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Engineering a high-barrier d-f single-molecule magnet centered with hexagonal bipyramidal Dy(Ⅲ)unit

Science China Chemistry 2024年第10期67卷 3291-3298页

作者： Wei Deng Chan-Ying Yao Yan-Cong chen Ying-Qian Zhou shan-Nan Du Jun-Liang Liu Ming-Liang Tong Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education School of ChemistryInstitute of Green Chemistry and Molecular EngineeringGuangdong Basic Research Center of Excellence for Functional Molecular EngineeringSun Yat-sen UniversityGuangzhou 510006China

In the pursuit of high-performance single-molecule magnets(SMMs),incorporating intramolecular magnetic coupling emerges as a pivotal *** these,d-f SMMs have garnered significant attention due to their remarkable versatility,which lies in their ability to tune coordination environments and facilely substitute metal ***,achieving performance-centric d-f SMMs through the synergistic interplay between highly anisotropic f ions and d-f magnetic interactions remains a formidable *** mononuclear hexagonal bipyramidal(D_(6h))Dy^(Ⅲ)SMMs have been successfully isolated,the exploration of d-f SMMs featuring D_(6h)-lanthanide metal centers remains uncharted *** this study,we employed planar bipodal ligands in conjunction with“staple-like”axial phenoxide ligands to synthesize the first hexagonal bipyramidal d-f ***,this compound exhibits alternating-current magnetic susceptibilities peaking up to 68 K with an energy barrier surpassing 1,200 K,thus establishing a new benchmark within the heterometallic d-f SMM landscape inclusive of complexes with diamagnetic d metals and paramagnetic f ***,the ferromagnetic interaction at the d-f sites engenders oscillating relaxation times contingent on the magnetic field—a characteristic distinct from mononuclear *** findings shed light on a deliberate design approach for d-f SMMs,emphasizing the cooperative utilization of high-barrier lanthanide modules alongside d ions through magnetic *** synergy significantly enhances and diversifies the magnetic dynamics of these intriguing molecular systems.

关键词： single-molecule magnets magnetic coupling crystal engineering hexagonal bipyramid energy barrier

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Design and optimization of an airflow-vibration sieving device for the effective cleaning of cyperus esculentus *** mixture

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International Journal of Agricultural and Biological Engineering 2024年第4期17卷 77-88页

作者： shan chen Shiguan An Za Kan Lidong Huang Hewei Meng Jiangtao Qi Huijie Peng College of Mechanical and Electrical Engineering Shihezi UniversityShihezi 832000XinjiangChina Engineering Research Center for Production Mechanization of Oasis Special Economic Crop Ministry of EducationShihezi 832000XinjiangChina Guilin Mike Machinery Co. LtdGuilin 541000GuangxiChina

The threshing mixture of Cyperus esculentus(Tiger nut)planted in sandy areas is complex during harvesting,and there are problems of high impurity rate and high cleaning loss rate of the *** this paper,the threshing mixture of Cyperus esculentus is taken as the research object,and the suspension speed of each component is measured to design an“airflow+vibration”sieving *** the vector polygon method to explore the law of motion of the vibrating sieve,establish the force model of the seeds on the sieve surface,and analyze the conditions for the seeds to penetrate the *** to the principle of seeds penetrating the sieve and long stalks not penetrating the sieve,the geometric model of sieve blades opening degree adjustment mechanism is *** of the conditions under which long stalks can be thrown out of the *** experiment bench of the cleaning device was built,and the evaluation indexes were the rate of seed impurity and the rate of cleaning loss of the device,and the crank speed,sieve blades opening degree and fan speed were used as the experiment factors to study the influence law of each influencing factor on the evaluation index through single-factor *** response surface methodology to find the optimal combination of working parameters of the cleaning *** verify the device’s application on the combine harvester to improve the effectiveness of the cleaning operation of the Cyperus esculentus combine harvester.

关键词： sand cultivation Cyperus esculentus wind sieve type cleaning device optimization

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Simultaneously realizing thermal andelectromagnetic cloaking by multi-physicalnull medium

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Opto-Electronic Science 2024年第2期3卷 45-59页

作者： Yichao Liu Xiaomin Ma Kun Chao Fei Sun Zihao chen Jinyuan shan Hanchuan chen Gang Zhao Shaojie chen Key Lab of Advanced Transducers and Intelligent Control System Ministry of Education and Shanxi ProvinceCollege of Electronic Information and Optical EngineeringTaiyuan University of TechnologyTaiyuan 030024China

Simultaneously manipulating multiple physical fields plays an important role in the increasingly complex integrated systems,aerospace equipment,biochemical productions,*** on-chip systems with high integration level,the precise and efficient control of the propagation of electromagnetic waves and heat fluxes simultaneously is particularly *** this study,we propose a graphical designing method(i.e.,thermal-electromagnetic surface transformation)based on thermal-electromagnetic null medium to simultaneously control the propagation of electromagnetic waves and thermal fields according to the pre-designed paths.A thermal-electromagnetic cloak,which can create a cloaking effect on both electromagnetic waves and thermal fields simultaneously,is designed by thermal-electromagnetic surface transformation and verified by both numerical simulations and experimental *** thermal-electromagnetic surface transformation proposed in this study provides a new methodology for simultaneous controlling on electromagnetic and temperature fields,and may have significant applications in improving thermal-electromagnetic compatibility problem,protecting of thermal-electromagnetic sensitive components,and improving efficiency of energy usage for complex onchip systems.

关键词： transformation optics multi-physical cloak null medium

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FKF1b controls reproductive transition associated with adaptation to geographical distribution in maize

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Journal of Integrative Plant Biology 2024年第5期66卷 943-955页

作者： Suhui chen shan Gao Dongyang Wang Jie Liu Yingying Ren Zhihan Wang Xin Wei Qin Wang Xuehui Huang shanghai Key Laboratory of Plant Molecular Sciences College of Life SciencesShanghai Normal UniversityShanghai 200234China

Maize(Zea mays subspecies mays)is an important commercial crop across the world,and its flowering time is closely related to grain yield,plant cycle and latitude ***1 is an essential clock-regulated blue-light receptor with distinct functions on flowering time in plants,and its function in maize remains *** this study,we identified two FKF1 homologs in the maize genome,named ZmFKF1a and ZmFKF1b,and indicated that ZmFKF1a and ZmFKF1b independently regulate reproductive transition through interacting with ZmCONZ1 and ZmGI1 to increase the transcription levels of ZmCONZ1 and *** demonstrated that ZmFKF1b underwent artificial selection during modern breeding in China probably due to its role in geographical ***,our data suggested that ZmFKF1bHap_C7 may be an elite allele,which increases the abundance of ZmCONZ1 mRNA more efficiently and adapt to a wider range of temperature zone than that of ZmFKF1bHap_Z58 to promote maize floral *** extends our understanding of the genetic diversity of maize *** allele is expected to be introduced into tropical maize germplasm to enrich breeding resources and may improve the adaptability of maize at different climate zones,especially at temperate region.

关键词： flowering geographical distribution maize ZmFKF1

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Increased population exposures to extreme precipitation in Central Asia under 1.5℃and 2℃global warming scenarios

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Geography and Sustainability 2024年第3期5卷 343-356页

作者： Wei Wei shan Zou Weili Duan Yaning chen Shuai Li Takahiro Sayama Jianyu Zhu State Key Laboratory of Desert and Oasis Ecology Key Laboratory of Ecological Safety and Sustainable Development in Arid LandsXinjiang Institute of Ecology and GeographyChinese Academy of SciencesÜrümqi 830011China University of Chinese Academy of Science Beijing 100049China Aksu National Station of Observation and Research for Oasis Agro-ecosystem Aksu 843017China Disaster Prevention Research Institute Kyoto UniversityKyoto 6110011Japan

The increase in extreme precipitation(EP)may pose a serious threat to the health and safety of population in arid and semi-arid *** current research on the impact of EP on population in Central Asia(CA)is insufficient and there is an urgent need for a comprehensive ***,we opted for precipitation and temperature data under two Shared Socioeconomic Pathways(SSP2-4.5 and SSP5-8.5)from ten Global Climate Models(GCMs),which were obtained from the NASA Earth Exchange Global Daily Downscaled Projections(NEX-GDDP-CMIP6).By integrating population data in 2020 and 2050(SSP2 and SSP5),we investigated the future changes in EP and population exposure in CA under 1.5℃and 2℃global warming scenarios(GWSs).Our analysis indicates that EP in CA is projected to increase with global *** the SSP5-8.5,the maximum daily precipitation(Rx1day)exhibits an average response rate to global warming of 3.58%/K(1.99-4.06%/K).With rising temperatures,an increasing number of areas and populations in CA will be impacted by EP,especially in the Fergana *** 25%of the population(land area)in CA is exposed to Rx1day with increases of more than 8.31%(9.32%)under 1.5℃GWS and 14.18%(13.25%)under 2℃*** temperature rise can be effective in reducing population exposures to *** instance,limiting the temperature increase to 1.5℃instead of 2℃results in a 2.79%(1.75%-4.59%)reduction in population exposure to ***,we found that climate change serves as the predominant factor influencing the population exposure to EP,while the role of population redistribution,although relatively minor,should not be *** for prolonged drought,the role of population redistribution manifests negatively.

关键词： Extreme precipitation Global warming Population exposure Central Asia

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Engineered nanoparticles for precise targeted drug delivery and enhanced therapeutic efficacy in cancer immunotherapy

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Acta Pharmaceutica Sinica B 2024年第8期14卷 3432-3456页

作者： Xueqiang Peng Jianjun Fang Chuyuan Lou Liang Yang Shaobo shan Zixian Wang Yutong chen Hangyu Li Xuexin Li Department of General Surgery The Fourth Affiliated HospitalChina Medical UniversityShenyang 110032China Department of Ophthalmology Xi’an People’s Hospital(Xi’an Fourth Hospital)Xi’an 710004China Department of Neurosurgery Beijing Tiantan HospitalCapital Medical UniversityBeijing 10050China Department of Medical Oncology Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center of Cancer MedicineGuangzhou 510060China Department of Pathology Medical CollegeJinan UniversityGuangzhou 510632China Department of Physiology and Pharmacology Karolinska InstitutetStockholm SE-17177Sweden

The advent of cancer immunotherapy has imparted a transformative impact on cancer treatment paradigms by harnessing the power of the immune ***,the challenge of practical and precise targeting of malignant cells *** address this,engineered nanoparticles(NPs)have emerged as a promising solution for enhancing targeted drug delivery in immunotherapeutic interventions,owing to their small size,low immunogenicity,and ease of surface *** comprehensive review delves into contemporary research at the nexus of NP engineering and immunotherapy,encompassing an extensive spectrum of NP morphologies and strategies tailored toward optimizing tumor targeting and augmenting therapeutic ***,it underscores the mechanisms that NPs leverage to bypass the numerous obstacles encountered in immunotherapeutic regimens and probes into the combined potential of NPs when co-administered with both established and novel immunotherapeutic ***,the review evaluates the existing limitations of NPs as drug delivery platforms in immunotherapy,which could shape the path for future advancements in this promising field.

关键词： Engineered nanoparticles Cancer immunotherapy Drug delivery Bloodebrain barrier Tumor-barrier Nanomedicine Nanomaterial Cancer

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Regulated reaction pathway of CO_(2)photoreduction into CH_(4)by metal atom pair sites

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Rare Metals 2024年第9期43卷 4620-4627页

作者： Dong-Po He Guang-Bing Huang Jun Hu Yang Wu Xiao-Dong Li Qing-Xia chen shan Zhu Wen-Sheng Yan Jun-Fa Zhu Yang Pan Xing-chen Jiao Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122China Hefei National Research Center for Physical Sciences at Microscale National Synchrotron Radiation LaboratoryUniversity of Science and Technology of ChinaHefei 230026China Max Planck Institute of Microstructure Physics Weinberg 206120 HalleGermany State Grid Anhui Electric Power Research Institute Hefei 230601China

The carbon dioxide(CO_(2))reduction process involves complex protonation,making the resulting product often *** achieve the desired product,it is crucial to manipulate the reaction ***,we build the metal atom pair sites for selective CO_(2)photoreduction into *** a prototype,Ni atom pair sites loaded on the Mo S_(2)nanosheets were synthesized and verified by highresolution transmission electron microscopy(HRTEM),X-ray photoelectron spectroscopy(XPS)and X-rayabsorption near edge structure spectra(XANES).In-situ Fourier transform infrared spectroscopy(FTIR)monitors the*CHO group,a crucial intermediate in CH_(4)production,during CO_(2)photoreduction on the Ni-Mo S_(2)nanosheets,whereas this monitoring is not observed for the Mo S_(2)***,theoretical calculations disclose that over the Ni-Mo S_(2)nanosheet slab,the formation energy of*CHO intermediates is determined to be lower(0.585 e V)than the desorption energy of*CO intermediates for CO production(0.64 e V),implying the higher selectivity of CH_(4)production.

关键词： steps dioxide desired

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Lightweight foam-like nitrogen-doped carbon nanotube complex achieving highly efficient electromagnetic wave absorption

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Journal of Materials Science & Technology 2024年第1期168卷 114-123页

作者： Zongcheng Li Jin Liang Zhiheng Wei Xin Cao Jiahui shan Chunwei Li Xiaoyi chen Dong Zhou Ruizhe Xing Chunjia Luo Jie Kong MOE Key Lab of Materials Physics and Chemistry in Extraordinary Conditions Shaanxi Key Laboratory of Macromolecular Science and TechnologySchool of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Key laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical UniversityNingbo 315103China Polymer Materials and Engineering Department School of Materials Science and EngineeringChang’an UniversityXi’an 710064China

With the increased electromagnetic wave(EMW)threat to military and human health,the develop-ment of EMW-absorbing materials is ***-organic framework derivatives containing magnetic nanoparticles and a carbon matrix are potential candidates for designing efficient EMW-absorbing ***,a zeolitic imidazolate framework-67(ZIF-67)-embedded three-dimensional melamine foam is pyrolyzed to afford carbon foam-based nitrogen-doped carbon nanotube composites,named 3D foam-like CoO/Co/*** CoO/Co particles are confined in the dielectric carbon nanotube *** carbon nanotubes provide considerable conductive loss,while CoO/Co magnetic particles are con-ducive to providing magnetic loss and adjusting impedance ***,the numerous defect structures introduced by heteroatomic doping(nitrogen)cause dipole polarization and simultaneously adjust impedance ***,the unique porous nanotube structure promotes multiple re-flections and scattering of EMWs,further optimizing impedance ***/Co/N-CNTs composites exhibit a minimum reflection loss of−52.3 dB at a matching thickness of 2.0 mm,while the correspond-ing effective absorption bandwidth is 5.28 GHz at a matching thickness of 2.2 *** study reports a novel approach to fabricating a lightweight high-performance EMW-absorbing material.

关键词： Lightweight porous carbon materials Carbon nanotubes CoO/Co magnetic particles Electromagnetic synergistic effect Impedance matching

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Chirality discerning and monitoring in a metal cladding optofluidic chip

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Chinese Optics Letters 2024年第8期22卷 52-57页

作者： Qiheng Wei Xueqian Wang Hongrui shan Yi Lai He Li Hailang Dai Xianfeng chen State Key Laboratory of Advanced Optical Communication Systems and Networks School of Physics and AstronomyShanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory for Molecular Engineering of Chiral DrugsSchool of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China Department of Head and Neck Surgery and Department of Traditional Chinese Medicine Renji HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghaiChina Collaborative Innovation Center of Light Manipulations and Applications Shandong Normal UniversityJinan 250358China

The metabolic process of chiral drugs plays a significant role in clinics and in research on ***,we experimentally demonstrate by all-optical means that the chiral molecules can be quickly discriminated and monitored with the ultrahighorder modes excited in a metal cladding optofluidic chip,achieving over 5 times sensitivity with a low-dosage *** show that the varying concentration of the chiral drugs can be monitored both in cell and animal experiments,presenting a significant difference between chiral enantiomers at the optimal function time and the effect of the *** our knowledge,this approach provides a new way to achieve important chiral discrimination for the pharmacokinetics and the pharmacodynamics and may present opportunities in indicating the health status of humans.

关键词： chiral detection ultrahigh-order guided modes metal cladding optofluidic chip high sensitivity circularly polarized light

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NCAPD2 serves as a potential prognostic biomarker for lung adenocarcinoma and promotes cell proliferation,migration,invasion and cell cycle in vitro

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Oncology Research 2024年第9期32卷 1439-1452页

作者： PEILING WU LIFANG ZHAO HONGYAN ZHANG YUEYAN LOU DONGFANG chen shan XUE XUEQING LIU HANDONG JIANG Department of Respiratory and Critical Care Medicine Renji HospitalShanghai Jiao Tong University School of MedicineShanghai200127China

Objectives:The pro-oncogenic effects of NCAPD2 have been extensively studied across various tumor types;however,its precise role within the context of lung adenocarcinoma(LUAD)remains *** study aims to elucidate the biological functions of NCAPD2 in LUAD and unravel the underlying mechanistic ***:Utilizing bioinformatics methodologies,we explored the differential expression of NCAPD2 between normal and tumor samples,along with its correlations with clinical-pathological characteristics,survival prognosis,and immune ***:In the TCGA-LUAD dataset,tumor samples demonstrated significantly elevated levels of NCAPD2 expression compared to normal samples(p<0.001).Clinically,higher NCAPD2 expression was notably associated with advanced T,N,and M stages,pathologic stage,gender,smoking status,and diminished overall survival(OS).Moreover,differentially expressed genes(DEGs)associated with NCAPD2 were predominantly enriched in pathways related to cell *** infiltration analysis revealed that NCAPD2 expression levels were linked to the infiltration of memory B cells,naïve CD4+T cells,activated memory CD4+T cells,and M1 *** vitro experiments demonstrated that silencing NCAPD2 suppressed LUAD cell proliferation,migration,invasion,epithelial-mesenchymal transition(EMT),and cell cycle ***:In summary,NCAPD2 may represent a promising prognostic biomarker and novel therapeutic target for LUAD.

关键词： NCAPD2 LUAD Prognosis Immune infiltration Cell cycle

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