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Observation of acoustic hybrid topological phases induced by the p-d orbital interactions

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 132-139页

作者： Xiao Xiang feng Gao yu-Gui peng peng Wu Zong-Lin Li Xue-feng Zhu School of Physics and Innovation Institute Huazhong University of Science and Technology

In spinless systems,growing attention has recently been attracted to synthetic gauge fields,which redefine the fundamental crystal symmetries by utilizing the projective algebraic ***,synthetic gauge fields have been commonly investigated in single orbital systems,and explorations on hybrid orbitals remain elusive in ***,we report the experimental observation of hybrid topological phases induced by hybrid synthetic gauge flux,which is formed by the interaction between p and d orbitals embedded in acoustic *** breaking the translation symmetries of Lxand/or Ly,we unambiguously demonstrate the first-order M?bius edge states and higher-order corner *** work establishes a platform for seeking exotic topological phases induced by hybrid-orbitals interactions and initializing the framework of hybrid-orbitalsrelated topological *** applications can be anticipated in scenarios such as high-quality sensing and robust wave trapping due to the stepwise energy distribution of the hybrid topological phase.

关键词： topological insulator synthetic gauge field projective symmetry corner states

Advances in the Development of Gradient Scaffolds Made of Nano‑Micromaterials for Musculoskeletal Tissue Regeneration

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Nano-Micro Letters 2025年第3期17卷 455-500页

作者： lei Fang Xiaoqi Lin Ruian Xu Lu Liu yu Zhang feng Tian Jiao Jiao Li Jiajia Xue Beijing Laboratory of Biomedical Materials Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China State Key Laboratory of Organic‑Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029People’s Republic of China School of Biomedical Engineering Faculty of Engineering and ITUniversity of Technology SydneySydneyNSW 2007Australia

The intricate hierarchical structure of musculoskeletal tissues,including bone and interface tissues,necessitates the use of complex scaffold designs and material structures to serve as tissue-engineered *** has led to growing interest in the development of gradient bone scaffolds with hierarchical structures mimicking the extracellular matrix of native tissues to achieve improved therapeutic *** on the anatomical characteristics of bone and interfacial tissues,this review provides a summary of current strategies used to design and fabricate biomimetic gradient scaffolds for repairing musculoskeletal tissues,specifically focusing on methods used to construct compositional and structural gradients within the *** latest applications of gradient scaffolds for the regeneration of bone,osteochondral,and tendon-to-bone interfaces are ***,the current progress of testing gradient scaffolds in physiologically relevant animal models of skeletal repair is discussed,as well as the challenges and prospects of moving these scaffolds into clinical application for treating musculoskeletal injuries.

关键词： Gradient scaffolds Musculoskeletal tissues Advanced manufacturing Biomaterials Tissue regeneration

Effect of order–disorder transition on thermodynamic and electronic properties of σ and χ phases in W–Re alloy: the first-principles calculation

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Tungsten 2025年第1期 195-213页

作者： Zhi-peng Zhu Dian Jia William Yi Wang Jun-lei Yin Xing-yu Gao Shu-feng yang Hai-feng Song Jin-Shan Li State Key Laboratory of Solidification Processing Northwestern Polytechnical University Laboratory of Computational Physics Institute of Applied Physics and Computational Mathematics School of Metallurgical and Ecological Engineering University of Science and Technology Beijing

The Tungsten-Rhenium(W-Re) alloys,celebrated for their high melting point,strength at elevated temperatures,electrical resistivity,and radiation resistance,have been widely utilized in high-temperature components,aerospace,electronics,and nuclear *** constituents of the topologically close-packed(TCP) phases,the sigma phase(σ) and chi phase(χ) formed within W-Re alloys wield considerable influence on the mechanical properties and the stability of the *** calculations were utilized in the present work to explore the structural,thermodynamic,and electronic properties of both ordered and disordered configurations within the σ and χ phases,culminating in a systematic elucidation of the higher phase stability exhibited by the ordered *** is found that the bulk modulus of these two phases is directly proportional to the concentration of Re in the alloy,while the equilibrium volume is inversely *** thermodynamic parameters of the σ and χ phases are calculated via the mean-field potential *** similar trends observed in the isobaric heat capacity,enthalpy increment,and entropy change curves for these two phases suggest they possess comparable thermodynamic *** is noteworthy that the contribution of ionic vibrations predominantly affects the isobaric heat capacity,while the contribution of thermal electronic excitations increases linearly with *** the structure and thermodynamic properties of TCP phases in W-Re alloys at low temperatures has profound significance for optimizing material performance,microstructures features,establishing theoretical foundations,and predicting material behavior.

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Modular Verification of SPARCv8 Code

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Journal of Computer Science & Technology 2020年第6期35卷 1382-1405页

作者： Jun-peng Zha Xin-yu feng lei Qiao Department of Computer Science and Technology Nanjing UniversityNanjing 210023China State Key Laboratory for Novel Software Technology Nanjing UniversityNanjing 210023China Beijing Institute of Control Engineering Beijing 100080China

Inline assembly code is common in system software to interact with the underlying hardware platforms. The safety and correctness of the assembly code is crucial to guarantee the safety of the whole system. In this paper, we propose a practical Hoare-style program logic for verifying SPARC (Scalable Processor Architecture) assembly code. The logic supports modular reasoning about the main features of SPARCv8 ISA (instruction set architecture), including delayed control transfers, delayed writes to special registers, and register windows. It also supports relational reasoning for refinement verification. We have applied it to verify that there is a contextual refinement between a context switch routine in SPARCv8 and a switch primitive. The program logic and its soundness proof have been mechanized in Coq.

关键词： Scalable Processor Architecture Version 8(SPARCv8) assembly code verification context switch Coq refinement verification

Oxygen vacancies enriched Ir/WOx catalysts for the directly chem-catalytic conversion of cellulose to ethanol

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Tungsten 2025年第1期 88-99页

作者： yu-Jing Weng Zhao-Ying Ding Ying-Chao Li yuan-feng Wu yuan-yang Xu Rui Chen Xiao-lei Zhao Hai-Yong Wang Da-lei Zhang yu-Long Zhang Henan Key Laboratory of Coal Green Conversion and International Joint Laboratory of Coal Clean Utilization College of Chemistry and Chemical Engineering Henan Polytechnic University Key Laboratory of Renewable Energy Guangzhou Institute of Energy Conversion Chinese Academy of Sciences Liaoning Institute of Energy Technology

Tungsten and its oxides are highly versatile catalysts with unique properties that hold great promise for a wide array of applications,including biological pathways and chemical *** chemo-catalysis of cellulose to ethanol presents a promising avenue for ethanol synthesis with the potential for enhanced efficiency compared to conventional methods,offering a sustainable and carbon-neutral alternative to existing petrochemical and biological ***,Ir/WOxcatalysts enriched with oxygen vacancies were meticulously prepared and demonstrated remarkable catalytic performance in converting cellulose to ethanol directly in the presence of tungstic *** catalyst achieved a high ethanol yield of 66.5%under optimal reaction conditions,approaching the theoretical yield limit of traditional ethanol *** results revealed the presence of oxygen defects,Bronsted/Lewis acidity,and Ir nanoclusters on the catalyst surface,working synergistically to facilitate the cascade catalysis of cellulose hydrolysis,sugar retro-aldol condensation reaction,and C2 intermediate hydrodeoxygenation to *** situ Fourier transform infrared spectrometer analysis confirmed the catalyst's ability to enhance the adsorption and activation of ethylene glycol for ethanol *** manipulating subtle structural features,this study offers a fresh perspective on tungsten group catalyst design and underscores the importance of synergistic effects among catalytic sites for the efficient production of ethanol from cellulose.

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Platinum-based ternary catalysts for the electrooxidation of ethanol

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Particuology 2021年第5期19卷 169-186页

作者： Guangxing yang Qiao Zhang Hao yu feng peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510641PR China School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou 510641PR China School of Chemistry and Chemical Engineering Guangzhou UniversityGuangzhou 510006PR China

Direct ethanol fuel cell(DEFC)as a promising device for converting chemical energy to electricity has been paid ever-increasing ***,the slow kinetics of ethanol electrooxidation at an anode hinders the application of *** Pt is the best catalyst among all the pure metal catalysts,it still has a relatively poor ability to break the Csingle bondC bond,is deactivated by the accumulated CO_(ad) intermediates,and undergoes unwanted desired structure change over long-term *** recent years,the addition of other metals to form binary,ternary,and quaternary catalysts have significantly improved electroactivity and *** catalysts can have numerous element combinations and complicated architectures and,therefore,have been the subject of considerable *** this review,most of the reported ternary catalysts will be summarized and categorized according to their structure while discussing the essence of the role of each component.

关键词： Direct ethanol fuel cell Ethanol oxidation reaction Ternary catalyst Composition-reactivity relationship

Removal Mechanism of Aqueous Lead by a Novel Eco-material: Carbonate Hydroxyapatite

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Journal of Materials Science & Technology 2007年第3期23卷 417-422页

作者： Huanyan XU lei yang peng WANG yu LIU Mingsheng peng School of Materials Science and Engineering Harbin University of Science and Technology Harbin 150040 China School of Municipal and Environmental Engineering Harbin Institute of Technology Harbin 150090 China School of Materials Science and Engineering Wuhan Institute of Technology Wuhan 430073 China Department of Earth Sciences Zhongshan University Guangzhou 510275 China

Kinetics and mechanisms on the removal of aqueous lead ion by carbonate hydroxyapatite （CHap） are investigated in the present work. Experimental results show that, in the whole pH range, the lead removal percentage increases with decreasing pH values and reaches a maximum at pH=2-3. Under some conditions, the lead residual concentration is below national integrated wastewater discharge standard, even drinking water standard. The removal behavior is a complicated non-homogeneous solid/liquid reaction, which can be described by two stages from kinetic point of view. At the earlier stage, reaction rate is so fast that its kinetic course is intricate, which requires further study. At the latter stage, the rate of reaction becomes slow and the process of reaction accords with one order reaction kinetic equation. Experimental results show that the relationship between reaction rate constant k1 and temperature T accords to Arrhenius Equation, and the activation energy of sorption （Ea） is 11.93 kJ/mol and frequency factor （A） is 2.51 s^-1. X-ray diffraction （XRD）, scanning electron microscopy with an energy dispersive X-ray fluoresence spectrometer （SEM-EDS） and toxicity characteristic leaching procedure （TCLP） test were conducted in this work. It is indicated that the main mechanism is dissolution-precipitation, accompanying with superficial sorption.

关键词： Carbonate hydroxyapatite Lead ion Mechanism Dissolution-precipitation

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抚仙湖浮游植物群落结构对水体垂直混合过程的响应

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湖泊科学 2025年第1期37卷 36-49页

作者：朱先龙雷逸伦杨予罗鸿赖睿聪罗文磊王荣徐润冰邢鹏云南大学生态与环境学院云南高原山地生态与退化环境修复重点实验室昆明650091 中国科学院南京地理与湖泊研究所湖泊与流域水安全重点实验室南京211135 中国科学院南京地理与湖泊研究所湖泊与环境国家重点实验室南京211135 中国科学院抚仙湖高原深水湖泊研究站玉溪652500 抚仙湖高原深水湖泊云南省野外科学观测研究站玉溪652500

深水湖泊冬季热力分层消亡,水体上下混合,水动力过程改变营养盐的分布格局,可能影响湖泊生态系统中浮游植物群落的演替。本研究在2022年11月2023年4月高原深水湖泊抚仙湖的热力分层消亡期、混合期和分层形成期,开展水体垂直剖面的理化... 详细信息

深水湖泊冬季热力分层消亡,水体上下混合,水动力过程改变营养盐的分布格局,可能影响湖泊生态系统中浮游植物群落的演替。本研究在2022年11月2023年4月高原深水湖泊抚仙湖的热力分层消亡期、混合期和分层形成期,开展水体垂直剖面的理化环境因子及浮游植物群落高频观测,探究浮游植物群落时空变化特征及其对热力学混合过程的响应。结果表明:水体混合过程引起湖泊理化环境因子显著的时空变化,与分层消亡期和形成期相比,混合期水体总磷(TP)、溶解性有机磷(DOP)、正磷酸盐(PO 3-4-P)和叶绿素a(Chl.a)浓度显著增加,总氮(TN)、溶解氮(DN)、颗粒氮(PN)、氨氮(NH 3-N)和硝态氮(NO-3-N)浓度显著降低。浮游植物群落中,绿藻门的转板藻属(Mougeotia)和小球藻属(Chlorella)在整个观测期密度较高,蓝藻门的长孢藻属(Dolichospermum)和拟柱孢藻属(Cylindrospermopsis)在分层消亡期密度较高,硅藻门的直链藻属(Melosira)和隐藻门隐藻属(Cryptomonas)在混合期密度高,绿藻门的栅藻属(Scenedesmus)在分层形成期密度较高。冗余分析发现,NH 3-N、PO 3-4-P和碱性磷酸酶活性的动态变化显著影响浮游植物群落组成;而且,浮游植物不同种类对氮、磷营养盐的敏感性各不相同,其中长孢藻属和转板藻属的密度与氮营养盐呈正相关、与磷营养盐呈负相关;而其他浮游植物密度则呈现相反规律,分别与氮营养盐呈负相关,与磷营养盐呈正相关。通过结构方程模型分析水体混合期间浮游植物群落动态变化的驱动机制,发现一方面水温对浮游植物群落结构有直接影响;另一方面,水温通过调节不同形态的氮(NO-3-N、NH 3-N)、磷(PO 3-4-P和DOP)营养盐浓度,从而间接地驱动浮游植物群落结构变化。这些直接和间接的影响共同作用,最终引起水体中Chl.a浓度变化。本研究有助于认识深水湖泊热力分层变化对生态系统结构和功能的影响。在全球变化背景下,加强对湖库热力分层的作用机制及其生态环境效应研究,有助于深水湖泊生态系统的保护和管理。

关键词：抚仙湖垂直混合浮游植物营养盐驱动因子

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Inclusions in wrought superalloys:a review

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Journal of Iron and Steel Research International 2021年第8期28卷 921-937页

作者： Shu-feng yang Shu-lei yang Jing-long Qu Jin-hui Du yu Gu peng Zhao Ning Wang School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China Gaona Aero Material Co. Ltd.Beijing 100081China

Inclusions in wrought superalloys significantly affect the stability of the alloy properties and limit their use and devel-opment in aeroengines and other *** types and sources of inclusions in wrought superalloys were reviewed with analysis of the conditions of inclusion formation from the viewpoints of thermodynamics and *** ther-modynamic data for inclusion formation in nickel-based and cobalt-based alloys were summarized and *** damage of inclusions to the fatigue and tensile properties and workability of these alloys and the mechanisms of crack initiation and propagation caused by inclusions were also discussed,and the effects of inclusions with different charac-teristics on crack propagation were *** addition,the control methods and mechanisms of inclusions in the triple smelting process(vacuum induction melting+protective electroslag remelting+vacuum arc remelting)were covered,providing a reference for improving the control technology of inclusions in wrought ***,the difficulties and development trends for inclusion control in wrought superalloys were discussed.

关键词： Wrought superalloy Triple smelting Inclusion Control method