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XPS characterization and corrosion resistance of cerium-treated magnesium coatings

Rare Metals 2011年第4期30卷 368-373页

作者： Samia Ben Hassen latifa bousselmi Patrice Berot El Mustafa Rezrazi Ezzeddine Triki Unité de Recherche Corrosion & Protection des Métalliques ENITBP 37Tunis-BelvédèreTunisie Institut UTINAM CNRS UMR 6213Université de Franche-Comté16 route de Gray 25030 Besanon CedexFrance Laboratoire Traitement et Recyclage des Eaux CERTEBorj CedriaTunisie

Cerium conversion treatment was applied on magnesium coatings in a solution containing CeC13. The composition ot the cenum conversion layer on magnesium was investigated using X-ray photoelectron spectroscopy （XPS）, It was revealed that the composition predominately consisted of a three-valent state cerium compound with a relative abundance around 90%. Some of Ce^3＋ was oxidized to Ce^4＋. Electrochemical impedance spectroscopy results revealed that the total impedance of cerium-treated samples increased for a short immersion time in NaC1 solution before coating deteriorating. This deterioration was due to the coating porosity increasing and the breakdown of the conversion layer

关键词： cerium compounds magnesium coatings X-ray photoelectron spectroscopy corrosion resistance

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Improvement in corrosion resistance of magnesium coating with cerium treatment

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Rare Metals 2009年第3期28卷 277-283页

作者： Samia Ben Hassen latifa bousselmi Patrice Berot El Mustafa Rezrazi Ezzeddine Triki Unité de Recherche Corrosion & Protection des Métalliques ENITBP 37Tunis-BelvédèreTunisia Institut UTINAM CNRS UMR 6213Université de Franche-Comté16 route de Gray 25030 Besanon CedexFrance Laboratoire Traitement et Recyclage des Eaux CERTEBorj CedriaTunisia

Corrosion protection afforded by a magnesium coating treated in cerium salt solution on steel substrate was investigated using open circuit potential, polarization curves, and electrochemical impedance spectroscopy （EIS） in 0.005 M sodium chloride solution （NaCl）. The morphology of the surface was characterized by scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, and X-ray diffraction （XRD）. The cerium treated coating was obtained by immersion in CeCl3 solution. The results showed that the corrosion resistance of the treated magnesium coating was improved. The corrosion potential of the treated coating was found to be nobler than that of the untreated magnesium coating and the corrosion current decreased significantly. Impedance results showed that the cerium treatment increased corrosion protection. The improvement of anti-corrosion properties was attributed to the formation of cerium oxides and hydroxides that gave rise to a physical barrier effect.

关键词： magnesium coating cerium corrosion protection impedance spectroscopy

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Cr-Doped TiO_(2)Thin Films Prepared by Means of a Magnetron Co-Sputtering Process:Photocatalytic Application

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American Journal of Analytical Chemistry 2014年第8期5卷 473-482页

作者： Anouar Hajjaji Atef Atyaoui Khaled Trabelsi Mosbah Amlouk latifa bousselmi Brahim Bessais My Ali El Khakani Mounir Gaidi Institut National de la Recherche Scientifique INRS-EnergieMatériaux et TélécommunicationsVarennesCanada Laboratoire de Photovoltaique Centre de Recherches et des Technologies de l’EnergieTechnopole de Borj-CédriaHammam-LifTunisia Laboratoire de Traitement et de Recyclage des Eaux Centre de Recherches et des Technologies des EauxTechnopole de Borj-CedriaHammam-LifTunisia Unitéde Physique des DispositifsàSemi-Conducteurs Facultédes Sciences de TunisCampus UniversitaireTunisTunisia Department of Applied Physics University of SharjahSharjahUAE

This paper deals with the effect of Cr content on photocatalytic activity of TiO2 thin films deposited on quartz and intrinsic silicon substrates by using the RF magnetron co-sputtering process. Some physical investigations on such sputtered films were made by means of X-ray Diffraction (XRD), atomic force microscopy (AFM), Raman spectroscopy as well as UV-Vis-IR absorption techniques. The heat treatment under oxygen atmosphere at 550°C reveals that the crystalline structure of TiO2: Cr depends on Cr content. Anatase-to-rutile phase transformation occurs at a Cr content of about 7%. On the other hand, the band gap energy value of annealed TiO2: Cr films varies in terms of Cr doping and a transition around 7% of Cr is accrued. The photocatalytic activity of undoped and doped TiO2 films was evaluated by photo-degrading of the amido black under UV light irradiation. Modification of the chemical structure of titanium dioxide by Cr doping allows moving the photocatalytic activity of titanium dioxide towards visible light. The results indicate that films doped with 2% Cr exhibit the highest UV and visible light photocatalytic activity.

关键词： TiO_(2) Cr-Doped TiO_(2) Photocatalysis Opto-Electronic

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