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laser additive manufacturing of biodegradable Mg-based alloys for biomedical applications: A review

Journal of Magnesium and Alloys 2022年第4期10卷 915-937页

作者： c.l.wu W.J.Xie H.c.Man Department of Industrial and Systems Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong KongChina

Metallic implants are widely used in internal fixation of bone fracture in surgical *** are mainly used for providing mechanical support and stability during bone reunion,which usually takes a few months to *** implants made of stainless steels,Ti-based alloys and cocrMo alloys have been widely used for orthopedic reconstruction due to their high strength and high corrosion *** metallic implants will remain permanently inside the body after implantation,and a second surgery after bone healing is needed because the long-term presence of implant will lead to various *** implant removal surgery not only incurs expenditure,but also risk and psychological *** a consequence,studies on the development of biodegradable implants,which would degrade and disappear in vivo after bone reunion is completed,have drawn researchers’*** this connection,Mg-based alloys have shown great potentials as promising implant materials mainly due to their low density,inherent biocompatibility,biodegradability and mechanical properties close to those of ***,the high degradation rate of Mg-based implants in vivo is the biggest hurdle to *** from materials selection,a fixation implant is ideally tailor-made in size and shape for an individual case,for best surgical ***,laser additive manufacturing(lAM),with the advent of sophisticated laser systems and software,is an ideal process to solve these *** this paper,we reviewed the progress in lAM of biodegradable Mg-based alloys for biomedical *** effect of powder properties and laser processing parameter on the formability and quality was thoroughly *** microstructure,phase constituents and metallurgical defects formed in the lAMed samples were *** mechanical properties,corrosion resistance,biocompatibility and antibacterial properties of the lAMed samples were summarized and compared with samples fabricated by

关键词： laser additive manufacturing Magnesium alloys Implant Biomedical applications Mechanical properties Biodegradability

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Anisotropic Inter-granular corrosion Behaviors and Microstructures of AlMgSicu Alloy Sheets Made by Thermal–Mechanical Treatments

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Acta Metallurgica Sinica(English letters) 2022年第2期35卷 275-284页

作者： l.M.liu Y.X.lai c.l.wu Z.Zhang J.H.chen center for High-Resolution Electron Microscopy College of Materials Science and EngineeringHunan UniversityChangsha 410082China

This study investigates the microstructure and local corrosion behavior of an Al-Mg-Si-cu alloy,which has been subjected to cold-rolling with different deformation strain ratios(DSRs)and followed by artificial *** corrosion tests show that peak-aged samples with a small DSR(5-10%)are sensitive to inter-granular corrosion(IGc)along both the normal and rolling *** the DSR increases to medium strength(20-40%),IGc sensitivity decreases along both directions and corrosion propagates *** the DSR is 60-80%,IGc sensitivity along the normal direction continues to decrease,but increases along the rolling direction,indicating pronounced corrosion *** characterization reveals the decreased IGc sensitivity is mainly attributed to a reduction in element segregation at high-angle grain boundaries and the kinked and discontinuous grain boundary corrosion *** increased IGc sensitivity along the rolling direction could be related to the significantly flattened grains.

关键词： Al alloys local corrosion Anisotropy Transmission electron microscopy(TEM) Electron backscattering diffraction(EBSD)

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Structures and formation mechanisms of dislocation-induced precipitates in relation to the age-hardening responses of Al-Mg-Si alloys

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Journal of Materials Science & Technology 2020年第6期41卷 127-138页

作者： Y.X.lai W.Fan M.J.Yin c.l.wu J.H.chen center for High-Resolution Electron Microscopy College of Materials Science&EngineeringHunan UniversityChangsha 410082China Electron Microscopy center Shenzhen UniversityShenzhen 518060China

In the slightly deformed Al-Mg-Si alloys,dislocation-induced precipitates are frequently observed,and they usually line up,forming sophisticated precipitation *** atomic-resolution electron microscopy in association with hardness measurements,we systematically investigated these precipitates in relation to the age-hardening responses of the *** study reveals that the majority of dislocation-induced complex precipitates are actually short-range ordered while long-range disordered polycrystalline precipitates and multiphase composite precipitates,including polycrystalline U2 precipitates,B’/U2,B’-2/U2,B’/B’-2/U2 and’/U2 composite *** is suggested that the formation of these complex precipitates is mainly owing to a high nucleation rate and rapid growth of different precipitate phases parallel to the associated dislocation *** dislocation-induced precipitates consume more Mg than Si from the matrix and have a high formation kinetics,they will have different impacts on the matrix precipitation in different types of Al-Mg-Si *** results further demonstrate that for the"normally-β"-hardened"alloy,their formation leads to a coarser precipitate microstructure in the matrix,whereas for the"normally-β’-hardened"alloy,their formation reverses the precipitation pathway in the matrix,resulting in a reduced age-hardening potential of the former alloy and an improved age-hardening potential of the latter alloy.

关键词： Al-Mg-Si alloys Precipitation Dislocation Age-hardening Electron microscopy

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A hidden precipitation scenario of theθ’-phase in Al-cu alloys

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Journal of Materials Science & Technology 2021年第16期75卷 126-138页

作者： l.Zhou c.l.wu P.Xie F.J.Niu W.Q.Ming K.Du J.H.chen center for high-resolution electron microscopy college of materials science and engineeringhunan universitychangshahunan410082china shenyang national laboratory for materials science institute of metal researchchinese academy of sciences.shenyan7.110016china

Al-cu binary alloys are important and interesting industry *** to date,the formation mechanisms of the key strengthening precipitates,namedθ’-phase,in the alloys are still ***,we report that for non-deformed bulk Al-cu alloys theθ’-phase actually has its own direct precursors that can form only at elevated aging temperature(>ca.200℃).These high-temperature precursors have the same plate-like morphology as theθ’-phase precipitates but rather different *** imaging reveals that they have a tetragonal structure with a=0.405 nm and c=1.213 nm,and an average composition of Al_(5-x)cu_(1+x)(0≤xlly coherent with the *** precursor phase may initiate with a composition of Al5 cu and evolve locally towards Al_(4)cu_(2)in composition,eventually leading to a consequent structural transformation into theθ’-phase(Al4 cu2=Al2 cu).There are evidences that because of their genetic links in structure,such a high-temperature precursor may transform to theθ’-phase without having to change their morphology and interface *** study reveals a well-defined and previously hidden precipitation scenario for theθ’-phase to form in Al-cu alloys at an elevated aging temperature.

关键词： Alcu alloy Age-hardening Precipitation Electron microscopy

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Variation of sulfate aerosol concentrations over the western Pacific and their effect on clouds, radiation and precipitation

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Acta Oceanologica Sinica 1993年第4期12卷 521-534页

作者： F.Parungo J.Rosinski M.l.c.wu c.T.Nagamoto Air Resources laboratory NOAA/ERL Boulder CO U.S.ANational Center for Atmospheric Research Boulder CO U.S.AGoddard Space Flight Center NASA Greenbelt MD U.S.AAir Resources Laboratory NOAA/ERL Boulder CO U.S.A

Under bilateral cooperation between the United States of America and the People's Republic of china, a series of research cruises were conducted over the western Pacific Ocean. It was found that a) the non-sea-salt sulfate aerosol particles are the major source of cloud condensation nuclei, b) the population of clouds and the total albedo are proportional to the concentration of condensation nuclei and consequently to the concentration of the non-sea-salt aerosol particles, and c) the amount of rainfall is inversely proportional to the concentration of non-sea-salt sulfate aerosol particles. It seems that anthropogenic sulfate aerosol particles affect the regional planetary albedo and climate and that the contribution from biogenically derived sulfate aerosol particles is of lesser importance.

关键词： data Variation of sulfate aerosol concentrations over the western Pacific and their effect on clouds radiation and precipitation over

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cONTROl OF cANcER PAIN TO ENSURE THE BEST POSSIBlE QUAlITY OF lIFE

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Journal of Traditional chinese Medicine 1992年第4期12卷 243-255页

作者： G Q Yu J X liu P W li J X Qin E X Yu l M liu l c wu M H Shen W S Zhou M M li Guang An Men Hospital China Academy of Traditional Chinese Medicine Beijing.

Yu Guiqing 余桂清(Guang An Men Hospi-tal,china Academy of Traditional chineseMedicine,Beijng 100053)The therapeutic strategy regarding can-cer pain is first to get rid of the causes ofpain with anticancer treatment so... 详细信息

关键词： Radix materia stasis anticancer verity herbal 田螺膏 relieve 黑龙丹大黄度虫丸

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Multiple sclerosis is at a checkpoint: advancing the program

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Neural Regeneration Research 2025年第3期20卷 811-812页

作者： Brandon c.Smith Jessica l.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a chronic inflammatory and demyelinating disease of the central nervous system(cNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage

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Tectonic modes of mantle convection and their implications for Earth's tectonic evolution based on three-dimensional numerical simulations

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Science china Earth Sciences 2025年第1期68卷 270-296页

作者： Song XIANG Jinshui HUANG Bingcheng wu School of Earth and Space Sciences University of Science and Technology of China cAS center of Excellence in comparative Planetary Studies

Five tectonic modes of mantle convection are obtained and analyzed with three-dimensional numerical models in a spherical shell domain. The five tectonic convective modes are non-plate mobile-lid, plate-like mobile-lid, episodic plate-like mobile-lid, episodic stagnant-lid, and stagnant-lid convective modes, respectively. The typical characteristics of these five tectonic modes and their numerical classification criteria based on plateness, mobility, and their standard deviations are presented and discussed. The results show that the yield stress of the lithosphere has profound effects on the tectonic convective *** the gradual increase of yield stress, the tectonic mode of mantle convection changes from one to another sequentially through the aforementioned five modes. Additionally, as the Rayleigh number increases, the range of yield stress for the platelike mobile-lid convective mode decreases, and the dimensionless transition stress between different tectonic modes ***, the dimensional transition stress between the non-plate mobile-lid convective mode and plate-like mobile-lid convective mode increases with the increase of Rayleigh number, but decreases between other tectonic modes. Furthermore, we find that the transition stress between different tectonic modes is inversely proportional to the internal heating rate, with the transition stress decreasing as the internal heating rate increases. The fitting analysis of the transition stress between tectonic modes shows that Earth's current plate tectonics correspond to a lithospheric yield stress of 150–250 MPa, which aligns with the strength of serpentinized mantle rock determined by experimental petrography. If the Archean mantle was 300°c warmer than it is today, then the Earth was in an episodic stagnant-lid convective mode. The tectonic evolution of the Earth's surface is closely related to the lithospheric strength and the process of thermal evolution. If the lithospheric strength w

关键词： Tectonic mode of mantle convection Plate-like mobile-lid convection Episodic plate-like mobile-lid convection Episodic stagnant-lid convection Plate tectonics and tectonic evolution of the Earth

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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy chemistry 2025年第1期100卷 710-720页

作者： Wenxuan chen Xiu-Qing Qiao Guo Hui Bojing Sun Dongfang Hou Meidi Wang Xueqian wu Tao wu Dong-Sheng li college of Materials and chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges laboratory college of chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-cdS/Mo2c@c heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the cdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-cdS （c-cdS） and hexagonal-cdS （h-cdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-cdS phase junction to realize gradient charge ***,the photothermal effect of Mo2c@c helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-cMc photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of cdS by constructing plasmonic tandem heterogeneous junctions.

关键词： cadmium sulfide

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A functional cathode sodium compensation agent for stable sodium-ion batteries

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Green Energy & Environment 2025年第1期10卷 173-182页

作者： Wei wu Zhenglin Hu Zhengfei Zhao Aoxuan Wang Jiayan luo Key laboratory for Green chemical Technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China State Key laboratory of Metal Matrix composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai200240China Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering Shaoxing312000China

Hard carbon(Hc)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial coulombic efficiency(IcE)and cycling *** compensation agent is a favorable strategy to make up for the loss of active sodium ions consumed *** it lacks agent that effectively decomposes to increase the active sodium ions as well as regulate carbon defects for decreasing the irreversible sodium ions ***,we propose 1,2-dihydroxybenzene Na salt(NaDB)as a cathode compensation agent with high specific capacity(347.9 mAh g^(-1)),lower desodiation potential(2.4–2.8 V)and high utilization(99%).Meanwhile,its byproduct could functionalize Hc with more c]O groups and promote its reversible ***,the presodiation hard carbon(pHc)anode exhibits highly reversible capacity of 204.7 mAh g^(-1) with 98%retention at 5 c rate over 1000 ***,with 5 wt%NaDB initially coated on the Na3V2(PO4)3(NVP)cathode,the capacity retention of NVP t NaDBjHc cell could increase from 22%to 89%after 1000 cycles at 1 c *** work provides a new avenue to improve reversible capacity and cycling performance of SIBs through designing functional cathode compensation agent.

关键词： Hard carbon IcE cathode compensation agent Reversible capacity Stability

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