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Volume-averaged modeling of multiphase solidification with equiaxed crystal sedimentation in a steel ingot

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China Foundry 2024年第3期21卷 229-238页

作者： Xiao-lei Zhu shuang Cao Rui Guan Ji Yang Zhe Ning Xin-gang Ai Sheng-li li Xin-cheng Miao The key Laboratory of Material Forming and Structure Property Control Anshan 114051LiaoningChina State Key Laboratory of Metal Material for Marine Equipment and Application Anshan 114009LiaoningChina School of Materials and Metallurgy University of Science and Technology LiaoningAnshan 114051LiaoningChina

Macrosegregation is a critical factor that limits the mechanical properties of *** impact of equiaxed crystal sedimentation on macrosegregation has been extensively studied,as it plays a significant role in determining the distribution of alloying elements and impurities within a *** improve macrosegregation in steel connecting shafts,a multiphase solidification model that couples melt flow,heat transfer,microstructure evolution,and solute transport was established based on the volume-averaged Eulerian-Eulerian *** this model,the effects of liquid phase,equiaxed crystals,columnar dendrites,and columnar-to-equiaxed transition(CET)during solidification and evolution of microstructure can be considered *** sedimentation of equiaxed crystals contributes to negative macrosegregation,where regions between columnar dendrites and equiaxed crystals undergo significant A-type positive macrosegregation due to the ***,noticeable positive macrosegregation occurs in the area of final solidification in the *** improvement in macrosegregation is beneficial for enhancing the mechanical properties of connecting *** mitigate the thermal convection of molten steel resulting from excessive superheating,reducing the superheating during casting without employing external fields or altering the design of the ingot mold is indeed an effective approach to control macrosegregation.

关键词： ingot casting multiphase solidification model equiaxed crystal sedimentation microstructure macrosegregation

Electronic structure engineering of single atomic sites by plasmoninduced hot electrons for highly efficient and selective photocatalysis

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Nano Research 2024年第8期17卷 6960-6967页

作者： Xiaoya Huang Xinyuan li Akang Chen Hongfei Gu Shouyuan li Tailei Hou Shuwen Zhu shuang Yu Yin Song Jiatao Zhang Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications MIIT Key Laboratory of Medical Molecule Science and Pharmaceutical EngineeringMOE Key Laboratory of Cluster ScienceSchool of Chemistry and Chemical EngineeringSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China MIIT Key Laboratory of Complex-field Intelligent Exploration School of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China

Single atom(SA)catalysts have achieved great success on highly selective heterogeneous catalysis due to their abundant and homogeneous active *** electronic structures of these active sites,restrained by their localized coordination environments,significantly determine their catalytic performances,which are difficult to ***,we investigated the effect of localized surface plasmon resonance(LSPR)on engineering the electronic structures of single atomic ***,core–shell structures consisted of Au core and transition metal SAs loaded N-doped carbon(CN)shell were constructed,namely Au@M-SA/CN(M=Ni,Fe,and Co).It was demonstrated that plasmon-induced hot electrons originated from Au were directionally injected to the M-SAs under visible light irradiation,which significantly changed their electronic structures and meanwhile facilitated improved overall charge separation *** as-prepared Au@Ni-SA/CN exhibited highly efficient and selective photocatalytic CO_(2) reduction to CO performance,which is 20.8,17.5,and 6.9 times those of Au nanoparticles,Au@CN,and Ni-SA/CN,*** spectroscopy analysis and theoretical calculations confirmed that the plasmon enhanced Ni-SA/CN sites featured increased charge density for efficient intermediate activation,contributing to the superb photocatalytic *** work provides a new insight on plasmon and atomic site engineering for efficient and selective catalysis.

关键词： single atom catalysts plasmon enhancement coupling effect photocatalysis CO_(2) reduction

lithium-induced graphene layer containing li_(3)P alloy phase to achieve ultra-stable electrode interface for lithium metal anode

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Rare Metals 2024年第2期43卷 562-574页

作者： Jia-Xin Chen Guo-Qiang Zhang Xian-Ying Qin Kui lin Zi-Jin Yang Ge-Meng liang Yue Xia Guo-Bin Zhang Hai-Kun Wu Qiu-Chan Cai Hai lin Bao-Hua li Shenzhen Key Laboratory on Power Battery Safety Research and Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolShenzhen518055China Shenzhen Graphene Innovation Center Co. Ltd.Shenzhen518107China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA5005Australia Department of Chemistry City University of Hong KongHong Kong990077China

Uncontrolled growth of lithium dendrite will lead to low Coulombic efficiency and poor cycle stability,which hinders the commercialization of lithium metal ***,a novel modified lithium anode with reduced graphene oxide conductive network containing trace lithiophilic phosphorus(P-rGO/Cu)is prepared by electrospraying technique combined with heat treatment *** rGO layer has a concave and undulating conductive structure,which can significantly improve the effective electrical contact between lithium metal and the current collector,speed up the kinetics of interfacial electron transport and reaction,and improve the resistance of the negative electrode to the internal stress caused by volume change of the lithium,which is advantageous for the stability of the SEI *** extremely small and uniformly distributed red phosphorus element avoids the volume change caused by lithiation to the maximum *** two-phase compound li_(3)P obtained by alloying P with li can directionally induce the homogeneous nucleation and dense deposition of lithium metal,address the issue of lithium dendrites and extend the cycle life of the *** obtained P-rGO/Cu exhibits excellent electrochemical performance with an average Coulombic efficiency(CE)of 98%at a current density of 1 mA·cm^(−2) for 400 cycles,and the capacity retention rate of the full cell matched with lithium iron phosphate(LFP)is 83%after 400 cycles at 1C.

关键词： lithium anode Dendrite-free lithiophilicity Induced nucleation deposition

Boosting Hydrogen Storage Performance of MgH_(2) by Oxygen Vacancy-Rich H-V_(2)O_(5) Nanosheet as an Excited H-Pump

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Nano-Micro Letters 2024年第8期16卷 398-416页

作者： li Ren Yinghui li Zi li Xi lin Chong Lu Wenjiang Ding Jianxin Zou National Engineering Research Center of light Alloys Net Forming&State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Shanghai Engineering Research Center of Mg Materials and Applications&School of Materials Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Center of Hydrogen Science Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Instrumental Analysis Center of SJTU Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

MgH_(2) is a promising high-capacity solid-state hydrogen storage material,while its application is greatly hindered by the high desorption temperature and sluggish ***,intertwined 2D oxygen vacancy-rich V_(2)O_(5) nanosheets(H-V_(2)O_(5))are specifically designed and used as catalysts to improve the hydrogen storage properties of MgH_(2).The as-prepared MgH_(2)-H-V_(2)O_(5) composites exhibit low desorption temperatures(Tonset=185℃)with a hydrogen capacity of 6.54 wt%,fast kinetics(Ea=84.55±1.37 kJ mol^(-1) H_(2) for desorption),and long cycling ***,hydrogen absorption can be achieved at a temperature as low as 30℃ with a capacity of 2.38 wt%within 60 ***,the composites maintain a capacity retention rate of~99%after 100 cycles at 275℃.Experimental studies and theoretical calculations demonstrate that the in-situ formed VH_(2)/V catalysts,unique 2D structure of H-V_(2)O_(5) nanosheets,and abundant oxygen vacancies positively contribute to the improved hydrogen sorption ***,the existence of oxygen vacancies plays a double role,which could not only directly accelerate the hydrogen ab/de-sorption rate of MgH_(2),but also indirectly affect the activity of the catalytic phase VH_(2)/V,thereby further boosting the hydrogen storage performance of MgH_(2).This work highlights an oxygen vacancy excited“hydrogen pump”effect of VH_(2)/V on the hydrogen sorption of Mg/MgH_(2).The strategy developed here may pave a new way toward the development of oxygen vacancy-rich transition metal oxides catalyzed hydride systems.

关键词： Hydrogen storage MgH_(2) V_(2)O_(5)nanosheets Oxygen vacancies VH_(2)

Understandings of Urban Sustainability in China:a Bibliometric Analysis Using Chinese literatures

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Journal of Geodesy and Geoinformation Science 2024年第1期7卷 105-122页

作者： WU shuang YUE Yang li Xuesong Department of Urban Informatics School of Architecture and Urban PlanningShenzhen UniversityShenzhen 518060China Shenzhen Key Laboratory of Spatial Smart Sensing and Services Guangdong Key Laboratory for Urban InformaticsShenzhen UniversityShenzhen 518060China.

Cities hold a critical responsibility for achieving the Sustainable Development Goals(SDGs)due to their high population density,extensive resource consumption,and significant economic *** examine the present state of understandings regarding urban sustainability(SDG 11:Sustainable Cities and Communities)within Chinese research communities,this study collected 15950 papers from 1994 to 2022 on the 12 indicators of SDG 11,from the China National Knowledge Infrastructure(CNKI),a hub of Chinese academic papers,that directly relate to *** research topics on SDG 11 were identified for each indicator using bibliometrics analysis *** high-frequency keywords and clusters of keywords over the last three decades reveal that existing studies primarily concentrated on the physical aspects,such as transportation and environment,while there is a lack of consideration of societal *** indicates a limited and biased understanding of the urban sustainability within the Chinese academic ***,it is crucial to prioritize the societal aspects in order to develop a research agenda that further advances urban sustainability.

关键词： urban sustainability SDG 11 bibliometric Chinese research communities

Novel Soft Magnetic Co-Based Ternary Co-Er-B Bulk Metallic Glasses

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1633-1642页

作者： Jie Lu Yanhui li shuang Ma Wanping li Feng Bao Zhengwang Zhu Qiaoshi Zeng Haifeng Zhang Man Yao Wei Zhang Key Laboratory of Materials Modification By Laser Ionand Electron Beams(Ministry of Education)School of Materials Science and EngineeringDalian University of TechnologyDalian116024China School of Metallurgy Northeastern UniversityShenyang110819China Center for High Pressure Science and Technology Advanced Research(HPSTAR) PudongShanghai201203China

In this work,a series of Co-based ternary Co-Er-B bulk metallic glasses(BMGs)with excellent soft magnetic properties and high strength were developed,and the local atomic structure of a typical Co_(71.5)Er_(3.5)B_(25) metallic glass was studied through in situ high-energy synchrotron X-ray diffraction and ab initio molecular dynamics *** results reveal that the BMG samples can be obtained in a composition region of Co_(68.5-71.5)Er_(3.5-4)B_(25-27.5) by a conventional copper-mold casting *** Co-Er-B metallic glasses possess stronger atomic bond strengths and denser local atomic packing structure composed of a higher fraction of icosahedral-like clusters but fewer deformed body-centered cubic and crystal-like polyhedrons,and they exhibit slower atomic diffusion behaviors during solidification,as compared to Co-Y-B *** enhancement in structural stability and the retardation of atomic-ordered diffusion lead to the better glass-forming ability of the Co-Er-B *** smaller magnetic anisotropy energy in the Co-Er-B metallic glasses results in a lower coercivity of less than 1.3 A/*** Co-Er-B BMGs exhibit high-yield strength of 3560-3969 MPa along with distinct plasticity of around 0.50%.

关键词： Co-based bulk metallic glass Glass-forming ability Soft magnetic property Ab initio molecular dynamics simulation Local atomic structure

Superhydrophobic melamine sponge prepared by radiation-induced grafting technology for efficient oil-water separation

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Nuclear Science and Techniques 2024年第9期35卷 103-114页

作者： Ying Sun Wen-Rui Wang Dan-Yi li Si-Yi Xu lin lin Man-li Lu Kai Fan Chen-Yang Xing lin-Fan li Ji-Hao li Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China School of Architecture and Materials Chongqing College of Electronic EngineeringChongqing 401331China Center for Stretchable Electronics and NanoSensors Key Laboratory of Optoelectronic Devices and Systems of Ministry of EducationCollege of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060China

This paper presents a superhydrophobic melamine(ME)sponge(ME-g-PLMA)prepared via high-energy radiation-induced in situ covalent grafting of long-alkyl-chain dodecyl methacrylate(LMA)onto an ME sponge for efficient oil–water *** obtained ME-g-PLMA sponge had an excellent pore structure with superhydrophobic(water contact angle of 154°)and superoleophilic *** can absorb various types of oils up to 66–168 times its *** ME-g-PLMA sponge can continuously separate oil slicks in water by connecting a pump or separating oil underwater with a gravity-driven *** addition,it maintained its highly hydrophobic properties even after long-term immersion in different corrosive solutions and repeated oil *** modified ME-g-PLMA sponge exhibited excellent separation properties and potential for oil spill cleanup.

关键词： Radiation-induced graft polymerization Oil–water separation Sponge Superhydrophobic

Functional Optical Fiber Sensors Detecting Imperceptible Physical/Chemical Changes for Smart Batteries

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Nano-Micro Letters 2024年第8期16卷 268-308页

作者： Yiding li li Wang Youzhi Song Wenwei Wang Cheng lin Xiangming He Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084People’s Republic of China National Engineering Research Center of Electric Vehicles Beijing Institute of Technology(BIT)Beijing 100081People’s Republic of China Shenzhen Automotive Research Institute of BIT(Shenzhen Research Institute of National Engineering Research Center of Electric Vehicles) Shenzhen 518118People’s Republic of China

The battery technology progress has been a contradictory process in which performance improvement and hidden risks *** the battery is still a“black box”,thus requiring a deep understanding of its internal *** battery should“sense its internal physical/chemical conditions”,which puts strict requirements on embedded sensing *** paper summarizes the application of advanced optical fiber sensors in lithium-ion batteries and energy storage technologies that may be mass deployed,focuses on the insights of advanced optical fiber sensors into the processes of one-dimensional nano-micro-level battery material structural phase transition,electrolyte degradation,electrode-electrolyte interface dynamics to three-dimensional macro-safety *** paper contributes to understanding how to use optical fiber sensors to achieve“real”and“embedded”*** the inherent advantages of the advanced optical fiber sensor,it helps clarify the battery internal state and reaction mechanism,aiding in the establishment of more detailed *** advancements can promote the development of smart batteries,with significant importance lying in essentially promoting the improvement of system ***,with the help of smart batteries in the future,the importance of consistency can be weakened or even *** application of advanced optical fiber sensors helps comprehensively improve the battery quality,reliability,and life.

关键词： Smart battery Advanced embedded optical fiber sensor Battery internal physical/chemical state Quality-reliability-life characteristic

Chromosome-level genome assembly of the Asian citrus psyllid,Diaphorina citri

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Insect Science 2024年第1期31卷 13-27页

作者： shuang Lei Shi-Jiang Yu Qi Pan li-li Ding Si-Chen li Lu-Yan Cheng Shu-Qi Wang Bing-Hai Lou Jun He Cui-Yun Lei lin Cong Hao-Qiang liu Xue-Feng Wang Chun Ran Citrus Research Institute Southwest University/Chinese Academy of Agricultural SciencesNational Engineering Research Center for CitrusChongqingChina

Diaphorina citri is a global citrus *** a vector insect,it can transmit the causative agents of citrus huanglongbing,causing irreversible losses to the citrus *** acquisition of genomic information can provide a molecular genetic basis for effective control of ***,the DNBSEQ™,Oxford Nanopore Technologies,and Hi-C technologies are applied to generate a high-quality chromosome-level genome of *** genome size of *** was 523.78 Mb with a scaffold N50 of 47.05 Mb distributed on 13 chromosomes.A total of 250.64 Mb(47.85%)repeat sequences and 24048 protein-coding genes were *** resequencing of female and male individuals indicated that the sex chromosome system of *** is *** analysis demonstrated that *** and Pachypsylla venusta,which separated from their most recent common ancestor about 336.62 million years ago,were the most closely ***,we identified genes potentially involved in detoxification metabolism,pathogen transmission,and honeydew secretion for further *** high-quality genome provides an important reference for developing effective management strategies of ***.

关键词： Asian citrus psyllid chromosome-level genome comparative genomics cytochrome P450 detoxification Huanglongbing