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Journal of Materials Science & Technology 2022年第24期119卷 11-24页

作者： W.l.wang W.q.liu X.Yang R.R.Xu q.Y.Dai School of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an 710055China

A model of coupling macro finite volume method(FVM) and cellular automata(CA) is proposed in this paper to explore the columnar-to-equiaxed transition(CET) during selective laser melting(SlM) of rare earth magnesium *** into account the impact of recoil pressure and Marangoni convection on the molten pool temperature field,the grain structure is *** suggested by the simulation results,with the undissolved Zr serving as heterogeneous nucleation sites,the liquid undercooled layer under the combined action of forced cooling,the temperature gradient and the liquid solute concentration gradient leads to *** considering the dissolution of Zr in magnesium matrix,the results demonstrate that the dissolution of element Zr is effective in significantly inhibiting the growth of columnar crystals and ensuring the sufficient constitutional supercooling(CS) required for *** addition,to raise the preheating temperature contributes to enhancing the outcome of nucleation and incresing the grain *** the interdependence model(IM),with the cooling rate gradually increasing in the SlM process of magnesium alloy,the nucleation-free zone(NFZ) reduces by decreasing the solute diffusion layer in the front of the solid/liquid(Sl) interface and the temperature *** reduction in temperature gradient can promote undercooling for nucleation and facilitate the development of equiaxed *** simulation results are qualitatively verified as highly consistent through experimentation.

关键词： Multi-scale simulation Columnar-to-equiaxed transition Selective laser melting Rare earth magnesium alloy Constitutional supercooling

Oxygen and Nitrogen Effects on MC Carbide in K465 Nickel-Base Superalloy

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稀有金属材料与工程 2009年第A03期38卷 13-16页

作者： wang l N Zheng q Sun X F Guan H R Hu Z q Institute of Metals Research Chinese Academy of Sciences Shenyang 110015 China

Effects of oxygen and nitrogen on MC carbide in nickel-base superalloy K465 were investigated, because neither of the two gas elements was found to decide MC carbide morphology monotonically. The morphology of MC carbide under alloy solidified in conventional investment casting condition was observed to transform from script-type to block-type with the total oxygen and nitrogen content (gas content) in samples rising up from 1.2×10-6 mol/g to 2.6×10-6 mol/g. The area fraction and composition of the MC carbide also varied with increase of gas content. However, the morphology of MC carbide kept to be script-type even when gas content was up to 3.4×10-6 mol/g in samples solidified with a much higher cooling rate. These results indicate that effects of gas content on formation of MC carbide can be observed in specimens solidified with low cooling rate, but such changes in MC carbide cannot be found when the cooling rate is high.

关键词：氧碳化物氮含量物理性能碳化物

Basic features of the multiscale interaction between tearing modes and slab ion-temperature-gradient modes

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Chinese Physics B 2019年第12期28卷 237-247页

作者： l Wei Z X wang J q li Z q Hu Y Kishimoto Key laboratory of Materials Modification by laser Ionand Electron Beams(Ministry of Education)School of PhysicsDalian University of TechnologyDalian 116024China Southwestern Institute of Physics Chengdu 610041China Graduate School of Energy Science Kyoto UniversityGokashoUjiKyoto 1-0011Japan

Nonlinear interaction between tearing modes(TM) and slab ion-temperature-gradient(ITG) modes is numerically investigated by using a landau fluid model. It is observed that the energy spectra with respect to wavenumbers become broader during the transition phase from the ITG-dominated stage to TM-dominated stage. Accompanied with the fast growth of the magnetic island, the frequency of TM/ITG with long/short wavelength fluctuations in the electron/ion diamagnetic direction decreases/increases respectively. The decrease of TM frequency is identified to result from the effect of the profile flattening in the vicinity of the magnetic island, while the increase of the frequencies of ITG fluctuations is due to the eigenmode transition of ITG induced by the large scale zonal flow and zonal current related to TM. Roles of zonal current induced by the ITG fluctuations in the instability of TM are also analyzed. Finally, the electromagnetic transport features in the vicinity of the magnetic island are discussed.

关键词： magnetic reconnection tearing modes magnetohydrodynamics drift waves nonlinear phenomena

Stochastic averaging of quasi integrable and resonant Hamiltonian systems excited by fractional Gaussian noise with Hurst index 1/2

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Acta Mechanica Solida Sinica 2017年第1期30卷 11-19页

作者： q.F.lü M.l.Deng W.q.Zhu Department of Mechanics State Key Laboratory of Fluid Power and Mechatronic SystemsKey Laboratory of Soft Machines and Smart Devices of Zhejiang ProvinceZhejiang University

A stochastic averaging method of quasi integrable and resonant Hamiltonian systems under excitation of fractional Gaussian noise （fGn） with the Hurst index 1/2 〈 H 〈 1 is proposed. First, the definition and the basic property of fGn and related fractional Brownian motion （iBm） are briefly introduced. Then, the averaged fractional stochastic differential equations （SDEs） for the first integrals and combinations of angle variables of the associated Hamiltonian systems are derived. The stationary probability density and statistics of the original systems are then obtained approximately by simulating the averaged SDEs numerically. An example is worked out to illustrate the proposed stochastic averaging method. It is shown that the results obtained by using the proposed stochastic averaging method and those from digital simulation of original system agree well.

关键词： quasi integrable and resonant Hamiltonian system Fractional Brownian motion Fractional Gaussian noise Stochastic averaging method Internal resonant

Precipitation of multi-type nano-quasicrystals in a Mg-Zn-Y alloy

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Journal of Magnesium and Alloys 2024年第3期12卷 997-1008页

作者： W.Z.wang X.Z.Zhou l.F.Zhang H.q.Ye Z.q.Yang Shenyang National laboratory for Materials Science Institute of Metal ResearchChinese Academy of ScienceShenyang 110016China Ji Hua laboratory Foshan 528251China Foshan University Foshan 528231China

Mg-6Zn-1Y(at.%)ribbons with strengthening precipitates of multi-type nanoquasicrystals were prepared by melt-spinning followed by aging *** evolution of the rapidly solidified ribbons during isothermal aging was comprehensively studied using various electron microscopy *** new kinds of decagonal quasicrystals were formed in aged ribbons,in addition to precipitation of nanometer icosahedral ***-resolution observations reveal that both decagonal quasicrystals can be modeled by quasiperiodic tiling with decagonal clusters of 2.5 nm in diameter,but overlap of neighboring clusters in both decagonal quasicrystals is different from the Gummelt model observed in other quasicrystals.A shell composed of complex laves Mg-Zn domains was formed surrounding each decagonal quasicrystal precipitate upon prolonged *** addition,all kinds of nanoprecipitates exhibit excellent structure and size stability at 573 *** findings may have implications for not only fundamental studies about quasicrystals,but also microstructural manipulation of high-performance Mg alloys.

关键词： quasicrystal Mg alloys Rapid solidification Scanning-transmission electron microscopy.

Effect and mechanism of coking residual ammonia water treating by flue gas

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Journal of Environmental Sciences 2001年第2期13卷 237-246页

作者： Z J Cheng G J Yin l q Yang W wang D D Cheng Environmental Protection Research Institute Central Research Institute of Building and Construction Ministry of Metallurgical Industry Beijing 100088 China.

The treatment of coking residual ammonia water has been a big difficult problem at home and abroad, and there is no breakthrough research achievement in the past. The invention patent "The method of treating all coking wastewater or treating coking residual ammonia water by flue gas" has been successfully used in Huaian Steel Works for high concentration and organic industry wastewater treatment. Not only can it realize the wastewater zero discharge, but also the wastewater treatment has an effect of de-sulfur and de-nitrogen for flue gas. So that the flue gas exhaust can meet the requirement of emission standard. The mass transfer and heat transfer, fly ash absorption and coagulation, acid and alkali neutralization reaction, catalysis oxidation and reduction reaction in flue gas would be the major factors.

关键词： Effect and mechanism of coking residual ammonia water

Synthesis and Room Temperature Ferromagnetism of Flower-shaped Mn Doped ZnO Nanostructures

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Journal of Materials Science & Technology 2011年第6期27卷 513-517页

作者： Y.q. Chang P.W. wang R.H. Tang q.l. Sun Y. long School of Materials Science and Engineering University of Science and Technology Beijing Beijing 100083 China Department of Physics National Key Laboratory of Mesoscopic Physics Peking University Beijing 100871 China

large-scale flower-shaped Mn doped ZnO nanostructures have been grown on silicon substrates by simple thermal evaporation at atmospheric *** flower-shaped nanostructure makes up of many nanorods,which are rooted in one *** of X-ray diffraction,high-resolution transmission electron microscopy and Raman spectra results reveal that the products are of single phase with wurtzite *** mapping results show that no impurity clusters exist in the doped *** photoluminescence spectra demonstrate that many oxygen vacancies exist in the doped materials,and the crystal quality is improved and the content of oxygen vacancies is decreased by annealing *** flower-shaped Mn doped ZnO nanostructures exhibit ferromagnetic ordering above room temperature,and its magnetization is decreased by the annealing treatment,which indicates that the magnetic behavior of the doped materials may be related to the interaction between Mn doping and the oxygen vacancies.

关键词： Mn doped ZnO nanomaterials Ferromagnetism Annealing treatment Chemical vapor deposition

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： Yong Hou Shuo Zhang Jie Dang Jia Guo Hanghang Zhou Xuewei lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(q^(3))/X_(q^(2))(X_(q^(i))is the molar fraction of q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy

Effect of grain size on fatigue cracking at twin boundaries in a CoCrFeMnNi high-entropy alloy

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Journal of Materials Science & Technology 2020年第4期39卷 1-6页

作者： A.G.wang X.H.An J.Gu X.G.wang l.l.li W.l.li M.Song q.q.Duan Z.F.Zhang X.Z.liao School of Aerospace Mechanical&Mechatronic EngineeringThe University of Sydne0ySydneyAustralia State Key laboratory of Powder Metallurgy Central South UniversityChangsha 410083China Materials Fatigue and Fracture Division Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Max-Planck-Institut für Eisenforschung Max-Planck-Stra?e 140237 DüsseldorfGermany

The fatigue cracking behavior at twin boundaries(TBs)in a Co Cr Fe Mn Ni high-entropy alloy with three different grain sizes was systematically investigated under low-cycle *** of grain size,the change from slip band cracking to TB cracking occurred with increasing the difference in the Schmid factors(DSF)between matrix and ***,the required critical DSF for the transition of the dominant cracking mode decreases with decreasing grain size due to the reduced slip band spacing that increases the impingement sites on the TBs and facilitates the coalescence of defects and voids to initiate TB cracks.

关键词： High-entropy alloy Fatigue cracking Twin boundary Slip band Grain size

Reliability of quasi integrable and non-resonant Hamiltonian systems under fractional Gaussian noise excitation

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Acta Mechanica Sinica 2020年第4期36卷 902-909页

作者： q.F.lu W.q.Zhu M.l.Deng Department of Mechanics State-Key Laboratory of Fluid Power and Mechatronic SystemsZhejiang UniversityHangzhou 310027China

The reliability of quasi integrable and non-resonant Hamiltonian system under fractional Gaussian noise(fGn)excitation is *** rather flat fGn power spectral density(PSD)in most part of frequency band,the fGn is innovatively regarded as a wide-band ***,the stochastic averaging method for quasi integrable Hamiltonian systems under wide-band noise excitation is applied to reduce 2n-dimensional original system into n-dimensional averaged ltd stochastic differential equations(SDEs).Reliability function and mean first passage time are obtained by solving the associated backward Kolmogorov equation and Pontryagin *** validity of the proposed procedure is tested by applying it to an example and comparing the numerical results with those from Monte Carlo simulation.

关键词： Reliability Fkst passage time quasi integrable and non-resonant Hamiltonian systems Fractional Gauss noise