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Rationally designed synthesis of bright AgInS2/ZnS quantum dots with emission control

Nano Research 2020年第9期13卷 2438-2450页

作者： Jose X.Soares K.David Wegner David S.m.Ribeiro Armindo melo Ines Hausler joao l.m.santos Ute Resch-Genger lAQV-REQUImTE Department of Chemical SciencesLaboratory of Applied ChemistryFaculty of PharmacyUniversity of PortoRua de Jorge Viterboferreira228Porto4050-313Portugal Federal Institute for materials Research and Testing(BAm) Division BiophotonicsRichard-Willstaetter-Strasse 1112489 BerlinGermany lAQV-REQUImTE Laboratorio de Bromatologia e HidrologiaDepartamento de Ciencias QutmicasFaculdade de Farmacia da Universidade do PortoRua de Jorge Viterboferreira228Porto4050-313Portugal Technische Universitat Berlin Institutfiir Optik und Atomare PhysikStrafie des 17.Juni 13510623 BerlinGermany

In the blossoming field of Cd-free semiconductor quantum dots(QDs),ternary Ⅰ-Ⅲ-VI QDs have received increasing attention due to the ease of the environmentally friendly synthesis of high-quality materials in water,their high photoluminescence(Pl)quantum yields(QYs)in the red and near infrared(NIR)region,and their inherently low ***,their oxygen-insensitive long Pl lifetimes of up to several hundreds of nanoseconds close a gap for applications exploiting the compound-specific parameter Pl *** overcome the lack of reproducible synthetic methodologies and to enable a design-based control of their Pl properties,we assessed and modelled the synthesis of high-quality mPA-capped AglnS2/ZnS(AlS/ZnS)*** refined parameters included reaction time,temperature,Ag:In ratio,S:In ratio,Zn:In ratio,mPA:ln ratio,and pH using a design-of-experiment *** for the optimization was provided by mathematical models developed for the application-relevant Pl parameters,maximum Pl wavelength,QY,and Pl lifetime as well as the elemental composition in terms of Ag:ln:Zn *** these experimental data-based models,mPA:ln and Ag:ln ratios and pH values were identified as the most important synthesis parameters for Pl control and an insight into the connection of these parameters could be ***,the experimental conditions to synthetize QDs with tunable emission and high QY were *** excellent agreement between the predicted and experimentally found Pl features confirmed the reliability of our methodology for the rational design of high quality AlS/ZnS QDs with defined Pl *** approach can be straightforwardly extended to other ternary and quaternary QDs and to doped QDs.

关键词： quantum dot core/shell nanoparticle silver indium sulfide microw ave-assisted synthesis design of experim ent photoluminescence

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A Theoretically Grounded Question Answering Data Set for Evaluating machine Common Sense

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Data Intelligence 2024年第1期6卷 1-28页

作者： Henrique santos Ke Shen Alice m.mulvehill mayank Kejriwal Deborah l.mcGuinness Rensselaer Polytechnic Institute Troy NY Information Sciences Institute Marina del Rey CA

Achieving machine common sense has been a longstanding problem within Artificial *** far,benchmark data sets that are grounded in a theory of common sense and can be used to conduct rigorous,semantic evaluations of common sense reasoning(CSR)systems have been *** expectation of the AI community is that neuro-symbolic reasoners can help bridge this gap towards more dependable systems with common *** propose a novel benchmark,called Theoretically Grounded common sense Reasoning(TG-CSR),modeled as a set of question answering instances,with each instance grounded in a semantic category of common sense,such as space,time,and *** benchmark is few-shot i.e.,only a few training and validation examples are provided in the public release to avoid the possibility of *** from recent evaluations suggest that TG-CSR is challenging even for state-of-the-art statistical *** to its semantic rigor,this benchmark can be used to evaluate the common sense reasoning capabilities of neuro-symbolic systems.

关键词： reasoning Intelligence instance

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Nickel sulfate solution fluoride separation with hydrous zirconium oxide

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Tungsten 2024年第2期6卷 367-381页

作者： Elbert m.Nigri Ummul K.Sultana André l.A.santos James W.Vaughan Sonia D.F.Rocha Department of mining Engineering Federal University of Minas GeraisBelo Horizonte 31270-901Brazil School of Chemical Engineering University of QueenslandSt Lucia 4072Australia

Fluoride is an impurity in nickel sulfate production,which is required for electric vehicle *** zirconium oxide(HZO)was evaluated for removing fl uoride from nickel sulfate *** fluoride removal occurred at pH value 4 and optimal pH value is 4–5,considering Zr *** availability decreases with pH due to hydrogen fluoride and zirconium fluoride aqueous *** removal is initially rapid,with 50 wt.%removal in 7 min,followed by slow removal up to 68 wt.%after 72 h and follows second order rate *** removal was dominated by an ion exchange mechanism and resulting Zr–F bonds were observed using Fourier-transform infrared *** presence of nickel sulfate decreased loading capacity compared to a salt-free *** maintained adsorption capacity through five cycles of loading and regeneration.

关键词： Hydrous zirconium oxide Nickel sulfate Fluoride Adsorption Anion exchange

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A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

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Bio-Design and manufacturing 2024年第3期7卷 277-291页

作者： I.A.O.Beeren G.Dos santos P.J.Dijkstra C.mota J.Bauer H.Ferreira Rui l.Reis N.Neves S.Camarero-Espinosa m.B.Baker l.moroni Department of Complex Tissue Regeneration MERLN Institute for Technology-Inspired Regenerative MedicineMaastricht University6229 ER MaastrichtThe Netherlands 3B’s Research Group I3Bs–Research Institute on BiomaterialsBiodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineUniversity of MinhoAveParkZona Industrial da Gandra4805-017 BarcoGuimarãesPortugal ICVS/3B’s-PT Government Associate laboratory 4806-909 Braga/GuimarãesPortugal POlYmAT University of the Basque Country UPV/EHU20018 Donostia/San SebastiánSpain IKERBASQUE Basque Foundation for Science48009 BilbaoSpain

melt extrusion-based additive manufacturing(mE-Am)is a promising technique to fabricate porous scaffolds for tissue engi-neering ***,most synthetic semicrystalline polymers do not possess the intrinsic biological activity required to control cell *** of biomolecules on polymeric surfaces of Am scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface ***,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(PCl5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight PCl75k at different *** porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight PCl *** a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).Subsequently,a bone morphogenetic protein 2(BmP-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hmSCs)was *** two weeks of culturing in a basic medium,cells expressed higher levels of BmP receptor II(BmPRII)on films with the conjugated *** addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface *** together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material ***,we have presented a viable strategy for mE-Am community that desires to tune the bulk and surface functionality via blending of(m

关键词： Additive manufacturing Blending Surface functionalization Surface density Click chemistry Human

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modelling dynamic pantograph loads with combined numerical analysis

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Railway Engineering Science 2024年第1期32卷 81-94页

作者： F.F.Jackson R.mishra J.m.Rebelo J.santos P.Antunes J.Pombo H.magalhaes l.Wills m.Askill School of Computing and Engineering University of HuddersfieldHuddersfieldUK School of Computing and Engineering Institute of Railway ResearchUniversity of HuddersfieldHuddersfieldUK IDmEC Instituto Superior TecnicoUniversidade de LisboaLisbonPortugal ISEl Instituto Politecnico de LisboaLisbonPortugal Hitachi Rail Newton AycliffeUK Wabtec/Brecknell Willis ChardUK

Appropriate interaction between pantograph and catenary is imperative for smooth operation of electric *** heights of overhead lines to accommodate level crossings,overbridges,and tunnels pose significant challenges in maintaining consistent current collection performance as the pantograph aerodynamic profile,and thus aerodynamic load changes significantly with operational *** research aims to analyse the global flow characteristics and aerodynamic forces acting on individual components of an HSX pantograph operating in different configurations and orientations,such that the results can be combined with multibody simulations to obtain accurate dynamic insight into contact ***,computational fluid dynamics simulations are used to investigate the pantograph component loads in a representative setting,such as that of the recessed cavity on a Class 800 *** an aerodynamic perspective,this study indicates that the total drag force acting on non-fixed components of the pantograph is larger for the knuckle-leading orientation rather than the knuckle-trailing,although the difference between the two is found to reduce with increasing pantograph *** the aerodynamic loads acting on individual components with multibody tools allows for realistic dynamic insight into the pantograph *** results obtained show how considering aerodynamic forces enhance the realism of the models,leading to behaviour of the pantograph-catenary contact forces closely matching that seen in experimental tests.

关键词： Pantograph-catenary interaction Pantograph aerodynamics Computational fluid dynamics Pantograph loads Current collection performance

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liquid crystal immunosensors for the selective detection of Escherichia coli with a fast analysis tool

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Photonics Research 2024年第7期12卷 1564-1573页

作者： SANDRO C.OlIVEIRA mARIA S.SOARES BÁRBARA V.GONÇAlVES ANDREIA C.m.RODRIGUES AmADEU m.V.m.SOARES RITA G.SOBRAl NUNO F.santos JAN NEDOmA PEDRO l.AlmEIDA CARlOS mARQUES CICECO-Aveiro Institute of materials Physics DepartmentUniversity of Aveiro3810-193 AveiroPortugal i3N Physics DepartmentUniversity of Aveiro3810-193 AveiroPortugal Associate laboratory i4HB-Institute for Health and Bioeconomy School of Sciences and TechnologyNOVA University of Lisbon1099-085 LisbonPortugal CESAm-Centre for Environmental and marine Studies and Department of Biology University of Aveiro3810-193 AveiroPortugal Department of Telecommunications VSB-Technical University of OstravaOstrava 70800Czech Republic i3N-CENImAT School of Sciences and TechnologyNOVA University of Lisbon1099-085 LisbonPortugal UnIRE ISELPolytechnic Institute of Lisbon1549-020 LisbonPortugal Department of Physics VSB-Technical University of OstravaOstrava 70800Czech Republic

The consumption of contaminated food may cause serious illnesses,and traditional methods to detect Escherichia coli are still associated with long waiting times and high costs given the necessity to transport samples to specialized *** is a need to develop new technologies that allow cheap,fast,and direct monitoring at the site of ***,in this work,we developed optical immunosensors for the selective detection of ***,based on liquid crystal technology,whose molecules can align in different manners depending on the boundary conditions (such as substrates) as well as the environment that they *** glass substrate was functionalized with *** antibody using cysteamine as an intermediate,and a vertical alignment was imposed on the liquid crystal molecules by using DmOAP during *** presence of bacteria disrupts the alignment of the liquid crystal molecules,changing the intensity of light emerging between cross polarizers,measured using a polarized optical microscope and a *** was possible to detect *** in suspensions in the concentration range from 2.8 cells/ml to 2.8×10^(9) cells∕*** was also evaluated,and the sensors were used to analyze contaminated water samples.A prototype was developed to allow faster,in-situ,and easier analysis avoiding bulky instruments.

关键词： crystal alignment analysis

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light demand characteristics,production performance,and changes in the feeding patterns of broilers

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International Journal of Agricultural and Biological Engineering 2024年第2期17卷 68-73页

作者： Shouyi Wang Guoping Jiang Chenghao Pan Thebano santos Yasser Elhadidi Ahmed Jado Shufang Jin Jinming Pan College of Biosystems Engineering and Food Science Zhejiang UniversityHangzhou 310058China Infinova(Hangzhou)Information System Technology Co. Ltd.Hangzhou 310012China Center of Information Technology"Renato Archer"(CIT) Ministry of ScienceTechnologyInnovation and CommunicationCEP:13069-901 Campinas(SP)Brazil Department of Agricultural Engineering Mansoura UniversityMansoura 35516Egypt

Poultry is a light-sensitive animal and the light environment has an important influence on the growth and development of these *** studies have mainly focused on the effects of the light environment on various physiological indicators of poultry but seldom explored the light demand characteristics of broilers under free *** experiment mainly studied the light demand characteristics of broilers under a yellow lED light environment and the influence of different breeding densities[low-density(2.5 broilers/m^(2)),high-density(7.5 broilers/m^(2))]on the production performance and diet characteristics of *** showed that the production performance indexes of low-density groups are higher than those of high-density *** feed and water consumption in the light area of the two experimental groups were significantly higher than those in the dark area,which means that the broilers showed a great preference for the light ***,as the age of the broilers increased,the food and water consumption of the broilers decreased,indicating that broilers had a lower preference for light in the middle and late stages of *** statistical results for the residence frequency distribution characteristics showed that broiler chickens had different light requirements at different growth stages under the condition of active selection:1)low-density breeding environment:23.8l(light):0.2D(dark)for chicks and 22.3l:1.7D for adult broilers;2)high-density breeding environment:22.6l:1.4D for chicks and 15.0l:9.0D for adult *** study will provide a reference for the optimization and control of light environment in broiler breeding.

关键词： broiler light-demand characteristics production performance feeding pattern

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Application of novel constrained friction processing method to produce fine grained biomedical mg-Zn-Ca alloy

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Journal of magnesium and Alloys 2024年第2期12卷 516-529页

作者： Ting Chen Banglong Fu Junjun Shen Uceu F.H.R.Suhuddin Björn Wiese Yuanding Huang min Wang Jorge F.dos santos Jean Pierre Bergmann Benjamin Klusemann Solid State materials Processing Institute of Material MechanicsHelmholtz-Zentrum HereonMax-Planck-Str.1Geesthacht 21502Germany Functional magnesium materials Institute of Metallic BiomaterialsHelmholtz-Zentrum HereonMax-Planck-Str.1Geesthacht 21502Germany Shanghai Key laboratory of materials laser Processing and modification Shanghai Jiao Tong UniversityDongchuan Road 800Shanghai 200240China Applied materials and manufacturing Energy and Environment DivisionPacific Northwest National LaboratoryPO Box 999RichlandWA 99352USA Production Technology Group Technisiche Universität IlmenauGustav-Kirchhoff-Platz 2Ilmenau 98693Germany Institute for Production Technology and Systems Leuphana University of LüneburgUniversitätsallee 1Lüneburg 21335Germany

In order to obtain mg alloys with fine microstructures and high mechanical performances,a novel friction-based processing method,name as“constrained friction processing(CFP)”,was *** CFP,defect-free mg-Zn-Ca rods with greatly refined grains and high mechanical properties were *** to the previous as-cast microstructure,the grain size was reduced from more than 1 mm to around 4μm within 3 s by a single process *** compressive yield strength was increased by 350%while the ultimate compressive strength by 53%.According to the established material flow behaviors by“tracer material”,the plastic material was transported by shear *** the base material to the rod,the material experienced three stages,*** by the tool,upward flow with additional tilt,followed by upward *** microstructural evolution was revealed by“stop-action”*** microstructural development at regions adjacent to the rod is mainly controlled by twinning,dynamic recrystallization(DRX)as well as particle stimulated nucleation,while that within the rod is related to DRX combined with grain growth.

关键词： Constrained friction processing magnesium alloys microstructure mechanical properties Grain refinement Plastic deformation

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巴西油气勘探开发历程:从陆上到超深水

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石油勘探与开发 2024年第4期51卷 796-806页

作者： ANJOS Sylvia m C SOmBRA Cristiano l SPADINI Adali R 巴西国家石油公司里约热内卢20231-030巴西

21世纪以来,随着桑托斯盆地深水盐下获得一系列重大油气发现,巴西东部海域成为全球深水油气勘探与生产的热点区域。通过全面回顾巴西油气勘探开发历程,系统阐述了从陆上到海域、从浅水到深水—超深水直至盐下勘探的探索实践、战略转变... 详细信息

21世纪以来,随着桑托斯盆地深水盐下获得一系列重大油气发现,巴西东部海域成为全球深水油气勘探与生产的热点区域。通过全面回顾巴西油气勘探开发历程,系统阐述了从陆上到海域、从浅水到深水—超深水直至盐下勘探的探索实践、战略转变、重大突破和关键理论技术。巴西国家石油公司(简称巴西国油)自1953年成立以后的15年间,在陆上古生界克拉通盆地和断陷盆地进行了勘探,并于断块和三角洲砂体圈闭获得了一些中小型油气发现。20世纪70年代,应用重力流沉积模式和高质量三维地震等勘探新技术,在坎波斯盆地浅水中发现Namorado和Enchova等油田,随后深水盐上勘探获得突破,成功发现marlim、Roncador等大型油田。21世纪初,通过盐下含油气系统、碳酸盐岩成储成藏模式和核磁共振测井等理论技术攻关,推动桑托斯盆地下白垩统湖相碳酸盐岩陆续获得Tupi(lula)、Buzios、mero等世界级超深水盐下大油田的系列重大发现。在复杂的深水作业环境下,油气开发工程面临巨大挑战,巴西国油通过启动深水研发计划(PROCAP),开发并实施窄压力窗口控压钻井、加压钻井液帽钻井、多段智能完井、水下采油及浮式生产平台开发和流动保障等关键技术,显著提升了钻完井、油气田开发和输运的效率及安全性。此外,在浮式采储卸油系统建产规模受限的情况下,推进全球最大规模的CO_(2)捕集、驱油利用与埋存工程(CCUS-EOR),有效减少温室气体排放并提高了原油采收率。上述理论技术的发展和应用,也为全球深水油气勘探开发提供了宝贵经验。未来巴西油气勘探将继续聚焦深水盐下碳酸盐岩和盐上浊积岩,并在古生界天然气等勘探领域持续寻求新的发现,同时通过技术创新和战略合作,促进巴西石油天然气行业的可持续发展。

关键词：巴西深水盐下勘探坎波斯盆地桑托斯盆地浊积岩湖相碳酸盐岩深水开发流动保障

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Dietary(poly)phenol intake is associated with cardiometabolic health parameters in adolescents

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Food Science and Human Wellness 2024年

作者： Emily P.laveriano-santos Sara Castro-Barquero Camila Arancibia-Riveros Ana maría Ruiz-león Rosa Casas Ramón Estruch Patricia Bodega mercedes de miguel Amaya de Cos-Gandoy Jesús martínez-Gómez Gloria santos-Beneit Juan m.Fernández-Alvira Rodrigo Fernández-Jiménez Rosa m.lamuela-Raventós Anna Tresserra-Rimbau The Zena and michael A.Wiener Cardiovascular Institute， Icahn School of medicine at mount Sinai Department de Nutrició， Ciències de l'Alimentació I Gastronomia， XIA， Facultat de Farmàcia i Ciències de l'alimentació， Institut de Recerca en Nutrició i Seguretat Alimentària (INSA-UB)， Universitat de Barcelona Department of Internal medicine， Hospital Clínic， Institutd'Investigacions Biomèdiques August Pi I Sunyer (IDIBAPS)， University of Barcelona Consorcio CIBER， m.P.Fisiopatología de la Obesidad y Nutrición (CIBERObn)， Instituto de Salud Carlos III (ISCIII) mediterranean Diet Foundation 5. Foundation for Science， Health and Education (SHE) 6. Centro Nacional de Investigaciones Cardiovasculares (CNIC) CIBER de Enfermedades Cardiovasculares (CIBERCV) 9. Hospital Universitario Clínico San Carlos

Background: The protective role of (poly)phenols against metabolic disorders has been extensively studied in adults but not in ***: To assess associations of dietary (poly)phenols and their subclasses with cardiometabolic health parameters in adolescents. methods: A cross-sectional study was conducted in 944 individuals aged 11 to 14 years enrolled in the SI! Program for Secondary Schools trial (NCT03504059). (Poly)phenol intake was assessed using semi-quantitative food frequency questionnaires and the Phenol-Explorer database. The measured cardiometabolic parameters were waist circumference (WC) age-sex z-score， blood pressure (BP) age-sex z-score， blood glucose (BG)， triglycerides (TG)， and high-density lipoprotein cholesterol (HDl-c). multilevel mixed-effect linear regression models were applied to examine the association between (poly)phenol quintiles and cardiometabolic health ***: Compared to the lowest quintile， adolescents in the highest quintile of total (poly)phenol intake had lower WC z-scores (β=-0.09， 95%CI=-0.09;-0.08， P-for trend=0.002)， mean arterial pressure z-scores (β =-0.11， 95%CI=-0.12;-0.09， P-for trend=0.206)， and HDl-c (β=-1.52， 95%CI=-2.90;-0.14， P-for trend=0.108)， after multivariable adjustment. The WC z-scores (β=-0.11， 95%CI=-0.19;-0.03， P-for trend=0.013) and HDl-c (β=-2.16， 95%CI=-3.78;-0.53， P-for trend=0.046) were lower in the highest quintile of flavonoid intake compared to the lowest quintile. The highest quintile of phenolic acid intake was associated with a lower WC z-score (β=-0.14， 95%CI=-0.26;-0.02， P-for trend=0.011) and TG levels (β=-8.83， 95%CI=-12.37;-5.30， P-for trend le of stilbene intake with lower BG (β=-1.83， 95%CI= -3.103;-0.64， P-for trend l-c (β=2.328， 95%CI= 1.40;3.17， P-for trend=0.466) compared to the lowest quintile. Conclusion: A higher intake of (poly)phenols， espe

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