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Tetradentate Pt(II) complex as a singlet exciton sensitizing host for highly efficient green fluorescent organic light-emitting diodes

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Science China Materials 2024年

作者： Unhyeok Jo Seung Chan Kim Chan Hee Ryu Kang Mun lee Jae-Min Kim jun yeob lee School of Chemical Engineering Sungkyunkwan University 2066 Seobu-ro Jangan-gu Suwon-si Department of Chemistry Institute for Molecular Science and Fusion Technology Kangwon National University Chuncheon Department of Advanced Materials Engineering Chung-Ang University 4726 Seodong-daero Daedeok-myeon Anseong-si SKKU Advanced Institute of Nano Technology Sungkyunkwan University 2066 Seobu-ro Jangan-gu SKKU Institute of Energy Science and Technology Sungkyunkwan University 2066 Seobu-ro Jangan-gu

Efficient green fluorescent organic light-emitting diodes were designed with a phosphorescent metal complex as a singlet exciton sensitizing host (SESH) for achieving high efficiency and low efficiency roll-off through exciton and polaron management. Tetradentate Pt(II) complex (Pt-Trz)possessing a tetradentate ligand with a bulky blocking group not only suppresses the severe formation of excimer or dimer itself but also transfers radiative excitons to fluorescent dopant effectively. The SESH assisted fluorescence (SESHF) device with Pt-Trz as the host exhibits the maximum external quantum efficiency of 13.3%and a lower efficiency roll-off compared with exciplex host device which is a general approach for harvesting triplet excitons. Numerical exciton dynamics modeling unravels that the SESHF device effectively utilizes triplet excitons in the host by intersystem crossing and resonance energy transfer from the triplet state of the host to the singlet state of the terminal emitter. Bimolecular quenching rates of the SESHF device are reduced by 11 times for triplet-triplet annihilation and 1.8 times for tripletpolaron annihilation compared with the exciplex device, which demonstrates that Pt-Trz could be a platform to be used as an efficient host for fluorophores.

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Tetradentate Pt(Ⅱ)complex as a singlet exciton sensitizing host for highly efficient green fluorescent organic light-emitting diodes

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Science China Materials 2024年第8期67卷 2618-2627页

作者： Unhyeok Jo Seung Chan Kim Chan Hee Ryu Kang Mun lee Jae-Min Kim jun yeob lee School of Chemical Engineering Sungkyunkwan University2066Seobu-roJangan-guSuwon-siGyeonggi-do 16419Republic of Korea Department of Chemistry Institute for Molecular Science and Fusion TechnologyKangwon National UniversityChuncheonGangwon 24341Republic of Korea Department of Advanced Materials Engineering Chung-Ang University4726Seodong-daeroDaedeok-myeonAnseong-siGyeonggi-do 17546Republic of Korea SKKU Advanced Institute of Nano Technology Sungkyunkwan University2066Seobu-roJangan-guSuwonGyeonggi 16419Republic of Korea SKKU Institute of Energy Science and Technology Sungkyunkwan University2066Seobu-roJangan-guSuwonGyeonggi 16419Republic of Korea

Efficient green fluorescent organic light-emitting diodes were designed with a phosphorescent metal complex as a singlet exciton sensitizing host(SESH)for achieving high efficiency and low efficiency roll-off through exciton and polaron *** Pt(Ⅱ)complex(Pt-Trz)possessing a tetradentate ligand with a bulky blocking group not only suppresses the severe formation of excimer or dimer itself but also transfers radiative excitons to fluorescent dopant *** SESH assisted fluorescence(SESHF)device with Pt-Trz as the host exhibits the maximum external quantum efficiency of 13.3%and a lower efficiency roll-off compared with exciplex host device which is a general approach for harvesting triplet *** exciton dynamics modeling unravels that the SESHF device effectively utilizes triplet excitons in the host by intersystem crossing and resonance energy transfer from the triplet state of the host to the singlet state of the terminal *** quenching rates of the SESHF device are reduced by 11 times for triplet-triplet annihilation and 1.8 times for tripletpolaron annihilation compared with the exciplex device,which demonstrates that Pt-Trz could be a platform to be used as an efficient host for fluorophores.

关键词： singlet annihilation polaron

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A silane-based host material with improved electron transport properties for phosphorescent OLEDs with high efficiency and low efficiency roll-off

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Science China Materials 2023年第5期66卷 1997-2003页

作者： Jinho Park junseop Lim jun yeob lee School of Chemical Engineering Sungkyunkwan University 2066Seobu-roJangan-guSuwon-siGyeonggi-do16419Republic of Korea

A dibenzosilole-based host material was designed and *** host material,9,9'-(5,5-diphenyl-5H-dibenzo[b,d]silole-2,8-diyl)bis(9H-carbazole)(SSiCz),was designed to enhance the electron transport properties and rigidity by coupling two phenyl units of the tetraphenyl silane of a strong hole transport type bis(4-(9Hcarbazol-9-yl)phenyl)diphenylsilane *** device efficiency roll-off was improved considerably by balancing the carriers in the phosphorescent organic light-emitting diodes(PhOLEDs),and the driving voltage at high luminance was *** red and green PhOLEDs exhibited high external quantum efficiencies(EQEs)of 23.8%and 24.9%,respectively,and a relieved efficiency *** addition,S-SiCz was used as an electron transport type host with a hole transport type3,3'-di(9H-carbazol-9-yl)-1,1'-biphenyl *** maximum EQEs of the red and green PhOLEDs using the mixed host were 26.0%and 25.5%,respectively,and EQE roll-off values were 18%and 6%,***,the planarization design strategy of the host is effective for better device performance.

关键词： OLEDs host material silane bipolar phosphorescent OLEDs

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A novel benzo[4,5]furo[3,2-d]pyrimidine-based host as a n-type host for blue phosphorescent organic light-emitting diodes

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Science China Materials 2022年第4期65卷 1028-1033页

作者： junsu Ha junseop Lim jun yeob lee School of Chemical Engineering Sungkyunkwan University2066Seobu-roJangan-guSuwon-siGyeonggi-do16419Republic of Korea

An electron-transport-type host was synthesized using a benzo[4,5]furo[3,2-d]pyrimidine(BFP)core to develop a high triplet energy *** host was designed to have both the tetraphenylsilyl blocking group and the hole-transport-type carbazole *** the device application,the host was used as an electron-transport-type host mixed with a hole-transport-type 3,3'-di(9H-carbazol-9-yl)-1,1†-biphenyl(mCBP)host in the blue phosphorescent organic light-emitting diodes(PhO-LEDs)doped with a[[5-(1,1-dimethylethyl)-3-phenyl-1H-imidazo[4,5-b]pyrazin-1-yl-2(3H)-ylidene]-1,2-phenylene]bis-[[6-(1,1-dimethylethyl)-3-phenyl-1H-imidazo[4,5-b]pyrazin-1-yl-2(3H)-ylidene]-1,2-phenylene]iridium(Ir(cb)3)blue *** a result,the mCBP:CzBFPmSi mixed host showed high external quantum efficiency over 20%at 1000 cd m^(−2) and low efficiency roll-off in the blue PhOLEDs.

关键词： blue device host efficiency lifetime

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Indolo[3,2,1-jk]carbazole-derived planar electron transport materials realizing high efficiency in green phosphorescent organic light-emitting diodes

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Science China Materials 2023年第11期66卷 4437-4444页

作者： Sejeong Um Unhyeok Jo jun yeob lee School of Chemical Engineering Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea SKKU Advanced Institute of Nano Technology Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea SKKU Institute of Energy Science and Technology Sungkyunkwan University 2066Seobu-roJangan-guSuwonGyeonggi16419Republic of Korea

Two novel electron transporting materials(ETMs),2-(4,6-diphenyl-1,3,5-triazin-2-yl)indolo[3,2,1-jk]-carbazole(DPTrz-ICz)and 5,11-bis(4,6-diphenyl-1,3,5-triazin-2-yl)-2-phenylindolo[3,2,1-jk]carbazole(2DPTrz-ICz),were developed based on the indolo[3,2,1-jk]carbazole(ICz)core,combined with 2,4-diphenyl-1,3,5-triazine(DPTrz).The introduced ICz core in ETM exhibited enhanced intermolecular charge transport properties owing to its planar and rigid geometry and high triplet energy,demonstrating the potential of designing ***,2DPTrz-ICz,featuring high triplet energy of 2.84 eV,effectively prevented triplet exciton quenching and showed increased electron mobility owing to the activation of intermolecular hopping charge transfer facilitated by stacking *** two materials were utilized as ETMs in green phosphorescent organic light-emitting diodes.2DPTrz-ICz exhibited a superior external quantum efficiency of 21.5%,higher than that of the spirobifluorene-derived ETM.

关键词： electron transport layer indolocarbazole efficiency OLED

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An Enhanced Jacobi Precoder for Downlink Massive MIMO Systems

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Computers, Materials & Continua 2021年第7期68卷 137-148页

作者： Park Chan-yeob Hyun-Ro Jae jun-Yong Jang Song Hyoung-Kyu Department of Information and Communication Engineering and Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea

Linear precoding methods such as zero-forcing(ZF)are near optimal for downlink massive multi-user multiple input multiple output(MIMO)systems due to their asymptotic channel ***,as the number of users increases,the computational complexity of obtaining the inverse matrix of the gram matrix *** the computational complexity problem,this paper proposes an improved Jacobi(JC)-based precoder to improve error performance of the conventional JC in the downlink massive MIMO *** conventional JC was studied for solving the high computational complexity of the ZF algorithm and was able to achieve parallel ***,the conventional JC has poor error performance when the number of users increases,which means that the diagonal dominance component of the gram matrix is *** this paper,the preconditioning method is proposed to improve the error *** executing the JC,the condition number of the linear equation and spectrum radius of the iteration matrix are reduced by multiplying the preconditioning matrix of the linear *** further reduce the condition number of the linear equation,this paper proposes a polynomial expansion precondition matrix that supplements diagonal *** results show that the proposed method provides better performance than other iterative methods and has similar performance to the ZF.

关键词： Jacobi(JC) massive MIMO precondition polynomial expansion linear precoding

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AMPK-associated signaling to bridge the gap between fuel metabolism and hepatocyte viability

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World Journal of Gastroenterology 2010年第30期16卷 3731-3742页

作者： Yoon Mee Yang Chang yeob Han Yoon jun Kim Sang Geon Kim Inno- vative Drug Research Center for Metabolic and Inflammatory Disease College of PharmacySeoul National UniversitySeoul 151-742South Korea Department of Internal Medicine and Liver Research Institute Seoul National University College of MedicineSeoul 110-744South Korea

The adenosine monophosphate-activated protein kinase (AMPK) and p70 ribosomal S6 kinase-1 pathway may serve as a key signaling flow that regulates energy metabolism; thus, this pathway becomes an attractive target for the treatment of liver diseases that result from metabolic derangements. In addition, AMPK emerges as a kinase that controls the redox-state and mitochondrial function, whose activity may be modulated by antioxidants. A close link exists between fuel metabolism and mitochondrial biogenesis. The relationship between fuel metabolism and cell survival strongly implies the existence of a shared signaling network, by which hepatocytes respond to challenges of external stimuli. The AMPK pathway may belong to this network. A series of drugs and therapeutic candidates enable hepatocytes to protect mitochondria from radical stress and increase cell viability, which may be associated with the activation of AMPK, liver kinase B1, and other molecules or components. Consequently, the components downstream of AMPK may contribute to stabilizing mitochondrial membrane potential for hepatocyte survival. In this review, we discuss the role of the AMPK pathway in hepatic energy metabolism and hepatocyte viability. This information may help identify ways to prevent and/or treat hepatic diseases caused by the metabolic syndrome. Moreover, clinical drugs and experimental therapeutic candidates that directly or indirectly modulate the AMPK pathway in distinct manners are discussed here with particular emphasis on their effects on fuel metabolism and mitochondrial function.

关键词： Adenosine monophosphate-activated protein kinase Cell survival Energy metabolism Fatty liver Insulin resistance Glycogen synthase kinase 3β p70 ribosomal S6 kinase-1

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A Study on Effective System for Harbor Container Delivery &Cargo Work Automatuion

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Wireless Sensor Network 2010年第8期2卷 629-638页

作者： Dong-Hoon Kim jun-yeob Song Seung-Ho lee Il-Yong Kang Suk-Keun Cha 不详

In this article, we have attempted to analyze current situation and the problem of domestic and overseas harbor container delivery & cargo work automation centered on major harbors and to suggest effective way to deal with the issue in order to improve the productivity of container cargo work per crane, the major index of productivity of high value-added shipbuilding industry. In particular, we have suggested the way to realize effective automation system that can improve the efficiency of harbor container delivery & cargo work through the development of high-tech measuring automation technology using microwave radar and applied design that have broken away from traditional automation system and traditional problems such as dependence on manual work and the problem of laser method in which workers cannot identify laser beam under sunlight and workers’ eyesight can be weakened by being exposed to laser beam.

关键词： Harbor Container Delivery Cargo Work Automation

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Efficacy of Pegylated Interferon Monotherapy versus Sequential Therapy of Entecavir and Pegylated Interferon in Hepatitis B e Antigen-Positive Hepatitis B Patients： A Randomized, Multicenter, Phase IIIb Open-Label Study （POTENT Study）

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Chinese Medical Journal 2018年第14期131卷 1645-1651页

作者： Dae Won jun Sang Bong Ahn Tae yeob Kim Joo Hyun Sohn Sang Gyune Kim Se Whan lee Byung Ho Kim Dong Joon Kim Ja Kyung Kim Hyoung Su Kim Seong Gyu Hwang Won Choong Choi Won Young Tak Heon Ju lee Ki Tae Yoon Byung Cheol Yun Sung Wook lee Soon Koo Baik Seung Ha Park Ji Won Park Sol Ji Park Ji Sung lee Department of Internal Medicine Hanyang University Seoul Hospital Hanyang University Seou104763 Korea Department of Internal Medicine Nowon Eulji Hospital Eulji University Seou101830 Korea Department of Internal Medicine Hanyang University Guri Hospital Hanyang University Guri 11923 Korea Department of Internal Medicine SoonChunHyang University Bucheon Hospital SoonChunHyang University Bucheon 14584 Korea Department of Internal Medicine SoonChunHyang University Cheonan Hospital SoonChunHyang University Cheonan 31151 Korea Department of Internal Medicine Kyung Hee University Hospital Kyung Hee University Seoul 02453 Korea Department of Internal Medicine Chuncheon Sacred Heart Hospital Hallym University Chuncheon 24252 Korea Department of Internal Medicine Kangdong Sacred Heart Hospital Hallym University Seou105355 Korea Department of Internal Medicine Gangnam Severance Hospital Yonsei University Seou106273 Korea Department of Internal Medicine CHA Bundang Medical Center CHA University Seongnam 13496 Korea Department of Internal Medicine Sanggye Paik Hospital Inje University Seoul 01757 Korea Department of Internal Medicine Kyungpook National University Hospital Kyungpook National University Daegu 41944 Korea Department of Internal Medicine Yeungnam University Medical Center Yeungnam University Daegu 42415 Korea Department of Internal Medicine Pusan National University Yangsan Hospital Pusan National University Yangsan 50612 Korea Department of Internal Medicine Kosin University Gospel Hospital Kosin University Pusan 49267 Korea Department of Internal Medicine Dong A University Medical Center Dong A University Pusan 49201 Korea Department of Internal Medicine Wonju Severance Christian Hospital Yonsei University Wonju 26426 Korea Department of Internal Medicine Haeundae Paik Hospital Inje University Pusan 48108 Korea Department of Internal Medicine Hallym University Sacred Heart Hospital Hallym University Anyang 14068 Korea Department of Cli

Background： Until now, various types of combined therapy with nucleotide analogs and pegylated interferon （Peg-INF） in patients with hepatitis B patients have been tried. Howe6ver, studies regarding the benefits of de novo combination, late-add on, and sequential treatmentare very limited. The objective of the current study was to identify the efficacy of sequential treatment of Peg-INF after short-term antiviral treatment. Methods： Between june 2010 and june 2015, hepatitis 13 e antigen （HBeAg）-positive patients （n = 162） received Peg-IFN for 48 weeks （mono-treatment group, n = 81） and entecavir （ETV） for 12 weeks with a 48-week course of Peg-IFN starting at week 5 of ETV therapy （sequential treatment group, n = 81）. The primary endpoint was HBeAg seroconversion at the end of follow-up period after the 24-week treatment. The primary endpoint was analyzed using Chi-square test, Fisher＇s exact test, and regression ***： HBeAg seroconversion rate （18.2% vs. 18.2%, t = 0.03, P = 1.000） and seroclearance rate （19.7% vs. 19.7%, t = 0.03, P = 1.000） were same in both mono-treatment and sequential treatment groups. The rate of alanine aminotransferase （ALT） normalization （45.5% vs. 54.5%, t = 1.12, P = 0.296） and serum hepatitis B virus （HBV）-DNA 〈2000 U/L （28.8% vs. 28.8%, t = 0.10, P = 1.000） was not different in sequential and mono-treatment groups at 24 weeks of Peg-INF. Viral response rate （HBeAg seroconversion and serum HBV-DNA 〈2000 U/L） was not different in the two groups （12.1% vs. 16.7%, t = 1.83, P = 0.457）. Baseline HBV-DNA level （7 log10 U/ml vs. 7.5 log10 U/ml, t = 1.70, P = 0.019） and hepatitis B surface antigen titer （3.6 log10 U/ml vs. 4.0 log10 U/ml, t = 2.19, P = 0.020） were lower and predictors of responder in mono-treatment and sequential treatment groups, respectively. Conclusions： The current study shows no differences in HBeAg seroconversion rate, ALT normalization, and HBV-DNA levels between mono-therapy and sequential therapy regimens.

关键词： Entecavir Hepatitis B Peginterferon Alfa-2a

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An Auto-Configuration of 4M Group Management Using Wireless Sensor Networks

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Wireless Sensor Network 2010年第5期2卷 402-410页

作者： Suk-Keun Cha Jeong-Hoon lee Han Gyu Kim Joon Jae Yoo jung Hoon Kang Dong Hoon Kim jun yeob Song 不详

The first tier of automotive manufacturers has faced to pressures about move, modify, updating tasks for manufacturing resources in production processes from demand response of production order sequence for motor company and process innovation purpose for productivity. For meets this requirements, it has to require absolutely lead time to re-wiring of physical interface for production equipment, needs for change existing program and test over again. For prepare this constraints, it needs studying an auto-configuration functions that build for both visibility and flexibility based on the 4M (Man, Machine, Material, Method) group management which is supports from WSN (Wireless Sensor Network) of the open embedded device called M2M (Machine to Machine) and major functions of middleware including point manager for real-time device communication, real-time data management, Standard API (Application Program Interface) and application template management. To be application system to RMS (Reconfigurable Manufacturing System) for rapidly response from various orders and model from motor company that is beginning to establishing the mapping of manufacturing resources of 4M using WSN.

关键词： Auto-Configuration Wireless Sensor Network Reconfigurable Production Resoureces of 4M Tinyos Machien to Machine Middleware Application Template Manager

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