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An Evidence-Based CoCoso Framework with Double Hierarchy Linguistic Data for Viable selection of Hydrogen storage Methods

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Computer Modeling in Engineering & sciences 2024年第3期138卷 2845-2872页

作者： Raghunathan krishankumar Dhruva sundararajan k.s.ravichandran Edmundas kazimieras Zavadskas Information Technology systems and Analytics Area Indian Institute of Management Bodh GayaBodh GayaBihar824234India Department of Mathematics Amrita School of Physical SciencesAmrita Vishwa VidyapeethamCoimbatore641112India Institute of sustainable Construction Vilnius Gediminas Technical UniversityVilnius10223Lithuania

Hydrogen is the new age alternative energy source to combat energy demand and climate *** of hydrogen is vital for a nation’s *** of literature provide different methods for storing the produced hydrogen,and the rational selection of a viable method is crucial for promoting sustainability and green ***,hydrogen storage is associated with diverse sustainable and circular economy(sCE)*** a result,the authors consider the situation a multi-criteria decision-making(MCDM)*** infer that previous models for hydrogen storage method(HsM)selection(i)do not consider preferences in the natural language form;(ii)weights of experts are not methodically determined;(iii)hesitation of experts during criteria weight assessment is not effectively explored;and(iv)three-stage solution of a suitable selection of HsM is *** by these gaps,in this paper,authors put forward a new integrated framework,which considers double hierarchy linguistic information for rating,criteria importance through inter-criteria correlation(CRITIC)for expert weight calculation,evidence-based Bayesian method for criteria weight estimation,and combined compromise solution(CoCoso)for ranking *** applicability of the developed framework is testified by using a case example of HsM selection in *** and comparative analysis reveal the merits and limitations of the developed framework.

关键词： Hydrogen storage methods double hierarchy hesitant fuzzy linguistic term set evidence theory CoCoso method sustainability circular economy

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Type Inversion and Certain Physical Properties of spray Pyrolysed snO_2:Al Films for Novel Transparent Electronics Applications

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Journal of Materials science & Technology 2014年第2期30卷 97-102页

作者： k.ravichandran k.Thirumurugan Post Graduate and Research Department of Physics AVVM Sri Pushpam College(Autonomous)

Aluminium doped tin oxide films have been deposited onto glass substrates by using a simplified and low cost spray pyrolysis technique. The AI doping level varies between 0 and 30 at.% in the step of 5 at.%. The resistivity （p） is the minimum （0.38 Ω cm） for 20 at.% of AI doping. The possible mechanism behind the phenomenal zig-zag variation in resistivity with respect to AI doping is discussed in detail. The nature of conductivity changes from n-type to p-type when the AI doping level is 10 at.%. The results show that 20 at.% is the optimum doping level for good quality p-type snO2：AI films suitable for transparent electronic devices.

关键词： Tin oxide films P-type transparent conducting oxide (TCO) spray pyrolysis Transparent electronics Electrical properties Optical properties

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Enhancement of Photocatalytic and Antibacterial Activities of ZnO：Ag Nanopowders Through the Addition of Bamboo Charcoal： An Efficient Natural Adsorbent

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Acta Metallurgica sinica(English Letters) 2017年第12期30卷 1249-1256页

作者： k. Nithiyadevi k. ravichandran PG Research and Department of Physics AVVM Sri Pushpam College (Autonomous) Poondi Thanjavur Tamil Nadu 613 503 India Department of Physics Bharathidasan University Constituent College (Women) Orathanadu Tamil Nadu 614 625 India

This research article explains the removal of methylene blue （MB） and malachite green （MG） from aqueous solution using adsorption/photodegradation activity of ZnO：Ag/bamboo charcoal （BC） nanocomposite. In addition, the antibacterial studies of the prepared samples were tested against staphylococcus aureus （s. aureus） Gram-positive and Escherichia coli （E. coli） Gram-negative bacteria by the well diffusion method. The ZnO：Ag/BC nanocomposite exhibits superior photocatalytic activity compared with ZnO：Ag. Remarkable degradation efficiencies of 93.95% （MB） and 95.75% （MG） were recorded for ZnO：Ag/BC nanocomposite after 45 min. The degradation process follows a pseudo-first-order kinetics. The rate constant of ZnO：Ag/BC nanocomposite is two times greater than that of pristine ZnO nanopowder for the degradation of MB dye, while for MG dye degradation, it is three times. It is found that the ZnO：Ag/BC nanocomposite shows a higher rate of dye removal due to excellent adsorbing properties of bamboo charcoal （BC）. The ZnO：Ag/BC nanocomposite showed better antibacterial properties compared to ZnO：Ag. In this study, the samples were prepared using a simple and low-cost soft chemical route and they were characterized by optical, structural, surface morphological, antibacterial and photocatalytic properties. These characterization studies substantiate the discussions on the photocatalytic and antibacterial activities of the synthesized samples.

关键词： Bamboo charcoal Adsorbent ZnO Photocatalysis Antibacterial

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simultaneous Enhancement of Transparent and Antibacterial Properties of ZnO Films by suitable F Doping

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Journal of Materials science & Technology 2015年第7期31卷 759-765页

作者： s.snega k.ravichandran M.Baneto s.Vijayakumar Post Graduate & Research Department of Physics AVVM Sri Pushpam College(Autonomous) CUER-UL Universite de LomeFaculte Des Sciences Post Graduate & Research Department of Botany and Microbiology AVVM Sri Pushpam College(Autonomous)

Undoped and fluorine doped ZnO （ZnO：F） thin films were deposited onto glass substrates by employing a simplified spray pyrolysis technique using a perfume atomizer. The fluorine doping level in the starting solution was varied from 0 to 20 at.% in steps of 5 at.~g and the effects of fluorine doping level on the structural, optical, surface morphological properties along with their antibacterial activity against Escherichia coil （E. coli） and Bacillus subtilis （B. subtilis） bacteria were studied and reported. The X-ray diffraction studies revealed that despite the orientation ofcrystallites was strongly influenced by fluorine doping, the preferential orientation was retained in favor of （002） plane even at the highest doping level. The crystallite size decreased as the F doping level was increased and the reason for this variation has been explained on the basis of Zener pinning effect. The average optical transparency in the visible range was about 80%-90g for doped films and the optical band gap was found to be slightly increased with the F doping level. The antibacterial efficiency of the F doped ZnO films was found to be enhanced as the F doping level was increased. The antibacterial efficiency was more pronounced in the case of B. subtilis （Gram-positive） when compared with E. coil （Gram-negative）.

关键词： ZnO filmAntibacterial activityspray pyrolysisDoping

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Corrosion Inhibition of Mild steel in sulphuric Acid Using Luffa Aegyptiaca Leaves Extract

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Acta Metallurgica sinica(English Letters) 2014年第6期27卷 969-980页

作者： s. Jyothi J. ravichandran Post Graduate and Research Department of Chemistry Sri Ramakrishna Mission Vidyalaya College of Arts and Science

The corrosion inhibition of mild steel（Ms） in sulphuric acid using Luffa aegyptiaca（LA） leaves extract was investigated by weight loss studies, colorimetric measurements, potentiodynamic polarisation and electrochemical impedance spectroscopy. The adsorption of LA leaves extract was confirmed by Fourier transform infrared spectroscopy and optical profilometry. The inhibition efficiency increased with increasing concentration of the extract but decreased with rise in temperature and with the increase in acid strength. Furthermore, the inhibition efficiency synergistically increased on the addition of halide ions. Polarisation studies revealed that the LA extract acts as mixed- type inhibitor. Physical adsorption mechanism is proposed from the trend in inhibition efficiency with the change in temperature and from thermodynamic parameters. The adsorption of LA on Ms surface obeys Langmuir adsorption isotherm and follows the kinetic thermodynamic model of ElAwady at all temperatures studied.

关键词： Mild steel Adsorption Corrosion Thermodynamic properties FTIR

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Tuning the structural and Optical Properties of sILAR-Deposited Cu_2O Films Through Zn Doping

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Acta Metallurgica sinica(English Letters) 2015年第8期28卷 1041-1046页

作者： A.T.ravichandran k.Dhanabalan k.ravichandran R.Mohan k.karthika A.Vasuhi B.Muralidharan Department of Physics National College (Autonomous) Department of Physics J. J. College of Arts and Science(Autonomous) Department of Physics AVVM Sri Pushpam College(Autonomous) Department of Physics H. H. The Rajah’s College(Autonomous) Department of Chemistry BITS–PILANI-Dubai Campus

Undoped and Zn-doped Cu2O films were deposited onto glass substrates using successive ionic layer adsorption and reaction（sILAR） technique with different Zn doping levels（0, 1, 2, 3, 5 and 10 wt%）. The structural,optical, and surface morphological studies were carried out and reported. The structural study revealed that the crystalline quality is gradually enhanced up to 5 wt% of Zn doping level, and then quality begins to degrade for further increase in doping level. Moreover, the preferential orientation changes from（111） to（110） for the highest doping level were examined. Optical study shows that the transmittance（65%） and optical band gap values are maximum（2.41 e V） when the Zn doping level is at 5 wt%. The photoluminescence study confirms the presence of various defects in the Cu2O matrix and also the variation obtained in the optical band gap from the transmittance data. sEM images revealed the annealinginduced changes in the surface morphology of the films.

关键词： Cu2O thin films structural properties Zener pinning effect Optical properties sEM

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Effect of multilayer CrN/CrAlN coating on the corrosion and contact resistance behavior of 316L ss bipolar plate for high temperature proton exchange membrane fuel cell

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Journal of Materials science & Technology 2022年第2期97卷 134-146页

作者： s.Pugal Mani P.Agilan M.kalaiarasan k.ravichandran N.Rajendran Y.Meng Department of Analytical Chemistry University of MadrasChennai-25India Department of Chemistry Anna UniversityChennai-25India state key Laboratory of Tribology Tsinghua UniversityBeijing 100084China

stainless steels have received wide attention as a substitute material for bipolar plates in high temperature proton exchange membrane fuel cell(HT-PEMFC).In the present work,the CrN,CrAlN and multilayer CrN/CrAlN coatings were deposited on 316 L ss to increase the corrosion resistance and decrease the interfacial contact *** deposited coatings exhibited face centered cubic phase structure and it was verified from the X-ray diffraction pattern.X-ray photo electron spectroscopy results showed the formation of both CrN and CrAlN layers on 316 L ***/CrAlN coating is more helpful in water management due to low surface roughness and high contact angle in the HT-PEMFC *** corrosion resistance behavior of all the samples were studied in 85%H_(3)PO_(4)solution at 140℃purged with H_(2)(HT-PEMFC anode)and O_(2)(HT-PEMFC cathode)*** results showed that all the coatings considerably improved the performance of 316 L ss and superior corrosion resistance was observed for CrN/CrAlN multilayer coating,whose protective efficiency was 98.12%and 96.14%in the two simulated HT-PEMFC *** results of electrochemical impedance spectroscopic studies demonstrated higher impedance for CrN/CrAlN *** morphological studies performed after corrosion studies revealed that protection ability of CrN/CrAlN coating still remained acceptable.A very low interfacial contact resistance value of 6 mΩ cm^(2) at 140 N/cm;was observed for CrN/CrAlN ***,after corrosion studies,the interfacial contact resistance value of CrN/CrAlN coated 316 L was much lower than that of CrN and CrAlN coatings due to the increased oxidation *** maximum power density of about 0.93 W/cm^(2) at 2 A/cm^(2) and output voltage of 0.96 V was observed for CrN/CrAlN coating.

关键词： Bipolar plate 316L ss Corrosion Contact resistance Contact angle surface roughness

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D2 analysis for estimating genetic divergence in different clones of Dalbergia sissoo

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Journal of Forestry Research 2016年第5期27卷 1085-1097页

作者： Ashok kumar s. ravichandran shivani Dobhal Vijay kumar Forest Research Institute (Indian Council of Forestry Research and Education) Dehradun India Directorate of Rice Research Rajendra Nagar HyderabadAndhra Pradesh India Research Circle Punjab Forest Department HoshiarpurPunjab India

Genetic divergence was studied in selected 36 genotypes of Dalbergia sissoo Roxb. on the basis of seven morphological parameters. The divergence among genotypes was estimated by Mahalanobis method and genotypes were grouped into clusters by Tocher＇s method. All the genotypes were classified into seven distinct clusters on the basis of seven morphological traits. Cluster 1 was the largest with 25 genotypes followed by Cluster 2 （four genotypes）. Cluster 3, 5, 6 and 7 were the divergent clusters. The D2 analysis revealed that D2 value （39.42） between clone 5040 and clone 201 was recorded maximum. The intra-cluster distance ranged from 0.00 （Cluster 3, 5, 6 and 7） to 3.89 （Cluster 1）, the Cluster 3 （clone 33） was the most divergent cluster with maximum inter cluster distance （13.97） with the Cluster 7. By the divergence analysis, the parents for hybridization from diverse clusters could be selected for heterotic hybrids.

关键词： Dalbergia sissoo Roxb. Genetic divergence Hybridization D2 analysis Heterotic

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Calibration of a hysteretic model for glass fiber reinforced gypsum wall panels

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Earthquake Engineering and Engineering Vibration 2014年第2期13卷 347-355页

作者： Maganti Janardhana Robin Davis P s.s.ravichandran A.M.Prasad D.Menon JNTUH College of Engineering National Institute of Technology Rourkela India Leslie E.Robertson Associates Consulting Engineers (India) Pvt.Ltd Indian Institute of Technology Madras

Glass fi ber reinforced gypsum(GFRG) wall panels are prefabricated panels with hollow cores, originally developed in Australia and subsequently adopted by India and China for use in buildings. This paper discusses identifi cation and calibration of a suitable hysteretic model for GFRG wall panels fi lled with reinforced concrete. As considerable pinching was observed in the experimental results, a suitable hysteretic model with pinched hysteretic rule is used to conduct a series of quasi-static as inelastic hysteretic response analyses of GFRG panels with two different widths. The calibration of the pinching model parameters was carried out to approximately match the simulated and experimental responses up to 80% of the peak load in the post peak region. Interestingly, the same values of various parameters(energy dissipation and pinching related parameters) were obtained for all fi ve test specimens.

关键词： glass fi ber reinforced gypsum walls hysteretic model pinching model

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Hemolymph proteins in marine crustaceans

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Asian Pacific Journal of Tropical Biomedicine 2012年第6期2卷 496-502页

作者： W sylvester Fredrick.s.ravichandran CAs in Marine Biology Faculty of Marine Sciences Annamalai University

This study is done with the aim to bring together the various antimicrobial peptides that are present in the crustacean hemolymph and their sources along with its *** lack immune systems that involve antigen-antibody reactions and do not have an immune memory, therefore most invertebrate species show no evidence of acquired *** possess an open circulatory system, where nutrients, oxygen, hormones, and cells are distributed in the hemolymph. They lack adaptive immune system and rely exclusively on their innate immune mechanisms that include both cellular and humoral responses. Antimicrobial peptides and proteins form an important means of host defense in eukaryotes. In addition to their role as endogenous antibiotics, antimicrobial peptides have functions in inflammation,wound repair and regulation of the adaptive immune system. Over the past several years, many antimicrobial peptides have been found and characterized in crabs.

关键词： Antimicrobial peptides Crabs Antibiotics Protein characterisation Immune response

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