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High Na-ion conductivity andmechanical integrity of anion-exchanged polymeric hydrogel electrolytes for flexible sodium ion hybrid energy storage

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SusMat 2024年第1期4卷 140-153页

作者： JungWoo hong Harpalsinh H.Rana Jeong Hee Park Jun Su kim Sang Joon Lee Gun Jang Tae hoon Kang Kang ho Shin Sang Ha Baek Wooseok Yang kwang ho kim Ju-Hyuk Lee ho Seok Park School of Chemical Engineering Sungkyunkwan UniversitySuwonRepublic of Korea Clean Energy Research Center Korea Institute of Science and Technology(KIST)SeoulRepublic of Korea KIST-SKKU Carbon-Neutral Research Center Sungkyunkwan University(SKKU)SuwonRepublic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwonRepublic of Korea COSMOS LAB/92 Jomaru-ro 385beon-gilBucheon-siRepublic of Korea SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan UniversitySuwonRepublic of Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan UniversitySuwonRepublic of Korea

The polymeric gel electrolytes are attractive owing to their higher ionic conductivities than those of dry polymer electrolytes and lowered water activity for enlarged potential ***,the ionic conductivity and mechanical strength of the Na-ion conducting polymeric gel electrolytes are limited by below 20 mS cm−1 and 2.2 ***,we demonstrate Na-ion conducting and flexible polymeric hydrogel electrolytes of the chemically coupled poly(diallyldimethylammonium chloride)-dextrin-N,N′-methylene-bisacrylamide film immersed in NaClO_(4) solution(ex-DDA-Dex+NaClO_(4))for flexible sodium-ion hybrid capacitors(f-NIHC).In particular,the anion exchange reaction and synergistic interaction of ex-DDA-Dex with the optimum ClO_(4)−enable to greatly improve the ionic conductivity up to 27.63 mS cm−1 at 25◦C and electrochemical stability window up to 2.6 V,whereas the double networking structure leads to achieve both the mechanical strength(7.48 MPa)and softness of hydrogel ***,the f-NIHCs with the ex-DDA-Dex+NaClO_(4) achieved high specific and high-rate capacities of 192.04 F g^(−1)at 500 mA g^(−1)and 116.06 F g^(−1)at 10000 mA g^(−1),respectively,delivering a large energy density of 120.03Wh kg^(−1)at 906Wkg^(−1)and long cyclability of 70%over 500 cycles as well as demonstrating functional operation under mechanical stresses.

关键词： anion exchange chemistry flexible energy storage hybrid energy storage hydrogel electrolytes renewable electrolytes sodium storage

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Microstructure evolution and mechanical properties of Ti-B-N coatings deposited by plasma-enhanced chemical vapor deposition

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中国有色金属学会会刊：英文版 2012年第S3期22卷 722-728页

作者： Jung ho SHIN kwang Soo ChoI Tie-gang WANG kwang ho kim Roman NOWAK National Core Research Center for Hybrid Materials Solution Pusan National University School of Materials Science and Engineering Pusan National University State Key Laboratory of Corrosion and Protection Institute of Metal ResearchChinese Academy of Sciences School of Chemical Technology Aalto University

Ternary Ti-B-N coatings were synthesized on AISI 304 and Si wafer by plasma-enhanced chemical vapor deposition (PECVD) technique using a gaseous mixture of TiCl4,BCl3,H2,N2,and *** virtue of X-ray diffraction analysis,X-ray photoelectron spectroscopy,scanning electron microscope,and high-resolution transmission electron microscope,the influences of B content on the microstructure and properties of Ti B N coatings were investigated *** results indicated that the microstructure and mechanical properties of Ti-B-N coatings largely depend on the transformation from FCC-TiN phase to HCP-TiB2 *** increasing B content and decreasing N content in the coatings,the coating microstructure evolves gradually from FCC-TiN/a-BN to HCP-TiB2 /a-BN via FCC-TiN+HCP-TiB2/*** highest microhardness of about 34 GPa is achieved,which corresponds to the nanocomposite Ti-63%B-N (mole fraction) coating consisting of the HCP-TiB2 nano-crystallites and amorphous BN *** lowest friction-coefficient was observed for the nanocomposite Ti-41%B-N (mole fraction) coating consisting of the FCC-TiN nanocrystallites and amorphous BN

关键词： Ti-B-N coating plasma-enhanced chemical vapor deposition (PECVD) nanocomposite coating hardness friction coefficient

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Effect of carbon on microstructure of CrAlC_xN_(1-x) coatings by hybrid coating system

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 78-82页

作者： Sung-Kyu AHN Se-Hun KWON kwang-ho kim National Core Research Center for Hybrid Materials Solution Pusan National University School of Materials Science and Engineering Pusan National University

A systematic investigation of the microstructure of CrA1CxN1-x coatings as a function of carbon contents was conducted. Quaternary CrA1CxN1-x coatings were deposited on Si wafers by a hybrid coating system combining an arc-ion plating technique and a DC reactive magnetron sputtering technique using Cr and AI targets in the Ar/N2/CH4 gaseous mixture. The effect of carbon content on microstructure of CrA1C^N~ x coatings was investigated with instrumental analyses of X-ray diffraction, X-ray photoelectron, and high-resolution transmission electron microscopy. The results show that the carbon content of CrA1CxN1-x coatings linearly increases with increasing CH4/（CH4/N2） gas flow rate ratio. The surface roughness of the CrA1CxN1-x coating layer decreases with the increase of carbon content.

关键词： CrA1C,N1-x, coating nanocomposite microstructure hybrid coating system

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Formation of nanocrystalline microstructure in arc ion plated CrN films

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 73-77页

作者： Qi-min WANG Se-Hun KWON kwang-ho kim National Core Research Center for Hybrid Materials Solution Pusan National University Busan 609-735 Korea School of Materials Science and Engineering Pusan National University Busan 609-735 Korea

Applying negative bias voltages caused significant microstructure changes in arc ion plated CrN films. Nanocrystalline microstructures were obtained by adjusting the negative bias voltage. Structural characterizations of the films were carried out using X-ray diffractometry (XRD) and high-resolution transmission electron microscopy (HR-TEM). The results indicated that increasing ion bombardment by applying negative bias voltages resulted in the formation of defects in the CrN films, inducing microstructure evolution from micro-columnar to nanocrystalline. The microhardness and residual stresses of the films were also affected. Based on the experimental results, the evolution mechanisms of the film microstructure and properties were discussed by considering ion bombardment effects.

关键词： CrN thin films deposition microstructure arc ion plating ion bombardment

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Synthesis and properties of Cr-Al-Si-N films deposited by hybrid coating system with high power impulse magnetron sputtering (HIPIMS) and DC pulse sputtering

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中国有色金属学会会刊：英文版 2012年第S3期22卷 729-734页

作者： Min Su KANG Tie-gang WANG Jung ho SHIN Roman NOWAK kwang ho kim School of Materials Science and Engineering Pusan National University State Key Laboratory of Corrosion and Protection Institute of Metal ResearchChinese Academy of Sciences National Core Research Center for Hybrid Materials Solution Pusan National University Extreme Energy-Density Research Institute Nagaoka University of Technology School of Chemical Technology Aalto University

The CrN and Cr-Al-Si-N films were deposited on Si wafer and SUS 304 substrates by a hybrid coating system with high power impulse magnetron sputtering (HIPIMS) and a DC pulse sputtering using Cr and AlSi targets under N2/Ar *** varying the sputtering current of the AlSi target in the range of 0-2.5 A,both the Al and Si contents in the films increased gradually from 0 to 19.1% and 11.1% (mole fraction),*** influences of the AlSi cathode DC pulse current on the microstructure,phase constituents,mechanical properties,and oxidation behaviors of the Cr-Al-Si-N films were investigated *** results indicate that the as-deposited Cr-Al-Si-N films possess the typical nanocomposite structure,namely the face centered cubic (Cr,Al)N nano-crystallites are embedded in the amorphous Si3N4 *** increasing the Al and Si contents,the hardness of the film first increases from 20.8 GPa for the CrN film to the peak value of 29.4 GPa for the Cr0.23Al0.14Si0.07 N film,and then decreases *** the meanwhile,the Cr0.23Al0.14Si0.07N film also possesses excellent high-temperature oxidation resistance that is much better than that of the CrN film at 900 or 1000 °C.

关键词： Cr-Al-Si-N film high power impulse magnetron sputtering DC pulsed sputtering high-temperature oxidation resistance

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Hemoglobin induces colon cancer cell proliferation by release of reactive oxygen species

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World Journal of Gastroenterology 2006年第35期12卷 5644-5650页

作者： Ryung-Ah Lee Hyun-Ah kim Bo-Young Kang kwang-ho kim Ewha Medical Institute Department of Surgery College of Medicine Ewha Womans University Seoul Korea Department of Surgery College of Medicine Ewha Womans University Seoul Korea Ewha Medical Institute Ewha Womans University Seoul Korea

AIM: To study whether hemoglobin could amplify colon cancer cell proliferation via reactive oxygen species (ROS) production. METhoDS: Colon cancer cell line HT-29 was grown in the conventional method using RPMI1640 media. The viability of the cells was measured using the colorimetric MTT [3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazo- lium bromide] assay after adding hemoglobin. We de- termined reactive oxygen species levels to be indicators of oxidative stress in HT 29 cell lines with and without hemoglobin and/or 5-fluorouracil (5-FU), 5’-deoxy-5-flu- orouridine (5-DFUR) using fluorometric dichlorofluorescin diacetate (DCFH-DA) assay. RESULTS: Cellular proliferation was increased with he- moglobin in a concentration-dependent manner. A signif- icant increment on ROS levels was found in HT 29 cells following hemoglobin incubation. The cytotoxic effects of 5-FU and 5-DFUR were significantly blunted by admin- istration of hemoglobin. There was a slight increase of peroxiredoxin 1, superoxide dismutase 1 concentration according to different hemoglobin concentrations. CONCLUSION: Hemoglobin has a cellular proliferative effect on HT-29 colon cancer cell line by production of ROS. Also, hemoglobin abates cytotoxic effects of che- motherapeutic agents such as 5-FU and 5-DFUR.

关键词： Colon cancer Hemoglobin Reactive oxygen species

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Effects of Cr interlayer on mechanical and tribological properties of Cr-Al-Si-N nanocomposite coating

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 62-67页

作者： Young Su hoNG Se Hun KWON Tiegang WANG Doo-In kim Jihwan ChoI kwang ho kim School of Materials Science and Engineering Pusan National University National Core Research Center for Hybrid Materials Solution Pusan National University

Cr-A1-Si-N coatings were deposited on SUS 304 substrate by a hybrid coating system. A Cr interlayer was introduced between Cr-A1-Si-N coating and SUS 304 substrate to improve the coating adherence. The effects of Cr interlayer on the microhardness, adhesion, and tribological behavior of Cr-A1-Si-N coatings were systematically investigated. The results indicate that the microhardness of the Cr-A1-Si-N coatings gradually deceases with increasing thickness of Cr interlayers. The adhesion between Cr-A1-Si-N and SUS 304 substrate is improved by addition of the Cr interlayers. A peak critical load of-50 N is observed for the coating containing Cr interlayer of 60 nm as compared - 20 N for the coating without Cr interlayer. The thicker Cr interlayers result in reduced critical load values. Moreover, the wear resistance of the Cr-AI-Si-N coatings is greatly enhanced by introducing the Cr interlayer with thickness of 60 nm in spite of the decreased microhardness. The friction coefficient of the coating system is also moderately reduced.

关键词： Cr-A1-Si-N coating Cr interlayer hardness adhesion wear

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Environmentally friendly hybrid coating prepared by electro-deposition method at various seawater conditions

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中国有色金属学会会刊：英文版 2009年第B9期19卷 110-113页

作者： Myeong-hoon LEE Kyung-Man MOON Jong-Do kim Kang JUN kwang-ho kim Division of Marine System Engineering Korea Maritime University Dongsam-Dong Youngdo Busan 606-791 Korea National Core Research Center for Hybrid Materials Solution Pusan National University Busan 609-735 Korea

The formation mechanism of calcareous deposit films in seawater involves an increase in pH at the metal/solution interface due to cathodic reactions, a raised carbonate ion concentration at the interface and precipitation of inorganic deposits such as CaCO3, Mg(OH)2. Environmentally friendly hybrid calcareous deposit films were formed by an electrochemical technique on steel substrates in various solution environments. And the influence of dissolved gas on formation of calcareous deposit films was investigated by scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray diffractometry(XRD). Consequently, these results showed that formation of good overall calcareous deposited films by dissolved gas in seawater environments can be achieved by controlling the material composition and structure through effective use of electrochemical method.

关键词：海水混合环保电沉积扫描电子显微镜涂层制备溶液界面

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Distribution of electric field for carbon nanotube assembly: Experiments (II)

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 121-125页

作者： Soongeun KWON Soo-Hyun kim kwang-ho kim Myung-chang KANG Hyung-woo LEE Department of Mechanical Engineering Korea Advanced Institute of Science and Technology (KAIST) Daejeon 305-701 Korea National Core Research Center for Hybrid Materials Solution Pusan National University

The distribution effect of electric field on the alignment and attachment of carbon nanotubes （CNTs） were investigated. The experimental results were compared with the simulation results according to three different shaped electrodes. In previous simulation, the round shaped electrodes were expected to be more effective for aligning and attaching a single CNT between two electrodes than conical or rectangular shaped electrodes. To verify the simulation results, three different shaped electrodes were introduced and a single multi-walled carbon nanotube （MWNT） was attached. The optimal conditions for aligning and attaching MWNTs such as the frequency, applied voltage and concentration of MWNTs solution were investigated. Through repeated experiments, frequency of 100 kHz-10 MHz, applied voltage of 0.3-1.3 V^s/~m, concentration of 5 ktg/mL in MWNTs solution were obtained as a possible condition range to attach MWNTs. Under these conditions, the yield of MWNTs attachment between two electrodes was up to 70%. In previous simulation, furthermore, it was verified that the size of the stable or quasi-stable region made CNTs aligned and attached on different shaped electrodes from the comparison of the experimental and simulation results. Most single MWNT attachment was accomplished on the round shaped electrodes.

关键词： carbon nanotubes dielectrophoresis round shaped electrode simulation

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Optical diffraction gratings embedded in BK-7 glass by low-density plasma formation using femtosecond laser

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 165-169页

作者： Jung-Kyu PARK Sung-Hak Cho kwang-ho kim Myung-Chang KANG Nano Machining Laboratory Korea Institute of Machinery and Material Daejeon 305-343 Korea National Core Research Center for Hybrid Materials Solution Pusan National University

The optical embedded diffraction gratings with the internal refractive index modification in BK-7 glass plates were demonstrated using low-density plasma formation excited by a high-intensity femtosecond （130 fs） Ti： sapphire laser （λp=790 rim）. The refractive index modifications with diameters ranging from 400 nm to 4 gm were photoinduced after plasma formation occurred upon irradiation with peak intensities of more than 1 ×10^13 W/cm2. The graded refractive index profile was fabricated to be a symmetric around the center of the point at which low-density plasma occurred. The maximum refractive index change （An） was estimated to be 1.5x10 2. Several optical embedded gratings in BK-7 glass plate were demonstrated with refractive index modification induced by the scanning of low-density plasma formation.

关键词： BK-7 glass plate diffraction grating refractive index modification plasma formation femtosecond laser

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