO Hua liao Yu-hua chen Zhi-jian Laboratory of Cardiovascular Immunology Institute of Cardiology Union Hospital Tongji Medical College Huazhong University of Science and Technology Wuhan Hubei 430022 China

Ventricular fibrillation （VF） in myocardial ischemia is called ＂ischemic VF＂. As a severe morbid state and a leading cause of sudden cardiac attack, ischemic VF induces approximately 3 million deaths in the United States each year. Ischemic VF is caused by ＂triggers＂ such as ventricular premature beat or ventricular tachycardia in the presence of a suitable ＂substrate＂. The triggers frequently occur at the border zone and the substrate is required for the maintenance of ischemic VE The critical factors for the initiation and maintenance of ischemic VF are obscure. Tumor necrosis factor-α （TNF-α）, an inflammatory cytokine expressed in myocardial ischemia, plays an important role in the pathophysiological process of acute myocardial infarction （AMI）. TNF-α also causes arrhythmia by action potential prolongation and abnormal Ca^2＋ handling, which also contribute to ischemic VE But the relationship between TNF-α and ischemic VF is unknown. In this article, we suggest that TNF-α may be a novel substrate of ischemic VE This may be a new mechanism for ischemic VF.

关键词： ischemic ventricular fibrillation tumor necrosis factor-alpha arrhythmias, cardiac

A Soft Sensor with Light and Efficient Multi-scale Feature Method for Multiple Sampling Rates in Industrial Processing

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Machine Intelligence Research 2024年第2期21卷 400-410页

作者： Dezheng Wang Yinglong Wang Fan Yang Liyang Xu Yinong Zhang Yiran chen Ning liao School of Automation Southeast UniversityNanjing 210096China Software and Artificial Intelligence College Chongqing Institute of EngineeringChongqing 400056China Beijing National Research Center for Information Science and Technology(BNRist) Department of AutomationTsinghua UniversityBeijing 100084China Liangjiang International College Chongqing University of TechnologyChongqing 401135China Smart City College Beijing Union UniversityBeijing 100101China

In industrial process control systems,there is overwhelming evidence corroborating the notion that economic or technical limitations result in some key variables that are very difficult to measure *** data-driven soft sensor is an effective solution because it provides a reliable and stable online estimation of such *** paper employs a deep neural network with multiscale feature extraction layers to build soft sensors,which are applied to the benchmarked Tennessee-Eastman process(TEP)and a real wind farm *** comparison of modelling results demonstrates that the multiscale feature extraction layers have the following advantages over other ***,the multiscale feature extraction layers significantly reduce the number of parameters compared to the other deep neural ***,the multiscale feature extraction layers can powerfully extract dataset ***,the multiscale feature extraction layers with fully considered historical measurements can contain richer useful information and improved representation compared to traditional data-driven models.

关键词： Multi-scale feature extractor deep neural network(DNN) multirate sampled industrial processes prediction

Deformation Characteristics of Hydrate-Bearing Sediments

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Journal of Ocean University of China 2024年第1期23卷 149-156页

作者： DONG Lin LI Yanlong ZHANG Yajuan HU Gaowei liao Hualin chen Qiang WU Nengyou Key Laboratory of Gas Hydrate Ministry of Natural ResourcesQingdao Institute of Marine GeologyQingdao 266237China Laboratory for Marine Mineral Resources Laoshan LaboratoryQingdao 266237China College of Oceanography Hohai UniversityNanjing 210098China College of Petroleum Engineering China University of Petroleum(East China)Qingdao 266555China

The safe and efficient development of natural gas hydrate requires a deep understanding of the deformation behaviors of *** this study,a series of triaxial shearing tests are carried out to investigate the deformation properties of hydrate-bearing *** of volumetric and lateral strains versus hydrate saturation are analyzed *** indicate that the sediments with high hydrate saturation show dilative behaviors,which lead to strain-softening characteristics during *** volumetric strain curves have a tendency to transform gradually from dilatation to compression with the increase in effective confining *** easy prediction model is proposed to describe the relationship between volumetric and axial *** model coefficientβis the key dominating factor for the shape of volumetric strain curves and can be determined by the hydrate saturation and stress ***,a modified model is established for the calculation of lateral *** corresponding determination method is provided for the easy estimation of model coefficients for medium sand sediments containing *** study provides a theoretical and experimental reference for deformation estimation in natural gas hydrate development.

关键词： gas hydrate deformation characteristics volumetric strain lateral strain prediction model

Comprehensive study on fail-safe topological design method for 3D structures

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Acta Mechanica Sinica 2024年第6期40卷 87-99页

作者： Hongxin Wang Yujun liao Guilin Wen Liangliang chen Jie Liu Center for Research on Leading Technology of Special Equipment School of Mechanical and Electric EngineeringGuangzhou UniversityGuangzhou510006China Department of Rehabilitation Medicine The Fifth Affiliated Hospital of Guangzhou Medical UniversityGuangzhou510735China Hebei Innovation Center for Equipment Lightweight Design and Manufacturing School of Mechanical EngineeringYanshan UniversityQinhuangdao066004China

Fail-safe topology optimization is valuable for ensuring that optimized structures remain operable even under damaged *** selectively removing material stiffness in patches with a fixed shape,the complex phenomenon of local failure is modeled in fail-safe topology *** this work,we first conduct a comprehensive study to explore the impact of patch size,shape,and distribution on the robustness of fail-safe *** findings suggest that larger sizes and finer distribution of material patches can yield more robust fail-safe ***,a finer patch distribution can significantly increase computational costs,particularly for 3D *** keep computational efforts tractable,an efficient fail-safe topology optimization approach is established based on the framework of multi-resolution topology optimization(MTOP).Within the MTOP framework,the extended finite element method is introduced to establish a decoupling connection between the analysis mesh and the topology description *** examples demonstrate that the developed methodology is 2 times faster for 2D problems and over 25 times faster for 3D problems than traditional fail-safe topology optimization while maintaining similar levels of robustness.

关键词： Robust design Fail-safe structures Multi-resolution topology optimization Computational efficiency XFEM

Unveiling the parasitic-reaction-driven surface reconstruction in Ni-rich cathode and the electrochemical role of Li_(2)CO_(3)

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Journal of Energy Chemistry 2023年第10期85卷 126-136,I0006页

作者： Jiyu Cai Zhenzhen Yang Xinwei Zhou Bingning Wang Ana Suzana Jianming Bai chen liao Yuzi Liu Yanbin chen Shunlin Song Xuequan Zhang Li Wang Xiangming He Xiangbo Meng Niloofar Karami Baasit Ali Shaik Sulaiman Natasha A.Chernova Shailesh Upreti Brad Prevel Feng Wang Zonghai chen Chemical Sciences and Engineering Division Argonne National Laboratory9700 South Cass AvenueLemontIL 60439USA Center for Nanoscale Materials Argonne National Laboratory9700 South Cass AvenueLemontIL 60439USA Condensed Matter Physics and Materials Science Department Brookhaven National LaboratoryUptonNY 11973USA Energy and Photon Sciences Directorate Brookhaven National LaboratoryUptonNY 11973USA Beijing Easprint Material Technology Co.Ltd. Beijing 100160China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Department of Mechanical Engineering University of ArkansasFayettevilleAR 72701USA Charge CCCV(C4V) 45 Murray Hill RoadCenter of ExcellenceBinghamton UniversityVestalNY 13850USA Primet Precision Materials 950 Danby RoadIthacaNY 14850USA Applied Materials Division Argonne National Labo

Nickel-rich transition-metal oxides are widely regarded as promising cathode materials for high-energydensity lithium-ion batteries for emerging electric vehicles. However, achieving high energy density in Ni-rich cathodes is accompanied by substantial safety and cycle-life obstacles. The major issues of Ni-rich cathodes at high working potentials are originated from the unstable cathode-electrolyte interface, while the underlying mechanism of parasitic reactions towards surface reconstructions of cathode materials is not well understood. In this work, we controlled the Li_(2)CO_(3) impurity content on LiNi_(0.83)Mn_(0.1)Co_(0.07)O_(2) cathodes using air, tank-air, and O_(2) synthesis environments. Home-built high-precision leakage current and on-line electrochemical mass spectroscopy experiments verify that Li_(2)CO_(3) impurity is a significant promoter of parasitic reactions on Ni-rich cathodes. The rate of parasitic reactions is strongly correlated to Li_(2)CO_(3) content and severe performance deterioration of Ni83 *** post-mortem characterizations via high-resolution transition electron microscope and X-ray photoelectron spectroscopy depth profiles reveal that parasitic reactions promote more Ni reduction and O deficiency and even rock-salt phase transformation at the surface of cathode materials. Our observation suggests that surface reconstructions have a strong affiliation to parasitic reactions that create chemically acidic environment to etch away the lattice oxygen and offer the electrical charge to reduce the valence state of transition metal. Thus, this study advances our understanding on surface reconstructions of Nirich cathodes and prepares us for searching for rational strategies.

关键词： Ni-rich cathodes Surface reconstructions Phase transformation Parasitic reactions Li_(2)CO_(3)

Configuring single-layer MXene nanosheet onto natural wood fiber via C-Ti-C covalent bonds for high-stability Li-S batteries

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Journal of Energy Chemistry 2024年第8期95卷 701-711,I0016页

作者： Yangyang chen Yu liao Ying Wu Lei Li Zhen Zhang Sha Luo Yiqiang Wu Yan Qing College of Materials Science and Technology Central South University of Forestry and TechnologyChangsha 410004HunanChina

Lithium-sulfur batteries(LSBs)are considered promising candidates for next-generation battery technologies owing to their outstanding theoretical energy density and ***,the low conductivity and polysulfide shuttling effect of S cathodes severely hamper the practical performance of ***,in situ-generated single layer MXene nanosheet/hierarchical porous carbonized wood fiber(MX/PCWF)composites are prepared via a nonhazardous eutectic activation strategy coupled with pyrolysis-induced gas *** unique architecture,wherein single layer MXene nanosheets are constructed on carbonized wood fiber walls,ensures rapid polysulfide conversion and continuous electron transfer for redox *** C-Ti-C bonds formed between MXene and PCWF can considerably expedite the conversion of polysulfides,effectively suppressing the shuttle *** impressive capacity of 1301.1 m A h g^(-1)at 0.5 C accompanied by remarkable stability is attained with the MX/PCWF host,as evidenced by the capacity maintenance of 722.6 m A h g^(-1)after 500 ***,the MX/PCWF/S cathode can still deliver a high capacity of 886.8 m A h g^(-1)at a high S loading of 5.6 mg cm^(-2).The construction of two-dimensional MXenes on natural wood fiber walls offers a competitive edge over S-based cathode materials and demonstrates a novel strategy for developing high-performance batteries.

关键词： Lithium-sulfur batteries S cathodes MXene nanosheets Wood fiber C-Ti-C bonds

A Parallel-type Load Damping Factor Controller for Frequency Regulation in Power Systems with High Penetration of Renewable Energy Sources

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Journal of Modern Power Systems and Clean Energy 2024年第4期12卷 1019-1030页

作者： Zhe Zhang Siyang liao Yuanzhang Sun Jian Xu Deping Ke Bo Wang Rui chen Yibo Jiang Hubei Engineering and Technology Research Center for AC/DC Intelligent Distribution Network School of Electrical Engineering and AutomationWuhan UniversityWuhan 430072China State Grid Hubei Electric Power Company Limited Economic Research Institute Wuhan 430074China State Grid(Suzhou)City&Energy Research Institute Company Limited Suzhou 215000China

Renewable energy sources(RESs)are rapidly devel-oping and their substitution for traditional power generation poses significant challenges to the frequency regulation in pow-er *** load damping factor D characterizes the active power of load that changes with power system frequency,which is an important factor influencing the frequency ***-ever,the value of D is small,resulting in the limitation in fre-quency regulation of the power *** paper proposes a parallel-type load damping factor controller to enhance load damping factor by utilizing static var generators(SVGs)in ***,it discusses the configuration method for the relevant parameters of the controller,evaluates its frequen-cy regulation capability,investigates the impact of large-scale application of the controller on static and dynamic loads,and conducts a comprehensive evaluation of the impact of the damp-ing factor control process on the voltage stability of the main *** large-scale application of the proposed controller can significantly improve the frequency regulation capability,and al-most have no influence on the working status of the *** can also significantly improve the dynamic performance of system *** proposed controller can provide technical sup-port for the frequency regulation of new power systems with high proportion of RESs.

关键词： Load damping factor parallel-type load damping factor controller power system frequency regulation highproportion renewable energy system

Discrimination of intra/extracellular sidedness segments of transmembrane proteins

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生物物理学报 2009年第S1期25卷 193-194页

作者： Wei chen, liao-fu Luo School of Physical Science and Technology, Inner Mongolia University, Hohhot 010021, China

Topology of the transmembrane protein is closely related to its functions. So, it is desiderated to depict the topology of transmembrane proteins. In this work, an effective approach

关键词： transmembrane protein topology increment of diversity quadratic discriminant analysis