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The gold-telluride connection:Evidence for multiple fluid pulses in the Jinqingding telluride-rich gold deposit of Jiaodong Peninsula,Eastern China

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Geoscience Frontiers 2024年第3期15卷 146-165页

作者： Wenyan Cai mingchun Song m.Santosh Jian li School of Resources and Environmental Engineering Shandong University of TechnologyZibo 255049China Hebei Key Laboratory of Strategic Critical mineral Resources Hebei GEO UniversityShijiazhuang 050031China School of Earth Sciences and Resources China University of Geosciences Beijing29 Xueyuan RoadBeijing 100083China Department of Earth Science University of AdelaideAdelaide SA 5005Australia

The mechanism of gold migration,enrichment,and precipitation in forming world-class gold deposits has been a topic of wide interest,particularly where these deposits are abundant in *** Jiaodong Peninsula in eastern China hosts some of the world-class gold deposits among which the Jinqingding deposit is one of the best examples with substantial telluride mineralization and thus provides opportunity to investigate the genetic connection between tellurium and gold *** orebody in this deposit is hosted in the NE-NNE-trending Jiangjunshi-Quhezhuang fault with the Jurassic Kunyushan granitic pluton as wall *** deposit involved three mineralization stages as inferred from assemblages and crosscutting relationships between *** stages are:(I)pre-ore gold-poor quartz-pyrite veins,(II)main ore auriferous quartz-pyrite-Te/Bi-minerals±sphalerite±chalcopyrite±barite±marcasite veins,and(III)post-ore quartz-calcite *** present here the textural,isotopic,and geochemical variations of different stages/generations of pyrite based on scanning electron microscopy-energy dispersive spectroscopy(SEm-EDS),electron probe microanalysis(EPmA),and laser ablation inductively coupled plasma mass spectrometry(LA-ICP-mS).Pyrite in the Jinqingding deposit displays distinct ***1a shows a porous and dissolution-reprecipitation texture in the core,whereas Py1b exhibits a smooth and flat *** analysis reveals contrasting elemental compositions,with Py1a characterized by low Au(avg.0.14 ppm),As(avg.15.57 ppm),Ag(avg.17.71 ppm),and Te(avg.19.22 ppm)contents,but elevated Co(avg.1068.10 ppm)and Ni(224.12 ppm)concentrations,and variable sulfur isotopic composition(δ^(34)SV-CDT=9.54‰-12.12‰).Conversely,Py1b displays increased concentrations of these elements and a more concentratedδ^(34)SV-CDT value(11.99‰-12.23‰),possibly associated with weak coupled dissolution-reprecipitation(CDR)*** Stage II,pyrite can be further categorized

关键词： Episodic fluid pulses Sulfur reservoir Gold-Te precipitation Jinqingding deposit Jiaodong Peninsula

FRACTURE RESISTANCE OF 3D-C/SiC COmPOSITES AT 1300℃

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Acta metallurgica Sinica(English Letters) 2004年第4期17卷 437-442页

作者： G.C.Ji S.R.Qiao S.m.Du m.li D.Han J.N.Wei College of materials Science and Engineering Northwestern Polytechnical University Xi'an 710072China Material Engineering Department Jiujiang College Jiujiang 332005 ChinaCollege of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072ChinaMaterial Engineering Department Xi'an Science and Technical University Xi'an 710060 ChinaCollege of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072ChinaCollege of Materials Science and Engineering Northwestern Polytechnical University Xi'an 710072ChinaMaterial Engineering Department Jiujiang College Jiujiang 332005 China

Based on the energy conservation, the elastic energy linked to the compliance change, non-elastic energy dissipated by irreversible deformation and the resistance for crack propagation were quantitatively characterized by evaluation the load/load point displacement curves tested by three points bend experiment with single notch beam at 1300℃. The cracks length was determined by compliance calibration curves. It is shown by experimental results that the compliance of 3D-C/SiC composites changes with the cracks can be described by third order polynomial. The variation of crack advancing resistance with non-dimensional equivalent crack length presents a convex curve. The crack advancing resistance increases firstly and then decreases with the non-dimensional equivalent crack length, finally is in comparatively low level. The maximum values of crack advancing resistance are 269.73kJ/m2 for non-dimensional equivalent crack length of 0.318 and original notch length of 0.35mm, and 138.65kJ/m2 for non-dimensional equivalent crack length of 0.381 and original notch length of 2.06mm, respectively.

关键词： fracture resistance 3D-C/SiC energy conservation

Sol-gel derived HA/TiO_2 double coatings on Ti scaffolds for orthopaedic applications

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中国有色金属学会会刊：英文版 2006年第B1期16卷 209-216页

作者： XU W HU W Y li m H mA Q Q P. D. HODGSON WEN C E Department of Applied Physics Hunan University Changsha 410082 China Centre for material and Fibre Innovation Deakin University Geelong Vic 3217 Australia

Hydroxyapatite/titania (HA/TiO2) double layers were coated onto Ti scaffolds throughout for orthopaedic applications by sol-gel method. Differential scanning calorimetry (DSC), thermogravimetric analysis (TG) and X-ray diffractometry (XRD) were used for the characterisation of the phase transformations of the dried gels and coated surface structures. Scanning electron microscope (SEm) equipped with energy dispersive spectrometry (EDS) was used for the observation and evaluation of the morphology and phases of the surface layers and for the assessment of the in vitro tests. The in vitro assessments were performed by soaking the HA/TiO2 double coated samples into the simulated body fluid (SBF) for various periods. The TiO2 dipping-coating method at a speed of 12 cm/min, followed by a heat treatment at 600 ℃ for 20 min. The HA la lyaeyre wr wasa ssu cbosaetqeude bnytl ya dipping-coated on the outer surface at the same speed and then heat-treated at difference temperatures. The results indicat that the HA phase begins to crystallize after a heat treatment at 560 ℃. The crystallinity increases obviously at 760 ℃. SEm observations find no delamination or crack at the interfaces of HA/TiO2 and TiO2/Ti. The HA/TiO2 coated Ti scaffolds displays excellent bone-like apatite forming ability when it is soaked into SBF. Ti scaffolds after HA/TiO2 double coatings can be anticipated as promising implant materials for orthopaedic

关键词：钛支架溶胶-凝胶法羟基磷灰石/二氧化钛涂层医学整形外科应用

Self‑Healing Dynamic Hydrogel microparticles with Structural Color for Wound management

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Nano-micro Letters 2024年第11期16卷 177-190页

作者： li Wang Xiaoya Ding Lu Fan Anne m.Filppula Qinyu li Hongbo Zhang Yuanjin Zhao Luoran Shang Department of General Surgery Ruijin HospitalShanghai Jiaotong University School of MedicineShanghai 200025People’s Republic of China Department of Rheumatology and Immunology Nanjing Drum Tower HospitalSchool of Biological Science and Medical EngineeringSoutheast UniversityNanjing 210096People’s Republic of China Pharmaceutical Sciences Laboratory Åbo Akademi University20520 TurkuFinland Oujiang Laboratory(Zhejiang Lab for Regenerative medicine Vision and Brain Health)Wenzhou InstituteUniversity of Chinese Academy of SciencesWenzhou 325001People’s Republic of China Shanghai Xuhui Central Hospital Zhongshan‑Xuhui Hospitaland the Shanghai Key Laboratory of Medical Epigeneticsthe International Co‑laboratory of Medical Epigenetics and Metabolism(Ministry of Science and Technology)Institutes of Biomedical SciencesFudan UniversityShanghai 200032People’s Republic of China

Chronic diabetic wounds confront a significant medical challenge because of increasing prevalence and difficult-healing *** is vital to develop multifunctional hydrogel dressings,with well-designed morphology and structure to enhance flexibility and effectiveness in wound *** achieve these,we propose a self-healing hydrogel dressing based on structural color microspheres for wound *** microsphere comprised a photothermal-responsive inverse opal framework,which was constructed by hyaluronic acid methacryloyl,silk fibroin methacryloyl and black phosphorus quantum dots(BPQDs),and was further re-filled with a dynamic *** dynamic hydrogel filler was formed by Knoevenagel condensation reaction between cyanoacetate and benzaldehyde-functionalized dextran(DEX-CA and DEX-BA).Notably,the composite microspheres can be applied arbitrarily,and they can adhere together upon near-infrared irradiation by leveraging the BPQDs-mediated photothermal effect and the thermoreversible stiffness change of dynamic ***,eumenitin and vascular endothelial growth factor were co-loaded in the microspheres and their release behavior can be regulated by the same ***,effective monitoring of the drug release process can be achieved through visual color *** microsphere system has demonstrated desired capabilities of controllable drug release and efficient wound *** characteristics suggest broad prospects for the proposed composite microspheres in clinical applications.

关键词： Black phosphorus Structural color Dynamic hydrogel Inverse opal Wound management

Impact of ozonation on disinfection byproducts formation from phenylalanine during chlorination

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Journal of Environmental Sciences 2024年第10期144卷 199-211页

作者： Sinong Huang Hongwei liu Kunming Wei liang Zhang Xiaoyan ma Qingsong li Xueyan li Andrea m.Dietrich College of Civil Engineering Zhejiang Key Laboratory of Civil Engineering Structures&Disaster Prevention and Mitigation TechnologyZhejiang University of TechnologyHangzhou 310023China Water Resources and Environmental Institute Xiamen University of TechnologyXiamen 361005China School of Environmental Science and Engineering Suzhou University of Science and TechnologySuzhou 215009China Civil and Environmental Engineering Virginia Polytechnic Institute and State UniversityBlackburgVA 24061USA

As a strong oxidizing agent,ozone is used in some water treatment facilities for disinfection,taste and odor control,and removal of organic ***(Phe)was used as the target amino acid to comprehensively investigate variability of disinfection byproducts(DBPs)formation during chlorine disinfection and residual chlorine conditions subsequent to *** results showed that subsequent to ozonation,the typical regulated and unregulated DBPs formation potential(DBPsFP),including trichloromethane(TCm),dichloroacetonitrile(DCAN),chloral hydrate(CH),dichloroacetic acid(DCAA),trichloroacetic acid(TCAA),and trichloroacetamide(TCAcAm)increased substantially,by 2.4,3.3,5.6,1.2,2.5,and 6.0 times,respectively,compared with only *** also significantly increased the DBPs yield under a 2 day simulated residual chlorine condition that mimicked the water distribution *** formations followed pseudo first order *** formation rates of DBPs in the first 6 hr were higher for TCm(0.214 hr^(−1)),DCAN(0.244 hr^(−1)),CH(0.105 hr^(−1)),TCAcAm(0.234 hr^(−1)),DCAA(0.375 hr^(−1))and TCAA(0.190 hr^(−1))than *** peak DBPsFP of TCm,DCAN,CH,TCAcAm,DCAA,and TCAA were obtained when that ozonation time was set at 5–15 *** times>30 min increased the mineralization of Phe and decreased the formation of DBPs upon *** bromine ion(Br^(−1))concentration increased production of bromine-DBPs and decreased chlorine-DBPs formation by 59.3%–92.2%.Higher ozone dosages and slight alkaline favored to reduce DBP formation and *** ozonation conditions should be optimized for all application purposes including DBPs reduction.

关键词： Ozone Amino acids Chlorination Disinfection by-products

Fatigue Crack Propagation in Steel A131 Under Ice Loading of Crushing,Bending and Buckling

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China Ocean Engineering 2001年第3期16卷 315-328页

作者：段梦兰樊晓东宋立崧方华灿 James C. m. li R. & D. Center China Classification Society Shanghai Offshore Petroleum Bureau China National Offshore Oil Co. University of Petroleum University of Rochester Rochester

Three types of ice loading, which are most commonly present when ice acts on structures, are chosen and simulated for use of fatigue crack propagation tests on offshore structural steel A131. The three types of ice categorized in accordance with the failure modes when acting on structures called Crushing ice, bending ice, and buckling ice, respectively. This paper presents an experimental investigation on the fatigue crack propagation behavior of widely used high strength steel A131 for offshore jackets in the loading environment of ice crushing, bending, and buckling. The test results of fatigue crack propagation in steel A131 tinder these simulated ice loading at temperature 292K are presented and analyzed in detail in this paper, The amplitude root mean square stress intensity factor is optimized to be the fundamental parameter of fatigue crack propagation for all types of ice loading histories. The results are also compared with constant amplitude fatigue crack propagation conclusions as in wave load mode, and a joint investigation on the results from ice forces, ice-induced vibrations, and ice-induced fatigue crack propagation is conducted. Conclusions are drawn for reference in structural design and material selection for offshore structures in ice environments.

关键词： fatigue crack crack growth rate stress intensity factor ice loading temperature steel A131 test

Synthesis of novel biscalixarene-tube containing two kinds of calix[4]arene derivative units

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Chinese Chemical Letters 2008年第1期19卷 9-11页

作者： Fa Fu Yang li m ing liu Chao Hui liu Xi-ao Hua Zheng Yu Guo College of Chemistry and materials Fujian Normal University Fuzhou 350007 China

A novel biscalixarene with two kinds of calix[4]arene derivative units connected by four bridging chains, was facilely＇ synthesized by ＂1 ＋ 1＂ condensation mode in high yield. The element analyses, ESI-mS, ^1H NmR and ^1H-^1H COSY spectrum showed that the calix[4]arene units of compound 4 were in cone conformations and compound 4 possessed biscalixarene-tube structure. 2007 Fa Fu Yang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

关键词： Biscalixarene Tube Synthesis ^1H-^1H COSY

SYNTHESIS AND SOliD STATE SINTERING OF W-Ni-Fe NANO-COmPOSITE POWDERS

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Acta metallurgica Sinica(English Letters) 2000年第3期13卷 917-920页

作者： Qu, X.H. Fan, J.L. li, Y.m. Huang, B.Y. Central South Univ of Technology Changsha China

The mixture of 90 wt%W, 7 wt%Ni and 3 wt%Fe elemental powders was milled in a planetary high-energy ball mill. The evolution of the structure during milling and the sintering behavior of the milled powders were tested. The results showed that by mechanical alloying W(Ni, Fe) supersaturated solid solution with nano-meter size formed, which can enhance the sintering process. Fully dense alloy from the milled powders was obtained through solid state sintering. The tensile strength of the obtained alloy is over 900 mPa which is comparable to that of the alloy sintered by traditional liquid-phase sintering from un-milled powders of the same composition.

关键词： Tungsten alloys Nickel alloys Iron alloys mechanical alloying Powder metals Sintering morphology Tensile strength

Degradation of superhydrophobic aluminium overhead line conductor surfaces

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High Voltage 2024年第4期9卷 763-772页

作者： Xu Zhang Chorphaka Plaengpraphan Chengxing lian Wenyuan li Qinghua Han Simon m.Rowland Ian Cotton Qi li School of Engineering University of WarwickCoventryUK State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong UniversityXi'anChina School of Engineering University of ManchesterManchesterUK School of Engineering Imperial College LondonLondonUK Electrical Engineering School Chongqing UniversityChongqingChina

It has been shown that noise emissions from HV overhead line conductors can be reduced under rain conditions by making their surfaces *** working environment makes ensuring the longevity of any treatment a major *** degradation of various superhydrophobic surfaces generated by applying a superhydrophobic coating and patterning microscale channels is assessed under an AC electric field(18 kV/cm)with continuous water *** examining the droplet distribution on the surfaces during the degradation and the surface roughness before and after degra-dation,the authors demonstrate that no water droplets were found on the microscale patterned surface,but droplets were formed on the coated surface after *** surface roughness reduction of the coated surface and microscale patterned surface was 29.8% and 11.3%,respectively,indicating that the microscale patterned surface has better durability than the superhydrophobic coating under the AC electric stress.

关键词： coating roughness surface