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Ionic Conduction and Fuel Cell Performance of Ba0.97Ce0.8Ho0.2O3-α Ceramic

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Chinese Journal of Chemical Physics 2006年第4期19卷 347-351页

作者： li-gan qiu Department of Chemistry Yancheng Normal College Yancheng 224002 China

The perovskite-type-oxide solid solution Ba0.97Ce0.8Ho0.2O3-α was prepared by high temperature solidstate reaction and its single-phase character was confirmed by X-ray diffraction. The ionic conduction of the sample was investigated using electrical methods at elevated temperatures, and the performance of the hydrogen-air fuel cell using the sample as solid electrolyte was measured, which were compared with those of BaCe0.8Ho0.2O3-α. In wet hydrogen, BaCe0.8Ho0.2O3-α almost exhibits pure protonic conduction at 600-1000℃, and its protonic transport number is 1 at 600-900 ℃ and 0.99 at 1000 ℃. Similarly, Ba0.97Ce9.8Ho0.2O3-α exhibits pure protonic conduction with the protonic transport number of 1 at 600- 700℃, but its protonic conduction is slightly lower than that of BaCe0.8Ho0.2O3-α, and the protonic transport number are 0.99-0.96 at 800-1000 ℃. In wet air, the two samples both show low protonic and oxide ionic conduction. For Ba0.97Ce0.8Ho0.2O3-α, the protonic and oxide ionic transport numbers are 0.01-0.11 and 0.30-0.31 respectively, and for BaCe0.8Ho0.2O3-α, 0.01-0.09 and 0.27-0.33 respectively. Ionic conductivities of Ba0.97Ce0.8Ho0.2O3-α are higher than those of BaCe0.8Ho0.2O3-α under wet hydrogen and wet air. The performance of the fuel cell using Ba0.97Ce0.8Ho0.2O3-α as solid electrolyte is better than that of BaCe0.8Ho0.2O3-α. At 1000 ℃, its maximum short-circuit current density and power output density are 465 mA/cm^2 and 112 mW/cm^2, respectively.

关键词： Ba0.97Ce0.8Ho0.2O3-α Protonic conduction Conductivity Gas concentration cell Fuel cell

Ionic Conduction and Fuel Cell Performance of Ba0.98Ce0.8Tm0.2O3-α Ceramic

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Chinese Journal of Chemical Physics 2010年第6期23卷 707-712,746页

作者：仇立干王茂元盐城师范学院化学化工学院盐城224051

The perovskite-type oxide solid solution Ba0.98Ce0.8Tm0.2O3-α was prepared by high temperature solid-state reaction and its single phase character was confirmed by X-ray diffraction. The conduction property of the sample was investigated by alternating current impedance spectroscopy and gas concentration cell methods under different gases atmospheres in the temperature range of 500-900 ℃. The performance of the hydrogen-air fuel cell using the sample as solid electrolyte was measured. In wet hydrogen, the sample is a pure protonic conductor with the protonic transport number of 1 in the range of 500-600 ℃, a mixed conductor of proton and electron with the protonic transport number of 0.945-0.933 above 600 ℃. In wet air, the sample is a mixed conductor of proton, oxide ion, and electronic hole. The protonic transport numbers are 0.010-0.021, and the oxide ionic transport numbers are 0.471-0.382. In hydrogen-air fuel cell, the sample is a mixed conductor of proton, oxide ion and electron, the ionic transport numbers are 0.942 0.885. The fuel cell using Ba0.98Ce0.8Tm0.2O3-α as solid electrolyte can work stably. At 900 ℃, the maximum power output density is 110,2 mW/cm2, which is higher than that of our previous cell using Ba0.98Ce0.8Tm0.2O3-α （x〈≤1, RE=Y, Eu, Ho） as solid electrolyte.

关键词： Ba0.98Ce0.8Tm0.2O3-α Ionic conduction Gas concentration cell Alternating current impedance Fuel cell

Unlocking the stable interface in aqueous zinc-ion battery with multifunctional xylose-based electrolyte additives

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Journal of Energy Chemistry 2025年第1期100卷 770-778页

作者： Xiaoqin li Jian Xiang Lu qiu Xiaohan Chen Yinkun Zhao Yujue Wang Qu Yue Taotao Gao Wenlong liu Dan Xiao Zhaoyu Jin Panpan li Institute for Advanced Study Chengdu University School of Mechanical Engineering Chengdu University College of Food and Biological Engineering Chengdu University Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China College of Materials Science and Engineering Sichuan University

The growth of dendrites and the side reactions occurring at the Zn anode pose significant challenges to the commercialization of aqueous Zn-ion batteries（AZIBs）. These challenges arise from the inherent conflict between mass transfer and electrochemical kinetics. In this study, we propose the use of a multifunctional electrolyte additive based on the xylose（Xylo） molecule to address these issues by modulating the solvation structure and electrode/electrolyte interface, thereby stabilizing the Zn anode. The introduction of the additive alters the solvation structure, creating steric hindrance that impedes charge transfer and then reduces electrochemical kinetics. Furthermore, in-situ analyses demonstrate that the reconstructed electrode/electrolyte interface facilitates stable and rapid Zn2+ion migration and suppresses corrosion and hydrogen evolution reactions. As a result, symmetric cells incorporating the Xylo additive exhibit significantly enhanced reversibility during the Zn plating/stripping process, with an impressively long lifespan of up to 1986 h, compared to cells using pure ZnSO4electrolyte. When combined with a polyaniline cathode, the full cells demonstrate improved capacity and long-term cyclic stability. This work offers an effective direction for improving the stability of Zn anode via electrolyte design, as well as highperformance AZIBs.

关键词： Solvation

Regulating the oxygen-atom configuration of carbon anode enabling extremely fast-charging potassium-ion hybrid capacitors

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Nano Research 2025年第1期18卷 373-381页

作者： Daping qiu Yuehui Wang Lulu Zhang Hang Lei Haizhou Ying Jin Niu Min li Xuelin Yang Feng Wang Ru Yang Hubei Provincial Collaborative Innovation Center for New Energy Microgrid College of Electrical Engineering and New EnergyChina Three Gorges UniversityYichang 443002China State Key Laboratory of Chemical Resource Engineering Laboratory of Electrochemical Process and Technology for MaterialsBeijing University of Chemical TechnologyBeijing 100029China College of Materials and Chemical Engineering China Three Gorges UniversityYichang 443002China

Metal-ion hybrid capacitors,such as potassium-ion hybrid capacitors(PIHCs),are regarded as promising fast-charging energy storage ***,the kinetics mismatch between the battery anode and the capacitive cathode restricts their fastcharging *** constructing carbon anodes with enhanced kinetics is an innovative approach to address this ***,using epigallocatechin gallate with high oxygen content as the precursor,oxygen-enriched carbon materials(OEC)with tunable C=O content are successfully ***,the C=O content of OEC is regulated by adjusting the pyrolysis *** as an anode for PIHCs,OEC-600 with the highest C=O content exhibits an attractive fast-charging specific capacity of 135.2 mAh·g^(-1)at 20 A·g^(-1),along with a superior fast-charging cycling *** theoretical calculations,comprehensive kinetics analysis and in-situ Raman,the positive effects of C=O on the potassium storage capability and reversibility of OEC-600 are ***,PIHCs assembled based on an OEC-600 anode deliver impressive energy/power density of 145.1 Wh·kg^(-1)/45.9 kW·kg^(-1)and superior fast-charging cycling stability with 87.5%of capacity retention over 20,000 cycles at 5 A·g^(-1).This work is anticipated to provide an optional design concept toward the carbon anode for fast-charging PIHCs.

关键词： carbon anode oxygen epigallocatechin gallate potassium-ion hybrid capacitor

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虎门服装品牌的发展路径、原因与未来趋势

东莞理工学院学报 2007年第6期14卷 1-8页

作者：邓宇鹏李淦球王宝敏东莞理工学院工商管理系广东东莞523808 东莞市经济贸易局广东东莞523002 虎门服装协会广东东莞523900

虎门服装品牌经过了萌芽、培育、升级三个阶段。虎门服装品牌快速成长的原因在于天时、地利、人和与政府的努力。它将来的发展趋势可能是:批发市场品牌将进入稳定阶段,独立品牌将会有较快的发展;一部分独立品牌可能采用虚拟经营模式;独... 详细信息

虎门服装品牌经过了萌芽、培育、升级三个阶段。虎门服装品牌快速成长的原因在于天时、地利、人和与政府的努力。它将来的发展趋势可能是:批发市场品牌将进入稳定阶段,独立品牌将会有较快的发展;一部分独立品牌可能采用虚拟经营模式;独立品牌可能会由争取政府或中介组织认可逐步转向争取市场认可。相应地,虎门政府可能采取七大应变措施。

关键词：虎门服装南派服装托因模式服装产业链

Drying characteristics, functional properties and in vitro digestion of purple potato slices dried by different methods

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Journal of Integrative Agriculture 2019年第9期18卷 2162-2172页

作者： qiu gan JIANG Yong-li DENG Yun Department of Food Science and Technology Shanghai Jiao Tong University

The drying characteristics,physico-chemical and functional properties,as well as starch digestibility,of purple potato slices dried using different methods(such as,vacuum freeze-drying,VFD;hot-air drying,HAD;air-impingement jet drying,AIJD;and far-infrared assisted heat-pump drying,FIHPD)were *** rate was the highest(3.0 g 100 g^-1 min^-1)using AIJD,followed by FIHPD and HAD,and the rate of VFD was the lowest one(0.3 g 100 g^-1 min^-1).Drying data were fitted to 12 thin-layer drying models,with the Midilli model giving the best ***,AIJD showed higher diffusivity(5.5×10^-10 m^2 s^–1)and energy efficiency(55 J g^-1)than any other drying method used in this *** reference to the samples dried by VFD,the starch granules of the samples obtained by HAD,FIHPD,and AIJD exhibited different extent of disruption,which significantly increased their water absorption capacity,swelling power,and in vitro digestibility,but decreased the peak *** sample resulting from AIJD had the greatest water absorption capacity(7.9 g g^-1)and solubility(21.6%),but the smallest syneresis rate(48%).Good correlation coefficients(R^2>0.98)implied that the pseudofirst order kinetic model adequately described the rate and extent of starch digestion of dried potato *** from AIJD and FIHPD showed the highest digestibility percentages,reaching to 72.4 and 72.5%.Based on the drying rate,specific energy consumption,functional properties and digestibility,AIJD appeared to be quite effective and suitable to be transferred on the industry scale.

关键词： purple potato air-impingement jet drying(AIJD) drying characteristics flour properties starch digestibility

Inhibitory gamma-aminobutyric acidergic neurons in the anterior cingulate cortex participate in the comorbidity of pain and emotion

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Neural Regeneration Research 2025年第10期20卷 2838-2854页

作者： Lu Guan Mengting qiu Na li Zhengxiang Zhou Ru Ye liyan Zhong Yashuang Xu Junhui Ren Yi liang Xiaomei Shao Jianqiao Fang Junfan Fang Junying Du Department of Neurobiology and Acupuncture Research Third School of Clinical MedicineZhejiang Chinese Medical UniversityHangzhouZhejiang ProvinceChina Key Laboratory for Research of Acupuncture Treatment and Transformation of Emotional Diseases Third School of Clinical MedicineZhejiang Chinese Medical UniversityHangzhouZhejiang ProvinceChina Fuchun Community Health Service Center of Fuyang District HangzhouZhejiang ProvinceChina

Pain is often comorbid with emotional disorders such as anxiety and *** of the anterior cingulate cortex has been implicated in pain and pain-related negative emotions that arise from impairments in inhibitory gamma-aminobutyric acid *** review primarily aims to outline the main circuitry(including the input and output connectivity)of the anterior cingulate cortex and classification and functions of different gamma-aminobutyric acidergic neurons;it also describes the neurotransmitters/neuromodulators affecting these neurons,their intercommunication with other neurons,and their importance in mental comorbidities associated with chronic pain *** understanding on their role in pain-related mental comorbidities may facilitate the development of more effective treatments for these ***,the mechanisms that regulate gamma-aminobutyric acidergic systems remain *** is also unclear as to whether the mechanisms are presynaptic or *** exploration of the complexities of this system may reveal new pathways for research and drug development.

关键词： anterior cingulate cortex anxiety chronic pain circuit communication comorbidity depression gamma-aminobutyric acidergic neurons parvalbumin neurons synaptic transmission

Design and preliminary experimental investigation of a 4K Stirling-type pulse tube cryocooler with precooling

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2009年第9期10卷 1277-1284页

作者： Zhi-hua gan Zhuo-pei li Jie CHEN li DAI li-min qiu Institute of Refrigeration and Cryogenics Zhejiang University Hangzhou 310027 China

A Stirling-type pulse tube cryocooler （PTC） with precooling was designed and manufactured to investigate its performance at 4 K. Numerical simulation was carried out based on the well-known regenerator model REGEN with an emphasis on the performance of a 4 K stage regenerator of the Stifling-type PTC as influenced by the warm end temperature, pressure ratio, frequency and average pressure with helium-4 and helium-3 as the working fluid respectively. This study demonstrates that the use of a cold inertance tube can significantly improve the efficiency of a 4 K Stirling-type PTC. A preliminary experimental investigation was carried out with helium-4 as the working fluid and a refrigeration temperature of 4.23 K was achieved. The experimental results show that the operating frequency has a significant influence on the performance of the Stirling-type PTC and a relatively low average pressure is favorable for decreasing the loss associated with the real gas effects of a 4 K Stirling-type PTC.

关键词： Stirling-type pulse tube cryocooler (PTC) Regenerator Helium-3 Cold inertance tube 4 K

liquid film dryout model for predicting critical heat flux in annular two-phase flow

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2009年第3期10卷 398-417页

作者： Bo JIAO li-min qiu Jun-liang LU Zhi-hua gan Institute of Refrigeration and Cryogenic Engineering Zhejiang University Hangzhou 310027 China

Gas-liquid two-phase flow and heat transfer can be encountered in numerous fields, such as chemical engineering, refrigeration, nuclear power reactor, metallurgical industry, spaceflight. Its critical heat flux (CHF) is one of the most important factors for the system security of engineering applications. Since annular flow is the most common flow pattern in gas-liquid two-phase flow, predicting CHF of annular two-phase flow is more significant. Many studies have shown that the liquid film dryout model is successful for that prediction, and determining the following parameters will exert predominant effects on the accuracy of this model: onset of annular flow, inception criterion for droplets entrainment, entrainment fraction, droplets deposition and entrainment rates. The main theoretical results achieved on the above five parameters are reviewed; also, limitations in the existing studies and problems for further research are discussed.

关键词： Annular two-phase flow Critical heat flux (CHF) liquid film dryout Deposition rate Entrainment rate