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Chinese Journal of Polymer Science 2024年第6期42卷 751-765页

作者： Jun-Hao Zhou li-ming tang Key Laboratory of Advanced Materials of Ministry of Education of China Department of Chemical EngineeringTsinghua UniversityBeijing100084China

In this study,a series of hindered urea bond(HUB)containing polyurethane-urea methacrylate prepolymers and a none HUB containing polyurethane methacrylate prepolymer were prepared using isobornyl methacrylate as the reactive diluent via one-pot *** prepolymers were characterized fully by various ***,their thermosets were fabricated via UV curing in presence of a photo initiator,and their mechanical property and thermal behavior were investigated and *** from the none HUB containing thermoset,the HUB containing thermosets(defined as PUT)could be recycled and reprocessed by hot press under relatively mild conditions with high recovery ratio of mechanical ***,zinc oxide(ZnO)nanoparticles were modified with 3-(trimethoxysilyl)propyl methacrylate and the modified ZnO(defined as ZnO-TPM)was dispersed and polymerized into PUT matrix to prepare their *** influence of ZnO-TPM on the mechanical performance of the composites was evaluated,which indicated that the Young’s modulus and tensile strength increased gradually to the maximum values at ZnO-TPM content of 1 wt%and then *** composites also displayed good reprocessability with improved recovery ratio compared to the pure PUT *** addition,the composite materials exhibited strong UV absorption capacity,implying their potential application in the circumstance where UV-shielding was required.

关键词： Polyurethane-urea methacrylate Hindered urea bond ZnO nanoparticles Reprocessing UV curing

炭基磷肥对黑土和红壤磷素有效性及形态变化的影响

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中国土壤与肥料 2024年第3期 40-48页

作者：常康李明堂杨晋霞吴迪吉林农业大学资源与环境学院吉林长春130118

为探究炭基磷肥作为磷源对土壤磷素有效性及形态变化的影响,采用土壤培养试验,将牛粪生物质炭(BC)、重过磷酸钙(TSP)、不同方式制备的炭基磷肥(TSP-1和TSP-2)添加到黑土(高磷)和红壤(低磷)中培养70 d,并作空白对照(CK)。研究结果表明,B... 详细信息

为探究炭基磷肥作为磷源对土壤磷素有效性及形态变化的影响,采用土壤培养试验,将牛粪生物质炭(BC)、重过磷酸钙(TSP)、不同方式制备的炭基磷肥(TSP-1和TSP-2)添加到黑土(高磷)和红壤(低磷)中培养70 d,并作空白对照(CK)。研究结果表明,BC处理对黑土和红壤磷素有效性影响很小,但呈现上升的趋势;TSP、TSP-1和TSP-2处理显著增加了黑土和红壤的全磷和有效磷含量。黑土培养前期(0~28 d),TSP、TSP-1和TSP-2处理的土壤有效磷含量分别下降了42.21%、16.81%和29.93%,培养中后期(28~70d),TSP-1和TSP-2处理的土壤有效磷含量平均分别比TSP处理高9.47%和9.81%;红壤培养前期(0~28 d),TSP、TSP-1和TSP-2处理的土壤有效磷含量分别下降了78.31%、24.64%和57.53%,培养中后期(28~70 d),TSP-1和TSP-2处理的土壤有效磷含量平均分别比TSP处理高129.23%和53.10%。BC处理增加了黑土HCl-P的含量及红壤NaOH-P、HCl-P的含量;TSP、TSP-1和TSP-2处理显著增加了黑土和红壤Water-P和NaHCO3-P的含量,对其他磷组分(NaOH-P、HCl-P、Residual-P)也有影响。BC、TSP-1和TSP-2处理显著提高了黑土和红壤的pH值,TSP处理降低了黑土的pH值,对红壤的pH值影响较小。综上所述,相比无机磷肥,以炭基磷肥作为磷源可以减缓磷素在黑土和红壤中的释放速率,避免磷素被土壤大量固定,并影响土壤磷素形态的分布,提高磷肥在土壤中的有效利用率,尤其在红壤中作用效果更为明显。

关键词：土壤磷素炭基磷肥缓释磷有效性磷组分

同方期刊数据库博看期刊评论

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生菜镉污染可见-近红外光谱分析模型

光谱学与光谱分析 2024年第10期44卷 2805-2811页

作者：周雷进雨周丽娜陈丽梅孔丽娟乔建磊李明堂吉林农业大学工程技术学院吉林长春130118 吉林农业大学园艺学院吉林长春130118 吉林农业大学资源与环境学院吉林长春130118

为了快速无损监测生菜受镉污染的程度,利用可见-近红外光谱进行生菜镉污染的分类监测。将土壤镉污染样品设置为0(CK,对照组)、 5、 10和20 mg·kg^(-1),以不同污染程度下种植的生菜为研究对象,采集生菜叶片的可见-近红外反射光谱,分析... 详细信息

为了快速无损监测生菜受镉污染的程度,利用可见-近红外光谱进行生菜镉污染的分类监测。将土壤镉污染样品设置为0(CK,对照组)、 5、 10和20 mg·kg^(-1),以不同污染程度下种植的生菜为研究对象,采集生菜叶片的可见-近红外反射光谱,分析镉污染下生菜叶片可见-近红外光谱反射率的变化规律。光谱信息经分析表明,在510~730 nm波段之间,随着土壤中镉含量的增加,生菜叶片的可见-近红外光谱反射率表现为先降低后增加;在730~799.53 nm波段之间,5和20 mg·kg^(-1)镉胁迫下生菜叶片反射率高于CK组,10 mg·kg^(-1)镉胁迫下生菜叶片反射率低于CK组;且在762.199 nm处出现了一个吸收谷。首先采用平滑(SG)、多元散射校正(MSC)、标准正态化(SNV)、平均归一化(MN)、 SG+MSC、 SG+SNV、 SG+MN、 SG+一阶导数(FD)、 SG+二阶导数(SD)方法对原始光谱进行预处理,以提高信噪比。然后通过主成分分析(PCA)对原始光谱和各种预处理的光谱进行降维处理,最后将降维处理后的数据按照4∶1的比例划分训练集和测试集,分别与粒子群优化随机森林(PSO-RF)、遗传算法优化支持向量机(GA-SVM)、 BP神经网络(BP-NN)、极限学习机(ELM)、朴素贝叶斯(Naive Bayes)结合建立生菜镉污染的分类监测模型,并进行分析比较。结果表明,在不同的模型中,PSO-RF(SG)模型的识别效果最佳,其次是GA-SVM(SG+FD)模型和ELM(MSC)模型,PSO-RF(SG)、 GA-SVM(SG+FD)、 ELM(MSC)模型训练集的准确率均为100%,而测试集的准确率分别为100%、 83.33%和79.17%;BP-NN模型和Naive Bayes模型的效果较差,BP-NN(SNV)模型训练集的准确率为42.72%,测试集准确率为50%;Naive Bayes(SG+FD)模型训练集准确率为71.84%,测试集准确率为83.33%。说明采用可见-近红外光谱结合粒子群优化随机森林建模能够为生菜重金属污染监测提供一种新思路。

关键词：镉重金属污染反射光谱随机森林监测模型

GaInX_3(X=S,Se,Te):Ultra-low thermal conductivity and excellent thermoelectric performance

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Chinese Physics B 2024年第8期33卷 460-465页

作者：段志福丁长浩丁中科肖威华谢芳罗南南曾犟唐黎明陈克求 Department of Physics School of Physics and ElectronicsHunan UniversityChangsha 410082China College of Physical Science and Engineering Technology Yichun UniversityYichun 336000China

Seeking intrinsically low thermal conductivity materials is a viable strategy in the pursuit of high-performance thermoelectric ***,by using first-principles calculations and semiclassical Boltzmann transport theory,we systemically investigate the carrier transport and thermoelectric properties of monolayer Janus GaInX_(3)(X=S,Se,Te).It is found that the lattice thermal conductivities can reach values as low as 3.07 W·m^(-1)·K^(-1),1.16 W·m^(-1)·K^(-1)and 0.57 W·m^(-1)·K^(-1)for GaInS_(3),GaInSe_(3),and GaInTe_(3),respectively,at room *** notably low thermal conductivity is attributed to strong acoustic-optical phonon coupling caused by the presence of low-frequency optical phonons in GaInX_(3) ***,by integrating the charac teristics of electronic and thermal transport,the dimensionless figure of merit ZT can reach maximum values of 0.95,2.37,and 3.00 for GaInS_(3),GaInSe_(3),and GaInTe_(3),*** results suggest that monolayer Janus GaInX_(3)(X=S,Se,Te)is a promising candidate for thermoelectric and heat management applications.

关键词： thermoelectric performance thermal conductivity Boltzmann transport two-dimensional materials

INFLUENCE OF MOLECULAR STRUCTURES OF SECONDARY AMINE TERMINATED POLY(ESTER-AMINE)S ON THE CURING PERFORMANCE WITH EPOXY RESIN

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Chinese Journal of Polymer Science 2007年第6期25卷 545-553页

作者： li-ming tang Ji Feng Yu Wang Advanced Materials Laboratory Department of Chemical Engineering Tsinghua University Beijing 100084 China

Five secondary amine terminated poly（ester-amine）s （defined as PEA） with controlled molecular structures were synthesized through reacting excessive piperazine with phthalicdiglycol diacrylate （PDDA） and 1,1,1-trimethylolpropane triacrylate （TMPTA） at a constant secondary amine/acrylate group ratio of 1.5/1 and at different PDDA/TMPTA molar ratios. Both IR and ^1H-NMR spectra indicated that all acrylate groups were consumed in the reaction, based on which the structural parameters were calculated from the ^1H-NMR spectra. With decreasing PDDA/TMPTA ratio, the content of secondary amine, degree of branching, molecular weight, Tg and Td increased accordingly. These polymers were further used as both crosslinkers and flexibilizers for a linear epoxy resin E51 to form cured films under ambient condition. The gel content, relative hardness and Tg of the resulting films increased as PEA molecules changed from linear to highly branching structures. Due to the flexibility of PEA molecules, all the films possessed excellent mechanical performance.

关键词： Poly(ester-amine) Molecular structure Epoxy resin Cured film.

Highly stable supramolecular hydrogels formed from 1,3,5-benzenetricarboxylic acid and hydroxyl pyridines

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Chinese Chemical Letters 2009年第10期20卷 1259-1262页

作者： li ming tang Yu Jiang Wang Laboratory of Advanced Materials Department of Chemical Engineering Tsinghua University Beijing 100084 China

New supramolecular hydrogels with the maximal sol-gel transition temperature （Tgel） of 95 ℃ were obtained by using gelators formed from 1,3,5-benzenetricarboxylic acid （BTA） and para-hydroxyl pyridine （PHP） or meta-hydroxyl pyridine （MHP）. The single crystal structure of the complex formed from BTA and ortho-hydroxyl pyridine （OHP） indicated that the molecules assembled into superstructure via both hydrogen bonds and π--π stacking interaction.

关键词： Supramolecular hydrogel Gelator Hydrogen bond

Experimental evaluation of the effect of an internal heat exchanger on a transcritical CO_2 ejector system

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2011年第2期12卷 146-153页

作者： Xiao-xiao XU Guang-ming CHEN li-ming tang Zhi-jiang ZHU Shuang liU Institute of Refrigeration and Cryogenics State Key Laboratory of Clean Energy Utilization Zhejiang University Hangzhou 310027 China

This study presents experimental results focused on a performance comparison of a transcritical CO2 ejector system without an internal heat exchanger(IHX) (EJE-S) to a transcritical CO2 ejector system with an IHX(EJE-IHX-S) . The comparison includes the effects of changes in operating conditions such as cooling water flow rate and inlet temperature. Experiments are conducted to assess the influence of the IHX on the heating coefficient of performance(COPr) ,heating capacity,entrainment ratio,pressure lift,and other parameters. The primary flow rate of the EJE-IHX-S is higher than that of the EJE-S. The pressure lift and actual ejector work recovery are reduced when the IHX is added to the transcritical CO2 ejector system. Using a more practical performance calculation,the compression ratio in the EJE-S is reduced by 10.0%-12.1%,while that of EJE-IHX-S is reduced only by 5.6%-6.7% compared to that of a conventional transcritical CO2 system. Experimental results are used to validate the findings that the IHX weakens the contribution of the ejector to the system performance.

关键词： CO2 ejector system Transcritical cycle Heating coefficient of performance (COPr)

Influence of gelator structures on formation and stability of supramolecular hydrogels

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Chinese Chemical Letters 2007年第12期18卷 1548-1550页

作者： Shunji Kono Yu Jiang Wang li ming tang Laboratory of Advanced Materials Department of Chemical Engineering Tsinghua University Beijing 100084 PR China Department of Organic ＆ Polymeric Materials Graduate School of Science ＆ Engineering Tokyo Institute of Technology

A supramolecular hydrogel （defined as G1） formed from 1,2,4,5-benzene tetracarboxylic acid （BTCA） and 2-amino-3- hydroxypyridine possessed higher Tgel than that of another hydrogel （defined as G2） formed from BTCA and 3-hydroxypyridine. Based on the analysis of their xerogels by 1H NMR, IR and XRD, the higher stability of G1 was attributed to the formation of stronger hydrogen binding enhanced by the ortho amino group of 2-amino-3-hydroxypyridine.

关键词： Supramolecular hydrogel Gelation Hydrogen bond

Effect of Temperature, pH and Salt on Fluorescent Quality of Water Extractable Organic Matter in Black Soil

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Journal of Integrative Agriculture 2013年第7期12卷 1251-1257页

作者： li ming-tang ZHAO Lan-po ZHANG Jin-jing College of Resource and Environmental Science Jilin Agricultural University

Water erosion is the major reason for the loss of soil organic carbon in the Northeast China, which leads to the soil quality deterioration and adjacent water pollution. In this study, the effect of extraction temperature, pH value, and salt on the water extractable organic matter （WEOM） was determined by means of the UV absorbance, fluorescence excitation-emission matrix, and derived fluorescence indexes. In general, the carbon content and aromaticity of WEOM increased with the increasing of extraction temperature, with the exception that there was no significant difference in the amount at 0 and 20℃. More fluorophores, especially microbially-derived organic matter were extracted at high temperature. The pH values of extractant, including 5, 7, and 10, showed no effect on the carbon amount of WEOM, whereas the aromaticity and microbially-derived component gradually increased with the increasing of pH values. The fluorescence intensity of humic acid-like fluorophore was stronger in neutral and alkali condition than that in acidic condition. The addition of 10 mmol L-1 CaCl2 significantly decreased the carbon amount of recovered WEOM. Moreover, it significantly decreased the aromaticity of WEOM and the quantity of fulvic acid-like and humic acid-like fluorophores, whereas increased the percentage of tyrosine-like and tryptophan-like fluorophores in the total fluorophores and the amount of microbially-derived organic matter. Generally, 10 mmol L-1 KCl showed the same influence trend, but with low influence degree.

关键词： black soil water extractable organic matter soil profile fluorescence spectroscopy

Experimental investigation of an adjustable ejector for CO_2 heat pump water heaters

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2009年第11期10卷 1678-1682页

作者： Guang-ming CHEN li-xia liANG li-ming tang Xiao-xiao XU Zhi-jiang ZHU Qi CHEN State Key Laboratory of Clean Energy Utilization Institute of Refrigeration and Cryogenics Zhejiang University Hangzhou 310027 China

An adjustable ejector expansion device for a CO2 heat pump water heater (HPWP) is proposed to improve the system performance. It has been designed to investigate experimentally the effects of the motive nozzle throat area of the ejector, entrained flow pressure, back pressure and primary flow pressure on the entrainment ratio. Experiments based on different motive nozzle throat areas were conducted and the results of the prototype ejector using CO2 as working fluid are presented. The results show that an adjustable ejector can achieve high performance and work well in a wide range of working conditions.

关键词： Adjustable elector System nerformance CO2 heat oumo water heater (HPWH) Entrainment ratio