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Minimum mass-entransy dissipation profile for one-way isothermal diffusive mass-transfer process with mass-resistance and massleakage

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Science China(Technological Sciences) 2024年第8期67卷 2427-2435页

作者： chen LinGen XIA ShaoJun Institute of Thermal Science and Power Engineering Wuhan Institute of TechnologyWuhan 430205China School of Mechanical Electrical EngineeringWuhan Institute of TechnologyWuhan 430205China School of Power Engineering Naval University of EngineeringWuhan 430033China

As a new concept,mass-entransy is one of the twins in the core of entransy *** can describe mass-transfer ability for masstransfer processes(MTPes),just as thermal-entransy for describing heat-transfer ***,mass-entransy dissipation can be utilized to evaluate the loss of mass-transfer *** mass-entransy dissipation(MMED) is utilized to optimize one-way isothermal diffusive MTPes with mass-leakage and mass-transfer law(g ∝ Δ(c),where c means concentration).For a given net amount of mass-transferred key components at the low-concentration side,optimality-condition for the MMED of isothermal diffusive MTPes is obtained by using the *** of the amount of mass-transferred and mass-leakage on optimal results are analyzed,and the obtained optimization profiles are compared with those for MTP profiles of constant-concentration-difference(c_1-c_2=const) and constant-concentration-ratio(c_1/c_2=const).The product of square of key-component-concentration(KCC) difference between high-and low-concentration sides and inert component concentration at high-concentration side for the MMED of the MTP with no mass-leakage is a constant,and the optimal relationship of the KCCs between high-and low-concentration sides with mass-leakage is significantly different from the *** mass-leakage is relatively small,the MTP with c_1-c_2=const strategy is superior to that with c_1/c_2=const strategy,and the latter is superior to the former with an increase in mass-leakage.A combination of mass-entransy concept,finite-time thermodynamics,and averaged-optimization-method is a meaningful tool for optimizing MTPes.

关键词： diffusive mass-transfer-law mass-leakage one-way isothermal mass-transfer minimum mass-entransy dissipation finite-time thermodynamics averaged-optimization-method

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Balancing Exploration–Exploitation of Multi-verse Optimizer for Parameter Extraction on Photovoltaic Models

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Journal of Bionic Engineering 2024年第2期21卷 1022-1054页

作者： Yan Han Weibin chen Ali Asghar Heidari Huiling chen Xin Zhang College of Computer Science and Artificial Intelligence Wenzhou UniversityWenzhou325035China School of Surveying and Geospatial Engineering College of EngineeringUniversity of TehranTehranIran School of Biomedical Engineering National Engineering Research Center of Ophthalmology and OptometryEye HospitalWenzhou Medical UniversityWenzhou325027China Key Lab of Biohealth Materials and Chemistry of Wenzhou Wenzhou UniversityWenzhouChina Key Laboratory of Intelligent Informatics for Safety&Emergency of Zhejiang Province Wenzhou UniversityWenzhouChina

Extracting photovoltaic(PV)model parameters based on the measured voltage and current information is crucial in the simulation and management of PV *** accurately and reliably extract the unknown parameters of different PV models,this paper proposes an improved multi-verse optimizer that integrates an iterative chaos map and the Nelder–Mead simplex method,*** experiments verified that the proposed INMVO fueled by both mechanisms has more affluent populations and a more reasonable balance between exploration and ***,to verify the feasibility and competitiveness of the proposal,this paper employed INMVO to extract the unknown parameters on single-diode,double-diode,three-diode,and PV module four well-known PV models,and the high-performance techniques are selected for *** addition,the Wilcoxon signed-rank and Friedman tests were employed to test the experimental results *** evaluation metrics,such as root means square error,relative error,absolute error,and statistical test,demonstrate that the proposed INMVO works effectively and accurately to extract the unknown parameters on different PV models compared to other *** addition,the capability of INMVO to stably and accurately extract unknown parameters was also verified on three commercial PV modules under different irradiance and *** conclusion,the proposal in this paper can be implemented as an advanced and reliable tool for extracting the unknown parameters of different PV *** that the source code of INMVO is available at https://***/woniuzuioupao/INMVO.

关键词： Photovoltaic models Multi-verse optimizer Nelder-Mead simplex Iterative chaos map

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Modeling solubility of oxaprozin and irbesartan in biorelevant complex solutions based on a combination of pH-dependent and micellar solubilization models

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CHINESE JOURNAL OF CHEMICAL ENGINEERING 2024年第8期72卷 34-43页

作者： Shen, chen Ji, Yuanhui Southeast Univ Sch Chem & Chem Engn Jiangsu Prov Hitech Key Lab Biomed Res Nanjing 211189 Peoples R China

Biological solubility is one of the important basic parameters in the development process of poorly soluble drugs, but the current measurement methods are mainly based on a large number of experiments, which are time-consuming and cost-intensive. There is still a lack of effective theoretical models to accurately describe and predict the biological solubility of drugs to reduce costs. Therefore, in this study, osaprazole and irbesartan were selected as model drugs, and their solubility in solutions containing surfactants and biorelevant media was measured experimentally. By calculating the parameters of each component using the perturbed-chain statistical associating fluid theory (PC-SAFT) model, combined with pH-dependent and micellar solubilization models, the thermodynamic phase behavior of the two drugs was successfully modeled, and the predicted results were in good agreement with the experimental values. These results demonstrate that the model combination used provides important basic parameters and theoretical guidance for the development and screening of poorly soluble drugs and related formulations. (c) 2024 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies.

关键词： Biorelevant media pH -dependent solubility Micellar solubilization PC-SAFT Active pharmaceutical ingredients POLYCYCLIC AROMATIC-HYDROCARBONS HUMAN GASTROINTESTINAL-TRACT PERTURBED-CHAIN SAFT THERMODYNAMIC MODEL DISSOLUTION MEDIA DRUG SURFACTANT TEMPERATURE BEHAVIOR SALT

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Fine description of unconventional clastic oil reservoirs

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Petroleum Research 2024年第2期9卷 289-303页

作者： Huanqing chen Research Institute of Petroleum Exploration&Development PetroChinaChina

The latest researches reveal that studies on unconventional clastic oil reservoirs in China generally lag far behind those in other countries in respect of content and *** study presents the definition and classification of unconventional oil reservoirs and analyzes the problems in the fine description of unconventional oil *** key content of the fine description of unconventional oil reservoirs is summarized from four aspects:fine fracture characterization based on fine structure interpretation,reservoir architecture characterization based on sedimentary facies,characteristics of nanoscale microscopic pore structure of reservoir,and evaluation of source rock and“sweet spot zone”.Finally,this study suggests that development of fine description of unconventional clastic oil reservoirs in the future should focus on rock brittleness analysis and fracture modeling,geophysical characterization of unconventional clastic oil reservoirs,fluid description of tight reservoirs,and physical/numerical simulation experiments of unconventional oil reservoirs.

关键词： Unconventional clastic reservoir Fine reservoir description Oil sand Tight oilShale oil Fracture characterization Nanoscale microscopic pore structure Sweet spot

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Gravitational wave fluxes on generic orbits in near-extreme Kerr spacetime:Higher spin and large eccentricity

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Science China(Physics,Mechanics & Astronomy) 2024年第11期Mechanics & Astronomy) .卷 20-32页

作者： Changkai chen Jiliang Jing Department of Physics Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of EducationSynergetic Innovation Center for Quantum Effects and Applications Hunan Normal University

To accurately obtain the waveform template of gravitational waves, substantial computational resources and extremely high precision are often required. In a previous study, we employed the confluent Heun function to obtain an exact solution to the Teukolsky equation. This approach allowed us to efficiently and accurately calculate the gravitational wave flux for a particle in circular orbits around a Schwarzschild black hole. Building on this method, we now extend its application to calculate the asymptotic gravitational wave fluxes from a particle in generic orbits around a near-extreme Kerr black hole. Our extended method proves particularly effective in handling computational challenges associated with large eccentricities(e = 0.9), higher spins(a = 0.999), higher harmonic modes, and strong-field regions. The results we obtained significantly outperform those derived from the numerical integration method based on the Mano-Suzuki-Takasugi method.

关键词： gravitational wave fluxes exact solution Teukolsky equation near-extreme Kerr black hole

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Yttrium‐and nitrogen‐doped NiCo phosphide nanosheets for high‐efficiency water electrolysis

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Carbon Energy 2024年第8期6卷 214-231页

作者： Guangliang chen Huiyang Xiang Yingchun Guo Jun Huang Wei chen Zhuoyi chen Tongtong Li Kostya(Ken)Ostrikov Department of Materials Engineering Huzhou UniversityHuzhouChina School of Materials Science and Engineering Zhejiang Sci‐Tech UniversityHangzhouChina School of Physics and Electronic Information Gannan Normal UniversityGanzhouChina School of Chemistry and Physics Centre for Materials ScienceCentre for Clean Energy Technologies and PracticesCentre for Waste−Free WorldQueensland University of Technology(QUT)BrisbaneQueenslandAustralia

Engineering high‐performance and low‐cost bifunctional catalysts for H_(2)(hydrogen evolution reaction[HER])and O_(2)(oxygen evolution reaction[OER])evolution under industrial electrocatalytic conditions remains ***,for the first time,we use the stronger electronegativity of a rare‐Earth yttrium ion(Y^(3+))to induce in situ NiCo‐layered double‐hydroxide nanosheets from NiCo foam(NCF)treated by a dielectric barrier discharge plasma NCF(PNCF),and then obtain nitrogen‐doped YNiCo phosphide(N‐YNiCoP/PNCF)after the phosphating process using radiofrequency plasma in *** obtained NYNiCoP/PNCF has a large specific surface area,rich heterointerfaces,and an optimized electronic structure,inducing high electrocatalytic activity in HER(331mV vs.2000mA cm^(−2))and OER(464mV vs.2000mA cm^(−2))reactions in 1MKOH electrolyte.X‐ray absorption spectroscopy and density functional theory quantum chemistry calculations reveal that the coordination number of CoNi decreased with the incorporation of Y atoms,which induce much shorter bonds of Ni and Co ions and promote long‐term stability of N‐YNiCoP in HER and OER under the simulated industrial ***,the CoN‐YP_(5)heterointerface formed by plasma N‐doping is the active center for overall water *** work expands the applications of rare‐Earth elements in engineering bifunctional electrocatalysts and provides a new avenue for designing highperformance transition‐metal‐based catalysts in the renewable energy field.

关键词： overall water splitting plasma etching plasma N‐doping rare‐earth electrocatalyst yttrium incorporation

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Atmospheric oxidation capacity and O_(3) formation in a coastal city of southeast China:Results from simulation based on four-season observation

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Journal of Environmental Sciences 2024年第2期136卷 68-80页

作者： Gaojie chen Taotao Liu Jinsheng chen Lingling Xu Baoye Hu chen Yang Xiaolong Fan Mengren Li Youwei Hong Xiaoting Ji Jinfang chen Fuwang Zhang Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Key Lab of Urban Environment and Health Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China Minnan Normal University Zhangzhou 363000China College of Harbour and Coastal Engineering Jimei UniversityXiamen 361021China Environmental Monitoring Center of Fujian Fuzhou 350013China

The pollution of atmospheric ozone in China shows an obvious upward trend in the past ***,the studies on the atmospheric oxidation capacity and O_(3)formation in four seasons in the southeastern coastal region of China with the rapid urbanization remain ***,a four-season field observation was carried out in a coastal city of southeast China,using an observation-based model combining with the Master Chemical Mechanism,to explore the atmospheric oxidation capacity(AOC),radical chemistry,O_(3)formation pathways and *** results showed that the average net O_(3)production rate(14.55 ppbv/hr)in summer was the strongest,but the average O_(3)concentrations in autumn was *** AOC and ROx levels presented an obvious seasonal pattern with the maximum value in summer,while the OH reactivity in winter was the highest with an average value of 22.75 sec^(-1).The OH reactivity was dominated by oxygenated VOCs(OVOCs)(30.6%-42.8%),CO(23.2%-26.8%),NO_(2)(13.6%-22.0%),and alkenes(8.4%-12.5%)in different *** photolysis dominated OH primary source on daytime in winter,while in other seasons,HONO photolysis in the morning and ozone photolysis in the afternoon contributed *** analysis indicated that O_(3)production was controlled by VOCs in spring,autumn and winter,but a VOC-limited and NOx-limited regime in summer,and alkene and aromatic species were the major controlling factors to O_(3)***,the study characterized the atmospheric oxidation capacity and elucidated the controlling factors for O_(3)production in the coastal area with the rapid urbanization in China.

关键词： Atmospheric oxidation capacity Radical chemistry Ozone production Sensitivity analysis

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Remodel the perifollicular microenvironment via Minoxidil-loaded microneedle patch and cold atmospheric plasma for treating androgenetic alopecia

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Nano Research 2024年第7期17卷 6411-6419页

作者： Hao chen Xianzhe Tang Yueye Huang chen chen Yuheng Yang Chaojie Hao Wenqi Xie Tingjing Huang Xiaofeng cheng Qingnan Xu Shicong Huang Zhi Ye Xucong Lin Zhaowei chen Zhitong chen MOE Key Laboratory for Analytical Science of Food Safety and Biology and New Cornerstone Science LaboratoryCollege of ChemistryFuzhou UniversityFuzhou 350108China Institute of Biomedical and Health Engineering Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China Advanced Therapeutic Center National Innovation Center for Advanced Medical DevicesShenzhen 518000China Department of Chemistry University College LondonLondon WC1H 0AJUK Engineering Technology Research Center on Reagent and Instrument for Rapid Detection of Product Quality and Food Safety in Fujian Province College of ChemistryFuzhou UniversityFuzhou 350108China Key Laboratory of Biomedical Imaging Science and System Chinese Academy of SciencesShenzhen 518055China

Androgenetic alopecia(AGA)is a chronic and progressive form of hair loss characterized by vascular degeneration in the perifollicular microenvironment,leading to cell apoptosis and eventual loss of hair follicles(HFs).Traditional therapeutic formulations,such as Minoxidil(MXD)tincture,have limitations in reshaping the perifollicular microenvironment and exhibit limited ***,we report a multi-synergistic therapeutic platform for high-performance hair regeneration *** platform combines microneedle(MN)patches loaded with MXD-encapsulated nanostructured lipid carriers(MXD-NLC-MNs)and cold atmospheric plasma(CAP).The MNs’mechanical strength enables efficient transdermal delivery of MXD to the targeted dermal papilla cells,promoting cell ***,in collaboration with MXD,the mechanical stimulation exerted by MN application synergistically upregulates the expression of vascular endothelial growth factor,leading to ***,the transient microchannels in the skin created by MNs facilitate the transdermal delivery of CAPgenerated nitric oxide(NO)to the sites of HF lesions,whereby the synergistic interaction between MXD and NO boosts perifollicular ***,the perifollicular microenvironment can be effectively reshaped to accelerate hair regeneration in AGA murine *** multi-synergistic combination therapy strategy would hold great promise for effectively treating AGA and promoting hair regrowth.

关键词： nanomedicine androgenetic alopecia microneedle cold atmospheric plasma drug delivery

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Detecting compromised accounts caused by phone number recycling on e-commerce platforms: taking Meituan as an example

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Frontiers of Information Technology & Electronic Engineering 2024年第8期25卷 1077-1095页

作者： Min GAO Shutong chen Yangbo GAO Zhenhua ZHANG Yu chen Yupeng LI Qiongzan YE Xin WANG Yang chen School of Computer Science Fudan UniversityShanghai 200438China Shanghai Key Lab of Intelligent Information Processing Fudan UniversityShanghai 200438China Meituan Beijing 100005China Department of Interactive Media Hong Kong Baptist UniversityHong Kong 999077China

Phone number recycling(PNR)refers to the event wherein a mobile operator collects a disconnected number and reassigns it to a new *** has posed a threat to the reliability of the existing authentication solution for e-commerce ***,a new owner of a reassigned number can access the application account with which the number is associated,and may perform fraudulent *** solutions that employ a reassigned number database from mobile operators are costly for e-commerce platforms with large-scale ***,alternative solutions that depend on only the information of the applications are *** this work,we study the problem of detecting accounts that have been compromised owing to the reassignment of phone *** analysis on Meituan's real-world dataset shows that compromised accounts have unique statistical features and temporal *** on the observations,we propose a novel model called temporal pattern and statistical feature fusion model(TSF)to tackle the problem,which integrates a temporal pattern encoder and a statistical feature encoder to capture behavioral evolutionary interaction and significant operation *** experiments on the Meituan and IEEE-CIS datasets show that TSF significantly outperforms the baselines,demonstrating its effectiveness in detecting compromised accounts due to reassigned numbers.

关键词： Phone number recycling Neural networks E-commerce Compromised account detection

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Reverse metasomatism of subduction zone fluids

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Science China Earth Sciences 2024年第2期67卷 634-638页

作者： Yixiang chen School of Earth and Space Sciences University of Science and Technology of ChinaHefei 230026China Key Laboratory of Crust-Mantle Materials and Environments Chinese Academy of SciencesHefei 230026China Center of Excellence for Comparative Planetology Chinese Academy of SciencesHefei 230026China

*** metasomatism in subduction zones Subduction zones are the key tectonic setting that links Earth's surficial sphere to deep sphere(Zheng and chen,2016).Fluid action occurring in subduction zones is closely related to many important geological processes such as volcanic and seismic activity,the migration,enrichment and mineralization of metallogenic elements,mass transport and crust-mantle material cycling,and the evolution of Earth's surface ***,it is of great significance to study the sources,properties and geochemical effects of subduction zone fluids(Zheng,2019).

关键词： subduction metasomatism Earth

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