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Emerging progress:photochemical transformation of nitroso compounds

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Science China Chemistry 2025年第1期68卷 118-133页

作者： Ze-le chen Qiang-Qiang Li Armido Studer Jun Xuan Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials School of Chemistry&Chemical EngineeringAnhui UniversityHefei 230601China Organisch-Chemisches Institut Universitat MünsterMunster 48149Germany

Nitroso compounds have emerged as highly valuable reaction partners or reagents in organic synthesis due to their rich *** versatile profile of these compounds allows them to function as electrophiles,nucleophiles,diradicals,and radical acceptors in diverse *** recent years,notable progress has been made in harnessing photochemical reactions with nitroso compounds to prepare N,O-containing structures using mild and eco-friendly *** nitroso compounds like nitrosoarenes,acyloxy nitroso compounds,N-nitrosoamines and nitrites have received significant attention for their ability to introduce NO moieties into complex molecules that are otherwise difficult to *** this review,we provide an overview of the recent advancements in the visible light-induced conversion of nitroso compounds,with particular emphasis on their role as bifunctional reagents and acceptors of radicals,carbenes and nitrenes.

关键词： nitroso compounds photochemistry radical reaction carbene transformation nitrosoarenes

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Support electron inductive effect of Pd-Mn/Ni foam catalyst for robust electrocatalytic hydrodechlorination

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Journal of Environmental Sciences 2025年第3期149卷 288-300页

作者： Junxi Li Chao Feng Chong chen yuan Pan Yunqi Liu State Key Laboratory of Heavy Oil Processing China University of Petroleum(East China)Qingdao 266580China Key Laboratory of Biofuels Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101China

Structural regulation of Pd-based electrocatalytic hydrodechlorination(EHDC)catalyst for constructing high-efficient cathode materials with low noble metal content and high atom utilization is crucial but still ***,a support electron inductive effect of Pd-Mn/Ni foam catalyst was proposed via in-situ Mn doping to optimize the electronic structure of the Ni foam(NF),which can inductive regulation of Pd for improving the EHDC *** mass activity and current efficiency of Pd-Mn/NF catalyst are 2.91 and 1.34 times superior to that of Pd/NF with 2,4-dichlorophenol as model compound,*** Mn-doped interlayer optimized the electronic structure of Pd by bringing the d-state closer to the Fermi level than Pd on the NF surface,which optimizied the binding of EHDC ***,the Mn-doped interlayer acted as a promoter for generating H∗and accelerating the EHDC *** work presents a simple and effective regulation strategy for constructing high-efficient cathode catalyst for the EHDC of chlorinated organic compounds.

关键词： Palladium Structural Regulation Electrocatalytic hydrodechlorination Support electron inductive effect

Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs3Bi2Br9/BiOBr epitaxial heterojunction for efficient photocatalysis

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Chinese Chemical letters 2025年第2期36卷 218-223页

作者： yuan Teng Zichun Zhou Jinghua chen Siying Huang Hongyan chen Daibin Kuang MOE Key Laboratory of Bioinorganic and Synthetic Chemistry LIFM GBRCE for Functional Molecular Engineering School of Chemistry IGCME Sun Yat-sen University National Experimental Teaching Demonstration Center for Chemistry College of Chemistry and Chemical Engineering Jishou University

Optimizing the interfacial quality of halide perovskites heterojunction to promote the photogenerated charge separation is of great significance in photocatalytic ***,the delicately regulation of interfacial structure and properties of halide perovskites hybrid is still a big challenge owing to the growth uncontrollability and incompatibility between different *** we use Bi OBr nanosheets as the start-template to in situ epitaxially grow Cs3Bi2Br9nanosheets by“cosharing”Bi and Br atoms strategy for designing a 2D/2D Cs3Bi2Br9/BiOBr *** studies show that the epitaxial heterojunction can optimize the synergistic effect of Bi OBr and Cs3Bi2Br9via the formation of tight-contact interfaces,strong interfacial electronic coupling and charge redistribution,which can not only drive the Z-scheme charge transfer mechanism to greatly promote the spatial separation of electronhole pairs,but also modulate the interfacial electronic structure to facilitate the adsorption and activation of toluene *** heterojunction exhibited 62.3 and 2.4-fold photoactivity improvement for toluene oxidation to benzaldehyde than parental Bi OBr and Cs3Bi2Br9,*** study not only proposed a novel dual atom-bridge protocol to engineer high-quality perovskite heterojunctions,but also uncovered the potential of heterojunction in promoting electron-hole separation as well as the application in photocatalytic organic synthesis.

关键词： Bismuth oxyhalide Bismuth-based perovskite Direct Z-scheme heterojunction Dual atom-bridge effect Photocatalytic C(sp3)-H bond activation

Phase equilibria of Fe_(3)O_(4)-Cr_(2)O_(3)-CaO system:experimental measurements and thermodynamic calculations

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Journal of Iron and Steel Research International 2025年第1期32卷 95-104页

作者： Ao Zhu chen-ying Shi Pei-yuan Ni Teng-fei Deng State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070HubeiChina College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083HunanChina Key Laboratory of Ecological Metallurgy of Multi-Metal Intergrown Ores of Education Ministry School of MetallurgyNortheastern UniversityShenyang 110819LiaoningChina

Understanding the phase equilibria of the Fe_(3)O_(4)-Cr_(2)O_(3)-CaO system is essential for the efficient recycling of stainless steel pickling *** isothermal section of this system at 1473 K under oxygen partial pressure of 0.15 Pa was *** experiments on the relevant binary systems were conducted using a combination of equilibrium-quenching techniques,X-ray diffraction,high-resolution transmission electron microscope,and electron probe *** systems were rigorously assessed using the CALPHAD(CALculation of Phase Diagram)method,incorporating the present experimental *** liquid phase was modeled using the ionic two-sublattice model,represented as(Ca^(2+),Cr^(3+),Fe^(2+))P(O_(2)^(-),Va,FeO_(1.5))Q,where Va represents vacancy,and P and Q denote the number of sites on the cation and anion sublattices,*** ensure electroneutrality,the values of P and Q adjust according to the composition of the *** this,the isothermal section of the Fe_(3)O_(4)-Cr_(2)O_(3)-CaO system at 1473 K under the specified oxygen partial pressure was obtained based on the thermodynamic parameters of the binary *** present experimental data and calculation results hold significant implications for the comprehensive recycling of stainless steel pickling sludge.

关键词： Fe_(3)O_(4)-Cr_(2)O_(3)-CaO system Ionic two-sublattice model Phase equilibria CALPHAD

Co/Co_(7)Fe_(3)heterostructures with controllable alloying degree on carbon spheres as bifunctional electrocatalyst forrechargeable zinc-air batteries

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 476-487页

作者： Junkang chen Yongyue Zhuang Yanxin Qiao Yu Zhang Aihua yuan Hu Zhou School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying *** optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline *** intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co *** the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based *** particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending *** work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.

关键词： bifunctional electrocatalysts oxygen reduction reaction oxygen evolution reaction zinc-air battery metal/alloy carbon sphere

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Integrating well logs, 3D seismic, and earthquake data for comprehensive prediction of 3D in-situ stress orientations: A case study from the Weiyuan area in the Sichuan Basin, China

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Petroleum Science 2025年第1期22卷 210-221页

作者： Huan Cao Yang Zhao Hai-Chao chen le-le Zhang cheng-Gang Xian Ji-Dong Yang Lu Liu State Key Laboratory of Petroleum Resources and Engineering and Unconventional Petroleum Research Institute China University of Petroleum (Beijing) Department of Geophysics China University of Petroleum (East China) Aramco Beijing Research Center Aramco Asia

Determining the orientation of in-situ stresses is crucial for various geoscience and engineering applications. Conventional methods for estimating these stress orientations often depend on focal mechanism solutions(FMSs) derived from earthquake data and formation micro-imager(FMI) data from well ***, these techniques can be costly, depth-inaccurate, and may lack spatial coverage. To address this issue, we introduce the use of three-dimensional(3D) seismic data(active sources) as a lateral constraint to approximate the 3D stress orientation field. Recognizing that both stress and fracture patterns are closely related to seismic velocity anisotropy, we derive the orientation of azimuthal anisotropy from multi-azimuth 3D seismic data to compensate for the lack of spatial stress orientation information. We apply our proposed workflow to a case study in the Weiyuan area of the Sichuan Basin, China, a region targeted for shale gas production. By integrating diverse datasets, including 3D seismic, earthquakes, and well logs, we develop a comprehensive 3D model of in-situ stress(orientations and magnitudes). Our results demonstrate that the estimated anisotropy orientations from 3D seismic data are consistent with the direction of maximum horizontal principal stress(SHmax) obtained from FMIs. We analyzed 12earthquakes(magnitude > 3) recorded between 2016 and 2020 for their FMSs and compressional axis(Paxis) orientations. The derived SHmax direction from our 3D stress model is 110°ES(East-South), which shows excellent agreement with the FMSs(within 3.96°). This close alignment validates the reliability and precision of our integrated method for predicting 3D SHmax orientations.

关键词： In-situ stress orientation SHmax Azimuthal velocity anisotropy Focal source mechanism Formation micro-imager

Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism

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Journal of Rock Mechanics and Geotechnical Engineering 2025年第1期17卷 573-585页

作者： Xiaoyi yuan lei Peng Bing chen Department of Civil Engineering Shanghai Jiao Tong UniversityShanghai200240China State Key Laboratory of Ocean Engineering Shanghai Jiao Tong UniversityShanghai200240China

This paper investigated the use of magnesium phosphate cement (MPC) for solidifying sludge with different humic acid (HA) content (ranging from 0 to 4.5%) and explored the solidification mechanism. Fluidity, setting time, unconfined compressive strength (UCS), the strength formation mechanism, and the spontaneous imbibition process of solidified sludge (SS) were studied. The results indicate that MPC can be used as a low-alkalinity curing agent. As the HA content increases, fluidity and setting time also increase, while hydration temperature and strength decrease. Additionally, the failure mode of SS transitions from brittleness to ductility. The strength of SS is composed of the cementation strength provided by MPC hydration products, matric suction, osmotic suction, and the structural strength of the sludge. MPC reduces the structural strength caused by the shrinkage of pure sludge under the action of matric suction, but the incorporation of MPC significantly improved the strength when the sludge is eroded by water. X-ray diffraction (XRD) and scanning electron microscopy (SEM) show that the sludge and MPC can form a dense solid body, forming various hydration products, and synergistically improve the mechanical properties of the sludge.

关键词： Sludge solidification MPC Unsaturated spontaneous imbibition Strength mechanism Humic acid

Optimal Scheduling of an Independent Electro-Hydrogen System with Hybrid Energy Storage Using a Multi-Objective Standardization Fusion Method

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Energy Engineering 2025年第1期122卷 63-84页

作者： Suliang Ma Zeqing Meng Mingxuan chen yuan Jiang School of Electrical and Control Engineering North China University of TechnologyBeijing100144China ChinaThree Gorges Technology Co. Ltd.Beijing100032China School of Automation and Electrical Engineering University of Science and Technology BeijingBeijing100083China

In the independent electro-hydrogen system(IEHS)with hybrid energy storage(HESS),achieving optimal scheduling is ***,it presents a challenge due to the significant deviations in values ofmultiple optimization objective functions caused by their physical *** deviations seriously affect the scheduling process.A novel standardization fusion method has been established to address this issue by analyzing the variation process of each objective function’s *** optimal scheduling results of IEHS with HESS indicate that the economy and overall energy loss can be improved 2–3 times under different optimization *** proposed method better balances all optimization objective functions and reduces the impact of their *** the cost of BESS decreases by approximately 30%,its participation deepens by about 1 ***,if the price of the electrolyzer is less than 15¥/kWh or if the cost of the fuel cell drops below 4¥/kWh,their participation will increase *** study aims to provide a more reasonable approach to solving multi-objective optimization problems.

关键词： Electro-hydrogen system multi-objective optimization standardization method hybrid energy storage system

Hausdorff Measure of Space Anisotropic Gaussian Processes with Non-stationary Increments

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Acta Mathematicae Applicatae Sinica 2025年第1期41卷 114-132页

作者： Jun WANG Zhen-long chen Wei-jie yuan Guang-jun SHEN School of Mathematics and Physics Anhui Polytechnic UniversityWuhu 241000China School of Statistics and Mathematics Zhejiang Gongshang UniversityHangzhou 310018China Department of Mathematics Anhui Normal UniversityWuhu 241000China

let X={X(t),t∈R+} be a centered space anisotropic Gaussian process values in R^(d) with non-stationary increments,whose components are independent but may not be identically *** certain conditions,then almost surely c_(1)≤ϕ-m(X([0,1]))≤c_(2),where ϕ denotes the exact Hausdorff measure associated with function ϕ(s)=s1/α_(k)+Σ_(i=1)k(1-αi/αk)log log 1/s for some 1≤k≤d,(α_(1),…,α_(d))∈(0,1]^(d).We also obtain the exact Hausdorff measure of the graph of X on[0,1].

关键词： Hausdorff measure self-similar Gaussian processes non-stationary increment Lamperti theorem

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