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Effect of surface layer softening from previous electrochemical corrosion on electrochemical cold drawing of Q235 steel.b.r

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Journal of Iron and Steel Research International 2022年第5期29卷 819-835页

作者： J.l.Guo T.J.chen State Key l.b.ratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou730050GansuChina

The effects of H_(2)SO_(4)concentration and current in electrochemical corrosion on surface layer softening or plasticizing of Q235 steel.b.r and their effects on subsequent electrochemical cold drawing(ECD)were *** results indicate that the electrochemical corrosion can soften or plasticize the surface layer of Q235 steel.b.r and then make the subsequent ECD be conducted more *** softening degree and thickness of the surface layer are continuously enhanced with increasing corrosion rate,i.e.,increasing H_(2)SO_(4)concentration or current,due to the generation of more vacancy clusters in deeper regions of surface *** vacancy clusters then relax dislocations through being absorbed during ECD,and the formation and movement of additional dislocation flux are thereby enhanced,resulting in the further obvious decrease in the drawing *** is also due to the enhanced formation and movement of additional dislocation flux that the dislocation density and thus the hardness of the surface layer are decreased,as well as that the texture structure is *** behaviors are enhanced as the corrosion rate increases.

关键词： Electrochemical corrosion Electrochemical cold drawing Surface layer softening Vacancy Additional dislocation flux

Corrosion protection of NiNb metallic glass coatings for 316SS by magnetron sputtering

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Journal of Materials Science & Technology 2021年第20期79卷 88-98页

作者： l.Jiang Z.Q.chen H.b.lu H.b.Ke Y.Yuan Y.M.Dong X.K.Meng School of Chemistry and life Sciences Suzhou University of Science and TechnologySuzhou 215009China Institute of Materials Engineering National Laboratory of Solid State MicrostructuresCollege of Engineering and Applied SciencesNanjing UniversityNanjing 210009China Songshan lake Materials l.b.ratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China Institute of Materials Engineering Nanjing UniversityNantong 226019China College of Chemistry and Chemical Engineering Nantong UniversityNantong 226019China

Metallic glasses(MGs)appear as promising anti-corrosion coating materials due to their microstructural and physicochemical ***,we proposed magnetron sputtered NiNb thin film MG coatings(MGCs)with different structures and compositions for corrosion protection of 316 stainless steel in an aggressive saline *** properties of monolayered Ni_(50)Nb_(50) and Ni_(60)Nb_(40),as well as the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40)(at.%)MGCs,were characterized in terms of morphology and microstructural properties,as well as the anticorrosion *** the NiNb MGCs presented compact structure and the monolayered coatings exhibited preferable adhesion properties in comparison with the multilayered *** electrochemical tests and XPS results imply that the monolayered Ni_(50)Nb_(50) MGC with high Nb content resisted corrosion mainly due to the formation of stable passive film that contained abundant Nb_(2)O_(5) species,whereas the Ni_(60)Nb_(40) MGC with high Ni content showed week corrosion protection performance during long-term service due to the dissolution of Ni cations and the devastation of the coating *** with bit worse adhesion and more vulnerable Ni_(60)Nb_(40) layers,the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40) MGC possessed comparable corrosion resistance with the monolayered Ni_(50)Nb_(50) MG coating,which remained stable even after 32 days of *** performance should be ascribed to the combined eff;ect of the repassivation property for the sub-layers,the hindrance of propagation paths of micro-defects,and the obstruction of corrosive species by interfaces in the multilayered coating.

关键词： Magnetron sputtering NiNb Metallic glasses Multilayer Corrosion protection

EVOlUTION OF ROUGHNESS ON THE SURFACE OF A STRAINED ElASTIC MATERIAl DUE TO STRESS-DRIVEN SURFACE DIFFUSION

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Acta Mechanica Sinica 1994年第1期10卷 16-26页

作者： l.b.Freund Division of Engineering Brown University Providence RI 02912 USA

The free energy of a stressed crystal is assumed to consist of elastic strain energy and surface energy, and the chemical potential for surface diffusion at constant temperature is obtained under this assumption. A gradient in chemical potential results in diffusive mass transport along the surface. The result is applied in considering the phenomena of instability of a flat surface in a stressed material under fluctuations in surface shape, and the transient evolution of surface roughness due to an initial perturbation in the nearly flat free surface of the material, both under plane strain conditions.

关键词： elastic material surface energy diffusion

Orbitronics for energy-efficient magnetization switching

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Science China(Information Sciences) 2025年第1期68卷 398-399页

作者： Yuxuan YAO Daoqian ZHU Qingtao XIA Jianing lIANG Yuhao JIANG Zhiyang PENG Jiaxu lI chen XIAO Renyou XU Wenwen WANG Xiantao SHANG Shiyang lU Dapeng ZHU Hong-Xi lIU Kaihua CAO Weisheng ZHAO Fert beijing Institute School of Integrated Circuit Science and Engineering Beihang University National Key l.b.of Spintronics Institute of International Innovation Beihang University Qingdao Research Institute Beihang University Truth Memory Corporation

Spin-orbit torque （SOT）,as a promising writing method for magnetic random-access memory （MRAM）,has garnered widespread interest for over a decade [1].Heavy metals,such as β-W,have been broadly adopted as spin current sources,but suffer from phase change at a limited thickness,resulting in a dramatic reduction of the charge-tospin conversion efficiency θSH[2].The thickness limitation leads to stringent etching conditions and large distribution among devices,posing challenges for simultaneously satisfying SOT efficiency,etching-stop margins,and back-end-ofline （bEOl） compatibility.

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Sulfolane‑based Flame‑Retardant Electrolyte for High‑Voltage Sodium‑Ion batteries

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Nano-Micro letters 2025年第2期17卷 498-516页

作者： Xuanlong He Jie Peng Qingyun lin Meng li Weibin chen Pei liu Tao Huang Zhencheng Huang Yuying liu Jiaojiao Deng Shenghua Ye Xuming Yang Xiangzhong Ren Xiaoping Ouyang Jianhong liu biwei Xiao Jiangtao Hu Qianling Zhang Graphene Composite Research Center College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhen 518060People’s Republic of China Center of Electron Microscopy State Key Laboratory of Silicon and Advanced Semiconductor MaterialsSchool of Materials Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China GRINM(Guangdong)Research Institute for Advanced Materials and Technology FoshanGuangdong 528051People’s Republic of China College of Energy Engineering Zhejiang UniversityHangzhouZhejiang 310027People’s Republic of China School of Materials Science and Engineering Xiangtan UniversityXiangtan 411105People’s Republic of China Shenzhen Eigen-Equation Graphene Technology Co.ltd Shenzhen 518000People’s Republic of China

Sodium-ion batteries hold great promise as next-generation energy storage ***,the high instability of the electrode/electrolyte interphase during cycling has seriously hindered the development of *** particular,an unstable cathode–electrolyte interphase(CEI)leads to successive electrolyte side reactions,transition metal leaching and rapid capacity decay,which tends to be exacerbated under high-voltage ***,constructing dense and stable CEIs are crucial for high-performance *** work reports localized high-concentration electrolyte by incorporating a highly oxidation-resistant sulfolane solvent with non-solvent diluent 1H,1H,5H-octafluoropentyl-1,1,2,2-tetrafluoroethyl ether,which exhibited excellent oxidative stability and was able to form thin,dense and homogeneous *** excellent CEI enabled the O3-type layered oxide cathode NaNi_(1/3)Mn_(1/3)Fe_(1/3)O_(2)(NaNMF)to achieve stable cycling,with a capacity retention of 79.48%after 300 cycles at 1 C and 81.15%after 400 cycles at 2 C with a high charging voltage of 4.2 *** addition,its nonflammable nature enhances the safety of *** work provides a viable pathway for the application of sulfolane-based electrolytes on SIbs and the design of next-generation high-voltage electrolytes.

关键词： Sodium-ion batteries Sulfolane-based electrolyte High voltage layered oxide cathode Flame retardant

Mineralogy of the deep lower mantle in the presence of H2O

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National Science Review 2021年第4期8卷 21-28页

作者： Qingyang Hu Jin liu Jiuhua chen bingmin Yan Yue Meng Vitali b.Prakapenka Wendy l.Mao Ho-Kwang Mao Center for High Pressure Science and Technology Advanced Research(HPSTAR) Department of Geological Sciences Stanford University Center for Study of Matter under Extreme Conditions Department of Mechanical and Materials Engineering Florida International University High Pressure Coll.b.rative Access Team(HPCAT) X-ray Science Division Argonne National Laboratory Center for Advanced Radiation Sources University of Chicago

Understanding the mineralogy of the Earth's interior is a prerequisite for unravelling the evolution and dynamics of our planet. Here, we conducted high pressure-temperature experiments mimicking the conditions of the deep lower mantle（DlM, 1800–2890 km in depth） and observed surprising mineralogical transformations in the presence of water. Ferropericlase,（Mg,Fe）O, which is the most abundant oxide mineral in Earth, reacts with H;2;O to form a previously unknown（Mg,Fe）O;2;H;x;（x ≤ 1）phase. The（Mg,Fe）O;2;H;x;has a pyrite structure and it coexists with the dominant silicate phases,bridgmanite and post-perovskite. Depending on Mg content and geotherm temperatures, the transformation may occur at 1800 km for(Mg;0.6;Fe;0.4;)O or beyond 2300 km for(Mg;0.7;Fe;0.3;)O. The（Mg,Fe）O;2;H;x;is an oxygen excess phase that stores an excessive amount of oxygen beyond the charge balance of maximum cation valences(Mg;2+;, Fe;3+;and H;+;). This important phase has a number of far-reaching implications including extreme redox inhomogeneity, deep-oxygen reservoirs in the DlM and an internal source for modulating oxygen in the atmosphere.

关键词： lower mantle water-mantle interaction ferropericlase high pressure mantle mineralogy

Improved mechanical properties in titanium matrix composites reinforced with quasi-continuously networked graphene nanosheets and in-situ formed carbides

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Journal of Materials Science & Technology 2022年第1期96卷 85-93页

作者： Q.Yan b.chen l.Cao K.Y.liu S.li l.Jia K.Kondoh J.S.li State Key l.b.ratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China School of Materials Science and Engineering Xi’an University of TechnologyXi’an 710048China Joining and Welding Research Institution Osaka University11-1 MihogaokaIbarakiOsaka 567-0047Japan

In order to construct quasi-continuously networked reinforcement in titanium(Ti)matrix composites,in this study,Ti-6 Al-4 V spherical powders were uniformly coated with a graphene nanosheet(GNS)layer by high energy ball milling and then consolidated by spark plasma *** showed that the GNS layer on the powder surface inhibited continuous metallurgy bonding between powders during sintering,which led to the formation of quasi-networked hybrid reinforcement structure consisting of insitu Ti C and remained *** networked GNSs/Ti64 composite possessed noticeably higher tensile strength but similar ductility to the Ti64 alloy,leading to both better tensile strength and ductility than the GNSs/Ti composite with randomly dispersed GNSs and Ti *** formation mechanism and the fracture mechanism of the networked hybrid reinforcement were *** results provided a method to fabricate Ti matrix composites with high strength and good ductility.

关键词： Titanium matrix composites(TMCs) Graphene Network structure Strength Ductility

Effect of anti-fibrosis compound on collagen expression of hepatic cells in experimental liver fibrosis of rats

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World Journal of Gastroenterology 2000年第6期6卷 877-880页

作者： Wang lT Zhang b chen JJ Shanghai TCM Univ Shuguang Hosp Dept Hepatopathy Shanghai 200021 Peoples R China

INTRODUCTIONliver fibrosis is mainly characterized by theexcessive synthesis and decreased degradation ofextracellular matrix(ECM),especially the synthesisand deposition of *** all kinds of cellsin the liver have part... 详细信息

关键词： liver cirrhosis collagen hepatic stellate cells immunohistochemistry antifibrosis complex prescription rats

Crystal Structure of 5-(l-Menthyloxy)-3-bromo-4-(R)-(+)-Methylbenzylamino-2(5H)-Furanone

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Chinese Journal of Structural Chemistry 1999年第2期18卷 32-34页

作者： Geng, Z Huang, b chen, QH Capital Normal Univ Dept Chem Beijing 100037 Peoples R China beijing Normal Univ Dept Chem Beijing 100875 Peoples R China

The crystal structure of the title compound 1, C 22 H 30 brNO 3, was determined by X ray analysis at 296(1)K. The crystal.b.longs to othorhombic system, space group P2 12 12 1 with a=9.842(5), b=12.510(5), c=17.763(6) , V=2187(3)  3, Z=4, M r=436.37, D x =1.33 g/cm 3, μ =18.79 cm 1 , F(000) =912 and the final R=0.047 and R w=0.053 for 1429 observed reflections with I≥3σ(I). Structure analysis reveals that the absolute configuration at C 14 of the acetal carbon of the title compound is S.

关键词： crystal structure 2(5H) furanone absolute configuration.