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Experimental study and numerical modeling of the thermal behavior of an industrial prototype ceramic furnace:Energy and environmental optimization

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Energy and Built Environment 2024年第2期5卷 244-254页

作者： lahcen balli Mohamed HLIMI Youssef ACHENANI Adil ATIFI Bachir HAMRI Engineering Sciences and Applications Laboratory(LSIA) National School of Applied Sciences(ENSAH)Abdelmalek Essaadi UniversityTetouanMorocco Faculty of Sciences and Techniques Moulay Ismaïl UniversityP.O.Box 509-BoutalamineErrachidiaMorocco Engineering and Health Sciences and Technologies Research Center M2SMENSAMMohammed.V UniversityRabatMorocco Research Team Quality Maintenance Safety QSMMechanical EngineeringDepartment Mohammadia School of EngineersMohammed V UniversityRabatMorocco

This article focuses on the experimental and numerical study of an industrial prototype furnace intended for the production of ceramics in order to improve the energy efficiency and therefore optimize the fuel consumption and the corresponding carbon dioxide *** order to understand the thermal behavior from which stems the energy efficiency of the experimental prototype,we establish in this work,a simplified modeling allowing to establish a mathematical model describing the thermal behavior of the *** model is able to accurately predict the spatial and temporal distribution of the temperature at each point of the furnace to control the firing of the refractory product so that the final product is of good quality in terms of resistance and *** addition,the power consumed by the prototype must be optimized in order to reduce energy and environmental *** particular,this efficient technology has allowed us to save 83% of energy used in the traditional furnace and to reduce 87.36% of the relative carbon dioxide *** simulation of the mathematical model made it possible to compare the numerical results with the experimental measurements obtained by the prototype as well as to validate the model and to adjust the heat transfer parameters.

关键词： Numerical modeling Thermal behavior Ceramic furnace Refractory materials Energy efficiency

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Determination of Latent Heats of Vaporization and Fusion

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Advances in Chemical Engineering and Science 2024年第3期14卷 113-124页

作者： Lahbib Abbas lahcen Bih Khalid Yamni Abderrahim Elyahyaouy Abdelmalik El Attaoui Zahra Ramzi Chemistry Department Faculty of Science and Technology Moulay Ismail University Meknes Er-Rachidia Morocco Engineering Sciences and Professions Laboratory National School of Arts and Crafts Moulay Ismail University Meknes Meknes Morocco Materials Membranes and Nanotechnology Chemistry Department Faculty of Sciences Moulay Ismail University Meknes Zitoune Mekns Morocco Physics Department Faculty of Sciences Ibn Tofail University Kenitra Morocco Laboratory of Molecular Chemistry Materials and Environment (LCM2E) Multidisciplinary Faculty of Nador Mohamed 1st University Oujda Nador Morocco Laboratory of SCiMATOP Chemistry Department Faculty of Sciences Semlalia Cadi Ayyad University Marrakech Morocco

Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporization temperatures are very high for a liquid that is neither ionic nor metallic, and whose molar mass is low. Thus, water remains liquid at atmospheric pressure up to 100C while similar molecules such as H2S, H2Se, H2Te for example would give a vaporization temperature close to 80C. This cohesion is in fact ensured by hydrogen bonds between water molecules. This type of bonds between neighboring molecules, hydrogen bonds, is quite often found in chemistry [1] [2]. Any change in the state of aggregation of a substance occurs with the absorption or release of a certain amount of latent heat of transformation. Latent heat of fusion, vaporization or sublimation is the ratio of the energy supplied as heat to the mass of the substance that is melted, vaporized or sublimated. As a result of the reversibility of the processes, the fusion heat is equal to the heat released in the reverse process: crystallization and solidification heat. And likewise the heat of vaporization is equal to the heat of condensation. This equality of heat is often used to determine experimentally either of these quantities. There are two main measurement methods: 1) Direct measurement using the calorimeter, 2) Indirect measure based on the use of the VantHoff relationship. The objective of this work is to measure the latent heat of water vaporization and verify the compatibility of the experimental values with the values given by the tables using the indirect method.

关键词： Latent Heat of Vaporization Latent Heat of Fusion Calorimetry Relationship of Vant’Hoff

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Graphite Carbone Structure

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Crystal Structure Theory and Applications 2024年第1期12卷 1-10页

作者： Lahbib Abbas lahcen Bih Khalid Yamni Abderrahim Elyahyaouy Abdelmalik El Attaoui Zahra Ramzi Materials Membranes and Nanotechnology Laboratory Faculty of Science and Technology Moulay Ismail University Errachidia Morocco Engineering Sciences and Professions Laboratory National School of Arts and Crafts Moulay Ismail University Meknes Morocco Materials Membranes and Nanotechnology Laboratory Chemistry Department Faculty of Sciences Moulay Ismail Univer-sity Meknes Morocco Physics Department Faculty of Sciences Ibn Tofail University Kenitra Morocco Laboratory of Molecular Chemistry Materials and Environment (LCM2E) Multidisciplinary Faculty of Nador Mohamed 1st University Nador Morocco Laboratory of SCiMATOP Chemistry Department Faculty of Sciences Semlalia Cadi Ayyad University Marrakech Morocco

Carbon graphite is a crystalline form of carbon consisting of layers of hexagonal carbon atoms arranged in a two-dimensional “graphene” structure. Graphene layers are stacked on top of each other, forming a three-dimensional structure with a high degree of anisotropy. The carbon atoms within each layer are linked together by strong covalent bonds, creating a strong, stable lattice structure. However, the layers themselves are held together by weak van der Waals forces, enabling them to slide easily over each other. The properties of carbon graphite are highly dependent on the orientation and alignment of the graphene layers. When the layers are aligned parallel to each other, the material exhibits high strength and stiffness along the alignment direction, but is weaker and more flexible in other directions. Carbon graphite is used in a variety of applications where high strength, rigidity and electrical conductivity are required. Some common applications include electrical contacts, electric motor brushes, and as a structural material in aerospace and defense applications. The aim of our work is to describe the structure of graphite, its physical and chemical properties and its applications.

关键词： Graphite Graphene Hexagonal Structure Hardness Rigidity Electrical Con-ductivity

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Systematic Method for Constructing Lewis Representations

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Open Journal of Inorganic Chemistry 2024年第1期14卷 1-18页

作者： Lahbib Abbas lahcen Bih Khalid Yamni Abderrahim Elyahyaouy Abdelmalik El Attaoui Zahra Ramzi Materials Membranes and Nanotechnology Faculty of Science and Technology Moulay Ismail University Meknes Er-Rachidia Morocco Engineering Sciences and Professions Laboratory National School of Arts and Crafts Moulay Ismail University Meknes Meknes Morocco Materials Membranes and Nanotechnology Chemistry Department Faculty of Sciences Moulay Ismail University Meknes Meknes Morocco Physics Department Faculty of Sciences Ibn Tofail University Kenitra Morocco Laboratory of Molecular Chemistry Materials and Environment (LCM2E) Multidisciplinary Faculty of Nador Mohamed 1st University Oujda Nador Morocco Laboratory of SCiMATOP Chemistry Department Faculty of Sciences Semlalia Cadi Ayyad University Marrakech Morocco

The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bond. Using a number of rules in a defined order, it is often better suited to complicated cases than the Lewis representation of atoms. This method allows us to determine the formal charge and oxidation number of each atom in the edifice more efficiently than other methods.

关键词： Systematic Method Lewis Representation Chemical Bond Formal Charge Oxidation Number

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Output stabilization of distributed bilinear systems

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Control Theory and Technology 2018年第1期16卷 58-71页

作者： EI Hassan ZERRIK lahcen EZZAKI MACS Laboratory Faculty of Sciences Moulay Ismail University Meknes 50000 Morocco

This paper studies regional stabilization of a distributed bilinear system evolving on a spatial domain Ω. Sufficient conditions for regional weak, strong and exponential stabilization are given. Also we discuss a re... 详细信息

关键词： Distributed bilinear systems stabilization regional stabilization

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Analysis of symbiotic microbial status of Atlantic sand dunes forest and its effects on Acacia gummifera and Retama monosperma(Fabaceae)to be used in reforestation

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Journal of Forestry Research 2020年第4期31卷 1309-1317页

作者： Abdessamad Fakhech lahcen Ouahmane Mohamed Hafidi Laboratoire Ecologie et Environnement(Unité Associée au CNRST URAC 32)Facultédes Sciences SemlaliaUniversité Cadi AyyadBP 2390MarrakeshMorocco Agrobiosciences Program University Mohammed VI Polytechnic(UM6P)BenguerirMorocco

Atlantic forest natural soil flora was tested on two leguminous pioneer species Acacia gummifera and Retama monosperma to be used in rehabilitation programs of the coastal sand dunes forest of the Essaouira *** rhizospheric soil of two endemic plant species:*** and Juniperus phoenicea was sampled and split into two categories,one from native rhizospheric soil,the other of the sterilized rhizospheric *** was focused on mycorrhizal formations,but other forms of beneficial symbiosis such as rhizobia and viable soil microflora were also *** and nutrition variables assessed included lengths of roots and shoots,number of branches,ratio of root to shoot dry mass and water,nitrogen and phosphorus *** showed important mycorrhizal associations in roots of both plants,presence of nodules and abundance of viable soil *** had a 100%frequency of mycorrhizal formation and an intensity of 80%compared to a frequency of 80%and intensity of 54%for *** had the same density of CFU regardless of the *** of viable microflora in rhisospheric soil of ***,*** and the control differed *** the studied variables for *** and ***,nitrogen and phosphorus uptakes significantly wit the use of the nonsterilized rhizospheric *** species doubled their phosphorus uptake when colonized by mycorrhizal species,*** doubled its nitrogen uptake and *** increased it by seven times compared with the *** significant difference was noted for the other variables.

关键词： Nitrogen Phosphorus Juniperus phoenicea Acacia gummifera Retama monosperma Mycorrhizae Rhizobia

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Valorization of mining waste and tailings through paste backfilling solution, Imiter operation, Morocco

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International Journal of Mining Science and Technology 2016年第3期26卷 511-516页

作者： Khaldoun Abdelhadi Ouadif Latifa Baba Khadija Bahi lahcen Mohammadia Engineering School Mohammed V University

Mine waste and process tailings storage is one of important challenge for which mining operations are increasingly confronted. Treatment discharges of plants and main part of waste rock development are generally stored on surface areas. The volume and chemical characteristics of these materials generate serious problem for required storage spaces and mainly environmental degradation. Paste backfill(PBF) is one of ingenious solutions to minimize the quantity of tailings to store. PBF is basically defined as a combination of mine processing tailings, binder, and water mixing. The purpose of this paper is to present backfilling components characterization and formula verification for a waste valorization solution through paste backfilling technology in Imiter operation. Obtained results and realized analysis demonstrate PBF conformity and adequacy with assigned underground functions. However the studied recipe can be more ameliorated to obtain an optimal mixture ensuring the required mechanical strength.

关键词： Mining waste Process tailings Valorization Paste backfill Uni-axial compressive strength

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Comparing growth and fine root distribution in monocultures and mixed plantations of hybrid poplar and spruce

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Journal of Forestry Research 2013年第2期24卷 247-254页

作者： lahcen Benomar Annie DesRochers Guy R. Larocque Chaire industrielle CRSNG-UQAT-UQAM en aménagement forestier durable. Université du Québec en Abitibi-Témiscamingue Natural Resources Canada Laurentian Forestry Centre

Disease prevention, biodiversity, productivity improvement and ecological considerations are all factors that contribute to increasing interest in mixed plantations. The objective of this study was to evaluate early growth and productivity of two hybrid poplar clones, P. balsamifera x trichocarpa （PBT） and P. maximowiczii x balsamifera （PMB）, one improved family of Norway spruce （Picea glauca （PA）） and one improved family of white spruce （Picea abies （PG）） growing under different spacings in monocultures and mixed plots. The plantations were established in 2003 in Abitibi-Témiscamingue, Quebec, Canada, in a split plot design with spacing as the whole plot factor （1 × 1 m, 3 × 3 m and 5 × 5 m） and mixture treatments as subplot factor （pure： PBT, PMB, PA and PG, and 1：1 mixture PBT：PA, PBT：PG, PMB：PA and PMB：PG）. Results showed a beneficial effect of the hybrid poplar-spruce mixture on diameter growth for hybrid poplar clones, but not for the 5 × 5 m spacing because of the relatively young age of the plantations. Diameter growth of the spruces decreased in mixed plantings in the 1 × 1 m, while their height growth increased, resulting in similar aboveground biomass per tree across treatments. Because of the large size differences between spruces and poplars, aboveground biomass in the mixed plantings was generally less than that in pure poplar plots. Leaf nitrogen concentration for the two spruce families and hybrid poplar clone PMB was greater in mixed plots than in monocultures, while leaf nitrogen concentration of clone PBT was similar among mixture treatments. Because of its faster growth rate and greater soil resources demands, clone PMB was the only one showing an increase in leaf N with increased spacing between trees. Fine roots density was greater for both hybrid poplars than spruces. The vertical distribution of fine roots was insensitive to mixture treatment.

关键词： Picea glauca Populus balsamifera × trichocarpa P. maximowiczii × balsamifera mixed-species monoculture spacing fine root

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Breaking seed dormancy in Cupressus atlantica Gaussen,an endemicand threatened coniferous tree in Morocco

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Journal of Forestry Research 2012年第3期23卷 385-390页

作者： Sfairi Youssef Ouahmane lahcen Abbad Abdelaziz Direction Provinciale des Eaux et Forets et de la lutte contre laDésertification MarrakechMaroc Laboratoire de Biotechnologies Protection et Valorisation des Ressources Végétalesdépartement deBiologieEquipe de Phytochimie et Pharmacologie des Plantes Aromatiques et MédicinalesFacultédes Sciences SemlaliaUniversitéCadi AyyadMarrakechMaroc Centre Régional de Recherche Forestière Circuit de la PalmeraieMarrakechMaroc Laboratoire de Biotechnologies Protection et Valorisation desRessources Végétalesdépartement de BiologieEquipe de Phytochimieet Pharmacologie des Plantes Aromatiques et MédicinalesFacultédesSciences SemlaliaUniversitéCadi AyyadMarrakechMaroc

Cupressus atlantica Gaussen （Cupressaceae） is an endemic and endangered coniferous tree geographically restricted to the N＇Fis valley in South-Western Morocco. Like many forest species, C. atlantica exhibits dormancy which delays and reduces germination. To improve seed germination, different pre-treatments were conducted on C. atlantica seeds after storage for different periods （one, two and five years） including： scarification with sandy paper; soaking seeds in hot distilled water at 60℃ and 80℃ for 15 min and soaking seeds for 48 h in a gibberellic acid （GA3） at 1,000 and 2,000 mg·L-1. Results showed that scarification with sandy paper increased the germination rate of Atlas cypress by up to 67%, indicating that the species possess essentially an exogenous dormancy （physical dormancy） due to the hard seed coat （hardseededness）. Exogenous application of gibberellic acid （GA3） at 1,000 mg.L-1 was also effective in breaking seed dormancy and germination induction. These two treatments induced faster speed germination expressed by low number of days to first germination （8-10 days） and low values of mean germination times （MGT）. However, germination rate, under any treatment, is greatly dependent on the year of seed collection. Seeds collected in year 2004 gave the highest value, suggesting that even after five years of storage, the germination capacity of C. atlantica seeds could remain high. This observation is very interesting in the ex-situ conservation of such endemic and endangered species where the production of seeds is irregular over the years.

关键词： Cupressus atlantica endemic endangered breaking seed dormancy germination capacity hand scarification ex-situ conservation

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Characterization and photoluminescence properties of ultrafine copper molybdate(α-CuMoO_4) powders prepared via a combustion-like process

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International Journal of Minerals,Metallurgy and Materials 2016年第11期23卷 1340-1345页

作者： Mohamed Benchikhi Rachida El Ouatib Sophie Guillemet-Fritsch lahcen Er-Rakho Bernard Durand Laboratoire de Physico-Chimie des Matériaux Inorganiques Faculté des Sciences Ain Chock Université Hassan Ⅱ Casablanca Institut Carnot CIRIMAT CNRS Université de Toulouse

We report a simple method for preparing copper（II） molybdate（CuMoO_4） powders via a combustion-like process. A gel was first prepared by the polymerizable complex method, where citric acid was used as a complexing and polymerizing agent and nitric acid was used as an oxidizing agent. The thermal decomposition behavior of the（CuMo）-precursor gel was studied by thermogravimetry–differential thermal analysis（TG–DTA）, Fourier transform infrared spectroscopy（FTIR）, and X-ray diffraction（XRD）. We observed that the crystallization of CuMoO_4 powder was completed at 450°C. The obtained homogeneous powder was composed of grains with sizes in the range from 150 to 500 nm and exhibited a specific surface area of approximately 5 m^2/g. The average grain size increased with increasing annealing temperature. The as-prepared CuMoO_4 crystals showed a strong green photoluminescence emission at room temperature under excitation at 290 nm, which we mainly interpreted on the basis of the Jahn-Teller effect on [MoO_4^（2-）] complex anions. We also observed that the photoluminescence intensity increased with increasing crystallite size.

关键词： copper molybdate chemical synthesis photoluminescence Jahn-Teller effect

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