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Performance measurement and evaluation of an ionic liquid electrospray thruster

Chinese Journal of Aeronautics 2023年第3期36卷 1-15页

作者： Chengjin HUANG jianling li Mu li School of Power and Energy Northwestern Polytechnical UniversityXi’an 710072China Shenzhen Key Laboratory of Ultraintense Laser and Advanced Material Technology Center for Advanced Material Diagnostic Technologyand College of Engineering PhysicsShenzhen Technology UniversityShenzhen 518118China

As a novel micro-propulsion system for small satellites(from micro to nano),the ionic liquid electro spray propulsion system is a promising ***,performance measurement and evaluation of the Ionic liquid Electrospray Thruster(ILET)is one of the most challenging issues for practical application,due to the difficulties in the development of a prototype and direct measurements of micro-thrust and small flow *** address this issue,a Modular Ionic liquid Electrospray Thruster(MILET)prototype is constructed,and a diagnostic system for thrust and mass flow rate is specially developed based on an analytical balance *** the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate as the propellant,a series of experiments is carried out on the MILET prototype under a wide operating condition through changing the applied voltage to control the *** different applied voltages,the thrust and the mass flow rate of the propellant are directly *** propulsive performance parameters of the thruster,such as thrust,specific impulse,thrust-to-power ratio,thruster efficiency,etc.,are comprehensively ***,a performance comparison is made between the MILET and other representative *** a relatively low applied voltage ranging from 1550 V to 2000 V,the MILET achieves a quasi-constant specific impulse of 1263 s with the averaged thrust-to-power ratio of 65.2μN/W and thruster efficiency of 40.7%.The performance of ILET is also compared with other typical electric *** results demonstrate that the ILET exhibits an excellent ability of minimalization with high specific impulse and thruster efficiency,which guarantees a great superiority in micro ***,the ways to further improve the performance of ILET are discussed,which further confirms the potential prospect of *** present result helps to advance the development and application of ILET.

关键词： Electrospray thruster Ionic liquids Performance measurement Performance estimation Micro-propulsion

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A theoretical and 1-D numerical investigation on a valve/valveless air-breathing pulse detonation engine

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Chinese Journal of Aeronautics 2021年第1期34卷 68-78页

作者： Hua QIU Cha XIONG jianling li School of Power and Energy Northwestern Polytechnical UniversityXi'an 710072China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China

The important operating characteristics of pulsed Pressure Gain Combustion(PGC)propulsion are the pressure gain of the combustor component and the propulsive performance gain of the engine.A ramjet-type valve/valveless air-breathing pulsed detonation engine with a supersonic internal compression inlet is *** on an ideal thermal cycle,the ideal equivalent pressure ratios(pcb)of the Pulsed Detonation Combustor(PDC)are obtained theoretically which are directly related with the propulsive performance of the *** introducing an orifice loss model into the cycles,the critical pressure drop ratios through the orifice for the PDC achieving pressure gain and the engine achieving thrust gain are *** influencing factors are investigated by the use of a one-dimensional(1-D)numerical simulation *** operating characteristics of the pulse detonation engine are investigated with changes of the valve type,the inlet/outlet area ratio of the PDC,the nozzle area ratio,and flight *** these factors can affect pcbof the PDC,and pcbcan be optimized by changing the geometry of the *** most important influence parameter is the valve *** using an orifice-type aerodynamic valve,simulation results show that the PDC cannot achieve the pressure gain *** a supersonic internal compression inlet is introduced to the engine,whether the Pulse Detonation Engine(PDE)can achieve thrust gain comparable with that of an ideal Brayton cycle engine not only is related to the pressure gain of the combustor,but also needs to optimize the engine structure to reduce the total pressure loss.

关键词： Detonation Pressure gain characteristics Propulsive performance Supersonic internal compression inlet Valve/valveless Thermal cycle

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Synergy effect of regulated li-plating and functional solid electrolyte interphase on graphite anodes

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Nano Research 2024年第9期17卷 8077-8085页

作者： Panpan Wang Baojia Xia jianling li State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Shanghai Institute of Microsystem and Information Technology Chinese Academy of SciencesShanghai 201800China

The growth of li dendrites poses potential safety hazard to lithium-ion batteries(liBs),and eliminating li dendrites thoroughly stills face tough difficulties ***,regulating li-plating is a critical optimization-direction to address the ***,a“graphite-li hybrid”anode with high reversibility is realized under the constant-capacity lithiation(CCL).Within CCL,the uniform distribution of li-plating on the graphite surface is successfully *** evolution in different states of solid electrolyte interphase(SEI)is investigated in detail to study the interaction between the potentials and impedance during the process of liintercalation and *** the potential below 0 V and the state of charge(SOC)of 110%relative to the theoretical capacity,the F-rich SEI with high stability is constructed to hinder the emergency of li dendrites and maintain the intact structure of graphite anode under long *** cell presents more than 100%Coulombic efficiency(CE)with the 900 cycles,demonstrating the reversible li-plating and the utilization of *** the CCL half-cell provides a good cycling performance and specific capacity of 900 cycles at 0.5 C,it is attributed to the synergy effect of stable inorganic-rich SEI and regulated active li-plating.

关键词： "graphite-li hybrid"anode li-plating reversibility solid electrolyte interphase(SEI)

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One-step electrochemical in-situ li doping and liF coating enable ultra-stable cathode for sodium ion batteries

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Journal of Energy Chemistry 2023年第7期82卷 228-238,I0005页

作者： Jiameng Feng Chaoliang Zheng De Fang jianling li State Key Laboratory of Advanced Metallurgy School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China

Despite of the higher energy density and inexpensive characteristics,commercialization of layered oxide cathodes for sodium ion batteries(SIBs)is limited due to the lack of structural stability at the high ***,the one-step electrochemical in-situ li doping and liF coating are successfully achieved to obtain an advanced Na0.79lix[li_(0.13)Ni_(0.20)Mn_(0.67)]O_(2)@liF(Nali-LNM@liF)cathode with superlattice *** results demonstrate that the li^(+)doped into the alkali metal layer by electrochemical cycling act as"pillars"in the form of li-li dimers to stabilize the layered *** supplementation of li to the superlattice structure inhibits the dissolution of transition metal ions and lattice ***,the in-situ liF coating restrains side reactions,reduces surface cracks,and greatly improves the cycling *** electrochemical in-situ modification strategy significantly enhances the electrochemical performance of the *** Nali-LNM@liF exhibits high reversible specific capacity(170.6 m A h g^(-1)at 0.05 C),outstanding capacity retention(92.65%after 200 cycles at 0.5 C)and excellent rate performance(80 mA h g^(-1)at 7 C)in a wide voltage range of 1.5-4.5 *** novel method of in-situ modification by electrochemical process will provide a guidance for the rational design of cathode materials for SIBs.

关键词： Sodium ion batteries Layered oxides In-situ li doping In-situ liF coating Superlattice structure

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Investigation of hot jet on active control of oblique detonation waves

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Chinese Journal of Aeronautics 2020年第3期33卷 861-869页

作者： Hongbin li jianling li Cha XIONG Wei FAN Lei ZHAO Wenhu HAN School of Power and Energy Northwestern Polytechnical UniversityXi’an 710072China Shaanxi Key Laboratory of Internal Aerodynamics in Aero-Engine Xi’an 710072China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China

The hot jet injection is utilized to actively control the oblique detonation wave,such as initiating and stabilizing an oblique detonation wave at a desired position that is shorter than the length of induction zone,and adjust the height of the oblique detonation wave at the exit of combustor when the oblique detonation wave engine is working on off-design flight *** fifth order Weighted Essentially Non-Oscillatory(WENO)scheme and a two-step reversible reaction mechanism of the stoichiometric H_2/Air are adopted in the *** the help of hot jet injection,the transition from inert oblique shock wave to the oblique detonation wave immediately occurs near the position of hot jet injection,and consequently the length of combustor can be *** angle of oblique detonation wave also decreases as the hot jet injection approaches the nose of ***,the height of the oblique detonation wave at the exit of combustor can be flexibly adjusted,and also depends on the injection position and the strength of the hot *** the velocity of the hot jet is too weak to directly trigger the overall oblique detonation wave at the position of injection,increasing the injection pressure will improve the strength of the hot jet and results in a successful transition.

关键词： Active control Hot jet Numerical simulation Oblique detonation wave Supersonic propulsion

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Structure and Electrochemical Performance of Hollow Tube Activated Carbon Prepared from Cotton as Electrode Material for Electric Double Layer Capacitor

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Chemical Research in Chinese Universities 2016年第1期32卷 82-89页

作者： li Xinping li jianling YAN Gang ZHU Zhixun KANG Feiyu State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Beijing 100083 P. R. China Lab of Advanced Materials Department of Materials Science and Engineering Tsinghua University Beijing 100084 P R. China

Hollow tube-like activated carbon（HTAC） was fabricated by a simple and efficient carbonization method with cotton as carbon precursor activated by KOH without any template. The activation time from 0 to 90 min showed no significant effect on the micro-morphology, but greatly influenced the specific surface area and electro- chemical performance. In the end, it was found that the sample activated for 60 min（HTAC-60） has a higher specific surface area of 2600 m2/g, a larger pore volume of 1.52 cm3/g and a greater specific capacitance of 483 F/g at a current density of 0.2 A/g in 1 mol/L H2SO4. Moreover, the sample HTAC-60 shows excellent cycle stability（only 12.2% loss after 5000 cycles） and a high energy density of 67.1 or 37.2 ***-1 at a power density of 200 or 1000 W/kg, respectively, operated in a voltage range of 0--1.0 V in 1 mol/L H2SO4. The results indicate that cotton can potentially be used as a raw material for producing low cost and high performance activated carbon electrode materials for electric double layer capacitor.

关键词： Cotton Hollow tube-like Activated carbon Electric double layer capacitor

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MOF-derived molybdenum selenide on Ti_(3)C_(2)T_(x) with superior capacitive performance for lithium-ion capacitors

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International Journal of Minerals,Metallurgy and Materials 2022年第5期29卷 1061-1072页

作者： Jianjian Zhong Lu Qin jianling li Zhe Yang Kai Yang Mingjie Zhang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Operation and Control of Renewable Energy and Storage Systems China Electric Power Research InstituteBeijing 100192China

Two-dimensional Ti_(3)C_(2)T_(x) exhibits outstanding rate property and cycle performance in lithium-ion capacitors(liCs)due to its unique layered structure,excellent electronic conductivity,and high specific surface ***,like graphene,Ti_(3)C_(2)T_(x) restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces,leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the ***,a transition metal selenide MoSe_(2) with a special three-stacked atomic layered structure,derived from metal-organic framework(MOF),is introduced into the Ti_(3)C_(2)T_(x) structure through a solvo-thermal *** synergic effects of rapid li+diffusion and pillaring effect from the MoSe_(2) and excellent conductivity from the Ti_(3)C_(2)T_(x) sheets endow the material with excellent electrochemical reaction kinetics and *** composite Ti_(3)C_(2)T_(x)@MoSe_(2) material exhibits a high capacity over 300 mAh·g^(-1) at 150 mA·g^(-1) and excellent rate property with a specific capacity of 150 mAh·g^(-1) at 1500 mA·g^(-1).Addition-ally,the material shows a superior capacitive contribution of 86.0%at 2.0 mV·s^(-1) due to the fast electrochemical reactions.A Ti_(3)C_(2)T_(x)@MoSe_(2)//AC liC device is also fabricated and exhibits stable cycle performance.

关键词： two-dimensional titanium carbide molybdenum selenide solvothermal method electrochemical kinetics

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Optimize two-phase distribution of lithium-rich materials to stabilize structure and suppress voltage attenuation

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International Journal of Minerals,Metallurgy and Materials 2022年第12期29卷 2201-2211页

作者： Yang Yu jianling li Guimei Han Zhe Yang Jianjian Zhong Feiyu Kang State Key Laboratory of Advanced Metallurgy School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China Chinese Research Academy of Environmental Sciences Beijing 100012China School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China

lithium-rich materials possess the ultra-high specific capacity,but the redox of oxygen is not completely reversible,resulting in voltage attenuation and structural instability.A stepwise co-precipitation method is used for the first time in this paper to achieve the control of the two-phase distribution through controlling the distribution of transition metal elements and realize the modification of particle surface structure without the aid of heterologous *** results of characterization tests show that the content of liMO_(2) phase inside the particles and the content of li_(2)MnO_(3) phase on the surface of the particles are successfully increased,and the surface induced formation of li_(4)Mn_(5)O_(12) spinel phase or some disorderly *** electrochemical performance of the modified sample is as follows:LR(pristine)shows specific discharge capacity of 72.7 mA·h·g^(−1)after 500 cycles at 1 C,while GR(modified sample)shows specific discharge capacity of 137.5 mA·h·g^(−1) at 1 C,and the discharge mid-voltage of GR still remains above 3 V when cycling to 220 cycles at 1 C(mid-voltage of LR remains above 3 V when cycling to 160 cycles at 1 C).Therefore,deliberately regulating the local state of the two phases is a successful way to reinforced the material structure and inhibition the voltage attenuation.

关键词： lithium-rich phase tuning engineering stepwise co-precipitation voltage attenuation 1.Introduction

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Analysis of the factors affecting the magnetic characteristics of nano-Fe_3O_4 particles

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Chinese Science Bulletin 2011年第8期56卷 803-810页

作者： li jianling li DeCai ZHANG ShaoLan CUI HongChao WANG Cui School of Mechanical Electronic and Control Engineering Beijing Jiaotong University Beijing 100044 China

We prepared Fe3O4 nanoparticles using chemical coprecipitation and studied the factors affecting the magnetic characteristics of nano-Fe3O4 *** identified four factors and three levels of an orthogonal experiment and investigated these four factors that affect the magnetic characteristics of the Fe3O4 *** obtained important information from this *** Fe3+ to Fe2+ molar ratio,the iron precursor salt,the amount of surfactant and the amount of alkali were found to be *** also studied the influence of the order of alkali and surfactant addition,the aging time and the stirring speed on the magnetic characteristics of the nano-Fe3O4 *** Fe3O4 preparation process was also analyzed.

关键词： Fe3O4纳米粒子磁特性铁颗粒纳米Fe3O4 表面活性剂氧化磁性粒子化学共沉淀

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Nanoscale noble metals with a hollow interior formed through inside-out diffusion of silver in solid-state core- shell nanoparticles

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Nano Research 2015年第2期8卷 512-522页

作者： Pengfei Hou Penglei Cui Hui liu jianling li Jun Yang State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing 30 College Road Beijing 100083 China State Key Laboratory of Multiphase Complex Sys tems Institute of Process Engineering Chinese Academy of Sciences Beijing 100190 China

Noble metal nanoparticles with hollow interiors and customizable shell com- positions have immense potential for a wide variety of applications. Herein, we present a facile, general, and cost-effective strategy for the synthesis of noble metal nanoparticles with hollow structures, which is based on the inside-out diffusion of Ag in solid-state core-shell nanoparticles. This approach starts with the preparation of core-shell nanoparticles with Ag residing in the core region, which are then loaded on a solid substrate and aged in air to allow the inside-out diffusion of Ag from the core region, leading to the formation of monometallic or alloy noble metal nanoparticles with a hollow interior. The synthesis was carried out at room temperature and could be achieved on different solid substrates. In particular, the inside-out diffusion of Ag calls for specific concern with respect to the evaluation of the catalytic performance of the Ag-based core--shell nanoparticles since it may potentially interfere with the physical and chemical properties of the core-shell particles.

关键词： noble metal nanoparticle inside-out diffusion solid-state core-shell hollow

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