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Lithium-Metal-Free Sulfur Batteries with Biochar and Steam-Activated Biochar-Based Anodes from Spent Common Ivy

ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 118-128页

作者： Salimi, Pejman Vercruysse, Willem Chauque, Susana Yari, Saeed Venezia, Eleonora lataf, amine Ghanemnia, Nahal Zafar, Muhammad Shajih Safari, Mohammadhosein Hardy, An Zaccaria, Remo Proietti Vandamme, Dries Ist Italiano Tecnol Via Morego 30 I-16163 Genoa Italy Univ Genoa Dept Chem & Ind Chem Via Dodecaneso 31 I-16146 Genoa Italy Hasselt Univ Analyt & Circular Chem ACC Martelarenlaan 42 BE-3500 Hasselt Belgium Hasselt Univ Inst Mat Res Imoimomec Martelarenlaan 42 BE-3500 Hasselt Belgium Hasselt Univ Ctr Environm Sci CMK Martelarenlaan 42 BE-3500 Hasselt Belgium Energyville Thor Pk 8310 BE-3600 Genk Belgium IMEC Div IMOMEC Wetenschapspk 1 BE-3590 Diepenbeek Belgium

Lithium-sulfur batteries are emerging as sustainable replacements for current lithium-ion batteries. The commercial viability of this novel type of battery is still under debate due to the extensive use of highly reactive lithium-metal anodes and the complex electrochemistry of the sulfur cathode. In this research, a novel sulfur-based battery has been proposed that eliminates the need for metallic lithium anodes and other critical raw materials like cobalt and graphite, replacing them with biomass-derived materials. This approach presents numerous benefits, encompassing ample availability, cost-effectiveness, safety, and environmental friendliness. In particular, two types of biochar-based anode electrodes (non-activated and activated biochar) derived from spent common ivy have been investigated as alternatives to metallic lithium. We compared their structural and electrochemical properties, both of which exhibited good compatibility with the typical electrolytes used in sulfur batteries. Surprisingly, while steam activation results in an increased specific surface area, the non-activated ivy biochar demonstrates better performance than the activated biochar, achieving a stable capacity of 400 mA h g(-1) at 0.1 A g(-1) and a long lifespan (>400 cycles at 0.5 A g-1). Our results demonstrate that the presence of heteroatoms, such as oxygen and nitrogen positively affects the capacity and cycling performance of the electrodes. This led to increased d-spacing in the graphitic layer, a strong interaction with the solid electrolyte interphase layer, and improved ion transportation. Finally, the non-activated biochar was successfully coupled with a sulfur cathode to fabricate lithium-metal-free sulfur batteries, delivering a specific energy density of similar to 600 Wh kg(-1).

关键词： activated biochar biochar electrochemical performance functional groups lithium-metal-free sulfur batteries ION BATTERIES ELECTROCHEMICAL PERFORMANCE MARINE BIOMASS CARBON ANODES HARD CARBON RICE HUSK ELECTROLYTE PYROLYSIS MICROWAVE LIQUID

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Security and Privacy in Solar Insecticidal Lamps Internet of Things:Requirements and Challenges

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IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 58-73页

作者： Qingsong Zhao Lei Shu Kailiang Li Mohamed amine Ferrag Ximeng Liu Yanbin Li the College of Artificial Intelligence Nanjing Agricultural UniversityNanjing 210031 the State Key Laboratory for Novel Software Technology Nanjing UniversityNanjing 210023 the State Key Laboratory of Cryptology Beijing 100878China IEEE the School of Engineering University of LincolnLincoln LN67TSUK the Artificial Intelligence and Digital Science Research Center Technology Innovation InstituteMasdar City 9639UAE the College of Computer and Data Science Fuzhou UniversityFuzhou 350108China

Solar insecticidal lamps(SIL) can effectively control pests and reduce the use of pesticides. Combining SIL and Internet of Things(IoT) has formed a new type of agricultural IoT,known as SIL-IoT, which can improve the effectiveness of migratory phototropic pest control. However, since the SIL is connected to the Internet, it is vulnerable to various security *** issues can lead to serious consequences, such as tampering with the parameters of SIL, illegally starting and stopping SIL,etc. In this paper, we describe the overall security requirements of SIL-IoT and present an extensive survey of security and privacy solutions for SIL-IoT. We investigate the background and logical architecture of SIL-IoT, discuss SIL-IoT security scenarios, and analyze potential attacks. Starting from the security requirements of SIL-IoT we divide them into six categories, namely privacy, authentication, confidentiality, access control, availability,and integrity. Next, we describe the SIL-IoT privacy and security solutions, as well as the blockchain-based solutions. Based on the current survey, we finally discuss the challenges and future research directions of SIL-IoT.

关键词： Challenges Internet of Things(IoT) privacy and security security requirements solar insecticidal lamps(SIL)

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Multi-task learning for PBFT optimisation in permissioned blockchains

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BLOCKCHAIN-RESEARCH AND APPLICATIONS 2024年第3期5卷 89-105页

作者： Riahi, Kenza Brahmia, Mohamed-el-amine Abouaissa, Abdelhafid Idoumghar, Lhassane CESI LINEACT UR 7527 Strasbourg France Univ Haute Alsace IRIMAS UR 7499 Mulhouse France

Finance, supply chains, healthcare, and energy have an increasing demand for secure transactions and data exchange. Permissioned blockchains fulfilled this need thanks to the consensus protocol that ensures that participants agree on a common value. One of the most widely used protocols in private blockchains is the Practical Byzantine Fault Tolerance (PBFT), which tolerates up to one-third of Byzantine nodes, performs within partially synchronous systems, and has superior throughput compared to other protocols. It has, however, an important bandwidth consumption: 2N(N-1) messages are exchanged in a system composed of N nodes to validate only one block. It is possible to reduce the number of consensus participants by restricting the validation process to nodes that have demonstrated high levels of security, rapidity, and availability. In this paper, we propose the first database that traces the behavior of nodes within a system that performs PBFT consensus. It reflects their level of security, rapidity, and availability throughout the consensus. We first investigate different Single-Task Learning (STL) techniques to classify the nodes within our dataset. Then, using Multi-Task Learning (MTL) techniques, the results are much more interesting, with classification accuracies over 98%. Integrating node classification as a preliminary step to the PBFT protocol optimizes the consensus. In the best cases, it is able to reduce the latency by up to 94% and the communication traffic by up to 99%.

关键词： Blockchain PBFT Dataset Nodes classification Single-task learning Multi-task learning

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Modelling the monthly hydrological balance using Soil and Water Assessment Tool(SWAT)model:A case study of the Wadi Mina upstream watershed

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Journal of Groundwater Science and Engineering 2024年第2期12卷 161-177页

作者： Hanane Mebarki Noureddine Maref Mohammed El-amine Dris Civil Engineering and Environmental Laboratory(LGCE) University of Djillali LiabèsFaculty of TechnologyHydraulics departmentBen M'Hidi districtP.O.Box 8922000Sidi Bel AbbèsAlgeria.

Modelling the hydrological balance in semi-arid zones is essential for effective water resource management,encompassing both surface water and *** study aims to model the monthly hydrological water cycle in the Wadi Mina upstream watershed(northwest Algeria)by applying the Soil and Water Assessment Tool(SWAT)hydrological *** modelling integrates spatial data such as the Digital Elevation Model(DEM),land use,soil types and various meteorological parameters including precipitation,maximum and minimum temperatures,relative humidity,solar radiation and wind *** SWAT model was calibrated and validated using data from January 2012 to December 2014,with a calibra-tion period from January 2012 to August 2013 and a validation period from September 2013 to December *** and parameter calibration were conducted using the SWAT-SA program,and model performance evaluation relied on comparing the observed discharge at the outlet of the basin with model-simulated discharge,assessed through statistical coefficients including Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R2)and Percent Bias(PBAIS).Calibration results indicated favourable objec-tive function values(NSE=0.79,R2=0.93,PBAIS=-8.53%),although a slight decrease was observed during validation(NSE=0.69,R2=0.86,and PBAIS=-11.41%).The application of the SWAT model to the Wadi Mina upstream watershed highlighted its utility in simulating the spatial distribution of different components of the hydrological balance in this *** SWAT model revealed that approximately 71%of the precipitation in the basin evaporates,while only 29%contributes to surface runoff or infiltration into the soil.

关键词： SWAT model Performance Parameters Runoff Groundwater Wadi

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Physico-Mechanical Characteristics of Earth Bricks Stabilized with Cement and Padouk Sawdust Residues

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Open Journal of Applied Sciences 2024年第7期14卷 1788-1806页

作者： Gabin Alex Nouemssi Bennis amine Martin Ndibi Mbozo’O Bonaventure Djeumako Doko K. Valery Guy Edgar Ntamack LA2MP: Laboratory of Mechanics Materials and Photonics National School of Agro-Industrial Sciences ENSAI Ngaoundr Cameroun Department of Mechanical and Production Engineering National School of Agro-Industrial Sciences ENSAI Ngaoundr Cameroun LMTM: Laboratory of Mechanics Materials and Thermal National School of Mineral Industry ENIM Rabat Morocco LEMA: Laboratory of Energertic and Applied Mechanics University of Abomey-Calavi Cotonou Benin GMMA: Group of Mechanics Materials and Acoustics Department of Physics Faculty of Sciences-EGCIM Ngaoundr Cameroun

The objective of this work is to improve the physical and mechanical properties of stabilized earth blocks (BTC) used in construction in the Ndé department of Cameroon. To achieve this, two stabilizers, cement and sawdust, were used at varying percentages of 0%, 4%, 6%, and 8%. Physical characterization tests, including natural water content, specific weight, jar test, Protor, and Atterberg limits, were conducted. Additionally, mechanical tests, such as compression and three-point bending, were performed. The results show that as the amount of stabilizer increases, the density of BTC decreases. The samples with 8% sawdust have the highest density, while those without stabilizers have the lowest. Porosity decreases as sawdust and cement content increases, with smaller values observed in samples with 8% sawdust or cement. Our tests indicate that blocks stabilized with cement have slightly higher compressive strength than those stabilized with sawdust. However, the water absorption rate increases with higher sawdust content.

关键词： Earth block Cement Sawdust Physico-mechanical Characteristics Bangante West Cameroon

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Unraveling the Impact of Direct-Acting Antivirals on Hepatitis-Linked Cirrhosis: A Comprehensive Analysis of Fibrosis, Child Score, and Disease Progression

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Open Journal of Gastroenterology 2024年第6期14卷 203-212页

作者： Hajar Cherkaoui Maryam Elkhayari Maria Lahlali Asmae Lamine Nada Lahmidani amine Mekkaoui Mounia Elyousfi Dafr Allah Benajah Mohammed El Abkari Adil Ibrahimi Hakima Abid Department of Hepato-Gastroenterology Hassan II University Hospital Fez Morocco Faculty of Medicine and Pharmacy of Fez USMBA Fez Morocco

The treatment of hepatitis C has undergone a significant boom since the advent of direct acting antivirals (DAA). Indeed, the interferon-ribavirin combination that has been used to treat hepatitis C has a virological response in only 45% of cases with significant side effects. The advent of direct-acting antivirals has changed the prognosis of cirrhotic patients with hepatitis C. DAAs have ensured a sustained viral response in the majority of patients. Our work aims to see the evolution of hepatitis C patients at the cirrhosis stage under DAA. We conducted a retrospective study over 15 years (January 2009, January 2024) including all patients with post-viral cirrhosis C, whom we divided into two groups: group A, cirrhotic patients who received ribavirin and interferon, and group B, patients on DAA. From January 2009 to January 2024, we conducted a study of 182 patients with viral hepatitis C, including 102 cirrhotic patients. The mean age was 55 years. 66% of patients were initially treated with the ribavirin interferon combination, while 34% received direct-acting antivirals (DAAs). Since the introduction of DAAs, the most commonly used regimens have been sofosbuvir/daclatasvir with or without ribavirin and sofosbuvir/ledipasvir with or without ribavirin. Group A achieved sustained virological response (SVR) in 60% of cases, with notable side effects. In Group B, SVR was 98.18%, with improved tolerability and fewer side effects than previous treatments. Fifteen patients developed hepatocellular carcinoma (HCC), with a significantly lower mortality rate in those treated with DAAs compared with pegylated dual therapy (p: 0.001).

关键词： Post-Viral Cirrhosis C Pegylated Interferon Direct Acting Antivirals Sustained Viral Response Child Score Fibrosis

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E-fuel system: a conceptual breakthrough for energy storage

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Science Bulletin 2019年第4期64卷 227-228页

作者： Khalil amine Chemical Sciences and Engineering Division Argonne National Laboratory

The demand for renewables such as solar and wind power has become stronger than ever in the past few decades and their numerous advantages have nearly risen to the status of common knowledge. However, as solar and wind power are intermittent in nature, the electricity generated from these renewable sources only comprise a low fraction of global electricity production. Enabling the widespread use of renewables requires energy storage technology that is site-independent, efficient, scalable, stable, cost-effective, safe, energy dense and continuous in operation. To date, none of the existing technologies have adequately met the attributes necessary for storing intermittent and scattered solar, wind and other sources of renewable energy. Pumped hydro and compressed air are scalable and cost-effective, but are limited by geography and geology [1].

关键词： demand technologies attributes

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An energy-degree evaluation metric for clustering purposes in mobile ad hoc networks

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International Journal of Modeling, Simulation, and Scientific Computing 2019年第2期10卷 114-132页

作者： Khalil amine MOAD6 Research Team MASI LaboratoryE3S Research Centre Mohammadia School of Engineering Mohammed V University of RabatMorocco

Network clustering is the process of partitioning a network into a number of virtual entities mastered by certain nodes,called cluster centers that are responsible for collecting and maintaining topology information and managing the routing *** ad hoc networking,clustering has been introduced to deal with the dynamic topology by providing a temporarily stable network *** process mainly depends on the metric upon which the selection of cluster centers is performed.A wide range of clustering metrics were introduced in the literature based on network issues including mobility and connectivity degree,giving rise to a variety of clustering *** clustering provides energy consumption reduction,residual energy has not received enough attention and few studies have addressed the clustering on the basis of this *** paper discusses the current clustering metrics and proposes an energy-degree evaluation metric with mobility consideration taking into account the nodes residual energy and the network connectivity as two main keys of clustering.

关键词： Ad hoc networks clustering dominating set energy aware mobility

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Stability analysis of an SIR epidemic model with homestead-isolation on the susceptible and infectious,immunity,relapse and general incidence rate

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生物数学学报:英文版 2023年第5期16卷 1-22页

作者： amine Bernoussi Equations au dérivees partielles Algebre et Géométrie spectrales Department of MathematicsFaculty of ScienceIbn Tofail University BP 13314000 KenitraMorocco

In this paper,we propose the global dynamics of an SIR epidemic model with distributed latent period,immunity,relapse,homestead-isolation of the susceptible and infectious individuals and general incidence *** resulting model has a disease-free equilibrium and if Ro>1,then the SIR epidemic model admits a unique endemic *** using suitable Lyapunov functionals and LaSalle's invariance principle,the global stability of the disease-free equilibrium and the endemic equilibrium is established,under suitable monotonicity conditions on the incidence function.

关键词： An SIR epidemic model homestead-isolation on the susceptible and infectious Lyapunov function LaSalle's invariance principle global stability.

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Dunbar Syndrome and Hypoxic Hepatitis: An Unusual Presentation

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Open Journal of Gastroenterology 2024年第6期14卷 226-232页

作者： Hajar Cherkaoui Ismail Chaouech Yousra El Abidi Haroun Robleh Asmae Lamine Maria Lahlali Nada Lahmidani amine Mekkaoui Mounia Elyousfi Dafr Allah Benajah Adil Ibrahimi Mohammed El Abkari Nizar Bouardi Mohammed Maaroufi Hakima Abid Department of Gastroenterology University Hospital Hassan II Fez Morocco Faculty of Medicine and Pharmacy Fez Morocco Department of Radiology University Hospital Hassan II Fez Morocco

Hypoxic hepatitis, also known as ischemic hepatitis, is characterized by acute hepatocellular injury due to inadequate oxygen delivery to the liver. Celiac trunk stenosis can lead to hepatic ischemia and subsequent liver damage. We present the case of an 81-year-old patient with a history of hypertension, ischemic heart disease, hypothyroidism, and biliary lithiasis, who developed hypoxic hepatitis secondary to Dunbar syndrome and a stenosis of the superior mesenteric artery. The patient improved symptoms and liver function tests with conservative management, including intravenous fluids and supportive care. Long-term management involved continued antiplatelet therapy and statins, with consideration of further interventions for celiac trunk stenosis. This case underscores the importance of recognizing Dunbar syndrome as well as superior mesentery trunk stenosis as a potential cause of hypoxic hepatitis. It highlights the need for multidisciplinary management in such cases.

关键词： Dunbar Syndrome Hypoxic Hepatitis Stenosis of Mesentery Artery

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