检索结果-南通市图书馆

SEI/dead li-turning capacity loss for high-performance anode-free solid-state lithium batteries

Journal of Energy Chemistry 2024年第9期96卷 145-152页

作者： Qianwen Yin Tianyu li Hongzhang Zhang Guiming zhong Xiaofei Yang Xianfeng li Division of Energy Storage Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of Sciences Beijing 100049China Key Laboratory of Long-Duration and Large-Scale Energy Storage Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Laboratory of Advanced Spectro-Electrochemistry and lithium-Ion Batteries Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina

Anode-free solid-state lithium metal batteries(AF-SSLBs)have the potential to deliver higher energy density and improved safety beyond lithium-metal ***,the unclear mechanism for the fast capacity decay in AF-SSLBs,either determined by dead li or solid electrolyte interface(SEI),limits the proposal of effective strategies to prolong cycling *** clarify the underlying mechanism,herein,the evolution of SEI and dead li is quantitatively analyzed by a solid-state nuclear magnetic resonance(ss-NMR)technology in a typical liPF6-based polymer *** results show that the initial capacity loss is attributed to the formation of SEI,while the dead li dominates the following capacity loss and the growth rate is 0.141 mA h cm^(−2)cycle−*** reduce the active li loss,the combination of inorganic-rich SEI and self-healing electrostatic shield effect is proposed to improve the reversibility of li deposition/dissolution behavior,which reduces the capacity loss rate for the initial SEI and following dead li generation by 2.3 and 20.1 folds,*** a result,the initial Coulombic efficiency(ICE)and stable CE increase by 15.1%and 15.3%in li-Cu cells,which guides the rational design of high-performance AF-SSLBs.

关键词： Solid-state lithium batteries Solid-state NMR Anode-free SEI Dead li

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Unconventional Fluorescent and Multi-responsive Polysiloxane:Synthesis,Characterization and Biological Applications

引用

Chinese Journal of Polymer Science 2024年第5期42卷 579-590,I0006页

作者： Xiao-Di li Shu-sheng li Xu-Bao Jiang Xiao-li Zhu Xiang Zheng Kong College of Chemistry and Chemical Engineering University of JinanJinan250022China College of Chemical Engineering Tianjin UniversityTianjin300072China Foshan(Southern China)Institute for New Materials Foshan528200China

Owing to their high significance in fundamental study and diverse applications,stimuli-responsive and fluorescent polymers,particularly those with cluster-triggered emission(CTE)featured by non-conjugated chromophores,have drawn tremendous attention in recent *** this work,fluorescent and multi-responsive polysiloxane(FRPS)was synthesized by hydrolytic condensation polymerization of 3-aminopropyl methyl diethoxysilane(APMS)with 3-(N-isopropyl propionamide)iminopropyl methyl diethoxysilane(APMS-NIP),which was formed in situ through aza-Michael addition between APMS and N-isopropyl *** was not only highly sensitive to temperature,pH and CO_(2) in water,but also showed an enhanced and stimuli-adjustable fluorescence *** effects of monomer feeding,pH and CO_(2) on its lower critical solution temperature and fluorescent property were *** fluorescence emission was ascribed to CTE *** addition,FRPS was shown to be highly potential as physiological indicator for cell imaging,and for controlled release and trace detection of *** study provides therefore a type of stimuli-responsive and fluorescent material for potential applications in biomedical fields,and it is also of great significance for understanding of the fluorescence mechanism of polysiloxane-based stimuli-responsive polymers.

关键词： Polysiloxane Multi-responsiveness Cluster-triggered emission Cell imaging Controlled drug release

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Metal-metal bonds in Zintl clusters:Synthesis,structure and bonding in[Fe_(2)Sn_(4)Bi_(8)]^(3-)and[Cr_(2)Sb_(12)]^(3-)

引用

Chinese Chemical Letters 2024年第8期35卷 558-566页

作者： Ya-Nan Yang Zi-sheng li Sourav Mondal Lei Qiao Cui-Cui Wang Wen-Juan Tian zhong-Ming Sun John E.McGrady State Key Laboratory of Element-Organic Chemistry Tianjin Key Lab for Rare Earth Materials and ApplicationsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Department of Chemistry University of OxfordInorganic Chemistry LaboratoryOxfordOX13QRUnited Kingdom

We report here the synthesis and characterization of two new members of the M2 E 12 family of endohe-dral Zintl clusters,[Fe_(2)Sn_(4)Bi_(8)]^(3-)and[Cr_(2)Sb_(12)]^(3-),both of which contain open-shell metal dimers encap-sulated inside a triple-decker cluster of main-group *** 75-electron[Fe_(2)Sn_(4)Bi_(8)]^(3-)cluster has a D4h-symmetric structure,while[Cr_(2)Sb_(12)]^(3-),despite having the same 75-electron count,is strongly dis-torted to a geometry that resembles a CrSb_(8)crown capped by a CrSb_(4)*** structural differences between the two are driven by the increasing availability of 3d electron density in the earlier transi-tion metal,which leads,ultimately,to different electronic configurations in the two *** trends precisely mirror those observed in the ME_(10)and ME_(12)families containing a single transition metal ion.

关键词： Zintl anions Endohedral clusters Metal-metal bond Second-order Jahn-Teller effect DFT calculation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

拘束模回转试验的CFD最优设置提取与多子样验证

引用

船舶力学 2022年第4期26卷 511-519页

作者：梁川赵峰李胜忠中国船舶科学研究中心江苏无锡214082

船舶水动力学领域中,数值水池虚拟试验结果的可信度是制约其应用与发展的关键因素之一。在传统不确定度分析方法的基础上,一种以“大子样验证”为特征的多重验证方法尝试为CFD模拟置信度研究提供一种新的思路,其初步实践中针对船模阻力... 详细信息

船舶水动力学领域中,数值水池虚拟试验结果的可信度是制约其应用与发展的关键因素之一。在传统不确定度分析方法的基础上,一种以“大子样验证”为特征的多重验证方法尝试为CFD模拟置信度研究提供一种新的思路,其初步实践中针对船模阻力这类流动相对简单的问题进行了多达332个样本点的验证分析。本文针对操纵性拘束模试验中开展的相对较少的旋臂回转试验,以8条CSSRC系列集装箱船的物理试验数据为基础展开相关验证研究,获得了较为满意的结果,进一步证实了“大子样验证”思路在流动复杂、子样较少情况下的有效性。

关键词：多子样验证 CFD置信度最优设定回转试验

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

分析模式在嵌入式系统建模中的应用研究

引用

系统仿真学报 2007年第14期19卷 3346-3349,3364页

作者：段盛彭蔓蔓李仁发李仲生湘南学院计算机系湖南大学计算机与通信学院长沙410012 湖南大学计算机与通信学院

面向对象建模语言UML(Unified Modeling Language)已广泛用于嵌入式系统建模,但它在嵌入式实时系统建模时存在模型重用性不高、概念模型形式化复杂和状态图对时间约束方面的建模功能不强的问题,针对这些问题,提出了对象分析模式与实时... 详细信息

面向对象建模语言UML(Unified Modeling Language)已广泛用于嵌入式系统建模,但它在嵌入式实时系统建模时存在模型重用性不高、概念模型形式化复杂和状态图对时间约束方面的建模功能不强的问题,针对这些问题,提出了对象分析模式与实时规范模式相结合的新思想,并给出了使用对象分析模式和实时描述模式进行嵌入式系统建模及模型分析、验证的方法,然后介绍了基于UML的模式驱动的嵌入式系统建模及分析的实现步骤,最后以一个实际应用进行了详细说明。

关键词：模式嵌入式系统建模 UML 实时系统模型验证

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Thermal fatigue and wear of compacted graphite iron brake discs with various thermomechanical properties

引用

China Foundry 2024年第3期21卷 248-256页

作者： Gui-quan Wang Zhuo Xu zhong-li liu Xiang Chen Yan-xiang li School of Nuclear Equipment and Nuclear Engineering Yantai UniversityYantai 264005ShandongChina School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationBeijing 100084China

The increase in payload capacity of trucks has heightened the demand for cost-effective yet high performance brake *** this work,the thermal fatigue and wear of compacted graphite iron brake discs were investigated,aiming to provide an experimental foundation for achieving a balance between their thermal and mechanical *** graphite iron brake discs with different tensile strengths,macrohardnesses,specific heat capacities and thermal diffusion coefficients were produced by changing the proportion and strength of *** peak temperature,pressure load and friction coefficient of compacted graphite iron brake discs were analyzed through inertia friction *** morphology of thermal cracks and 3D profiles of the worn surfaces were also *** is found that the thermal fatigue of compacted graphite iron discs is determined by their thermal properties.A compacted graphite iron with the highest specific heat capacity and thermal diffusion coefficient exhibits optimal thermal fatigue *** of the matrix at low temperatures significantly weakens the function of alloy strengthening in hindering the propagation of thermal *** the reduced hardness,increasing the ferrite proportion can mitigate wear loss resulting from low disc temperatures and the absence of abrasive wear.

关键词： compacted graphite iron brake disc thermomechanical properties thermal fatigue wear

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

New formula for predicting the plastic buckling pressure of steel torispherical heads under internal pressure

引用

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第8期25卷 618-630页

作者： sheng YE Keming li Jinyang ZHENG Shan SUN Institute of Process Equipment Zhejiang UniversityHangzhou 310027China Engineering Research Center for High Pressure Process Equipment and Safety of Ministry of Education Hangzhou 310027China State Key Laboratory of Fluid Power and Mechatronic Systems Hangzhou 310058China

Thin-walled torispherical heads under internal pressure can fail by plastic buckling because of compressive circumferential stresses in the head ***,existing formulas still have limitations,such as complicated expressions and low accuracy,in determining buckling *** this paper,we propose a new formula for calculating the buckling pressure of torispherical heads based on elastic-plastic analysis and experimental ***,a finite element(FE)method based on the arc-length method is established to calculate the plastic buckling pressure of torispherical heads,considering the effects of material strain hardening and geometrical *** buckling pressure results calculated by the FE method in this paper have good consistency with those of BOSOR5,which is a program for calculating the elastic-plastic bifurcation buckling pressure based on the finite difference energy ***,the effects of geometric parameters,material parameters,and restraint form of head edge on buckling pressure are ***,a new formula for calculating plastic buckling pressure is developed by fitting the curve of FE results and introducing a reduction factor determined from experimental ***,based on the experimental results,we compare the predictions of the new formula with those of existing *** is shown that the new formula has a higher accuracy than the existing ones.

关键词： Torispherical head Plastic buckling Elastic-plastic analysis Prediction formula Finite element method

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Snowpack variations and their hazardous effects under climate warming in the central Tianshan Mountains

引用

Advances in Climate Change Research 2024年第3期15卷 442-451页

作者： Jian-sheng HAO Yan WANG Lan-Hai li Key Laboratory of Land Surface Pattern and Simulation Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of Sciences(CAS)Beijing 100101China Xinjiang Key Laboratory of Water Cycle and Utilization in Arid Zone Urumqi 830011China State Key Laboratory of Desert and Oasis Ecology Xinjiang Institute of Ecology and GeographyChinese Academy of SciencesUrumqi 830011China Tianshan Snowcover and Avalanche Observation and Research Station of Xinjiang Xinyuan 835800China CAS Research Center for Ecology and Environment of Central Asia Urumqi 830011China

Climate change alters snowpack evolution,which in turn influences the likelihood of snow avalanches and flood *** lack of systemic observational data on key snow characteristics in high mountains remains a scientific challenge in terms of systematically elucidating the dynamic chain of variations in climate-snowpack-snow *** restricts our understanding and poses challenges in the prediction of snow-related disaster *** such,this study analysed the variations of temperature and snowfall and the physical characteristics of snowpacks based on ground-based observations from the Kunse River Valley situated in the Tianshan Mountains from 1967 to *** results reveal that the temperature increased significantly by 0.32°C per decade(plier ***,average and maximum snow depths increased along with an increase in peak snow water equivalent,thus indicating a higher frequency of extremely scarce or abundant snow *** low snowpack temperature gradient and earlier snowmelt dates in spring lead to earlier occurrences of snowmelt floods and wet *** the risks of these events increase,they pose greater threats to farmlands,road transportation,water-electricity infrastructure and several other human ***,these insights are critical for providing vital information that can deepen our understanding of the impact of climate change on snowpack characteristics and improve management strategies for snow-related disaster prevention and mitigation.

关键词： Climate change Snowpack variations Snow-related disaster Tianshan Mountains

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Uncertainty and disturbance estimator-based model predictive control for wet flue gas desulphurization system

引用

Chinese Journal of Chemical Engineering 2024年第3期67卷 182-194页

作者： Shan liu Wenqi zhong li Sun Xi Chen Rafal Madonski School of Energy and Environment Key Laboratory of Energy Thermal Conversion and Control of Ministry of EducationSoutheast UniversityNanjing 210096China Faculty of Automatic Control Electronics and Computer ScienceSilesian University of TechnologyGliwise 44-100Poland

Wet flue gas desulphurization technology is widely used in the industrial process for its capability of efficient pollution *** desulphurization control system,however,is subjected to complex reaction mechanisms and severe disturbances,which make for it difficult to achieve certain practically relevant control goals including emission and economic performances as well as system *** address these challenges,a new robust control scheme based on uncertainty and disturbance estimator(UDE)and model predictive control(MPC)is proposed in this *** UDE is used to estimate and dynamically compensate acting disturbances,whereas MPC is deployed for optimal feedback regulation of the resultant *** viewing the system nonlinearities and unknown dynamics as disturbances,the proposed control framework allows to locally treat the considered nonlinear plant as a linear *** obtained simulation results confirm that the utilization of UDE makes the tracking error negligibly small,even in the presence of unmodeled *** the conducted comparison study,the introduced control scheme outperforms both the standard MPC and PID(proportional-integral-derivative)control strategies in terms of transient performance and ***,the results reveal that a lowpass-filter time constant has a significant effect on the robustness and the convergence range of the tracking error.

关键词： Desulphurization system Disturbance rejection Model predictive control Uncertainty and disturbance estimator Nonlinear system

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Robust-augmentation nonlinear dynamic inversion control of over-actuated coaxial high-speed helicopter in transition mode

引用

Chinese Journal of Aeronautics 2024年第8期37卷 404-420页

作者： Yuqing QIU Yan li Jinxi LANG Yuxian liU zhong WANG School of Automation Northwestern Polytechnical UniversityXi’an 710129China

As the elevator and rudder can be used actively for control,in addition to the rotors,Coaxial High-speed Helicopters(CHHs)have the problems of control redundancy and changing control authority in the transition *** paper presents a robust-augmentation transitioning flight control design for a CHH under the adverse conditions of parametric uncertainties and external ***,based on control characteristic analysis,an Adaptive Filtered Nonlinear Dynamic Inversion(AFNDI)controller is proposed for the angular rate to handle the effect of unknown unstructured uncertainties and external *** analysis proves that the presented angular rate controller can guarantee steady-state and transient ***,the attitude angle and velocity controllers are also ***,an Incremental-based Nonlinear Prioritizing Control Allocation(INPCA)method is designed to take into account control surface transition and changing control authority,which efficiently distributes the required moments between coaxial rotors and aero-surfaces,and avoids the control reversal problem of the yaw *** the proposed control architecture,the low-pass filter is introduced to alleviate the adverse influence of time delay and measurement ***,the effectiveness of the proposed controller is demonstrated through nonlinear numerical simulations,and is compared with existing *** results show that the proposed control law can improve both capabilities of disturbance rejection and fast response,and works satisfactorily for the CHH transitioning control characteristic.

关键词： Coaxial high-speed helicopter Transition mode Attitude control Control allocation Robust adaptive control

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：