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Electrochemical sensor for dopamine detection based on multiwalled carbon nanotube/molybdenum disulfide quantum dots with machine learning integration and anti-interference capability

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Tungsten 2025年第1期7卷 137-151页

作者： Geethukrishnan Onkar Apte kiran Kumar Tadi Energy Electrodics and Electrocatalysis (EEE) Lab Department of Chemistry School of Advanced Sciences Vellore Institute of Technology School of Computer Science and Engineering Vellore Institute of Technology

The precise detection and measurement of dopamine（DA）,a crucial neurotransmitter in the human body,plays a significant role in diagnosing,preventing,and treating neurological diseases associated with its levels.A highly sensitive DA electrochemical sensor was constructed by combining molybdenum disulfide quantum dots（MSQDs） with multiwalled carbon nanotubes（MWCNTs）.The MSQDs were synthesized using the shear exfoliation *** sensors consist of MSQDs with Mo-S edge catalytic centers for the DA redox reaction,and MWCNTs amplify the sensor *** linearity of the sensor for the detection of DA was tested in the presence of ascorbic acid(AA,50 μmol·L-1) and uric acid(UA,200 μmol·L-1),and exhibited linearity from 2 to 966 μmol·L-1of DA with 0.097 μA(mol·L-1)-1sensitivity and a low limit of detection of0.6 μmol·L-1（the ratio between signal and noise,S/N=3）.Moreover,the sensitivity and selectivity of the sensor were also studied using *** is no increase in amperometric current after adding the most potentially interfering *** sensor was successfully applied to recover DA in human blood sera ***,machine learning algorithms were operated to aid in the near-precise detection of DA in the heterogeneous mixture containing AA and *** algorithms facilitate the identification and quantification of DA amidst coexisting interferents,including AA,that are commonly present in biological matrices.

关键词： Biosensor Complex mixture Dopamine Machine learning MoS2 Multiwalled carbon nanotubes

Ultra‑Transparent and Multifunctional IZVO Mesh Electrodes for Next‑Generation Flexible Optoelectronics

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Nano-Micro Letters 2025年第1期17卷 293-309页

作者： kiran A.Nirmal Tukaram D.Dongale Atul C.Khot Chenjie Yao Nahyun Kim Tae Geun Kim School of Electrical Engineering Korea UniversityAnam‑ro 145Seongbuk‑guSeoulRepublic of Korea Computational Electronics and Nanoscience Research Laboratory School of Nanoscience and BiotechnologyShivaji UniversityKolhapur 416004India

Mechanically durable transparent electrodes are essential for achieving long-term stability in flexible optoelectronic ***,they are crucial for applications in the fields of energy,display,healthcare,and soft *** meshes represent a promising alternative to traditional,brittle,metal oxide conductors due to their high electrical conductivity,optical transparency,and enhanced mechanical *** this paper,we present a simple method for fabricating an ultra-transparent conducting metal oxide mesh electrode using selfcracking-assisted *** this method,we produced an electrode with ultra-transparency(97.39%),high conductance(Rs=21.24Ωsq^(−1)),elevated work function(5.16 eV),and good mechanical *** also evaluated the effectiveness of the fabricated electrodes by integrating them into organic photovoltaics,organic light-emitting diodes,and flexible transparent memristor devices for neuromorphic computing,resulting in exceptional device *** addition,the unique porous structure of the vanadium-doped indium zinc oxide mesh electrodes provided excellent flexibility,rendering them a promising option for application in flexible optoelectronics.

关键词： Self-cracking template Vanadium-doped indium zinc oxide mesh Organic solar cells Organic light-emitting diodes Flexible transparent memory

Machine learning empowers efficient design of ternary organic solar cells with PM6 donor

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Journal of Energy Chemistry 2025年第1期100卷 337-347页

作者： kiran A.Nirmal Tukaram D.Dongale Santosh S.Sutar Atul C.Khot Tae Geun Kim School of Electrical Engineering Korea University Computational Electronics and Nanoscience Research Laboratory School of Nanoscience and Biotechnology Shivaji University Yashwantrao Chavan School of Rural Development Shivaji University

Organic solar cells(OSCs) hold great potential as a photovoltaic technology for practical ***, the traditional experimental trial-and-error method for designing and engineering OSCs can be complex, expensive, and time-consuming. Machine learning(ML) techniques enable the proficient extraction of information from datasets, allowing the development of realistic models that are capable of predicting the efficacy of materials with commendable accuracy. The PM6 donor has great potential for high-performance OSCs. However, it is crucial for the rational design of a ternary blend to accurately forecast the power conversion efficiency(PCE) of ternary OSCs(TOSCs) based on a PM6 ***, we collected the device parameters of PM6-based TOSCs and evaluated the feature importance of their molecule descriptors to develop predictive models. In this study, we used five different ML algorithms for analysis and prediction. For the analysis, the classification and regression tree provided different rules, heuristics, and patterns from the heterogeneous dataset. The random forest algorithm outperforms other prediction ML algorithms in predicting the output performance of PM6-based TOSCs. Finally, we validated the ML outcomes by fabricating PM6-based TOSCs. Our study presents a rapid strategy for assessing a high PCE while elucidating the substantial influence of diverse descriptors.

关键词： Random forests

A comprehensive investigation on nonlinear vibration and bending characteristics of bio-inspired helicoidal laminated composite structures

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 81-100页

作者： S.SAURABH R.kiran D.SINGH R.VAISH V.S.CHAUHAN School of Mechanical and Materials Engineering Indian Institute of Technology Mandi

Bio-inspired helicoidal composite laminates, inspired by the intricate helical structures found in nature, present a promising frontier for enhancing the mechanical properties of structural designs. Hence, this study provides a comprehensive investigation into the nonlinear free vibration and nonlinear bending behavior of bio-inspired composite plates. The inverse hyperbolic shear deformation theory(IHSDT) of plates is employed to characterize the displacement field, with the incorporation of Green-Lagrange nonlinearity. The problem is modeled using the C0finite element method(FEM), and an in-house code is developed in the MATLAB environment to solve it numerically. Various helicoidal layup configurations including helicoidal recursive(HR), helicoidal exponential(HE), helicoidal semi-circular(HS), linear helicoidal(LH), and Fibonacci helicoidal(FH)with different layup sequences and quasi-isotropic configurations are studied. The model is validated, and parametric studies are conducted. These studies investigate the effects of layup configurations, side-to-thickness ratio, modulus ratios, boundary conditions, and loading conditions at different load amplitudes on the nonlinear vibration and nonlinear bending behaviors of bio-inspired composite plates. The results show that the laminate sequence exerts a substantial impact on both nonlinear natural frequencies and nonlinear bending behaviors. Moreover, this influence varies across different side-to-thickness ratios and boundary conditions of the bio-inspired composite plate.

关键词： Inverse problems

Throughflow and g-jitter effects on binary fluid saturated porous medium

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Applied Mathematics and Mechanics(English Edition) 2015年第10期36卷 1285-1304页

作者： P.kiran Department of Applied Mathematics School for Physical Sciences Babasaheb Bhimrao Ambedkar University

A non-autonomous complex Ginzburg-Landau equation （CGLE） for the finite amplitude of convection is derived, and a method is presented here to determine the amplitude of this convection with a weakly nonlinear thermal instability for an oscillatory mode under throughflow and gravity modulation. Only infinitesimal disturbances are considered. The disturbances in velocity, temperature, and solutal fields are treated by a perturbation expansion in powers of the amplitude of the applied gravity field. Throughfiow can stabilize or destabilize the system for stress free and isothermal boundary conditions. The Nusselt and Sherwood numbers are obtained numerically to present the results of heat and mass transfer. It is found that throughfiow and gravity modulation can be used alternately to heat and mass transfer. Further, oscillatory flow, rather than stationary flow, enhances heat and mass transfer.

关键词： weakly nonlinear theory throughflow complex Ginzburg-Landau equation(CGLE) gravity modulation

Arraying of microphotosynthetic power cells for enhanced power output

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Microsystems & Nanoengineering 2022年第2期8卷 185-202页

作者： kiran Kuruvinashetti Muthukumaran Packirisamy Optical-Bio Microsystems Laboratory Department of MechanicalIndustrial and Aerospace EngineeringConcordia UniversityMontrealQC H3G1M8Canada

Microphotosynthetic power cells(μPSCs)generate power through the exploitation of living photosynthetic’microorganisms by harvesting *** thermodynamic limitations of this process restrict the power output of a single ***,we demonstrateμPSCs in four different array configurations to enhance power output from these power *** this effect,sixμPSCs were arrayed in series,parallel,and combinations of series and parallel *** pPSC was injected with a 2 mL liquid culture of photosynthetic microorganisms(Chlamydomonas reinhardtii)in the anode and 2 mL of 25%(w/v)electron acceptor potassium ferricyanide(K_(3)Fe(CN)_(6))in the *** combinations ofμPSCs connected in series and parallel'generated higher power than the individual series and parallel *** combinations of sixμPSCs connected in series and in parallel produced a high power density of 1914 mWm^(-2)in the presence of white fluorescent light illumination at 20μEm^(-2)s^(-1).Furthermore,to realize the array strategy for real-time applications,a 1.7V/2mA rating light-emitting diode(LED)was powered by combinations of series and parallel array *** results indicate the reliability ofμPSCs to produce electricity from photosynthetic microorganisms for low-power *** addition,the results suggest that a combination of microlevel photosynthetic cells in array format represents a powerful optimal design strategy to enhance the power output fromμPSCs.

关键词： power illumination harvesting

Drained rock volume around hydraulic fractures in porous media:planar fractures versus fractal networks

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Petroleum Science 2019年第5期16卷 1064-1085页

作者： kiran Nandlal Ruud Weijermars Harold Vance Department of Petroleum Engineering Texas A&M University3116 TAMUCollege StationTX 77843-3116USA

This study applies the Lindenmayer system based on fractal theory to generate synthetic fracture networks in hydraulically fractured *** applied flow model is based on complex analysis methods,which can quantify the flow near the fractures,and being gridless,is computationally faster than traditional discrete volume *** representation of hydraulic fractures as fractals is a more realistic representation than planar bi-wing fractures used in most reservoir *** withdrawal from the reservoir with evenly spaced hydraulic fractures may leave dead zones between planar *** fractal networks will drain the reservoir matrix more effectively,due to the mitigation of stagnation flow *** flow velocities,pressure response,and drained rock volume(DRV)are visualized for a variety of fractal fracture networks in a single-fracture treatment *** major advancement of this study is the improved representation of hydraulic fractures as complex fractals rather than restricting to planar fracture *** models indicate that when the complexity of hydraulic fracture networks increases,this will suppress the occurrence of dead flow *** order to increase the DRV and improve ultimate recovery,our flow models suggest that fracture treatment programs must find ways to create more complex fracture networks.

关键词： Hydraulic fractures Drained rock volume Dead zones Fractals Branched fractures

CompactChain:an efficient stateless chain for UTXO-model blockchain

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Frontiers of Computer Science 2024年第2期18卷 167-179页

作者： B Swaroopa REDDY T Uday kiran REDDY Department of Electrical Engineering Indian Institute of Technology HyderabadHyderabadTelangana 502285India

In this work,we propose a stateless blockchain called CompactChain,which compacts the entire state of the UTXO(Unspent Transaction Output)based blockchain systems into two RSA *** first accumulator is called Transaction Output(TXO)commitment which represents the TXO *** second one is called Spent Transaction Output(STXO)commitment which represents the STXO *** this work,we discuss three algorithms:(i)To update the TXO and STXO commitments by the *** miner also provides the proofs for the correctness of the updated commitments;(ii)To prove the transaction’s validity by providing a membership witness in TXO commitment and non-membership witness against STXO commitment for a coin being spent by a user;(iii)To update the witness for the coin that is not yet spent;The experimental results evaluate the performance of the CompactChain in terms of time taken by a miner to update the commitments and time taken by a validator to verify the commitments and validate the *** compare the performance of CompactChain with the existing state-of-the-art works on stateless *** shows a reduction in commitments update complexity and transaction witness size which inturn reduces the mempool size and propagation latency without compromising the system throughput(Transactions per second(TPS)).

关键词： stateless blockchain RSA Accumulator STXO commitment TXO commitment UTXO Non-interactive Proof of Exponentiation(NI-PoE) Transactions per second(TPS)

Effect of Tributyltin on Escherichia coli:Role of Modifying Factors

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Biomedical and Environmental Sciences 1989年第4期2卷 366-375页

作者： kiran SINGH Department of Microbiology Bhopal UniversityBhopal.462026M.P.India

The effects of inorganic and organic tin compounds and various factors affecting the toxicity of the latter to Escherichia coli were *** comparison to stannous chloride,tributyltin chloride(TBTC)was more inhibitory to the growth of the test organism;this may be due to its greater liposolubility and ready absorption through the bacterial *** toxicity of TBTC to *** was modulated by various factors,such as pH,sulfate and chloride ions,and the presence of glucose,succinate,and reducing agents like cysteine and dithiothreitol(DTT). TBTC was more toxic to cells in minimal than in complex ***,this compound was more inhibitory to the growth of *** at acid pH than at basic *** in contrast to glucose,when used as a carbon source,made the bacterium more sensitive to *** and DTT(both at a final concentration of 0.5 mM)partially protected the cells against the inhibitory effect of this agent.1989 Academic Press,Inc.

关键词： TBTC Effect of Tributyltin on Escherichia coli coli